GB1366334A - Hydrocarbon conversion catalyst and preparation and use thereof - Google Patents

Hydrocarbon conversion catalyst and preparation and use thereof

Info

Publication number
GB1366334A
GB1366334A GB5929071A GB5929071A GB1366334A GB 1366334 A GB1366334 A GB 1366334A GB 5929071 A GB5929071 A GB 5929071A GB 5929071 A GB5929071 A GB 5929071A GB 1366334 A GB1366334 A GB 1366334A
Authority
GB
United Kingdom
Prior art keywords
tin
catalyst
carrier material
alumina
group metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5929071A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Universal Oil Products Co
Original Assignee
Universal Oil Products Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Universal Oil Products Co filed Critical Universal Oil Products Co
Publication of GB1366334A publication Critical patent/GB1366334A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/14—Inorganic carriers the catalyst containing platinum group metals or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/22—Halogenating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/22—Halogenating
    • B01J37/24—Chlorinating
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2702—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
    • C07C5/2724—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/06—Catalytic reforming characterised by the catalyst used
    • C10G35/085—Catalytic reforming characterised by the catalyst used containing platinum group metals or compounds thereof
    • C10G35/09—Bimetallic catalysts in which at least one of the metals is a platinum group metal
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of germanium, tin or lead
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/56—Platinum group metals
    • C07C2523/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

1366334 Hydrocarbon conversion catalyst UNIVERSAL OIL PRODUCTS CO 21 Dec 1971 [28 Dec 1970] 59290/71 Heading B1E [Also in Division C5] A process for preparing a catalyst containing a tin component in combination with a platinum group metal component on a carrier material comprises preparing an impregnating solution comprising a complex tin-platinum group metal. anionic species acidified with an aqueous halogen acid, impregnating a carrier material with the said impregnating solution, and drying and calcining the impregnated carrier material to recover a tin-platinum group metal catalyst. The impregnating solution contains divalent tin and either divalent or tetravalent platinum; it may be formed by mixing an aqueous solution of chloroplatinic acid or sodium chloroplatinate with a hydrochloric acid solution of stannous chloride. Pd, Ru, Ir, Os or Rh may be used instead of Pt. Suitable carriers are charcoal, clays, natural silicates, natural or synthetic alumina, silica, zirconia, thoria; boria, silica-alumina, silicazirconia or alumina-zirconia. Bulk density, pore diameter, pore volume and surface area values are quoted. The catalyst may be reduced in hydrogen: additional halogen may be included, e.g. by calcining in an atmosphere containing HCl.
GB5929071A 1970-12-28 1971-12-21 Hydrocarbon conversion catalyst and preparation and use thereof Expired GB1366334A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US10205970A 1970-12-28 1970-12-28

Publications (1)

Publication Number Publication Date
GB1366334A true GB1366334A (en) 1974-09-11

Family

ID=22287903

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5929071A Expired GB1366334A (en) 1970-12-28 1971-12-21 Hydrocarbon conversion catalyst and preparation and use thereof

Country Status (7)

Country Link
US (1) US3725304A (en)
JP (1) JPS5120196B1 (en)
CA (1) CA988496A (en)
DE (1) DE2164295A1 (en)
FR (1) FR2120993A5 (en)
GB (1) GB1366334A (en)
IT (1) IT945659B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4982047A (en) * 1988-07-14 1991-01-01 The British Petroleum Company, P.L.C. Chemical process and catalyst
EP0448858A1 (en) * 1988-12-05 1991-10-02 Uop Hydrocarbon dehydrogenation catalyst
US5126502A (en) * 1988-07-14 1992-06-30 British Petroleum Company P.L.C. Process for dehydrogenation of C2 -C10 paraffin to yield alkene product

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3875049A (en) * 1969-10-09 1975-04-01 Chevron Res Platinum-tin catalyst regeneration
US3844938A (en) * 1970-12-28 1974-10-29 Universal Oil Prod Co Reforming of hydrocarbon feed stocks with a catalyst comprising platinum and tin
BE787953A (en) * 1971-08-26 1973-02-26 Franc De Comp PROCESS FOR REGULATING THE HALOGEN CONTENT OF HYDROCARBON CONVERSION CATALYSTS
USRE29198E (en) * 1972-10-23 1977-05-03 Toa Nenry Kogyo Kabushiki Kaisha Process for preparing platinum-tin reforming catalyst and use thereof
US3883419A (en) * 1973-10-17 1975-05-13 Exxon Research Engineering Co Process for preparing platinum-tin reforming catalysts and use thereof
DE2652116C2 (en) * 1976-11-16 1987-05-14 Uop Inc., Des Plaines, Ill. Catalyst carrier
GB8716565D0 (en) * 1987-07-14 1987-08-19 British Petroleum Co Plc Catalyst
US5128300A (en) * 1989-06-30 1992-07-07 Uop Reforming catalyst with homogeneous metals dispersion
US5105032A (en) * 1990-10-04 1992-04-14 The Dow Chemical Company Vapor phase hydrogenation of carbon tetrachloride
US5202102A (en) * 1991-05-22 1993-04-13 The Dow Chemical Company Gas phase dehydrohalogenation using a pretreated catalyst
CN1032678C (en) * 1992-12-21 1996-09-04 中国石油化工总公司 Catalyst for dehydrogen of saturated hydrocarbon
US5972207A (en) * 1998-10-08 1999-10-26 Texaco Inc. Catalytic reforming process for heavy cracked naphtha

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB929800A (en) *
NL247951A (en) * 1959-02-02
US3501531A (en) * 1964-12-15 1970-03-17 Ethyl Corp Hydroformylation process
US3511888A (en) * 1968-02-08 1970-05-12 Shell Oil Co Paraffin conversion catalyst and process

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4982047A (en) * 1988-07-14 1991-01-01 The British Petroleum Company, P.L.C. Chemical process and catalyst
AU615552B2 (en) * 1988-07-14 1991-10-03 British Petroleum Company Plc, The Chemical process and catalyst
US5126502A (en) * 1988-07-14 1992-06-30 British Petroleum Company P.L.C. Process for dehydrogenation of C2 -C10 paraffin to yield alkene product
EP0448858A1 (en) * 1988-12-05 1991-10-02 Uop Hydrocarbon dehydrogenation catalyst

Also Published As

Publication number Publication date
US3725304A (en) 1973-04-03
IT945659B (en) 1973-05-10
DE2164295A1 (en) 1972-07-13
FR2120993A5 (en) 1972-08-18
CA988496A (en) 1976-05-04
JPS5120196B1 (en) 1976-06-23

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee