DE69411545D1 - Imidazolidinondiamin und seine derivate als kettenverlängernde monomere - Google Patents
Imidazolidinondiamin und seine derivate als kettenverlängernde monomereInfo
- Publication number
- DE69411545D1 DE69411545D1 DE69411545T DE69411545T DE69411545D1 DE 69411545 D1 DE69411545 D1 DE 69411545D1 DE 69411545 T DE69411545 T DE 69411545T DE 69411545 T DE69411545 T DE 69411545T DE 69411545 D1 DE69411545 D1 DE 69411545D1
- Authority
- DE
- Germany
- Prior art keywords
- derivatives
- chain extension
- extension monomers
- imidazolidinone
- diamine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/02—Polycondensates containing more than one epoxy group per molecule
- C08G59/10—Polycondensates containing more than one epoxy group per molecule of polyamines with epihalohydrins or precursors thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/04—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
- C07D233/28—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D233/30—Oxygen or sulfur atoms
- C07D233/32—One oxygen atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/04—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
- C07D233/28—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D233/30—Oxygen or sulfur atoms
- C07D233/32—One oxygen atom
- C07D233/36—One oxygen atom with hydrocarbon radicals, substituted by nitrogen atoms, attached to ring nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/10—Esters
- C08F20/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
- C08F20/36—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate containing oxygen in addition to the carboxy oxygen, e.g. 2-N-morpholinoethyl (meth)acrylate or 2-isocyanatoethyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
- C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
- C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
- C08G18/3819—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
- C08G18/3842—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring
- C08G18/3848—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring containing two nitrogen atoms in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6633—Compounds of group C08G18/42
- C08G18/6637—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/664—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
- C08G18/6644—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203 having at least three hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/671—Unsaturated compounds having only one group containing active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/675—Low-molecular-weight compounds
- C08G18/6755—Unsaturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/703—Isocyanates or isothiocyanates transformed in a latent form by physical means
- C08G18/705—Dispersions of isocyanates or isothiocyanates in a liquid medium
- C08G18/706—Dispersions of isocyanates or isothiocyanates in a liquid medium the liquid medium being water
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/81—Unsaturated isocyanates or isothiocyanates
- C08G18/8108—Unsaturated isocyanates or isothiocyanates having only one isocyanate or isothiocyanate group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/81—Unsaturated isocyanates or isothiocyanates
- C08G18/8125—Unsaturated isocyanates or isothiocyanates having two or more isocyanate or isothiocyanate groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Dispersion Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Polyamides (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyesters Or Polycarbonates (AREA)
- Epoxy Resins (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/025,091 US5399706A (en) | 1993-03-02 | 1993-03-02 | Imidazolidinone diamine and derivatives thereof |
PCT/US1994/002265 WO1994020474A1 (en) | 1993-03-02 | 1994-03-02 | Imidazolidinone diamine and derivatives thereof as chain extending monomers |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69411545D1 true DE69411545D1 (de) | 1998-08-13 |
DE69411545T2 DE69411545T2 (de) | 1999-01-28 |
Family
ID=21824003
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69411545T Expired - Fee Related DE69411545T2 (de) | 1993-03-02 | 1994-03-02 | Imidazolidinondiamin und seine derivate als kettenverlängernde monomere |
Country Status (6)
Country | Link |
---|---|
US (1) | US5399706A (de) |
EP (1) | EP0683769B1 (de) |
JP (1) | JP2875890B2 (de) |
CA (1) | CA2157606A1 (de) |
DE (1) | DE69411545T2 (de) |
WO (1) | WO1994020474A1 (de) |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5496907A (en) * | 1993-03-02 | 1996-03-05 | H. B. Fuller Licensing & Financing, Inc. | Wet adhesion monomers with ureido functionality and polymers prepared therefrom |
US6013200A (en) * | 1997-05-13 | 2000-01-11 | Baker Hughes Incorporated | Low toxicity corrosion inhibitor |
US6288151B1 (en) * | 1999-10-14 | 2001-09-11 | Air Products And Chemicals, Inc. | Alkylated aminoalkyl cyclic urea surfactants |
AU2003219871A1 (en) * | 2002-03-28 | 2003-10-13 | Rhodia, Inc. | Application of imidazolidone-modified latexes to carbonyl-containing plastic substrates |
JP4440888B2 (ja) | 2003-11-04 | 2010-03-24 | スプラポリックス・ビー.ブイ. | 重合体幹内に4重水素結合単位を含む超分子重合体の製造 |
WO2006006855A1 (en) * | 2004-07-12 | 2006-01-19 | Suprapolix B.V. | Supramolecular ionomers |
WO2006118461A2 (en) | 2005-05-04 | 2006-11-09 | Suprapolix B. V. | Modular bioresorbable or biomedical, biologically active supramolecular materials |
ATE527305T1 (de) | 2006-11-20 | 2011-10-15 | Suprapolix Bv | Supramolekulare polymere aus niedrigschmelzenden, leicht verarbeitbaren bausteinen |
US8628789B2 (en) | 2007-03-23 | 2014-01-14 | Suprapolix, B.V. | Strong reversible hydrogels |
US8754213B2 (en) | 2008-07-04 | 2014-06-17 | Suprapolix B.V. | High flow supramolecular compounds |
US9006386B2 (en) | 2010-11-05 | 2015-04-14 | Suprapolix B.V. | Process for the preparation of a supramolecular polymer |
FR2988725B1 (fr) * | 2012-04-02 | 2015-04-03 | Arkema France | Monomeres porteurs de groupements associatifs pour la synthese de polycondensats supramoleculaires |
WO2016028511A1 (en) | 2014-08-22 | 2016-02-25 | Arkema Inc. | Voided latex particles |
CN110271235B (zh) | 2014-08-22 | 2021-04-20 | 阿科玛股份有限公司 | 空隙胶乳颗粒 |
CN107848248B (zh) | 2015-08-04 | 2021-04-27 | 阿科玛股份有限公司 | 含官能化外壳的空化胶乳粒子 |
WO2017137531A1 (en) * | 2016-02-12 | 2017-08-17 | Akzo Nobel Chemicals International B.V. | Process to prepare higher ethylene amines and ethylene amine derivatives |
FR3055333B1 (fr) * | 2016-08-25 | 2020-03-27 | Arkema France | Adduit epoxy porteur de groupes associatifs, son procede de preparation et ses utilisations |
CN109705339A (zh) * | 2017-10-26 | 2019-05-03 | 南京曦浪新材料科技有限公司 | 一种水性多功能树脂及其制备方法 |
MX2023007037A (es) | 2020-12-16 | 2023-06-28 | Nouryon Chemicals Int Bv | Elaboracion de compuestos de nitrilo. |
Family Cites Families (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA622832A (en) * | 1961-06-27 | Horst Karl | Reacting aldehydes, urea derivatives and long-chain aliphatic compounds | |
US2531013A (en) * | 1949-01-22 | 1950-11-21 | Sterling Drug Inc | 9-[3-(2-hydroxyethylamino)-propylamino]-2-methoxyacridine and method for its production |
GB689705A (en) * | 1950-09-15 | 1953-04-01 | Saint Gobain | Glycol carbamates and processes for the manufacture thereof |
US2613212A (en) * | 1950-10-26 | 1952-10-07 | Rohm & Haas | Imidazolidone derivatives |
US2858319A (en) * | 1954-12-22 | 1958-10-28 | Rohm & Haas | Derivatives of imidazolidinone and pyrimidinone |
GB834411A (en) * | 1955-03-21 | 1960-05-11 | Rohm & Haas | Quaternary ammonium compounds |
US2840561A (en) * | 1955-09-09 | 1958-06-24 | Rohm & Haas | Nu-(aminoalkyl)-nu, nu'-alkyleneureas and methods of producing them |
US2767184A (en) * | 1955-11-10 | 1956-10-16 | Monsanto Canada Ltd | 1, 3-diazacycloalkane compounds |
US2840546A (en) * | 1956-01-06 | 1958-06-24 | Rohm & Haas | Unsaturated quaternary ammonium compounds and polymers |
US2980652A (en) * | 1958-09-19 | 1961-04-18 | Rohm & Haas | Unsaturated derivatives of n-(omega-aminoalkyl)-1, 3-cyclodiazolidin-2-ones and copolymers thereof |
US3169991A (en) * | 1960-12-21 | 1965-02-16 | Gen Mills Inc | (gamma-aminopropyl) aminohydroxyalkyl amines |
US3222402A (en) * | 1962-03-20 | 1965-12-07 | Armour & Co | Preparation of n-aliphatic trimethylene diamines |
US3194825A (en) * | 1962-04-19 | 1965-07-13 | Union Carbide Corp | (isothiocyanatoalkyl) amines |
CH470396A (de) * | 1963-08-12 | 1969-03-31 | Hoffmann La Roche | Verfahren zur Herstellung von 4-Imidazolidon-Verbindungen |
US3398196A (en) * | 1964-12-31 | 1968-08-20 | Armour Ind Chem Co | Nu-secondary-alkyl trimethylene diamines |
BE789830A (fr) * | 1971-10-09 | 1973-02-01 | Asta Werke Ag Chem Fab | Procede de preparation de nouveaux derives cycliques d'uree et de leurssels avec des acides pharmacologiquement acceptables |
GB1574214A (en) * | 1976-03-11 | 1980-09-03 | Smith Kline French Lab | Amidines |
US4314067A (en) * | 1976-07-29 | 1982-02-02 | Air Products And Chemicals, Inc. | Monomeric compounds having vinyl and imidazolidin-2-one terminal groups |
US4104220A (en) * | 1976-07-29 | 1978-08-01 | Air Products & Chemicals, Inc. | Alkenyl 1-(2-Aminoethyl) alkyleneureido succinamates, their synthesis, and use in aqueous emulsion polymer systems |
JPS5948056B2 (ja) * | 1977-07-04 | 1984-11-24 | 三菱油化株式会社 | エポキシ樹脂硬化剤 |
US4319032A (en) * | 1980-06-06 | 1982-03-09 | Alcolac Inc. | Derivatives of aminoalkyl alkylene ureas |
CA1269378A (en) * | 1981-10-23 | 1990-05-22 | George Emile Abboud | Polymerisable monomers, polymer dispersions and derived paints |
US4487941A (en) * | 1983-07-08 | 1984-12-11 | Desoto, Inc. | Wet adhesion promoters for emulsion polymers |
EP0135725B1 (de) * | 1983-08-02 | 1989-03-08 | Tosoh Corporation | Verfahren zur Herstellung vn Polyaminen |
US4632957A (en) * | 1984-09-04 | 1986-12-30 | Ppg Industries, Inc. | Ethylenically unsaturated ethylene and propylene ureas containing alkylene urea groups or alkylene urethane groups, useful in coating compositions |
US4883854A (en) * | 1988-09-30 | 1989-11-28 | Medtronic, Inc. | Hydroxyl functional monomers |
US4990672A (en) * | 1989-05-30 | 1991-02-05 | Air Products And Chemicals, Inc. | Propylene-linked polyethylene polyamines and a process for making same |
EP0594596A1 (de) * | 1990-02-14 | 1994-05-04 | H.B. FULLER LICENSING & FINANCING, INC. | Copolymerisierbare imidazolidinon-monomere |
US5138016A (en) * | 1990-12-18 | 1992-08-11 | H. B. Fuller Company | Isocyanurate-free oxazolidone compound made from epoxy and a hindered isocyanate compound and a novel catalyst for their production |
US5196589A (en) * | 1991-09-16 | 1993-03-23 | Lce Partnership | Stabilized acrylonitrile polymerizations |
-
1993
- 1993-03-02 US US08/025,091 patent/US5399706A/en not_active Expired - Fee Related
-
1994
- 1994-03-02 WO PCT/US1994/002265 patent/WO1994020474A1/en active IP Right Grant
- 1994-03-02 DE DE69411545T patent/DE69411545T2/de not_active Expired - Fee Related
- 1994-03-02 EP EP94910810A patent/EP0683769B1/de not_active Expired - Lifetime
- 1994-03-02 JP JP6520133A patent/JP2875890B2/ja not_active Expired - Lifetime
- 1994-03-02 CA CA002157606A patent/CA2157606A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
JPH08508246A (ja) | 1996-09-03 |
EP0683769A1 (de) | 1995-11-29 |
WO1994020474A1 (en) | 1994-09-15 |
US5399706A (en) | 1995-03-21 |
DE69411545T2 (de) | 1999-01-28 |
CA2157606A1 (en) | 1994-09-15 |
JP2875890B2 (ja) | 1999-03-31 |
EP0683769B1 (de) | 1998-07-08 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition | ||
8339 | Ceased/non-payment of the annual fee |