DE69204850D1 - Verfahren zur herstellung von gleichmaessigen zeolithkristallen des mfi-typs. - Google Patents

Verfahren zur herstellung von gleichmaessigen zeolithkristallen des mfi-typs.

Info

Publication number
DE69204850D1
DE69204850D1 DE69204850T DE69204850T DE69204850D1 DE 69204850 D1 DE69204850 D1 DE 69204850D1 DE 69204850 T DE69204850 T DE 69204850T DE 69204850 T DE69204850 T DE 69204850T DE 69204850 D1 DE69204850 D1 DE 69204850D1
Authority
DE
Germany
Prior art keywords
uniformed
producing
zeolite crystals
mfi type
mfi
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69204850T
Other languages
English (en)
Other versions
DE69204850T2 (de
Inventor
Johannes Verduijn
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Publication of DE69204850D1 publication Critical patent/DE69204850D1/de
Application granted granted Critical
Publication of DE69204850T2 publication Critical patent/DE69204850T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/02—Crystalline silica-polymorphs, e.g. silicalites dealuminated aluminosilicate zeolites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38—Type ZSM-5
    • C01B39/40—Type ZSM-5 using at least one organic template directing agent
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S423/00—Chemistry of inorganic compounds
    • Y10S423/22—MFI, e.g. ZSM-5. silicalite, LZ-241

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
DE69204850T 1991-10-23 1992-10-08 Verfahren zur herstellung von gleichmaessigen zeolithkristallen des mfi-typs. Expired - Lifetime DE69204850T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB919122498A GB9122498D0 (en) 1991-10-23 1991-10-23 Process for preparing uniform mfitype zeolite crystals
PCT/EP1992/002330 WO1993008124A1 (en) 1991-10-23 1992-10-08 Process for preparing uniform mfi-type zeolite crystals

Publications (2)

Publication Number Publication Date
DE69204850D1 true DE69204850D1 (de) 1995-10-19
DE69204850T2 DE69204850T2 (de) 1996-02-22

Family

ID=10703410

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69204850T Expired - Lifetime DE69204850T2 (de) 1991-10-23 1992-10-08 Verfahren zur herstellung von gleichmaessigen zeolithkristallen des mfi-typs.

Country Status (11)

Country Link
US (1) US5672331A (de)
EP (1) EP0609270B1 (de)
JP (1) JPH07500561A (de)
KR (1) KR100245940B1 (de)
CA (1) CA2122049A1 (de)
DE (1) DE69204850T2 (de)
ES (1) ES2077433T3 (de)
GB (1) GB9122498D0 (de)
MX (1) MX9206080A (de)
TW (1) TW250441B (de)
WO (1) WO1993008124A1 (de)

Families Citing this family (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0609304B1 (de) * 1991-10-23 1997-08-27 Exxon Chemical Patents Inc. Molekülarsieb-kristalle oder agglomerate mit nanometer-dimensionen sowie verfahren zu ihrer herstellung
US5863516A (en) * 1992-09-02 1999-01-26 Exxon Chemical Patent Inc. Micro particles
EP0758626A1 (de) 1995-08-04 1997-02-19 Unilever Plc Aluminosilikate
EP0753485A1 (de) 1995-07-10 1997-01-15 Exxon Chemical Patents Inc. Zeolithe und Verfahren zu ihrer Herstellung
EP0753483A1 (de) 1995-07-10 1997-01-15 Exxon Chemical Patents Inc. Zeolithe und Verfahren zu ihrer Herstellung
EP0753482A1 (de) 1995-07-10 1997-01-15 Exxon Chemical Patents Inc. Zeolithe und Verfahren zu ihrer Herstellung
GB9600082D0 (en) 1996-01-04 1996-03-06 Exxon Chemical Patents Inc Molecular sieves and processes for their manufacture
MX218796B (es) * 1996-10-17 2004-01-23 Exxon Chemical Patents Inc Conversion de hidrocarburos usando un catalizador de zeolita de cristales grandes.
ZA979264B (en) * 1996-10-17 1998-12-29 Exxon Chemical Patents Inc Synthesis of large crystal zeolites
DE19707994A1 (de) † 1997-02-27 1998-09-03 Sued Chemie Ag Verfahren zur Herstellung von Zeolithen mit einem hohen Si/Al-Atomverhältnis
EP1044069B1 (de) 1997-12-03 2002-04-17 ExxonMobil Chemical Patents Inc. Herstellung einer durch eine zeolith von mfi-strukturtyp gebundenen zeolith und ihre verwendung
GB9816508D0 (en) 1998-07-29 1998-09-23 Exxon Chemical Patents Inc Molecular sieves and processes for their manufacture
CN1214976C (zh) 1998-07-29 2005-08-17 埃克森美孚化学专利公司 结晶分子筛
DE69907935T2 (de) 1998-09-22 2004-03-11 Exxonmobil Chemical Patents Inc., Baytown Verfahren zur herstellung von durch zeolith gebundenen zeolithen mit hohem sio2-gehalt und ihre verwendung
DE19951781A1 (de) * 1999-10-27 2001-05-03 Sued Chemie Ag Verfahren zur Herstellung von synthetischen Zeolithen mit MFI-Struktur
US6521198B2 (en) 2000-05-17 2003-02-18 The Regents Of The University Of California Metal surfaces coated with molecular sieve for corrosion resistance
DE10036953A1 (de) 2000-07-28 2002-02-07 Bayer Ag Verfahren zur Herstellung von Hydroxyaromaten
BR0313822B1 (pt) * 2002-08-28 2012-09-18 processo para a preparação de zeólito de tipo pentasil dopado usando-se sementes dopadas.
US20070059238A1 (en) * 2004-01-16 2007-03-15 Thakur Ram M Process for enhancing yield of sodium aluminosilicate molecular sieves during synthesis
US7112316B1 (en) * 2005-08-08 2006-09-26 Uop Llc Process for preparing molecular sieves via continuous addition of nutrients
US8048402B2 (en) * 2005-08-18 2011-11-01 Exxonmobil Chemical Patents Inc. Synthesis of molecular sieves having the chabazite framework type and their use in the conversion of oxygenates to olefins
DE102005049362A1 (de) * 2005-10-12 2007-04-19 Basf Ag Verfahren zur Herstellung eines Silikates
US20110009680A1 (en) * 2008-03-31 2011-01-13 Sebastien Kremer Molecular Sieve Composition and Method of Making and Using the Same
FR2936791B1 (fr) * 2008-10-07 2011-05-06 Inst Francais Du Petrole Procede de preparation d'une zeolithe de type structural mfi
US7846994B2 (en) * 2008-12-23 2010-12-07 Potters Industries, Inc. Inorganic microspheres
CZ301937B6 (cs) 2010-02-05 2010-08-04 Výzkumný ústav anorganické chemie, a. s. Zpusob výroby zeolitu pentasilové struktury s rízenou distribucí hliníkových atomu ve skeletu
KR101248880B1 (ko) * 2010-07-06 2013-03-29 한국에너지기술연구원 열균열이 방지된 제올라이트 분리막 및 그 제조 방법
US20120157741A1 (en) * 2010-12-17 2012-06-21 Guang Cao Synthesis of Silicoaluminophosphate Having Lev Framework-Type
EP2676728A1 (de) 2012-06-18 2013-12-25 ExxonMobil Chemical Patents Inc. Synthese von kristallinen EUO Molekularsieben
US9289755B2 (en) 2012-12-07 2016-03-22 Exxonmobil Research And Engineering Company Synthesis of ZSM-5 crystals with improved morphology
US10081552B2 (en) * 2012-12-21 2018-09-25 Exxonmobil Research And Engineering Company Small crystal ZSM-5, its synthesis and use
JP2016512191A (ja) 2013-03-14 2016-04-25 ヨーナス・ヘドルンド ゼオライト結晶および／またはゼオライト様結晶を生成するための方法
CN103708497A (zh) * 2013-12-27 2014-04-09 复旦大学 用于甲醇制烯烃的纳米颗粒堆积的B-Al-ZSM-5沸石催化剂及其制备方法和应用
CA2981736C (en) 2015-04-09 2023-05-09 Basf Corporation Zsm-5 catalyst
CN112619685B (zh) * 2020-12-18 2021-11-12 复旦大学 具有mfi结构的纳米雏晶催化剂及其制备方法和应用

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3702886A (en) * 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
US3808326A (en) * 1971-03-19 1974-04-30 Grace W R & Co Preparation of zeolites
US3781225A (en) * 1972-04-17 1973-12-25 Mobil Oil Corp Treatment of colloidal zeolites
US4002697A (en) * 1973-12-03 1977-01-11 Mobil Oil Corporation Selective production of para-xylene
US4166099A (en) * 1974-04-20 1979-08-28 W. R. Grace & Co. Preparation of zeolites
US4061724A (en) * 1975-09-22 1977-12-06 Union Carbide Corporation Crystalline silica
US4100262A (en) * 1977-08-15 1978-07-11 Mobil Oil Corporation Synthesis of zeolite ZSM-5
US4526879A (en) * 1978-11-13 1985-07-02 Mobil Oil Corporation Synthesis of zeolite ZSM-5
US4205053A (en) * 1979-02-01 1980-05-27 Mobil Oil Corporation Manufacture of nitrogenous zeolites
NL182469C (nl) * 1979-08-02 1988-03-16 Shell Int Research Werkwijze voor de bereiding van kristallijne ijzersilicaten; werkwijze voor het uitvoeren van katalytische processen.
NZ206295A (en) * 1982-11-22 1986-09-10 Mobil Oil Corp Preparation of zeolites
US4908342A (en) * 1985-09-04 1990-03-13 Mobil Oil Corporation ZSM-5 zeolites having uniformly large crystals
FR2608068B1 (fr) * 1986-12-16 1989-03-24 Inst Francais Du Petrole Nouveau procede de synthese de zeolithes du type ferrisilicate, produits ainsi obtenus et leurs utilisations
US5240892A (en) * 1987-09-02 1993-08-31 Mobil Oil Corporation Small crystal ZSM-5, as a catalyst
US4797267A (en) * 1987-12-23 1989-01-10 Mobil Oil Corporation Method of producing rod-shaped ZSM-5 zeolite
FR2631327B1 (fr) * 1988-05-11 1990-09-07 Inst Francais Du Petrole Synthese de nouveaux gallosilicates de structure mfi
EP0514715B1 (de) * 1991-05-17 1997-12-29 Asahi Kasei Kogyo Kabushiki Kaisha Verfahren zur Herstellung eines teilchenförmigen Zeoliths

Also Published As

Publication number Publication date
WO1993008124A1 (en) 1993-04-29
KR100245940B1 (ko) 2000-03-02
TW250441B (de) 1995-07-01
MX9206080A (es) 1993-05-01
JPH07500561A (ja) 1995-01-19
CA2122049A1 (en) 1993-04-29
EP0609270A1 (de) 1994-08-10
EP0609270B1 (de) 1995-09-13
ES2077433T3 (es) 1995-11-16
US5672331A (en) 1997-09-30
GB9122498D0 (en) 1991-12-04
DE69204850T2 (de) 1996-02-22

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