DE69500730T2 - Kationische fluorierte Copolymere für die öl- und wasserabweisende Behandlung von Baumaterialien - Google Patents

Kationische fluorierte Copolymere für die öl- und wasserabweisende Behandlung von Baumaterialien

Info

Publication number
DE69500730T2
DE69500730T2 DE69500730T DE69500730T DE69500730T2 DE 69500730 T2 DE69500730 T2 DE 69500730T2 DE 69500730 T DE69500730 T DE 69500730T DE 69500730 T DE69500730 T DE 69500730T DE 69500730 T2 DE69500730 T2 DE 69500730T2
Authority
DE
Germany
Prior art keywords
opt
alkyl
oil
fluorinated copolymers
water repellent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69500730T
Other languages
English (en)
Other versions
DE69500730D1 (de
Inventor
Jean-Marc Corpart
Christian Bonardi
Marie-Jose Lina
Andre Dessaint
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
Original Assignee
Elf Atochem SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Elf Atochem SA filed Critical Elf Atochem SA
Application granted granted Critical
Publication of DE69500730D1 publication Critical patent/DE69500730D1/de
Publication of DE69500730T2 publication Critical patent/DE69500730T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/48Macromolecular compounds
    • C04B41/4838Halogenated polymers
    • C04B41/4842Fluorine-containing polymers
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/22Esters containing halogen
    • C08F220/24Esters containing halogen containing perhaloalkyl radicals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/62Polymers of compounds having carbon-to-carbon double bonds
    • C08G18/6275Polymers of halogen containing compounds having carbon-to-carbon double bonds; halogenated polymers of compounds having carbon-to-carbon double bonds
    • C08G18/6279Polymers of halogen containing compounds having carbon-to-carbon double bonds; halogenated polymers of compounds having carbon-to-carbon double bonds containing fluorine atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/703Isocyanates or isothiocyanates transformed in a latent form by physical means
    • C08G18/705Dispersions of isocyanates or isothiocyanates in a liquid medium
    • C08G18/706Dispersions of isocyanates or isothiocyanates in a liquid medium the liquid medium being water
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • C09K3/18Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C26/00Coating not provided for in groups C23C2/00 - C23C24/00
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/395Isocyanates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/277Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D06M15/576Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them containing fluorine
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/10Processes in which the treating agent is dissolved or dispersed in organic solvents; Processes for the recovery of organic solvents thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/203Oil-proof or grease-repellant materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/27Water resistance, i.e. waterproof or water-repellent materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Textile Engineering (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Structural Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Metallurgy (AREA)
  • Mechanical Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
  • Paints Or Removers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
DE69500730T 1994-11-29 1995-10-25 Kationische fluorierte Copolymere für die öl- und wasserabweisende Behandlung von Baumaterialien Expired - Fee Related DE69500730T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9414281A FR2727417B1 (fr) 1994-11-29 1994-11-29 Copolymeres fluores cationiques pour le traitement oleophobe et hydrophobe des materiaux de construction

Publications (2)

Publication Number Publication Date
DE69500730D1 DE69500730D1 (de) 1997-10-23
DE69500730T2 true DE69500730T2 (de) 1998-03-26

Family

ID=9469249

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69500730T Expired - Fee Related DE69500730T2 (de) 1994-11-29 1995-10-25 Kationische fluorierte Copolymere für die öl- und wasserabweisende Behandlung von Baumaterialien

Country Status (10)

Country Link
US (1) US5798415A (de)
EP (1) EP0714921B1 (de)
JP (1) JPH08225620A (de)
KR (1) KR960017705A (de)
CN (1) CN1131679A (de)
AT (1) ATE158313T1 (de)
CA (1) CA2163712A1 (de)
DE (1) DE69500730T2 (de)
ES (1) ES2109065T3 (de)
FR (1) FR2727417B1 (de)

Families Citing this family (64)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5773091A (en) * 1996-07-11 1998-06-30 Brandeis University Anti-graffiti coatings and method of graffiti removal
AU750886B2 (en) 1998-07-24 2002-08-01 Ciba Specialty Chemicals Holding Inc. Compositions and methods to protect calcitic and/or siliceous surfaces
US6383569B2 (en) 1998-07-24 2002-05-07 Ciba Specialty Chemicals Corporation Compositions and methods to protect calcitic and/or siliceous materials
CA2337946A1 (en) * 1998-09-10 2000-03-23 Ciba Specialty Chemicals Holding Inc. Aqueous fluorinated polymer dispersions capable to protect asphaltic materials
FR2805288A1 (fr) * 2000-02-23 2001-08-24 Atofina Composition pour le traitement anti-taches et anti- salissures des moquettes et procede de traitement correspondant
FR2812643B1 (fr) * 2000-08-07 2002-09-13 Atofina Nouveaux copolymeres fluores, leur utilisation pour le revetement et l'impregnation de substrats, et les substrats ainsi traites
US20030124330A1 (en) * 2001-12-27 2003-07-03 Hector Belmares Stain resistant acoustical panels
DE102004002499A1 (de) * 2004-01-17 2005-08-11 Degussa Ag Verfahren zur Verhinderung von Anfeuerungseffekten bei Imprägnierungen von Substraten
KR20070094981A (ko) * 2004-01-30 2007-09-27 그레이트 레이크스 케미칼 코퍼레이션 조성물, 할로겐화 조성물, 화학적 제조 및 텔로머화 방법
EP1718722A4 (de) 2004-01-30 2012-08-08 Du Pont Produktionsverfahren und -systeme, zusammensetzungen, tenside, monomereinheiten, metallkomplexe, phosphatester, glykole, wässrige filmbildende schäume sowie schaumstabilisatoren
JP2007528917A (ja) * 2004-01-30 2007-10-18 グレート・レークス・ケミカル・コーポレーション 製造方法並びにシステム、組成物、界面活性剤、モノマー単位、金属錯体、燐酸エステル、グリコール、水性皮膜形成フォーム、及びフォーム安定剤
US7713629B2 (en) * 2004-03-26 2010-05-11 Florida State University Research Foundation Hydrophobic fluorinated polyelectrolyte complex films and associated methods
US20060047032A1 (en) * 2004-09-01 2006-03-02 Miller Chandra T Anionic/cationic masonry sealing systems
ATE505447T1 (de) 2004-09-02 2011-04-15 3M Innovative Properties Co Verfahren zur behandlung von porösem stein, bei dem eine fluorchemische zusammensetzung verwendet wird
US7344758B2 (en) * 2004-09-07 2008-03-18 E.I. Du Pont De Nemours And Company Hydrocarbon extenders for surface effect compositions
US20070027349A1 (en) * 2005-07-28 2007-02-01 Stephan Brandstadter Halogenated Compositions
AU2006275700A1 (en) * 2005-07-28 2007-02-08 Great Lakes Chemical Corporation Production processes and systems, compositions, surfactants, monomer units, metal complexes, phosphate esters, glycols, aqueous film forming foams, and foam stabilizers
JP2008081671A (ja) * 2006-09-28 2008-04-10 Soken Chem & Eng Co Ltd 熱硬化性樹脂組成物
US8318656B2 (en) 2007-07-03 2012-11-27 E. I. Du Pont De Nemours And Company Production processes and systems, compositions, surfactants, monomer units, metal complexes, phosphate esters, glycols, aqueous film forming foams, and foam stabilizers
CN101815755B (zh) * 2007-10-01 2012-09-05 3M创新有限公司 包含阳离子氟化醚硅烷的组合物以及相关方法
US8080170B2 (en) * 2007-10-01 2011-12-20 3M Innovative Properties Company Cationic fluorinated ether silane compositions and related methods
DE102007048734B4 (de) * 2007-10-05 2009-11-12 Kupfer, Michael Verfahren zur Bewertung des Zustands von mit Anti-Graffiti-Systemen behandelten Baustoffen
WO2009073537A2 (en) 2007-12-03 2009-06-11 3M Innovative Properties Company Cationic polymeric fluorinated ether silane compositions and methods of use
CN101925620B (zh) 2007-12-03 2012-10-17 3M创新有限公司 阳离子聚合物型氟化醚硅烷组合物及使用方法
US8586184B2 (en) * 2007-12-13 2013-11-19 Daikin Industries, Ltd. Fluorine-containing polymer and aqueous treatment agent
US8286561B2 (en) 2008-06-27 2012-10-16 Ssw Holding Company, Inc. Spill containing refrigerator shelf assembly
US11786036B2 (en) 2008-06-27 2023-10-17 Ssw Advanced Technologies, Llc Spill containing refrigerator shelf assembly
AU2009302806B9 (en) 2008-10-07 2015-10-01 Ross Technology Corporation Highly durable superhydrophobic, oleophobic and anti-icing coatings and methods and compositions for their preparation
GB2466270A (en) 2008-12-19 2010-06-23 3M Innovative Properties Co Composition for providing stain release or stain repellency to stone substrates
GB2466281A (en) 2008-12-19 2010-06-23 3M Innovative Properties Co Composition comprising a fluorinated compound and a phosphate ester for treating surfaces
RU2520454C2 (ru) * 2009-01-09 2014-06-27 Айдиапэйнт Инк. Отверждающиеся в условиях окружающей среды покрытия на водной основе для поверхностей, допускающих запись и стирание
EP2496886B1 (de) 2009-11-04 2016-12-21 SSW Holding Company, Inc. Oberflächen eines kochgeräts mit überlaufbegrenzungsstruktur und herstellungsverfahren dafür
CA2690768A1 (en) 2010-01-21 2011-07-21 Trican Well Services Ltd. Compositions and methods for enhancing fluid recovery for hydraulic fracturing treatments
BR112012023312A2 (pt) 2010-03-15 2019-09-24 Ross Tech Corporation desentupidor e métodos de produção de superfícies hidrofóbicas
JP2014512417A (ja) 2011-02-21 2014-05-22 ロス テクノロジー コーポレーション. 低voc結合剤系を含む超疎水性および疎油性被覆物
DE102011085428A1 (de) 2011-10-28 2013-05-02 Schott Ag Einlegeboden
WO2013090939A1 (en) 2011-12-15 2013-06-20 Ross Technology Corporation Composition and coating for superhydrophobic performance
EP2607397A1 (de) * 2011-12-21 2013-06-26 Clariant International Ltd. Fluorchemische Zusammensetzung und Verwendung damit
WO2014003852A2 (en) 2012-06-25 2014-01-03 Ross Technology Corporation Elastomeric coatings having hydrophobic and/or oleophobic properties
FR3003572B1 (fr) * 2013-03-25 2015-03-27 Seppic Sa Nouveaux polymeres amphiphiles et leur utilisation dans le traitement de surfaces de materiaux hydrophobes
CN103483513B (zh) * 2013-09-09 2015-09-23 陕西科技大学 一种含氟高分子表面活性剂的制备方法
US10876025B2 (en) 2014-03-14 2020-12-29 Hrl Laboratories, Llc Bugphobic and icephobic compositions with liquid additives
US11034846B2 (en) 2014-03-14 2021-06-15 Hrl Laboratories, Llc Polymer-liquid composites for improved anti-fouling performance
US11072713B2 (en) 2014-03-14 2021-07-27 Hrl Laboratories, Llc Bugphobic and icephobic compositions with fluid additives
US10836974B2 (en) 2014-03-14 2020-11-17 Hrl Laboratories, Llc Low-adhesion coatings with solid-state lubricants
US10619057B2 (en) 2015-08-19 2020-04-14 Hrl Laboratories, Llc Compositions and methods for fabricating durable, low-ice-adhesion coatings
US11247228B2 (en) 2014-08-19 2022-02-15 Hrl Laboratories, Llc Methods for fabricating transparent icephobic coatings, and transparent icephobic coatings obtained therefrom
US10865267B2 (en) 2014-08-19 2020-12-15 Hrl Laboratories, Llc Compositions for fabricating durable, low-ice-adhesion coatings
US9376585B2 (en) 2014-08-26 2016-06-28 Covestro Llc Coating compositions capable of producing surfaces with dry-erase properties
US9387721B2 (en) 2014-08-26 2016-07-12 Covestro Llc Coating compositions capable of producing surfaces with dry-erase properties
US10246632B2 (en) 2015-10-30 2019-04-02 Carbo Ceramics Inc. Proppant having amphiphobic coatings and methods for making and using same
EP3458261A4 (de) 2016-05-20 2019-12-25 Ideapaint, Inc. Trockenlöschbare zusammensetzungen und verfahren zur herstellung und verwendung davon
CN106046245B (zh) * 2016-06-21 2019-03-08 衢州氟硅技术研究院 一种含氟共聚物及其阳离子化产物
CN106008793B (zh) * 2016-06-21 2019-03-08 衢州氟硅技术研究院 一种纸张防水防油用含氟共聚物及其分散液制备方法
US10442935B2 (en) 2016-08-06 2019-10-15 Hrl Laboratories, Llc Coatings combining oil-absorbing and oil-repelling components for increased smudge resistance
US10704262B2 (en) 2016-09-26 2020-07-07 U.S. Silica Company Self-cleaning cool roof system
WO2018071349A1 (en) * 2016-10-14 2018-04-19 Hrl Laboratories, Llc Bugphobic and icephobic compositions with liquid additives
US11859098B2 (en) 2017-08-10 2024-01-02 Hrl Laboratories, Llc Formulas and methods for making shelf-stable antimicrobial biphasic polymers
US11369109B2 (en) 2020-06-11 2022-06-28 Hrl Laboratories, Llc Fast-acting antimicrobial surfaces, and methods of making and using the same
CN111655791B (zh) * 2018-01-31 2022-11-04 Hrl实验室有限责任公司 具有流体添加剂的疏虫性和疏冰性组合物
CN111040072B (zh) * 2019-11-27 2022-07-19 广州熵能创新材料股份有限公司 乙烯基系含氟共聚物、含有该乙烯基系含氟共聚物的防水防油组合物及其应用
CN111348922B (zh) * 2020-02-19 2023-04-07 佛山市山有海科技有限公司 一种基于硅酸盐体系的强化浆料流动性的解胶剂
CN111454629A (zh) * 2020-04-29 2020-07-28 湖北中科博策新材料科技有限公司 一种超疏水水漆及其生产工艺
US11891538B1 (en) 2021-08-25 2024-02-06 Hrl Laboratories, Llc Gradient-responsive corrosion-resistant coatings

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2138763A (en) 1938-03-30 1938-11-29 Du Pont Amino alcohol esters of the alpha substituted acrylic acids
DE2526287C2 (de) 1975-06-12 1982-09-30 Wacker-Chemie GmbH, 8000 München Verfahren zum Öl- und Wasserabweisendmachen von offene Porosität aufweisenden Oberflächen normalerweise fester anorganischer Stoffe
US4127711A (en) * 1977-03-31 1978-11-28 E. I. Du Pont De Nemours And Company Fluorine-containing terpolymers
FR2442880A1 (fr) 1978-11-17 1980-06-27 Savoldelli Claude Composition antiadhesive a base de cire
FR2445361A1 (fr) 1978-12-28 1980-07-25 Sejournant Francine Composition antiadhesive a base de cire en milieu solvant organique
US4241141A (en) 1979-03-19 1980-12-23 S. C. Johnson & Son, Inc. Removable coatings which prevent penetration from felt tip marking inks
FR2469437A1 (fr) 1979-11-09 1981-05-22 Bois Raymond Produit de revetement sous forme d'une peinture rendant anti-adhesives les surfaces revetues et application de ce produit
DE3001127A1 (de) 1980-01-14 1981-07-16 Toray Silicone Co., Ltd., Tokyo Bei raumtemperatur haertbare siliconharzmasse
US4353745A (en) 1981-08-26 1982-10-12 Chemed Corporation Cleaner for anti-graffiti system
FR2540131B1 (fr) 1983-01-28 1986-04-04 Atochem Compositions et procede pour le traitement oleophobe et hydrophobe des materiaux de construction
BE901692A (fr) 1985-02-08 1985-05-29 G Levasseur Sa Sa Revetement pour materiaux de construction et procede de fabrication des constituants de ce revetement.
DE3521618A1 (de) 1985-06-15 1986-12-18 Bayer Ag, 5090 Leverkusen In wasser dispergierbare polyisocyanat-zubereitung und ihre verwendung als zusatzmittel fuer waessrige klebstoffe
FR2601027B1 (fr) 1986-02-11 1988-09-09 Gosselin Claude Revetement de protection presentant une face externe anti-adherente, et son procede de fabrication
US4663337A (en) 1986-04-18 1987-05-05 E. R. Squibb & Sons, Inc. 7-oxabicycloheptane substituted amides useful in the treatment of thrombotic disease
FR2607821B1 (fr) 1986-12-03 1989-08-18 Laforge Denys Composition et procede pour la protection des surfaces contre les graffitis
US4716056A (en) 1986-12-24 1987-12-29 Frank Fox System for treating a surface
SE8704588D0 (sv) 1987-06-17 1987-11-20 Bioboat Ab Contamination removal process
WO1990006958A1 (en) 1988-12-14 1990-06-28 Bramite Limited Silicone modified polyurethanes
FR2683535B1 (fr) * 1991-11-12 1994-10-28 Atochem Nouveaux copolymeres fluores et leur utilisation pour le revetement et l'impregnation de substrats divers.
DE4201604A1 (de) * 1992-01-22 1993-07-29 Bayer Ag Fluorhaltige copolymerisate und daraus hergestellte waessrige dispersionen
JPH06240238A (ja) * 1993-02-17 1994-08-30 Asahi Glass Co Ltd 溶剤型撥水撥油剤組成物

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EP0714921A1 (de) 1996-06-05
CA2163712A1 (fr) 1996-05-30
ES2109065T3 (es) 1998-01-01
FR2727417A1 (fr) 1996-05-31
FR2727417B1 (fr) 1997-01-03
CN1131679A (zh) 1996-09-25
EP0714921B1 (de) 1997-09-17
KR960017705A (ko) 1996-06-17
DE69500730D1 (de) 1997-10-23
JPH08225620A (ja) 1996-09-03
US5798415A (en) 1998-08-25
ATE158313T1 (de) 1997-10-15

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