DE60313053D1 - Oligomerisierung von olefinen mit einem nicht geträgerten preaktivierten festen metallocen katalysator - Google Patents

Oligomerisierung von olefinen mit einem nicht geträgerten preaktivierten festen metallocen katalysator

Info

Publication number
DE60313053D1
DE60313053D1 DE60313053T DE60313053T DE60313053D1 DE 60313053 D1 DE60313053 D1 DE 60313053D1 DE 60313053 T DE60313053 T DE 60313053T DE 60313053 T DE60313053 T DE 60313053T DE 60313053 D1 DE60313053 D1 DE 60313053D1
Authority
DE
Germany
Prior art keywords
olefines
oligomerization
supported
metallocene catalyst
solid metallocene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60313053T
Other languages
English (en)
Other versions
DE60313053T2 (de
Inventor
Vahid Bagheri
Robert E Farritor
Randall J Stolk
Andrew D Overstreet
David Eisenberg
Frederic Grzeszczak
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ineos USA LLC
Original Assignee
Ineos USA LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ineos USA LLC filed Critical Ineos USA LLC
Publication of DE60313053D1 publication Critical patent/DE60313053D1/de
Application granted granted Critical
Publication of DE60313053T2 publication Critical patent/DE60313053T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • C07C2/34—Metal-hydrocarbon complexes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
DE60313053T 2002-01-03 2003-01-02 Oligomerisierung unter Verwendung eines trägerlosen Feststoff-Metallocen-Katalysator-Systems Expired - Lifetime DE60313053T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/037,654 US6680417B2 (en) 2002-01-03 2002-01-03 Oligomerization using a solid, unsupported metallocene catalyst system
US37654 2002-01-03

Publications (2)

Publication Number Publication Date
DE60313053D1 true DE60313053D1 (de) 2007-05-24
DE60313053T2 DE60313053T2 (de) 2007-12-13

Family

ID=21895537

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60313053T Expired - Lifetime DE60313053T2 (de) 2002-01-03 2003-01-02 Oligomerisierung unter Verwendung eines trägerlosen Feststoff-Metallocen-Katalysator-Systems

Country Status (5)

Country Link
US (1) US6680417B2 (de)
EP (1) EP1325899B1 (de)
AT (1) ATE359249T1 (de)
CA (1) CA2414108C (de)
DE (1) DE60313053T2 (de)

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US7041617B2 (en) 2004-01-09 2006-05-09 Chevron Phillips Chemical Company, L.P. Catalyst compositions and polyolefins for extrusion coating applications
US6869917B2 (en) * 2002-08-16 2005-03-22 Exxonmobil Chemical Patents Inc. Functional fluid lubricant using low Noack volatility base stock fluids
US7294599B2 (en) 2004-06-25 2007-11-13 Chevron Phillips Chemical Co. Acidic activator-supports and catalysts for olefin polymerization
US7148298B2 (en) 2004-06-25 2006-12-12 Chevron Phillips Chemical Company, L.P. Polymerization catalysts for producing polymers with low levels of long chain branching
JP4731181B2 (ja) * 2005-02-21 2011-07-20 出光興産株式会社 不飽和炭化水素化合物の製造方法
WO2007077834A1 (ja) * 2005-12-28 2007-07-12 Idemitsu Kosan Co., Ltd. 金属加工用潤滑剤
US7517939B2 (en) 2006-02-02 2009-04-14 Chevron Phillips Chemical Company, Lp Polymerization catalysts for producing high molecular weight polymers with low levels of long chain branching
US7619047B2 (en) 2006-02-22 2009-11-17 Chevron Phillips Chemical Company, Lp Dual metallocene catalysts for polymerization of bimodal polymers
US7576163B2 (en) 2006-03-31 2009-08-18 Chevron Phillips Chemical Company, Lp Polymerization catalysts for producing polymers with low levels of long chain branching
US20110251445A1 (en) * 2008-11-18 2011-10-13 Kunio Takeuchi Base oil for oil drilling fluid and oil drilling fluid composition
WO2011003047A1 (en) * 2009-07-01 2011-01-06 Conocophillips Company - Ip Services Group Heterogeneous dimerization of alpha-olefins with activated metallocene complexes
US8395007B2 (en) * 2009-07-29 2013-03-12 The United States Of America As Represented By The Secretary Of The Navy Diesel and jet fuels based on the oligomerization of butene
US8969636B2 (en) 2009-07-29 2015-03-03 The United States Of America As Represented By The Secretary Of The Navy Homogeneous metallocene ziegler-natta catalysts for the oligomerization of olefins in aliphatic-hydrocarbon solvents
US9181144B2 (en) * 2009-07-29 2015-11-10 The United States Of America As Represented By The Secretary Of The Navy Diesel and jet fuels based on the oligomerization of butene
US9522854B2 (en) 2009-07-29 2016-12-20 The United States Of America As Represented By The Secretary Of The Navy Process and apparatus for the selective dimerization of terpenes and poly-alpha-olefins with a single-stage reactor and a single-stage fractionation system
US8785702B2 (en) 2009-07-29 2014-07-22 The United States Of America As Represented By The Secretary Of The Navy Turbine and diesel fuels and methods for making the same
US8912373B2 (en) 2009-07-29 2014-12-16 The United States Of America As Represented By The Secretary Of The Navy Process for the dehydration of aqueous bio-derived terminal alcohols to terminal alkenes
US8987539B1 (en) 2009-07-29 2015-03-24 The United States Of America As Represented By The Secretary Of The Navy Acyclic monoterpenes as biofuels based on linalool and method for making the same
US9649626B2 (en) * 2009-07-29 2017-05-16 The United States Of America As Represented By The Secretary Of The Navy Process for the dehydration of aqueous bio-derived terminal alcohols to terminal alkenes
US8344196B2 (en) * 2009-07-29 2013-01-01 The United States Of America As Represented By The Secretary Of The Navy Selective isomerization and oligomerization of olefin feedstocks for the production of turbine and diesel fuels
US9242226B2 (en) 2009-07-29 2016-01-26 The Government Of The United States Of America As Represented By The Secretary Of The Navy Process for the dehydration of aqueous bio-derived terminal alcohols to terminal alkenes
US8067652B2 (en) * 2009-08-13 2011-11-29 Chemtura Corporation Processes for controlling the viscosity of polyalphaolefins
RU2014118599A (ru) 2011-10-10 2015-11-20 Эксонмобил Кемикэл Пейтентс Инк. Композиции поли-альфа-олефинов и способы получения композиций поли-альфа-олефинов
US8664461B2 (en) 2012-03-19 2014-03-04 Exxonmobil Chemical Patents Inc. Catalysts for producing polyalpha-olefins and processes related thereto
WO2013162573A1 (en) * 2012-04-26 2013-10-31 The Government Of The Usa As Represented By The Secretary Of The Navy Diesel and jet fuels based on the oligomerization of butene
US8895679B2 (en) 2012-10-25 2014-11-25 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US8937139B2 (en) 2012-10-25 2015-01-20 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US9266793B2 (en) 2012-12-26 2016-02-23 Chevron Phillips Chemical Company Lp Acid-catalyzed olefin oligomerizations
US9034991B2 (en) 2013-01-29 2015-05-19 Chevron Phillips Chemical Company Lp Polymer compositions and methods of making and using same
US8877672B2 (en) 2013-01-29 2014-11-04 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US20140275664A1 (en) 2013-03-13 2014-09-18 Chevron Phillips Chemical Company Lp Processes for Preparing Low Viscosity Lubricants
CN105339334B (zh) 2013-06-28 2017-10-24 陶氏环球技术有限责任公司 用于制备轻度支化的疏水物的方法和对应的表面活性剂和其应用
US9303106B1 (en) 2014-10-17 2016-04-05 Chevron Phillips Chemical Company Lp Processes for preparing solid metallocene-based catalyst systems
CA3090994A1 (en) 2018-02-12 2019-08-15 Exxonmobil Chemical Patents Inc. Catalyst systems and processes for poly alpha-olefin having high vinylidene content
US11021553B2 (en) 2018-02-12 2021-06-01 Exxonmobil Chemical Patents Inc. Metallocene dimer selective catalysts and processes to produce poly alpha-olefin dimers
US11078308B2 (en) 2018-02-12 2021-08-03 Exxonmobil Chemical Patents Inc. Processes to produce poly alpha-olefin trimers
EP3853272A4 (de) * 2018-09-17 2022-08-24 ExxonMobil Chemical Patents Inc. Verfahren zur herstellung von polyalpha-olefin-trimeren

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US4752597A (en) 1985-12-12 1988-06-21 Exxon Chemical Patents Inc. New polymerization catalyst
US4658078A (en) 1986-08-15 1987-04-14 Shell Oil Company Vinylidene olefin process
JP2618384B2 (ja) 1986-12-27 1997-06-11 三井石油化学工業株式会社 オレフイン重合用固体触媒およびその製法
US5914376A (en) 1993-01-21 1999-06-22 Targor Gmbh Catalyst for the polymerization of olefins, process for the preparation thereof, and use thereof
DE19827323A1 (de) 1998-06-19 1999-12-23 Basf Ag Verwendung von metallocenkatalysiert hergestellten Oligodecenen als Komponenten in Schmierstoffen
AU2393000A (en) 1998-12-30 2000-07-31 Union Carbide Chemicals & Plastics Technology Corporation Preactivated unsupported catalysts and methods of using same
JP4958358B2 (ja) * 1999-09-23 2012-06-20 ビーピー・コーポレーション・ノース・アメリカ・インコーポレーテッド オリゴマーオイル及びその製造方法

Also Published As

Publication number Publication date
US20030125595A1 (en) 2003-07-03
US6680417B2 (en) 2004-01-20
DE60313053T2 (de) 2007-12-13
EP1325899A1 (de) 2003-07-09
EP1325899B1 (de) 2007-04-11
CA2414108A1 (en) 2003-07-03
ATE359249T1 (de) 2007-05-15
CA2414108C (en) 2008-10-07

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Representative=s name: GRAF VON STOSCH PATENTANWALTSGESELLSCHAFT MBH, 805