GB1272122A - A process for the dehydrocyclization of hydrocarbons - Google Patents

A process for the dehydrocyclization of hydrocarbons

Info

Publication number
GB1272122A
GB1272122A GB39408/69A GB3940869A GB1272122A GB 1272122 A GB1272122 A GB 1272122A GB 39408/69 A GB39408/69 A GB 39408/69A GB 3940869 A GB3940869 A GB 3940869A GB 1272122 A GB1272122 A GB 1272122A
Authority
GB
United Kingdom
Prior art keywords
catalyst
per cent
metal
group viii
weight per
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB39408/69A
Inventor
Frits Mathias Dautzenberg
Herman Wouter Kouwenhoven
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Priority to GB39408/69A priority Critical patent/GB1272122A/en
Priority to BE754019D priority patent/BE754019A/en
Priority to AU18336/70A priority patent/AU1833670A/en
Priority to ZA705369A priority patent/ZA705369B/en
Priority to FR7028737A priority patent/FR2057008B1/fr
Priority to CA089,880A priority patent/CA993854A/en
Priority to SE10654/70A priority patent/SE367999B/xx
Priority to NL7011476A priority patent/NL7011476A/xx
Priority to JP45067809A priority patent/JPS5013780B1/ja
Priority to DE19702038791 priority patent/DE2038791A1/en
Publication of GB1272122A publication Critical patent/GB1272122A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/656—Manganese, technetium or rhenium
    • B01J23/6567—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/06—Catalytic reforming characterised by the catalyst used
    • C10G35/085—Catalytic reforming characterised by the catalyst used containing platinum group metals or compounds thereof
    • C10G35/09—Bimetallic catalysts in which at least one of the metals is a platinum group metal

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

1,272,122. Hydrocarbon dehydrocyclization catalysts. SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ N.V. 4 Aug., 1970 [6 Aug., 1969], No. 39408/69. Heading B1E. [Also in Division C5] A non-acidic hydrocarbon dehydrocyclization catalyst comprises alumina which supports at least one Group VIII nozle metal, for example Ru, Rh, Pd, Os, Ir or Pt, at least one additional metal having an electronegativity of from 1.6 to 2.0 and chosen from the 5th and 6th Periods of the Periodic Table, for example Ag, Cd, Hg, Im, Tl, Sn, Pb, Bi, Mo, W or Re, and optionally sodium or potassium. The catalyst may contain from 0.01 to 5 weight per cent of Group VIII noble metal, from 0.01 to 10 weight per cent of additional metal as aforesaid and from 0.05 to 1 weight per cent of sodium or potassium; the weight ratio of additional metal as aforesaid to Group VIII noble metal in the catalyst preferably is between 0.05 to 1 and 2 to 1. The catalyst may be prepared in conventional manner using materials which will not impart acidic character to the catalyst; in order to remove any acidity derived for example from the alumina, the catalyst may be subjected to steam treatment at a high temperature, for example above 200‹C in the presence of a mixture containing oxygen and water vapour: The catalyst may be regenerated by oxidative burn-off, for example at a temperature of from 350 to 420‹C. Exemplified catalyst contain rhodium and tin; platinum and tin; platinum and rhenium.
GB39408/69A 1969-08-06 1969-08-06 A process for the dehydrocyclization of hydrocarbons Expired GB1272122A (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
GB39408/69A GB1272122A (en) 1969-08-06 1969-08-06 A process for the dehydrocyclization of hydrocarbons
BE754019D BE754019A (en) 1969-08-06 1970-07-28 METHOD AND CATALYST FOR THE DEHYDROCYCLISATION OF HYDROCARBON
AU18336/70A AU1833670A (en) 1969-08-06 1970-08-03 A process and catalyst forthe dehydrocyclization of hydrocarbons
ZA705369A ZA705369B (en) 1969-08-06 1970-08-04 "a process and catalyst for the dehydrocylization of hydrocarbons"
FR7028737A FR2057008B1 (en) 1969-08-06 1970-08-04
CA089,880A CA993854A (en) 1969-08-06 1970-08-04 Process and catalyst for the dehydrocyclization of hydrocarbons
SE10654/70A SE367999B (en) 1969-08-06 1970-08-04
NL7011476A NL7011476A (en) 1969-08-06 1970-08-04
JP45067809A JPS5013780B1 (en) 1969-08-06 1970-08-04
DE19702038791 DE2038791A1 (en) 1969-08-06 1970-08-04 Process for the dehydrocyclization of hydrocarbons and process for the production of a catalyst suitable therefor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB39408/69A GB1272122A (en) 1969-08-06 1969-08-06 A process for the dehydrocyclization of hydrocarbons

Publications (1)

Publication Number Publication Date
GB1272122A true GB1272122A (en) 1972-04-26

Family

ID=10409386

Family Applications (1)

Application Number Title Priority Date Filing Date
GB39408/69A Expired GB1272122A (en) 1969-08-06 1969-08-06 A process for the dehydrocyclization of hydrocarbons

Country Status (10)

Country Link
JP (1) JPS5013780B1 (en)
AU (1) AU1833670A (en)
BE (1) BE754019A (en)
CA (1) CA993854A (en)
DE (1) DE2038791A1 (en)
FR (1) FR2057008B1 (en)
GB (1) GB1272122A (en)
NL (1) NL7011476A (en)
SE (1) SE367999B (en)
ZA (1) ZA705369B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3223975A1 (en) * 1981-06-30 1983-01-13 Institut Français du Pétrole, 92502 Rueil-Malmaison, Hauts-de-Seine METHOD FOR REFINING FRACTIONS THAT ARE VERY RICH IN CYCLOPARAFFINS

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2125126A1 (en) * 1971-02-12 1972-09-29 Universal Oil Prod Co Hydrocarbon conversion - with a catalyst contg a platinum group metal,rhenium,tin and halogen
GB1432943A (en) * 1972-05-05 1976-04-22 Shell Int Research Regeneration process
FR2666249B1 (en) * 1990-09-03 1994-07-22 Inst Francais Du Petrole CATALYST AND METHOD FOR AROMATIZING HYDROCARBONS CONTAINING 2 TO 4 CARBON ATOMS PER MOLECULE.
US5268522A (en) * 1990-09-03 1993-12-07 Institut Francais De Petrole Process for the aromatization of hydrocarbons containing 5 to 9 carbon atoms per molecule in the presence of a particular catalyst
FR2674769B1 (en) * 1991-04-04 1994-04-29 Inst Francais Du Petrole GALLOALUMINOSILICATE TYPE CATALYST CONTAINING GALLIUM, A NOBLE METAL OF THE PLATINUM FAMILY AND AT LEAST ONE ADDITIONAL METAL, AND ITS USE IN FLAVORING HYDROCARBONS.
JP6803729B2 (en) * 2016-11-16 2020-12-23 Ｅｎｅｏｓ株式会社 Manufacturing method of p-xylene

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2888397A (en) * 1953-06-02 1959-05-26 Kellogg M W Co Hydrocarbon conversion process
US3531543A (en) * 1968-05-28 1970-09-29 Chevron Res Group viii noble metal,tin and solid inorganic refractory metal oxide catalyst composites and their use in hydrocarbon dehydrogenations

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3223975A1 (en) * 1981-06-30 1983-01-13 Institut Français du Pétrole, 92502 Rueil-Malmaison, Hauts-de-Seine METHOD FOR REFINING FRACTIONS THAT ARE VERY RICH IN CYCLOPARAFFINS

Also Published As

Publication number Publication date
FR2057008B1 (en) 1973-10-19
CA993854A (en) 1976-07-27
ZA705369B (en) 1971-04-28
NL7011476A (en) 1971-02-09
DE2038791A1 (en) 1971-02-18
SE367999B (en) 1974-06-17
AU1833670A (en) 1972-02-10
JPS5013780B1 (en) 1975-05-22
FR2057008A1 (en) 1971-05-07
BE754019A (en) 1971-01-28

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee