DE69027215D1 - Katalysator auf träger für 1-olefin und 1,4-diolefin kopolymerisation - Google Patents

Katalysator auf träger für 1-olefin und 1,4-diolefin kopolymerisation

Info

Publication number
DE69027215D1
DE69027215D1 DE69027215T DE69027215T DE69027215D1 DE 69027215 D1 DE69027215 D1 DE 69027215D1 DE 69027215 T DE69027215 T DE 69027215T DE 69027215 T DE69027215 T DE 69027215T DE 69027215 D1 DE69027215 D1 DE 69027215D1
Authority
DE
Germany
Prior art keywords
copolymerisation
diolefin
olefin
catalyst
support
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69027215T
Other languages
English (en)
Other versions
DE69027215T2 (de
Inventor
Main Chang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Publication of DE69027215D1 publication Critical patent/DE69027215D1/de
Application granted granted Critical
Publication of DE69027215T2 publication Critical patent/DE69027215T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE69027215T 1989-07-25 1990-07-20 Katalysator auf träger für 1-olefin und 1,4-diolefin kopolymerisation Expired - Fee Related DE69027215T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/385,339 US5017665A (en) 1989-07-25 1989-07-25 Supported catalyst for 1-olefin and 1,4-diolefin copolymerization
PCT/US1990/004119 WO1991001337A1 (en) 1989-07-25 1990-07-20 Supported catalyst for 1-olefin and 1,4-diolefin copolymerization

Publications (2)

Publication Number Publication Date
DE69027215D1 true DE69027215D1 (de) 1996-07-04
DE69027215T2 DE69027215T2 (de) 1996-10-31

Family

ID=23521002

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69027215T Expired - Fee Related DE69027215T2 (de) 1989-07-25 1990-07-20 Katalysator auf träger für 1-olefin und 1,4-diolefin kopolymerisation

Country Status (10)

Country Link
US (1) US5017665A (de)
EP (1) EP0484405B1 (de)
JP (1) JPH0725845B2 (de)
AU (1) AU633776B2 (de)
CA (1) CA2063809A1 (de)
DE (1) DE69027215T2 (de)
IL (1) IL95171A0 (de)
PL (1) PL286208A1 (de)
PT (1) PT94808A (de)
WO (1) WO1991001337A1 (de)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6025448A (en) 1989-08-31 2000-02-15 The Dow Chemical Company Gas phase polymerization of olefins
DE3929693A1 (de) * 1989-09-07 1991-03-14 Hoechst Ag Verfahren zur herstellung eines polyolefinwachses
JP2936172B2 (ja) * 1990-03-07 1999-08-23 東ソー株式会社 シンジオタクチック芳香族ビニル化合物重合体製造用触媒およびシンジオタクチック芳香族ビニル化合物重合体の製造方法
US5155197A (en) * 1990-03-14 1992-10-13 Exxon Chemical Patents Inc. Copolymer of propylene and trans-1,4-hexadiene and method for preparation thereof
US6538080B1 (en) 1990-07-03 2003-03-25 Bp Chemicals Limited Gas phase polymerization of olefins
TW218884B (de) * 1991-05-01 1994-01-11 Mitsubishi Kakoki Kk
JP3193066B2 (ja) * 1991-05-02 2001-07-30 三菱化学株式会社 プロピレンランダム共重合体の製造法
US6545088B1 (en) 1991-12-30 2003-04-08 Dow Global Technologies Inc. Metallocene-catalyzed process for the manufacture of EP and EPDM polymers
ES2126647T3 (es) * 1992-04-20 1999-04-01 Exxon Chemical Patents Inc Copolimeros de etileno/olefinas ramificadas.
US5688887A (en) * 1992-05-26 1997-11-18 Amoco Corporation Reactive, low molecular weight, viscous poly(1-olefins) and copoly(1-olefins) and their method of manufacture
US6043401A (en) * 1992-05-26 2000-03-28 Bp Amoco Corporation Reactive, low molecular weight, viscous poly(1-olefins) and copoly(1-olefins) and their method of manufacture
DE69333470T2 (de) * 1992-10-28 2004-08-19 Idemitsu Kosan Co. Ltd. Olefincopolymere und verfahren zu ihrer herstellung
US5523136A (en) * 1993-04-30 1996-06-04 Cypress Packaging Packaging film, packages and methods for using them
FI96866C (fi) 1993-11-05 1996-09-10 Borealis As Tuettu olefiinipolymerointikatalyytti, sen valmistus ja käyttö
WO1995016716A1 (en) * 1993-12-14 1995-06-22 Exxon Chemical Patents Inc. Process for producing elastomers with an indenyl metallocene catalyst system
US5569515A (en) * 1994-09-12 1996-10-29 Moore Business Forms, Inc. Printable linerless label and method for making same
US5763543A (en) * 1994-09-14 1998-06-09 Exxon Chemical Patents Inc. Olefin polymerization process with little or no scavenger present
KR970706320A (ko) * 1994-09-14 1997-11-03 카덴헤드 벤 씨 중합방법(polymerization process)
US5712353A (en) * 1994-10-31 1998-01-27 Exxon Chemical Patents Inc. Gas phase polymerization process
AR005066A1 (es) * 1995-12-15 1999-04-07 Union Carbide Chem Plastic Un procedimiento para hacer un homopolimero, copolimero o terpolimero de polietileno con ramificacion de cadena larga, una composicion de polietilenoasi obtenida y un articulo de pelicula o moldeado por inyeccion que comprende dicha composicion.
US6153551A (en) 1997-07-14 2000-11-28 Mobil Oil Corporation Preparation of supported catalyst using trialkylaluminum-metallocene contact products
EP1650234A1 (de) * 2004-10-21 2006-04-26 Total Petrochemicals Research Feluy Nickelverbindungen zur heterogenen Katalyse
CA2706822C (en) * 2007-11-19 2013-05-28 Mitsui Chemicals, Inc. Bridged metallocene compound, olefin polymerization catalyst containing the same, and ethylene polymer obtained with the catalyst
EP2119732A1 (de) 2008-05-16 2009-11-18 Borealis Technology Oy Metallocen-Katalysator-Zusammensetzungen mit verbesserten Eigenschaften, Verfahren zu ihrer Herstellung und ihre Verwendung zur Herstellung von Polyolefin-Homo- oder Copolymeren
NL2025222B1 (en) 2020-03-27 2021-10-20 Innograaf B V A polymeric foam material for shock pads in artificial grass systems.
CN111732682B (zh) * 2020-06-19 2022-12-23 浙江大学 一种高透光太阳能电池封装用交联型聚烯烃的制备方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1268754A (en) * 1985-06-21 1990-05-08 Howard Curtis Welborn, Jr. Supported polymerization catalyst
US4808561A (en) * 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
JPH06104701B2 (ja) * 1985-11-20 1994-12-21 三井石油化学工業株式会社 プロピレン系ランダム共重合体およびそれからなる熱可塑性樹脂用耐衝撃性改善剤
JPH06820B2 (ja) * 1985-11-21 1994-01-05 三井石油化学工業株式会社 低結晶性エチレン系ランダム共重合体およびその用途
JPS62121711A (ja) * 1985-11-21 1987-06-03 Mitsui Petrochem Ind Ltd 低結晶性エチレン系ランダム共重合体
JPH0753766B2 (ja) * 1985-11-22 1995-06-07 三井石油化学工業株式会社 α−オレフイン系ランダム共重合体の製造法
IL84641A (en) * 1986-12-19 1992-05-25 Exxon Chemical Patents Inc Unsaturated ethylene polymers
AU603487B2 (en) * 1987-09-14 1990-11-15 Exxon Chemical Patents Inc. Method for preparing an active metallocene-alumoxane catalyst in situ during polymerization
CA1327673C (en) * 1988-06-16 1994-03-08 Sigmund Floyd Process for production of high molecular weight epdm elastomers using a metallocene-alumoxane catalyst system

Also Published As

Publication number Publication date
AU633776B2 (en) 1993-02-04
AU6148890A (en) 1991-02-22
IL95171A0 (en) 1991-06-10
JPH0725845B2 (ja) 1995-03-22
US5017665A (en) 1991-05-21
CA2063809A1 (en) 1991-01-26
EP0484405B1 (de) 1996-05-29
PL286208A1 (en) 1991-04-08
JPH04506372A (ja) 1992-11-05
DE69027215T2 (de) 1996-10-31
EP0484405A1 (de) 1992-05-13
WO1991001337A1 (en) 1991-02-07
PT94808A (pt) 1991-03-20

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Legal Events

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8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee