DE60318533D1 - Phosphinverbindungen, Übergangsmetallkomlexe mit den Verbindungen, die als Liganden darin enthalten sind, und asymmetrische Synthesekatalysatoren mit diesen Komplexen - Google Patents
Phosphinverbindungen, Übergangsmetallkomlexe mit den Verbindungen, die als Liganden darin enthalten sind, und asymmetrische Synthesekatalysatoren mit diesen KomplexenInfo
- Publication number
- DE60318533D1 DE60318533D1 DE60318533T DE60318533T DE60318533D1 DE 60318533 D1 DE60318533 D1 DE 60318533D1 DE 60318533 T DE60318533 T DE 60318533T DE 60318533 T DE60318533 T DE 60318533T DE 60318533 D1 DE60318533 D1 DE 60318533D1
- Authority
- DE
- Germany
- Prior art keywords
- complexes
- ligands
- transition metal
- compounds
- phosphine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003054 catalyst Substances 0.000 title abstract 4
- 239000003446 ligand Substances 0.000 title abstract 4
- 150000003003 phosphines Chemical class 0.000 title abstract 4
- 229910052723 transition metal Inorganic materials 0.000 title abstract 4
- 238000011914 asymmetric synthesis Methods 0.000 title abstract 2
- 150000001875 compounds Chemical class 0.000 title abstract 2
- 150000003624 transition metals Chemical class 0.000 title abstract 2
- -1 transition metal phosphine complexes Chemical class 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2419—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member
- B01J31/2428—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising P as ring member with more than one complexing phosphine-P atom
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2442—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
- B01J31/2461—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as ring members in the condensed ring system or in a further ring
- B01J31/2471—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as ring members in the condensed ring system or in a further ring with more than one complexing phosphine-P atom
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2442—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
- B01J31/2461—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as ring members in the condensed ring system or in a further ring
- B01J31/2471—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as ring members in the condensed ring system or in a further ring with more than one complexing phosphine-P atom
- B01J31/2476—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as ring members in the condensed ring system or in a further ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B53/00—Asymmetric syntheses
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0046—Ruthenium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0046—Ruthenium compounds
- C07F15/0053—Ruthenium compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/5027—Polyphosphines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/655—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms
- C07F9/65515—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms the oxygen atom being part of a five-membered ring
- C07F9/65517—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms the oxygen atom being part of a five-membered ring condensed with carbocyclic rings or carbocyclic ring systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
- C07F9/65683—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms the ring phosphorus atom being part of a phosphine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
- B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
- B01J2231/643—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of R2C=O or R2C=NR (R= C, H)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
- B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
- B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0261—Complexes comprising ligands with non-tetrahedral chirality
- B01J2531/0266—Axially chiral or atropisomeric ligands, e.g. bulky biaryls such as donor-substituted binaphthalenes, e.g. "BINAP" or "BINOL"
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
- B01J2531/16—Copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/821—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/824—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/827—Iridium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/828—Platinum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/847—Nickel
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2002327889 | 2002-11-12 | ||
JP2002327889A JP4231274B2 (ja) | 2002-11-12 | 2002-11-12 | ホスフィン化合物、該化合物を配位子とする遷移金属錯体及び該錯体を含む不斉合成用触媒 |
Publications (2)
Publication Number | Publication Date |
---|---|
DE60318533D1 true DE60318533D1 (de) | 2008-02-21 |
DE60318533T2 DE60318533T2 (de) | 2009-01-08 |
Family
ID=32171350
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE60318533T Expired - Lifetime DE60318533T2 (de) | 2002-11-12 | 2003-11-10 | Phosphinverbindungen, Übergangsmetallkomlexe mit den Verbindungen, die als Liganden darin enthalten sind, und asymmetrische Synthesekatalysatoren mit diesen Komplexen |
Country Status (6)
Country | Link |
---|---|
US (2) | US6987202B2 (de) |
EP (1) | EP1419815B1 (de) |
JP (1) | JP4231274B2 (de) |
AT (1) | ATE383200T1 (de) |
DE (1) | DE60318533T2 (de) |
ES (1) | ES2297088T3 (de) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1911516B1 (de) * | 2005-07-07 | 2014-05-14 | Takasago International Corporation | Verfahren zur homogenen asymmetrischen hydrierung |
US8184798B2 (en) * | 2006-06-13 | 2012-05-22 | Tekelec | Methods, systems and computer program products for accessing number portability (NP) and E.164 number (ENUM) data using a common NP/ENUM data locator structure |
US8455661B2 (en) * | 2007-02-18 | 2013-06-04 | University Of Florida Research Foundation, Inc. | Catalysts containing N-heterocyclic carbenes for enantioselective synthesis |
CA3000442A1 (en) * | 2009-03-04 | 2010-09-10 | Chevron Phillips Chemical Company Lp | Selective hydrogenation catalyst and methods of making and using same |
JP5135264B2 (ja) * | 2009-03-12 | 2013-02-06 | 独立行政法人科学技術振興機構 | ホスホン酸類縁体の製造方法、及び触媒 |
US10029969B2 (en) * | 2013-03-06 | 2018-07-24 | Takasago International Corporation | Method of producing optically-active aldehyde |
KR20160003388A (ko) | 2014-07-01 | 2016-01-11 | 울산대학교 산학협력단 | 유사 휘발유 검출 장치 및 그 방법 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5171892A (en) * | 1991-07-02 | 1992-12-15 | E. I. Du Pont De Nemours And Company | Chiral phospholanes via chiral 1,4-diol cyclic sulfates |
DE59407903D1 (de) | 1993-10-08 | 1999-04-15 | Hoffmann La Roche | Optisch aktive phosphorverbindungen |
DE19846559A1 (de) | 1998-10-09 | 2000-04-20 | Aventis Res & Tech Gmbh & Co | Substituierte Isophosphindoline und ihre Verwendung |
US6137012A (en) | 1998-10-13 | 2000-10-24 | E. I. Du Pont De Nemours And Company | Phosphole and diphosphole ligands for catalysis |
-
2002
- 2002-11-12 JP JP2002327889A patent/JP4231274B2/ja not_active Expired - Lifetime
-
2003
- 2003-11-06 US US10/701,430 patent/US6987202B2/en not_active Expired - Fee Related
- 2003-11-10 AT AT03025726T patent/ATE383200T1/de not_active IP Right Cessation
- 2003-11-10 DE DE60318533T patent/DE60318533T2/de not_active Expired - Lifetime
- 2003-11-10 ES ES03025726T patent/ES2297088T3/es not_active Expired - Lifetime
- 2003-11-10 EP EP03025726A patent/EP1419815B1/de not_active Expired - Fee Related
-
2005
- 2005-08-18 US US11/206,068 patent/US7078568B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
JP2004161645A (ja) | 2004-06-10 |
DE60318533T2 (de) | 2009-01-08 |
ES2297088T3 (es) | 2008-05-01 |
EP1419815A1 (de) | 2004-05-19 |
US20050288531A1 (en) | 2005-12-29 |
ATE383200T1 (de) | 2008-01-15 |
US6987202B2 (en) | 2006-01-17 |
EP1419815B1 (de) | 2008-01-09 |
US20040092388A1 (en) | 2004-05-13 |
JP4231274B2 (ja) | 2009-02-25 |
US7078568B2 (en) | 2006-07-18 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Halterman et al. | Practical synthesis of two annelated optically active cyclopentadienes from the chiral pool and their transition metal complexes | |
Mukaiyama et al. | Tin (II) Enolates in the Aldol, M ichael, and Related Reactions | |
EP1277752A4 (de) | Verfahren zur herstellung von optisch-aktiven sulfoxid-derivaten | |
Jenter et al. | Aminotroponiminate zinc complexes as catalysts for the intramolecular hydroamination | |
TNSN06407A1 (en) | 1-aza-bicyclo [3.3.1] nonanes | |
ATE300528T1 (de) | Synthese von cannabinoiden | |
CN111420709B (zh) | 氮杂环卡宾基混配型镍(ii)配合物在合成2-直链烷基苯并噻唑类化合物反应中的应用 | |
GB1452182A (en) | Crown compounds and processes for their preparation | |
ATE383200T1 (de) | Phosphinverbindungen, übergangsmetallkomlexe mit den verbindungen, die als liganden darin enthalten sind, und asymmetrische synthesekatalysatoren mit diesen komplexen | |
PL368527A1 (en) | Novel disphospines, their complexes with transition metals and their use in asymmetric synthesis | |
ATE531702T1 (de) | Verfahren zur herstellung von epoxytriazolderivat und zwischenprodukten dafür | |
JP5144865B2 (ja) | ホスフィニト−オキサゾリン及び金属錯体 | |
ATE337327T1 (de) | Substituierte ferrocenyldiphosphinligande für homogene hydrogenieringskatalysatoren | |
HU0203890D0 (en) | Novel thiazoline intermediates | |
MXPA04002599A (es) | Ligandos para reacciones asimetricas. | |
DE60116201D1 (de) | Verfahren zur Herstellung von Cephalosporin-Verbindungen und Zwischenprodukte für die Synthese dieser Verbindungen | |
HU903266D0 (en) | Process for producing amine-derivatives and pharmaceutical preparatives containing these compounds as active substance | |
ATE291581T1 (de) | Neuer asymmetrischer phosphin-ligand | |
CA1109479A (en) | PROCESS FOR PRODUCING OPTICALLY ACTIVE .alpha.- HYDROXYCARBOXYLIC ACID ESTER | |
Liao et al. | Oxidation of Alkenes and Sulfides with Transition Metal Catalysts | |
KR20170091501A (ko) | 금속 카보네이트의 제조 방법 및 그 제조용 촉매 | |
DE3882015D1 (de) | Photochromische zusammensetzung und diese zusammensetzung enthaltende gegenstaende. | |
ATE227298T1 (de) | Phosphabenzolverbindungen und ihre verwendung als liganden für hydroformylierungskatalysatoren | |
Fu et al. | Facile transformation of a metal carbonyl to a metal carbonyl sulfide by reaction with elemental sulfur | |
ATE337325T1 (de) | Neue diphosphinverbindung, zwischenprodukte für deren herstellung, übergangsmetallkomplex enthaltend die verbindung als ligand und katalysator für asymmetrische hydrierungen, welcher den komplex enthält |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition |