DE69110804T2 - Verfahren zur Aromatisierung von C2-C4-Kohlenwasserstoffen. - Google Patents

Verfahren zur Aromatisierung von C2-C4-Kohlenwasserstoffen.

Info

Publication number
DE69110804T2
DE69110804T2 DE69110804T DE69110804T DE69110804T2 DE 69110804 T2 DE69110804 T2 DE 69110804T2 DE 69110804 T DE69110804 T DE 69110804T DE 69110804 T DE69110804 T DE 69110804T DE 69110804 T2 DE69110804 T2 DE 69110804T2
Authority
DE
Germany
Prior art keywords
aromatizing
hydrocarbons
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69110804T
Other languages
English (en)
Other versions
DE69110804D1 (de
Inventor
Jean-Paul Bournonville
Francis Raatz
Bernard Juguin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Application granted granted Critical
Publication of DE69110804D1 publication Critical patent/DE69110804D1/de
Publication of DE69110804T2 publication Critical patent/DE69110804T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/08—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of gallium, indium or thallium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of germanium, tin or lead
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C07C2529/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing iron group metals, noble metals or copper
    • C07C2529/44—Noble metals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
DE69110804T 1990-09-03 1991-08-21 Verfahren zur Aromatisierung von C2-C4-Kohlenwasserstoffen. Expired - Fee Related DE69110804T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9010946A FR2666249B1 (fr) 1990-09-03 1990-09-03 Catalyseur et procede d'aromatisation des hydrocarbures contenant 2 a 4 atomes de carbone par molecule.

Publications (2)

Publication Number Publication Date
DE69110804D1 DE69110804D1 (de) 1995-08-03
DE69110804T2 true DE69110804T2 (de) 1995-11-23

Family

ID=9400031

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69110804T Expired - Fee Related DE69110804T2 (de) 1990-09-03 1991-08-21 Verfahren zur Aromatisierung von C2-C4-Kohlenwasserstoffen.

Country Status (7)

Country Link
US (1) US5227557A (de)
EP (1) EP0474536B1 (de)
JP (1) JPH04244236A (de)
AU (1) AU641881B2 (de)
CA (1) CA2050523A1 (de)
DE (1) DE69110804T2 (de)
FR (1) FR2666249B1 (de)

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FR2680515B1 (fr) * 1991-08-23 1993-10-22 Institut Francais Petrole Utilisation d'un catalyseur contenant une zeolithe, un metal noble de la famille du platine et un metal additionnel dans l'aromatisation des hydrocarbures contenant de 5 a 12 atomes de carbone par molecule.
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FR2701866B1 (fr) * 1993-02-24 1995-06-02 Inst Francais Du Petrole Catalyseur composite contenant un halogène, un métal noble et au moins un métal additionnel, et son utilisation en aromatisation d'hydrocarbures C2-C12.
FR2704864B1 (fr) 1993-05-06 1995-11-17 Inst Francais Du Petrole Procede d'hydroreformage catalytique.
FR2724852B1 (fr) * 1994-09-26 1996-12-27 Indo French Centre For The Pro Procede de preparation d'un catalyseur metallique et utilisations
FR2772751B1 (fr) * 1997-12-22 2000-04-14 Inst Francais Du Petrole Catalyseur a base de mordenite contenant au moins un metal du groupe viii et au moins un metal des groupes iii et iv et son utilisation en isomerisation d'une coupe c8 aromatique
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US6784333B2 (en) * 2002-08-06 2004-08-31 Saudi Basic Industries Corporation Catalyst for aromatization of alkanes, process of making and using thereof
CN1257769C (zh) 2003-10-31 2006-05-31 中国石油化工股份有限公司 一种含磷和金属组分的mfi结构分子筛及其应用
US7186871B2 (en) * 2003-12-30 2007-03-06 Saudi Basic Industries Corporation Process for alkane aromatization using platinum-zeolite catalyst
JP4790356B2 (ja) * 2005-09-16 2011-10-12 勝 市川 低級炭化水素改質触媒
WO2008153759A2 (en) * 2007-05-24 2008-12-18 Saudi Basic Industries Corporation Catalyst for conversion of hydrocarbons, process of making and process of using thereof-bimetallic deposition
US8993468B2 (en) * 2007-05-24 2015-03-31 Saudi Basic Industries Corporation Catalyst for conversion of hydrocarbons, process of making and process of using thereof—Ge zeolites
US9221723B2 (en) * 2007-05-24 2015-12-29 Saudi Basic Industries Corporation Catalyst for conversion of hydrocarbons, process of making and process of using thereof—incorporation-1
US8969232B2 (en) 2007-05-24 2015-03-03 Saudi Basic Industries Corporation Catalyst for conversion of hydrocarbons, process of making and process of using thereof—incorporation 2
EP2027917A1 (de) 2007-07-31 2009-02-25 Shell Internationale Researchmaatschappij B.V. Katalysatorzusammensetzung sowie ihre Herstellung und Verwendung
WO2009076393A2 (en) * 2007-12-12 2009-06-18 Shell Oil Company Process for the conversion of ethane or mixed lower alkanes to aromatic hydrocarbons
UA98538C2 (ru) 2008-02-18 2012-05-25 Шелл Интернационале Рисерч Маатшаппидж Б.В. Процесс и катализатор для производства ароматических углеводородов
US8809608B2 (en) * 2008-02-18 2014-08-19 Shell Oil Company Process for the conversion of lower alkanes to aromatic hydrocarbons
EA201070972A1 (ru) * 2008-02-18 2011-02-28 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способ конверсии этана в ароматические углеводороды
AU2009215655B2 (en) 2008-02-20 2012-03-15 Shell Internationale Research Maatschappij B.V. Process for the conversion of ethane to aromatic hydrocarbons
WO2010021909A2 (en) * 2008-08-19 2010-02-25 Shell Oil Company Process for the conversion of lower alkanes to ethylene and aromatic hydrocarbons
EA201170359A1 (ru) * 2008-08-19 2011-08-30 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способ конверсии низших алканов в ароматические углеводороды и этилен
EA022457B1 (ru) 2009-11-02 2016-01-29 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способ конверсии смесей низших алканов в ароматические углеводороды
US8119551B2 (en) 2010-01-14 2012-02-21 Saudi Basic Industries Corporation Zeolite catalyst with deposited germanium, aluminum and platinum for aromatization of alkanes, process of making and process of using thereof
US8779224B2 (en) 2010-04-12 2014-07-15 Shell Oil Company Process for the production of gasoline blending components and aromatic hydrocarbons from lower alkanes
CN102858720A (zh) 2010-04-23 2013-01-02 国际壳牌研究有限公司 生产芳族烃和乙烯的方法
WO2011143303A2 (en) * 2010-05-12 2011-11-17 Shell Oil Company Methane aromatization catalyst, method of making and method of using the catalyst
CN102892730A (zh) 2010-05-12 2013-01-23 国际壳牌研究有限公司 低级烷烃转化为芳香烃的方法
US8772192B2 (en) 2012-06-29 2014-07-08 Saudi Basic Industries Corporation Germanium silicalite catalyst and method of preparation and use
WO2015061055A1 (en) 2013-10-14 2015-04-30 Shell Oil Company Process for the aromatization of alkanes in an alkane-containing gas stream
WO2015057485A1 (en) 2013-10-14 2015-04-23 Shell Oil Company A process for the aromatization of alkanes in an alkane-containing gas stream
CN105636693B (zh) 2013-11-22 2019-12-13 沙特基础工业公司 用于轻石脑油芳构化的具有改善的活性/选择性的催化剂
US9446389B2 (en) 2013-12-13 2016-09-20 Saudi Basic Industries Corporation Hydrocarbon aromatization catalyst composition and method of formation
US10059641B2 (en) 2015-09-25 2018-08-28 Exxonmobil Chemical Patents Inc. Conversion of non-aromatic hydrocarbon
JP6541073B2 (ja) * 2016-03-07 2019-07-10 Ｊｘｔｇエネルギー株式会社 低級炭化水素用の脱水素触媒、及び芳香族化合物の製造方法
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Also Published As

Publication number Publication date
US5227557A (en) 1993-07-13
EP0474536A1 (de) 1992-03-11
FR2666249A1 (fr) 1992-03-06
FR2666249B1 (fr) 1994-07-22
JPH04244236A (ja) 1992-09-01
AU8350991A (en) 1992-03-05
AU641881B2 (en) 1993-09-30
CA2050523A1 (fr) 1992-03-04
DE69110804D1 (de) 1995-08-03
EP0474536B1 (de) 1995-06-28

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Legal Events

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8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee