DE69107516T2 - Druckwechseladsorption zur Lufttrennung. - Google Patents
Druckwechseladsorption zur Lufttrennung.Info
- Publication number
- DE69107516T2 DE69107516T2 DE69107516T DE69107516T DE69107516T2 DE 69107516 T2 DE69107516 T2 DE 69107516T2 DE 69107516 T DE69107516 T DE 69107516T DE 69107516 T DE69107516 T DE 69107516T DE 69107516 T2 DE69107516 T2 DE 69107516T2
- Authority
- DE
- Germany
- Prior art keywords
- pressure
- adsorption
- adsorbent
- desorption
- nitrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Revoked
Links
- 238000001179 sorption measurement Methods 0.000 title claims abstract description 70
- 238000000926 separation method Methods 0.000 title claims abstract description 41
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 144
- 239000003463 adsorbent Substances 0.000 claims abstract description 80
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 72
- 238000003795 desorption Methods 0.000 claims abstract description 44
- 238000002336 sorption--desorption measurement Methods 0.000 claims abstract description 12
- 238000000034 method Methods 0.000 claims description 44
- 239000001301 oxygen Substances 0.000 claims description 41
- 229910052760 oxygen Inorganic materials 0.000 claims description 41
- 230000008569 process Effects 0.000 claims description 41
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 40
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 21
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 20
- 229910021536 Zeolite Inorganic materials 0.000 claims description 20
- 239000010457 zeolite Substances 0.000 claims description 20
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 16
- 229910052744 lithium Inorganic materials 0.000 claims description 16
- -1 lithium cations Chemical class 0.000 claims description 13
- 239000003518 caustics Substances 0.000 claims description 12
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 10
- 229910052786 argon Inorganic materials 0.000 claims description 10
- 229910052593 corundum Inorganic materials 0.000 claims description 10
- 238000005265 energy consumption Methods 0.000 claims description 10
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 10
- 229910052681 coesite Inorganic materials 0.000 claims description 8
- 229910052906 cristobalite Inorganic materials 0.000 claims description 8
- 239000000377 silicon dioxide Substances 0.000 claims description 8
- 235000012239 silicon dioxide Nutrition 0.000 claims description 8
- 229910052682 stishovite Inorganic materials 0.000 claims description 8
- 229910052905 tridymite Inorganic materials 0.000 claims description 8
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical group [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 7
- 229910001415 sodium ion Inorganic materials 0.000 claims description 7
- 125000004122 cyclic group Chemical group 0.000 claims description 6
- 230000029087 digestion Effects 0.000 claims description 5
- 230000002349 favourable effect Effects 0.000 claims 3
- 230000001351 cycling effect Effects 0.000 claims 2
- 238000012545 processing Methods 0.000 description 18
- 239000000463 material Substances 0.000 description 16
- 238000004519 manufacturing process Methods 0.000 description 10
- 239000007789 gas Substances 0.000 description 9
- 238000010926 purge Methods 0.000 description 8
- 238000003860 storage Methods 0.000 description 8
- 238000011068 loading method Methods 0.000 description 7
- 238000011282 treatment Methods 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000011161 development Methods 0.000 description 5
- 230000018109 developmental process Effects 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 5
- 239000002808 molecular sieve Substances 0.000 description 5
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- 150000001768 cations Chemical class 0.000 description 4
- 239000004927 clay Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000005342 ion exchange Methods 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 238000012993 chemical processing Methods 0.000 description 1
- 238000005094 computer simulation Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229910052680 mordenite Inorganic materials 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000011946 reduction process Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 230000005654 stationary process Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229910001427 strontium ion Inorganic materials 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/047—Pressure swing adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/106—Silica or silicates
- B01D2253/108—Zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/106—Silica or silicates
- B01D2253/108—Zeolites
- B01D2253/1085—Zeolites characterized by a silicon-aluminium ratio
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/12—Oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/18—Noble gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/10—Single element gases other than halogens
- B01D2257/102—Nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/402—Further details for adsorption processes and devices using two beds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S95/00—Gas separation: processes
- Y10S95/90—Solid sorbent
- Y10S95/902—Molecular sieve
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Separation Of Gases By Adsorption (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Oxygen, Ozone, And Oxides In General (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/530,285 US5074892A (en) | 1990-05-30 | 1990-05-30 | Air separation pressure swing adsorption process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69107516D1 DE69107516D1 (de) | 1995-03-30 |
| DE69107516T2 true DE69107516T2 (de) | 1995-09-14 |
Family
ID=24113099
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69107516T Revoked DE69107516T2 (de) | 1990-05-30 | 1991-05-29 | Druckwechseladsorption zur Lufttrennung. |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US5074892A (enExample) |
| EP (1) | EP0461478B1 (enExample) |
| JP (1) | JPH0794004B2 (enExample) |
| KR (1) | KR960000007B1 (enExample) |
| CN (1) | CN1029821C (enExample) |
| AT (1) | ATE118698T1 (enExample) |
| BR (1) | BR9102180A (enExample) |
| CA (1) | CA2043491C (enExample) |
| DE (1) | DE69107516T2 (enExample) |
| DK (1) | DK0461478T3 (enExample) |
| ES (1) | ES2068426T3 (enExample) |
| GR (1) | GR3015165T3 (enExample) |
| TW (1) | TW218850B (enExample) |
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5174979A (en) * | 1989-10-06 | 1992-12-29 | Uop | Mixed ion-exchanged zeolites and processes for the use thereof in gas separations |
| US5152813A (en) * | 1991-12-20 | 1992-10-06 | Air Products And Chemicals, Inc. | Nitrogen adsorption with a Ca and/or Sr exchanged lithium X-zeolite |
| WO1994006541A1 (en) * | 1992-09-22 | 1994-03-31 | Arbor Research Corporation | System for separation of oxygen from argon/oxygen mixture |
| US5258060A (en) † | 1992-09-23 | 1993-11-02 | Air Products And Chemicals, Inc. | Adsorptive separation using diluted adsorptive phase |
| US5266102A (en) * | 1992-09-23 | 1993-11-30 | Air Products And Chemicals, Inc. | O2 VSA process with low O2 capacity adsorbents |
| US5415683A (en) * | 1993-11-17 | 1995-05-16 | Praxair Technology, Inc. | Vacuum pressure swing adsorption process |
| US5464467A (en) * | 1994-02-14 | 1995-11-07 | The Boc Group, Inc. | Adsorptive separation of nitrogen from other gases |
| FR2722426B1 (fr) * | 1994-07-18 | 1996-08-23 | Air Liquide | Procede de separation d'azote d'un melange gazeux par adsorption |
| DE19528188C1 (de) * | 1995-08-01 | 1996-12-05 | Bayer Ag | Verfahren zur Adsorption von Stickstoff aus Gasgemischen mittels Druckwechseladsorption mit Zeolithen |
| US5674311A (en) * | 1995-10-20 | 1997-10-07 | Praxair Technology, Inc. | Adsorption process and system using multilayer adsorbent beds |
| FR2743507B1 (fr) | 1996-01-16 | 1998-03-06 | Air Liquide | Procede pour la separation de melanges d'oxygene et d'azote utilisant un adsorbant a porosite amelioree |
| FR2764681B1 (fr) * | 1997-06-13 | 1999-07-16 | Air Liquide | Procede et installation de separation d'air par distillation cryogenique |
| JPH119990A (ja) | 1997-06-24 | 1999-01-19 | Daido Hoxan Inc | 窒素吸着剤およびその使用方法 |
| FR2766476B1 (fr) * | 1997-07-22 | 1999-09-03 | Ceca Sa | Adsorbant zeolitique ameliore pour la separation des gaz de l'air et son procede d'obtention |
| CN1155433C (zh) | 1998-02-27 | 2004-06-30 | 普莱克斯技术有限公司 | 改进的psa吸附剂 |
| CN1168522C (zh) | 1998-02-27 | 2004-09-29 | 普莱克斯技术有限公司 | Vpsa法用改进的吸附材料 |
| US6500234B1 (en) | 1998-02-27 | 2002-12-31 | Praxair Technology, Inc. | Rate-enhanced gas separation |
| JP4601164B2 (ja) | 1998-02-27 | 2010-12-22 | プラクスエア・テクノロジー・インコーポレイテッド | 固有の拡散性の高い吸着剤及び低い圧力比を使用する圧力スウィング吸着によるガス分離方法 |
| US6171370B1 (en) | 1998-03-04 | 2001-01-09 | Tosoh Corporation | Adsorbent for separating gases |
| US6780806B1 (en) | 1998-12-30 | 2004-08-24 | The Regents Of The University Of Michigan | Lithium-based zeolites containing silver and copper and use thereof for selective absorption |
| US6691702B2 (en) | 2000-08-03 | 2004-02-17 | Sequal Technologies, Inc. | Portable oxygen concentration system and method of using the same |
| US6651658B1 (en) | 2000-08-03 | 2003-11-25 | Sequal Technologies, Inc. | Portable oxygen concentration system and method of using the same |
| AU2002215752A1 (en) * | 2000-12-08 | 2002-06-18 | Denis Connor | Methods and apparatuses for gas separation by pressure swing adsorption with partial gas product feed to fuel cell power source |
| US6468328B2 (en) * | 2000-12-18 | 2002-10-22 | Air Products And Chemicals, Inc. | Oxygen production by adsorption |
| US6506236B2 (en) † | 2001-03-28 | 2003-01-14 | Air Products And Chemicals, Inc. | Process for reducing the level of carbon dioxide in a gaseous mixture |
| US6471744B1 (en) | 2001-08-16 | 2002-10-29 | Sequal Technologies, Inc. | Vacuum-pressure swing absorption fractionator and method of using the same |
| FR2848983B1 (fr) | 2002-12-18 | 2005-01-28 | Air Liquide | Procede de fourniture a des occupants d'un aeronef d'un melange gazeux riche en oxygene |
| WO2004087300A1 (en) * | 2003-02-18 | 2004-10-14 | Jej Co., Ltd. | Gas concentration method and its apparatus |
| US7713334B1 (en) * | 2006-10-27 | 2010-05-11 | The United States Of America As Represented By The Secretary Of The Army | Process for removing epoxides |
| US8226745B2 (en) * | 2009-04-28 | 2012-07-24 | Lehigh University | Miniature oxygen concentrators and methods |
| JP2014512259A (ja) | 2011-03-01 | 2014-05-22 | エクソンモービル リサーチ アンド エンジニアリング カンパニー | 制御された吸着フロントを用いたスイング吸着法 |
| US8808426B2 (en) | 2012-09-04 | 2014-08-19 | Exxonmobil Research And Engineering Company | Increasing scales, capacities, and/or efficiencies in swing adsorption processes with hydrocarbon gas feeds |
| WO2014130833A1 (en) | 2013-02-21 | 2014-08-28 | Lehigh University | Oxygen concentrator system and method |
| US10449479B2 (en) | 2016-08-04 | 2019-10-22 | Exxonmobil Research And Engineering Company | Increasing scales, capacities, and/or efficiencies in swing adsorption processes with hydrocarbon gas feeds |
| WO2021096752A1 (en) * | 2019-11-15 | 2021-05-20 | Praxair Technology, Inc. | Energy efficient vesa process with direct drive high speed centrifugal compressors |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3140933A (en) * | 1960-12-02 | 1964-07-14 | Union Carbide Corp | Separation of an oxygen-nitrogen mixture |
| NL136033C (enExample) * | 1962-04-12 | 1900-01-01 | ||
| US3280536A (en) * | 1963-07-30 | 1966-10-25 | Exxon Research Engineering Co | Method for providing an oxygen-enriched environment |
| US3313091A (en) * | 1963-11-04 | 1967-04-11 | Exxon Research Engineering Co | Vacuum cycle adsorption |
| GB1449864A (en) * | 1973-10-24 | 1976-09-15 | Boc International Ltd | Adsorption system |
| GB1529701A (en) * | 1975-01-02 | 1978-10-25 | Boc International Ltd | Oxygen enriched air |
| GB1559325A (en) * | 1976-02-27 | 1980-01-16 | Boc Ltd | Gas separation |
| JPS52152893A (en) * | 1976-06-15 | 1977-12-19 | Toray Ind Inc | Separation and recovery of nitrogen |
| DE3144012A1 (de) * | 1981-11-05 | 1983-05-19 | Bayer Ag, 5090 Leverkusen | Druckwechselverfahren zur trennung von gasgemischen mittels adsorption |
| US4477265A (en) * | 1982-08-05 | 1984-10-16 | Air Products And Chemicals, Inc. | Argon purification |
| US4539019A (en) * | 1983-09-29 | 1985-09-03 | Air Products & Chemicals, Inc. | Control system for air fractionation by selective adsorption |
| DE3413895A1 (de) * | 1984-04-13 | 1985-10-17 | Bayer Ag, 5090 Leverkusen | Druckwechselverfahren zur adsorptiven trennung von gasgemischen |
| GB8503712D0 (en) * | 1985-02-13 | 1985-03-13 | British Petroleum Co Plc | Selective adsorption process |
| JPS61266302A (ja) * | 1985-05-17 | 1986-11-26 | Seitetsu Kagaku Co Ltd | 濃縮酸素回収方法 |
| US4859217A (en) * | 1987-06-30 | 1989-08-22 | Uop | Process for separating nitrogen from mixtures thereof with less polar substances |
| US4892565A (en) * | 1987-12-29 | 1990-01-09 | Air Products And Chemicals, Inc. | Adsorptive separation utilizing multiple adsorption beds |
| US4810265A (en) * | 1987-12-29 | 1989-03-07 | Union Carbide Corporation | Pressure swing adsorption process for gas separation |
| US4813977A (en) * | 1987-12-29 | 1989-03-21 | Air Products And Chemicals, Inc. | Adsorptive nitrogen generation utilizing multiple adsorption beds |
| JP2683806B2 (ja) * | 1988-03-17 | 1997-12-03 | 住友精化株式会社 | 濃縮酸素回収方法 |
| US4857083A (en) * | 1988-10-25 | 1989-08-15 | Air Products And Chemicals, Inc. | Vacuum swing adsorption process with vacuum aided internal rinse |
| US4925460A (en) * | 1989-07-20 | 1990-05-15 | Air Products And Chemicals, Inc. | Chabazite for gas separation |
-
1990
- 1990-05-30 US US07/530,285 patent/US5074892A/en not_active Expired - Lifetime
-
1991
- 1991-05-28 BR BR919102180A patent/BR9102180A/pt not_active IP Right Cessation
- 1991-05-29 DE DE69107516T patent/DE69107516T2/de not_active Revoked
- 1991-05-29 DK DK91108835.9T patent/DK0461478T3/da active
- 1991-05-29 ES ES91108835T patent/ES2068426T3/es not_active Expired - Lifetime
- 1991-05-29 EP EP91108835A patent/EP0461478B1/en not_active Revoked
- 1991-05-29 CA CA002043491A patent/CA2043491C/en not_active Expired - Lifetime
- 1991-05-29 JP JP3152232A patent/JPH0794004B2/ja not_active Expired - Lifetime
- 1991-05-29 CN CN91104555A patent/CN1029821C/zh not_active Revoked
- 1991-05-29 KR KR1019910008766A patent/KR960000007B1/ko not_active Expired - Fee Related
- 1991-05-29 AT AT91108835T patent/ATE118698T1/de not_active IP Right Cessation
- 1991-06-26 TW TW080104938A patent/TW218850B/zh not_active IP Right Cessation
-
1995
- 1995-02-23 GR GR950400326T patent/GR3015165T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| GR3015165T3 (en) | 1995-05-31 |
| CN1058920A (zh) | 1992-02-26 |
| EP0461478A1 (en) | 1991-12-18 |
| JPH0794004B2 (ja) | 1995-10-11 |
| US5074892A (en) | 1991-12-24 |
| TW218850B (enExample) | 1994-01-11 |
| ES2068426T3 (es) | 1995-04-16 |
| KR910019666A (ko) | 1991-12-19 |
| CA2043491A1 (en) | 1991-12-01 |
| DK0461478T3 (da) | 1995-07-24 |
| DE69107516D1 (de) | 1995-03-30 |
| CN1029821C (zh) | 1995-09-27 |
| BR9102180A (pt) | 1991-12-24 |
| JPH04227814A (ja) | 1992-08-17 |
| KR960000007B1 (ko) | 1996-01-03 |
| CA2043491C (en) | 1998-10-27 |
| ATE118698T1 (de) | 1995-03-15 |
| EP0461478B1 (en) | 1995-02-22 |
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