DE69219931D1 - Verfahren zur Herstellung eines Styrolpolymers - Google Patents

Verfahren zur Herstellung eines Styrolpolymers

Info

Publication number
DE69219931D1
DE69219931D1 DE69219931T DE69219931T DE69219931D1 DE 69219931 D1 DE69219931 D1 DE 69219931D1 DE 69219931 T DE69219931 T DE 69219931T DE 69219931 T DE69219931 T DE 69219931T DE 69219931 D1 DE69219931 D1 DE 69219931D1
Authority
DE
Germany
Prior art keywords
styrene polymer
catalyst
producing
aluminoxane
specific
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69219931T
Other languages
English (en)
Other versions
DE69219931T2 (de
Inventor
Masami Watanabe
Shoji Naganuma
Norio Tomotsu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Idemitsu Kosan Co Ltd Tokio/tokyo Jp Dow C
Original Assignee
Idemitsu Kosan Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Idemitsu Kosan Co Ltd filed Critical Idemitsu Kosan Co Ltd
Application granted granted Critical
Publication of DE69219931D1 publication Critical patent/DE69219931D1/de
Publication of DE69219931T2 publication Critical patent/DE69219931T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06—Hydrocarbons
    • C08F12/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06—Hydrocarbons
    • C08F12/12—Monomers containing a branched unsaturated aliphatic radical or a ring substituted by an alkyl radical
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/643—Component covered by group C08F4/64 with a metal or compound covered by group C08F4/44 other than an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C08F4/74—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals
    • C08F4/76—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from refractory metals selected from titanium, zirconium, hafnium, vanadium, niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/04—Cp or analog not bridged to a non-Cp X ancillary anionic donor
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)
  • Polymerization Catalysts (AREA)
DE69219931T 1991-03-26 1992-03-17 Verfahren zur Herstellung eines Styrolpolymers Expired - Fee Related DE69219931T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3084373A JP2939354B2 (ja) 1991-03-26 1991-03-26 スチレン系重合体の製造方法及びその触媒

Publications (2)

Publication Number Publication Date
DE69219931D1 true DE69219931D1 (de) 1997-07-03
DE69219931T2 DE69219931T2 (de) 1997-09-11

Family

ID=13828733

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69219931T Expired - Fee Related DE69219931T2 (de) 1991-03-26 1992-03-17 Verfahren zur Herstellung eines Styrolpolymers

Country Status (9)

Country Link
US (1) US5294685A (de)
EP (1) EP0505890B1 (de)
JP (1) JP2939354B2 (de)
KR (1) KR0135270B1 (de)
AT (1) ATE153676T1 (de)
CA (1) CA2063933A1 (de)
DE (1) DE69219931T2 (de)
MY (1) MY110442A (de)
TW (1) TW241271B (de)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0505972B1 (de) * 1991-03-27 1997-06-11 Idemitsu Kosan Company Limited Verfahren zur Herstellung eines Styrolpolymerisats
JP2927566B2 (ja) * 1991-03-28 1999-07-28 出光興産株式会社 スチレン系共重合体の製造方法
US5461127A (en) * 1992-09-22 1995-10-24 Idemitsu Kosan Co., Ltd. Polymerization catalysts and process for producing polymers
JP3473955B2 (ja) * 1993-03-31 2003-12-08 出光興産株式会社 ビニル系重合体製造用の触媒及びビニル芳香族系重合体の製造方法
JPH0733812A (ja) * 1993-07-02 1995-02-03 Idemitsu Kosan Co Ltd スチレン系重合体製造触媒及びそれを用いたスチレン系重合体の製造方法
JP3216748B2 (ja) * 1993-07-23 2001-10-09 出光興産株式会社 芳香族ビニル化合物重合体組成物の製造触媒及びそれを用いた芳香族ビニル化合物重合体組成物の製造方法
US5453474A (en) * 1993-10-08 1995-09-26 The Dow Chemical Company Process for preparation of syndiotactic vinylidene aromatic polymers using reduced metal cationic catalysts
US5428120A (en) * 1993-10-08 1995-06-27 The Dow Chemical Company Process for preparation of syndiotactic vinylidene aromatic polymers using chain transfer agent
EP0988957A1 (de) * 1994-11-29 2000-03-29 Idemitsu Petrochemical Co., Ltd. Styrolharzherstellungsverfahren
US5569428A (en) * 1995-03-13 1996-10-29 The Dow Chemical Company Process for the preparation of fibers of syndiotactic vinylaromatic polymers
US6191197B1 (en) 1996-09-23 2001-02-20 Bridgestone Corporation Extended polymer compostion derived from blends of elastomers and syndiotactic polystyrene
US6329459B1 (en) 1996-09-23 2001-12-11 Bridgestone Corporation Extended syndiotactic polystyrene-elastomeric block copolymers
US6479424B1 (en) 1998-12-14 2002-11-12 Bp Corporation North America Inc. Fluxional catalysts and related ligands containing bulky substituents
JP2003128720A (ja) 2001-10-19 2003-05-08 Sunallomer Ltd オレフィン重合用固体助触媒成分、オレフィン重合用触媒およびイオン含有化合物
US6894102B2 (en) * 2002-05-20 2005-05-17 General Electric Syndiotactic polystyrene blends
US6818737B2 (en) * 2003-02-28 2004-11-16 Dow Global Technologies Inc. Method of producing articles from syndiotactic vinyl aromatic polymers
US20070106000A1 (en) * 2005-11-10 2007-05-10 Hua Guo Polymer blend and method for its isolation
US20070238831A1 (en) * 2006-03-30 2007-10-11 Steven Klei Poly(arylene ether) composition and method of making the same
US20070238190A1 (en) * 2006-03-30 2007-10-11 Steven Klei Method of authenticating a poly(arylene ether) composition

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2531583B2 (ja) * 1987-01-28 1996-09-04 出光興産株式会社 スチレン系共重合体およびその製造方法
CA1276748C (en) * 1985-07-29 1990-11-20 Michitake Uoi Styrene polymers
JPS62187708A (ja) * 1985-11-11 1987-08-17 Idemitsu Kosan Co Ltd スチレン系重合体の製造法
JPH085929B2 (ja) * 1987-01-22 1996-01-24 出光興産株式会社 スチレン系重合体の製造法
US5153157A (en) * 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
PL276385A1 (en) * 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
IL85097A (en) * 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
JPH02252706A (ja) * 1989-03-28 1990-10-11 Idemitsu Kosan Co Ltd スチレン系重合体の製造方法
US5064802A (en) * 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
US5066741A (en) * 1990-03-22 1991-11-19 The Dow Chemical Company Process for preparation of syndiotactic vinyl aromatic polymers
CA2024830A1 (en) * 1989-09-29 1991-03-30 Richard E. Campbell, Jr. Process for preparation of syndiotactic vinyl aromatic polymers

Also Published As

Publication number Publication date
MY110442A (en) 1998-05-30
KR920018090A (ko) 1992-10-21
DE69219931T2 (de) 1997-09-11
EP0505890A2 (de) 1992-09-30
ATE153676T1 (de) 1997-06-15
TW241271B (de) 1995-02-21
US5294685A (en) 1994-03-15
CA2063933A1 (en) 1992-09-27
EP0505890A3 (en) 1992-12-16
JP2939354B2 (ja) 1999-08-25
EP0505890B1 (de) 1997-05-28
KR0135270B1 (ko) 1998-04-23
JPH04296306A (ja) 1992-10-20

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Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8327 Change in the person/name/address of the patent owner

Owner name: IDEMITSU KOSAN CO. LTD., TOKIO/TOKYO, JP THE DOW C

8339 Ceased/non-payment of the annual fee
8370 Indication related to discontinuation of the patent is to be deleted
8339 Ceased/non-payment of the annual fee