DE602005015111D1 - Verfahren zur oligomerisierung von olefinen - Google Patents
Verfahren zur oligomerisierung von olefinenInfo
- Publication number
- DE602005015111D1 DE602005015111D1 DE602005015111T DE602005015111T DE602005015111D1 DE 602005015111 D1 DE602005015111 D1 DE 602005015111D1 DE 602005015111 T DE602005015111 T DE 602005015111T DE 602005015111 T DE602005015111 T DE 602005015111T DE 602005015111 D1 DE602005015111 D1 DE 602005015111D1
- Authority
- DE
- Germany
- Prior art keywords
- oligomerizing
- olefines
- molecular sieve
- sieve catalyst
- feedstock
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7042—TON-type, e.g. Theta-1, ISI-1, KZ-2, NU-10 or ZSM-22
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7026—MFS-type, e.g. ZSM-57
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/703—MRE-type, e.g. ZSM-48
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7046—MTT-type, e.g. ZSM-23, KZ-1, ISI-4 or EU-13
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/12—Catalytic processes with crystalline alumino-silicates or with catalysts comprising molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/14—Catalytic processes with inorganic acids; with salts or anhydrides of acids
- C07C2/18—Acids of phosphorus; Salts thereof; Phosphorus oxides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/80—Mixtures of different zeolites
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Steroid Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB0412139.8A GB0412139D0 (en) | 2004-06-01 | 2004-06-01 | Olefin oligomerization process |
PCT/EP2005/005785 WO2005118512A1 (en) | 2004-06-01 | 2005-05-26 | Olefin oligomerization process |
Publications (1)
Publication Number | Publication Date |
---|---|
DE602005015111D1 true DE602005015111D1 (de) | 2009-08-06 |
Family
ID=32671359
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE602005015111T Active DE602005015111D1 (de) | 2004-06-01 | 2005-05-26 | Verfahren zur oligomerisierung von olefinen |
Country Status (7)
Country | Link |
---|---|
US (2) | US7834229B2 (de) |
EP (2) | EP1765747B1 (de) |
CN (2) | CN1960955B (de) |
AT (1) | ATE434594T1 (de) |
DE (1) | DE602005015111D1 (de) |
GB (1) | GB0412139D0 (de) |
WO (1) | WO2005118512A1 (de) |
Families Citing this family (44)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB0412151D0 (en) | 2004-06-01 | 2004-06-30 | Exxonmobil Chem Patents Inc | Olefin oligomerization process |
GB0412139D0 (en) | 2004-06-01 | 2004-06-30 | Exxonmobil Chem Patents Inc | Olefin oligomerization process |
BRPI0609156A2 (pt) * | 2005-02-28 | 2016-08-23 | Exxonmobil Res & Eng Co | método para a conversão de uma unidade do processo de oligomerização de olefina por spa, processo para a produção de um componente de mistura da faixa de ebulição de gasolina, e, método para a produção de um produto na faixa de ebulição de gasolina |
GB0512377D0 (en) | 2005-06-17 | 2005-07-27 | Exxonmobil Chem Patents Inc | Oligomerisation of olefins with zeolite catalyst |
EP2272939B1 (de) * | 2009-07-03 | 2012-09-12 | BP Corporation North America Inc. | Alken-Oligomerisierungsverfahren |
WO2011072992A1 (en) | 2009-12-15 | 2011-06-23 | Exxonmobil Chemical Patents Inc. | Temperature control of an oligomerisation process and reactor |
ES2749501T3 (es) * | 2010-05-14 | 2020-03-20 | Bp Oil Int | Procedimiento de oligomerización de alquenos |
EP2404980A1 (de) | 2010-07-08 | 2012-01-11 | Total Raffinage Marketing | Erhöhung des durchschnittlichen Molekulargewichts von Kohlenwasserstoffeinsätzen |
US20120022224A1 (en) * | 2010-07-22 | 2012-01-26 | Geraldine Tosin | Particles Including Zeolite Catalysts And Their Use In Oligomerization Processes |
WO2012033562A1 (en) * | 2010-09-07 | 2012-03-15 | Exxonmobil Chemical Patents Inc. | Extrudates including zeolite catalysts and their use in oligomerization processes |
BR112013014763A2 (pt) | 2010-12-28 | 2016-10-04 | Total Raffinage Marketing | matéria-prima de hidrocarboneto contendo nitrila, processo para a sua fabricação e seu uso |
WO2013013888A2 (en) | 2011-07-25 | 2013-01-31 | Exxonmobil Chemical Patents Inc. | Olefin oligomerization process |
WO2013013886A2 (en) | 2011-07-25 | 2013-01-31 | Exxonmobil Chemical Patents Inc. | Olefin oligomerization process |
WO2013013887A2 (en) | 2011-07-25 | 2013-01-31 | Exxonmobil Chemical Patents Inc. | Olefin oligomerization process |
US9428427B2 (en) | 2011-07-25 | 2016-08-30 | Exxonmobil Chemical Patents Inc. | Process for nitrile removal from hydrocarbon feeds |
CN103796748B (zh) | 2011-07-25 | 2016-08-17 | 埃克森美孚化学专利公司 | 集成的腈毒物吸附及解吸系统 |
WO2013104614A1 (en) | 2012-01-09 | 2013-07-18 | Total Raffinage Marketing | Method for the conversion of low boiling point olefin containing hydrocarbon feedstock |
US9663415B2 (en) | 2012-11-12 | 2017-05-30 | Uop Llc | Process for making diesel by oligomerization of gasoline |
US9522375B2 (en) | 2012-11-12 | 2016-12-20 | Uop Llc | Apparatus for fluid catalytic cracking oligomerate |
RU2015122620A (ru) * | 2012-11-12 | 2017-01-10 | Юоп Ллк | Способ олигомеризации легких олефинов |
US20140135549A1 (en) * | 2012-11-12 | 2014-05-15 | Uop Llc | Process for recovering oligomerate |
WO2014074824A1 (en) * | 2012-11-12 | 2014-05-15 | Uop Llc | Process for making propylene from oligomerization and cracking |
US9441173B2 (en) | 2012-11-12 | 2016-09-13 | Uop Llc | Process for making diesel by oligomerization |
US9834492B2 (en) * | 2012-11-12 | 2017-12-05 | Uop Llc | Process for fluid catalytic cracking oligomerate |
US9278893B2 (en) | 2012-11-12 | 2016-03-08 | Uop Llc | Process for making gasoline by oligomerization |
WO2014074856A1 (en) * | 2012-11-12 | 2014-05-15 | Uop Llc | Process for fluid catalytic cracking oligomerate |
US9914673B2 (en) * | 2012-11-12 | 2018-03-13 | Uop Llc | Process for oligomerizing light olefins |
US9644159B2 (en) | 2012-11-12 | 2017-05-09 | Uop Llc | Composition of oligomerate |
US9434891B2 (en) | 2012-11-12 | 2016-09-06 | Uop Llc | Apparatus for recovering oligomerate |
US9522373B2 (en) | 2012-11-12 | 2016-12-20 | Uop Llc | Apparatus for oligomerizing light olefins |
US10508064B2 (en) | 2012-11-12 | 2019-12-17 | Uop Llc | Process for oligomerizing gasoline without further upgrading |
US9567267B2 (en) | 2012-11-12 | 2017-02-14 | Uop Llc | Process for oligomerizing light olefins including pentenes |
US9724493B2 (en) | 2013-08-27 | 2017-08-08 | Catheter Precision, Inc. | Components and methods for balancing a catheter controller system with a counterweight |
US20150166432A1 (en) * | 2013-12-17 | 2015-06-18 | Uop Llc | Process for oligomerization of gasoline |
US9732285B2 (en) | 2013-12-17 | 2017-08-15 | Uop Llc | Process for oligomerization of gasoline to make diesel |
US9670425B2 (en) * | 2013-12-17 | 2017-06-06 | Uop Llc | Process for oligomerizing and cracking to make propylene and aromatics |
US9834495B2 (en) * | 2014-06-26 | 2017-12-05 | Uop Llc | Exotherm, conversion and selectivity management for oligomerization process |
EP3271315A1 (de) | 2015-03-20 | 2018-01-24 | ExxonMobil Chemical Patents Inc. | Verfahren zur umwandlung eines olefinhaltigen kohlenwasserstoffeinsatzes in ein oligomerisierungsprodukt oder ein hydriertes oligomerisationsprodukt |
US10184089B2 (en) | 2015-08-13 | 2019-01-22 | Invista North America S.A.R.L. | Process for the aromatization of dilute ethylene |
CN106675621B (zh) * | 2015-11-09 | 2018-04-10 | 中国石油化工股份有限公司 | 一种劣质汽油非临氢改质的方法 |
US10563135B2 (en) | 2015-12-04 | 2020-02-18 | Uop Llc | Process for producing a diesel fuel by oligomerization |
WO2018096551A1 (en) | 2016-11-25 | 2018-05-31 | Hindustan Petroleum Corporation Limited | Oligomerization process involving crystalline molecular sieve |
CN110642266B (zh) * | 2018-06-26 | 2021-03-16 | 国家能源投资集团有限责任公司 | Zsm-48分子筛及其制备方法与应用 |
KR20220083701A (ko) * | 2019-10-18 | 2022-06-20 | 이데미쓰 고산 가부시키가이샤 | 프로필렌 올리고머의 제조 방법 |
Family Cites Families (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3960978A (en) | 1974-09-05 | 1976-06-01 | Mobil Oil Corporation | Converting low molecular weight olefins over zeolites |
US4021502A (en) | 1975-02-24 | 1977-05-03 | Mobil Oil Corporation | Converting low molecular weight olefins over zeolites |
US4016218A (en) | 1975-05-29 | 1977-04-05 | Mobil Oil Corporation | Alkylation in presence of thermally modified crystalline aluminosilicate catalyst |
CA1064890A (en) | 1975-06-10 | 1979-10-23 | Mae K. Rubin | Crystalline zeolite, synthesis and use thereof |
DE2931398A1 (de) | 1979-08-02 | 1981-02-26 | Kali Chemie Pharma Gmbh | Neue 1-benzoxepin-5(2h)-on-derivate und ihre salze, verfahren und zwischenprodukte zu deren herstellung und diese verbindungen enthaltende arzneimittel |
US4440871A (en) | 1982-07-26 | 1984-04-03 | Union Carbide Corporation | Crystalline silicoaluminophosphates |
US4456781A (en) * | 1983-04-26 | 1984-06-26 | Mobil Oil Corporation | Catalytic conversion system for oligomerizing olefinic feedstock to produce heavier hydrocarbons |
US4547609A (en) * | 1983-09-19 | 1985-10-15 | Mobil Oil Corporation | Multi-stage process for the conversion of olefins into high viscosity lubricants |
US4556477A (en) | 1984-03-07 | 1985-12-03 | Mobil Oil Corporation | Highly siliceous porous crystalline material ZSM-22 and its use in catalytic dewaxing of petroleum stocks |
US4520221A (en) * | 1984-04-09 | 1985-05-28 | Mobil Oil Corporation | Process of making high VI lubes |
US4497968A (en) * | 1984-04-11 | 1985-02-05 | Mobil Oil Corporation | Multistage process for converting olefins or oxygenates to heavier hydrocarbons |
BR8506698A (pt) * | 1984-04-27 | 1986-04-15 | Atlantic Richfield Co | Processo em dois estagios para a conversao catalitica de olefinas em hidrocarbonetos superiores |
US4740645A (en) * | 1984-09-14 | 1988-04-26 | Mobil Oil Corporation | Multistage conversion of lower olefins with interreactor quenching |
US4675463A (en) * | 1986-02-05 | 1987-06-23 | Exxon Chemical Patents Inc. | Process for reducing fouling in higher olefin plants |
US4919896A (en) * | 1987-12-28 | 1990-04-24 | Mobil Oil Corporation | Multistage catalytic reactor system for production of heavy hydrocarbons |
JPH0429136Y2 (de) | 1988-07-11 | 1992-07-15 | ||
US5157201A (en) * | 1990-06-22 | 1992-10-20 | Exxon Chemical Patents Inc. | Process for adsorbing sulfur species from propylene/propane using regenerable adsorbent |
EP0625132B1 (de) * | 1992-01-30 | 1997-07-16 | Exxon Chemical Patents Inc. | Alkenoligomerisierung |
CA2137071C (en) | 1992-06-05 | 2001-12-04 | Johannes P. Verduijn | Zsm-22 zeolite |
GB9225183D0 (en) | 1992-12-02 | 1993-01-20 | British Petroleum Co Plc | Process for the production of branched olefins |
ATE176220T1 (de) | 1994-02-22 | 1999-02-15 | Exxon Chemical Patents Inc | Oligomerisierung und katalysator dafuer |
US6025533A (en) | 1998-04-10 | 2000-02-15 | Uop Llc | Oligomer production with catalytic distillation |
US6294081B1 (en) | 1998-05-26 | 2001-09-25 | Exxonmobil Chemical Patents, Inc. | Hydroprocessing with catalytic silicoaluminophosphates having an AEL structure |
US6875899B2 (en) * | 2001-02-01 | 2005-04-05 | Exxonmobil Chemical Patents Inc. | Production of higher olefins |
US7186874B2 (en) * | 2001-10-24 | 2007-03-06 | Exxonmobil Chemical Patents Inc. | Process for the oligomerization of olefins |
AR036902A1 (es) * | 2001-10-24 | 2004-10-13 | Exxonmobil Chem Patents Inc | Un proceso para la oligomerizacion de un material de alimentacion olefinico, usos de un limite en el nivel de azufre en el material de alimentacion, una mezcla oligomerica olefinica, y un ester o una composicion polimerica plastificada |
GB0412139D0 (en) | 2004-06-01 | 2004-06-30 | Exxonmobil Chem Patents Inc | Olefin oligomerization process |
GB0412151D0 (en) | 2004-06-01 | 2004-06-30 | Exxonmobil Chem Patents Inc | Olefin oligomerization process |
-
2004
- 2004-06-01 GB GBGB0412139.8A patent/GB0412139D0/en not_active Ceased
-
2005
- 2005-05-26 CN CN2005800179330A patent/CN1960955B/zh active Active
- 2005-05-26 WO PCT/EP2005/005785 patent/WO2005118512A1/en active Application Filing
- 2005-05-26 DE DE602005015111T patent/DE602005015111D1/de active Active
- 2005-05-26 EP EP05753587A patent/EP1765747B1/de active Active
- 2005-05-26 AT AT05753587T patent/ATE434594T1/de not_active IP Right Cessation
- 2005-05-26 CN CN2010105804631A patent/CN102050692B/zh active Active
- 2005-05-26 EP EP09157119.0A patent/EP2072484B1/de active Active
- 2005-05-26 US US11/596,168 patent/US7834229B2/en active Active
-
2010
- 2010-09-02 US US12/874,852 patent/US8716542B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
CN102050692A (zh) | 2011-05-11 |
EP1765747B1 (de) | 2009-06-24 |
GB0412139D0 (en) | 2004-06-30 |
CN102050692B (zh) | 2013-01-30 |
EP2072484B1 (de) | 2015-03-11 |
US7834229B2 (en) | 2010-11-16 |
ATE434594T1 (de) | 2009-07-15 |
US20080039669A1 (en) | 2008-02-14 |
US8716542B2 (en) | 2014-05-06 |
CN1960955A (zh) | 2007-05-09 |
CN1960955B (zh) | 2013-07-03 |
US20100331591A1 (en) | 2010-12-30 |
EP2072484A1 (de) | 2009-06-24 |
WO2005118512A1 (en) | 2005-12-15 |
EP1765747A1 (de) | 2007-03-28 |
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