DE602006018358D1 - Selektive oxidation von alkylbenzolen - Google Patents
Selektive oxidation von alkylbenzolenInfo
- Publication number
- DE602006018358D1 DE602006018358D1 DE602006018358T DE602006018358T DE602006018358D1 DE 602006018358 D1 DE602006018358 D1 DE 602006018358D1 DE 602006018358 T DE602006018358 T DE 602006018358T DE 602006018358 T DE602006018358 T DE 602006018358T DE 602006018358 D1 DE602006018358 D1 DE 602006018358D1
- Authority
- DE
- Germany
- Prior art keywords
- sup
- formula
- alkylbenzene
- sub
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 150000004996 alkyl benzenes Chemical class 0.000 title abstract 6
- 230000003647 oxidation Effects 0.000 title abstract 2
- 238000007254 oxidation reaction Methods 0.000 title abstract 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 abstract 2
- -1 cyclic imide Chemical class 0.000 abstract 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 2
- 150000002576 ketones Chemical class 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- NBIJDQIBCRZHFK-UHFFFAOYSA-N 1,3,5-trihydroxy-1,3,5-triazinane-2,4,6-trione Chemical compound ON1C(=O)N(O)C(=O)N(O)C1=O NBIJDQIBCRZHFK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000003277 amino group Chemical group 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 150000001768 cations Chemical class 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
- C07C409/04—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom being acyclic
- C07C409/08—Compounds containing six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B61/00—Other general methods
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/08—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by decomposition of hydroperoxides, e.g. cumene hydroperoxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
- C07C409/04—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom being acyclic
- C07C409/08—Compounds containing six-membered aromatic rings
- C07C409/10—Cumene hydroperoxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
- C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/318,731 US7326815B2 (en) | 2005-12-27 | 2005-12-27 | Selective oxidation of alkylbenzenes |
| PCT/EP2006/012323 WO2007073916A1 (en) | 2005-12-27 | 2006-12-15 | Selective oxidation of alkylbenzenes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE602006018358D1 true DE602006018358D1 (de) | 2010-12-30 |
Family
ID=36061376
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE602006018358T Active DE602006018358D1 (de) | 2005-12-27 | 2006-12-15 | Selektive oxidation von alkylbenzolen |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US7326815B2 (enExample) |
| EP (1) | EP1966114B1 (enExample) |
| JP (1) | JP2009521514A (enExample) |
| KR (1) | KR20080085062A (enExample) |
| CN (1) | CN101389586B (enExample) |
| AT (1) | ATE488487T1 (enExample) |
| DE (1) | DE602006018358D1 (enExample) |
| TW (1) | TW200736206A (enExample) |
| WO (1) | WO2007073916A1 (enExample) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7692046B2 (en) | 2007-06-21 | 2010-04-06 | Exxonmobil Chemical Patents Inc. | Heterogeneous arylalkyl oxidation promoter |
| CN101687784B (zh) * | 2007-08-22 | 2014-11-12 | 埃克森美孚化学专利公司 | 烃的氧化 |
| WO2009058527A1 (en) * | 2007-10-31 | 2009-05-07 | Exxonmobil Chemical Patents Inc. | Oxidation of hydrocarbons |
| WO2009058531A1 (en) | 2007-10-31 | 2009-05-07 | Exxonmobil Chemical Patents Inc. | Oxidation of hydrocarbons |
| EP2098504A1 (en) * | 2008-03-06 | 2009-09-09 | ExxonMobil Chemical Patents Inc. | Oxidation of hydrocarbons |
| EP2098505A1 (en) * | 2008-03-06 | 2009-09-09 | ExxonMobil Chemical Patents Inc. | Oxidation of hydrocarbons |
| CN102076648A (zh) * | 2008-08-26 | 2011-05-25 | 埃克森美孚化学专利公司 | 用于生产烷基苯氢过氧化物的方法 |
| WO2010042273A1 (en) * | 2008-10-10 | 2010-04-15 | Exxonmobil Chemical Patents Inc. | Oxidation of hydrocarbons |
| US8445730B2 (en) | 2008-10-10 | 2013-05-21 | Exxonmobil Chemical Patents Inc. | Process for producing phenol |
| KR20140015548A (ko) * | 2008-12-15 | 2014-02-06 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 알킬방향족 화합물의 산화 |
| CN105732304A (zh) * | 2009-02-26 | 2016-07-06 | 埃克森美孚化学专利公司 | 苯酚的制备方法 |
| IT1395594B1 (it) | 2009-06-29 | 2012-10-16 | Polimeri Europa Spa | Processo per la preparazione di fenolo e cicloesanone |
| CN102482211A (zh) * | 2009-08-28 | 2012-05-30 | 埃克森美孚化学专利公司 | 烃的氧化 |
| WO2011066037A1 (en) * | 2009-11-25 | 2011-06-03 | Exxonmobil Chemical Patents Inc. | Oxidation of hydrocarbons |
| CN102666482B (zh) * | 2009-11-25 | 2015-03-04 | 埃克森美孚化学专利公司 | 烃的氧化 |
| WO2012145030A1 (en) | 2011-04-19 | 2012-10-26 | Exxonmobil Chemical Patents Inc. | Process for producing phenol |
| WO2012145031A2 (en) | 2011-04-19 | 2012-10-26 | Exxonmobil Chemical Patents Inc. | Process for producing phenol |
| IT1400710B1 (it) | 2010-06-25 | 2013-06-28 | Milano Politecnico | Procedimento per l'ossidazione di idrocarburi alchilaromatici catalizzata da n-idrossiderivati |
| US8921610B2 (en) * | 2010-09-14 | 2014-12-30 | Exxonmobil Chemical Patents Inc. | Oxidation of alkylbenzenes |
| SG10201509483QA (en) | 2010-09-14 | 2015-12-30 | Exxonmobil Chem Patents Inc | Oxidation of cyclohexylbenzene |
| WO2012082229A1 (en) | 2010-12-17 | 2012-06-21 | Exxonmobil Chemical Patents Inc. | Composition comprising cyclohexylbenzene and 1 - phenyl - 1 -methylcyclopentane and use thereof in oxidation processes |
| WO2012082232A1 (en) | 2010-12-17 | 2012-06-21 | Exxonmobil Chemical Patenst Inc. | Process for producing cycloalkylaromatic compounds |
| US9388102B2 (en) | 2011-04-19 | 2016-07-12 | Exxonmobil Chemical Patents Inc. | Process for producing phenol |
| WO2013052217A2 (en) | 2011-10-07 | 2013-04-11 | Exxonmobil Chemical Patents Inc. | Mixed metal oxide catalysts and use thereof |
| WO2014043478A1 (en) | 2012-09-17 | 2014-03-20 | Exxonmobil Chemical Patents Inc. | Process for producing phenol and/or cyclohexanone from cyclohexylbenzene |
| US9272974B2 (en) | 2012-09-17 | 2016-03-01 | Exxonmobil Chemical Patents Inc. | Process for producing phenol and/or cyclohexanone from cyclohexylbenzene |
| US9062271B2 (en) | 2013-10-30 | 2015-06-23 | Chevron Oronite Technology B.V. | Process for preparing an overbased salt of a sulfurized alkyl-substituted hydroxyaromatic composition |
| US9376359B2 (en) | 2013-10-31 | 2016-06-28 | Chevron Oronite Company Llc | Process for preparing a para-linear alkyl-substituted hydroxyaromatic compound |
| US9803154B2 (en) | 2013-10-31 | 2017-10-31 | Chevron Oronite Company Llc | Process for preparing a para-branched alkyl-substituted hydroxyaromatic compound |
Family Cites Families (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2300903A1 (de) * | 1972-01-10 | 1973-08-02 | Union Carbide Corp | Verfahren zur herstellung von butylbenzolhydroperoxid und dessen verwendung zur herstellung von phenol, acetophenon und methylaethylketon |
| US4490566A (en) * | 1983-05-06 | 1984-12-25 | Mobil Oil Corporation | Production of phenol |
| US4490565A (en) * | 1983-05-06 | 1984-12-25 | Mobil Oil Corporation | Production of phenol |
| US4992606A (en) * | 1988-10-06 | 1991-02-12 | Mobil Oil Corp. | Process for preparing short chain alkyl aromatic compounds |
| US5183945A (en) * | 1991-11-18 | 1993-02-02 | Exxon Research And Engineering Company | Catalytic production of aryl alkyl hydroperoxides by manganese complexes |
| TW226011B (enExample) * | 1991-12-26 | 1994-07-01 | Sumitomo Chemical Co | |
| JP3265659B2 (ja) | 1992-06-05 | 2002-03-11 | 住友化学工業株式会社 | フェノールの精製方法 |
| TW237445B (enExample) | 1992-07-07 | 1995-01-01 | Sumitomo Chemical Co | |
| US5335774A (en) * | 1993-07-19 | 1994-08-09 | Riverwood International Corporation | Can carrier |
| US5336820A (en) * | 1993-08-11 | 1994-08-09 | Mobil Oil Corporation | Process for the alkylation of benzene-rich gasoline |
| US5504256A (en) * | 1995-03-10 | 1996-04-02 | Exxon Research And Engineering Company | Catalytic production of aryl alkyl hydroperoxides by polynuclear transition metal aggregates (LAW229) |
| ES2199340T3 (es) | 1996-02-07 | 2004-02-16 | Daicel Chemical Industries, Ltd. | Utilizacion de un sistema catalizador de oxidacion y proceso de oxidacion que recurre a este sistema. |
| US6162416A (en) * | 1996-07-12 | 2000-12-19 | Uop Llc | Zeolite beta and its use in aromatic alkylation |
| US6002057A (en) * | 1996-09-06 | 1999-12-14 | Exxon Chemical Patents Inc. | Alkylation process using zeolite beta |
| JP4756719B2 (ja) | 1997-02-17 | 2011-08-24 | ダイセル化学工業株式会社 | 酸化触媒系、酸化方法および酸化物の製造方法 |
| JP3985174B2 (ja) * | 1997-07-09 | 2007-10-03 | 三井化学株式会社 | ヒドロペルオキシド類の製造方法 |
| US6305046B1 (en) * | 1998-06-02 | 2001-10-23 | The Procter & Gamble Company | Cleaning implements having structures for retaining a sheet |
| US6051521A (en) * | 1998-08-25 | 2000-04-18 | Mobil Oil Corporation | Method of producing an aromatics alkylation catalyst |
| US6169215B1 (en) * | 1999-03-25 | 2001-01-02 | Mobil Oil Corporation | Production of phenol |
| US6169216B1 (en) * | 1999-04-22 | 2001-01-02 | Mobil Oil Corporation | Production of phenol |
| US6297406B1 (en) * | 1999-08-03 | 2001-10-02 | Mobil Oil Corporation | Production of phenol |
| DE19946888A1 (de) | 1999-09-30 | 2001-04-05 | Phenolchemie Gmbh & Co Kg | Verfahren zur Herstellung von Phenol, Aceton und Methylethylketon |
| US6410804B1 (en) * | 1999-12-21 | 2002-06-25 | Exxon Mobil Oil Corporation | Production of phenol using reactive distillation |
| DE10015880A1 (de) * | 2000-03-30 | 2001-10-11 | Creavis Tech & Innovation Gmbh | Verfahren zur Oxidation von Kohlenwasserstoffen |
| DE10015874A1 (de) * | 2000-03-30 | 2001-10-11 | Creavis Tech & Innovation Gmbh | Verfahren zur Herstellung von aromatischen Alkoholen insbesondere Phenol |
| JP2002282698A (ja) | 2001-03-29 | 2002-10-02 | Mitsui Chemicals Inc | 固体に担持したｎ−ヒドロキシフタルイミド触媒 |
| JP2003034679A (ja) | 2001-07-17 | 2003-02-07 | Daicel Chem Ind Ltd | アリールアルキルヒドロペルオキシドの製造方法 |
| CN100537031C (zh) * | 2001-12-25 | 2009-09-09 | 大赛璐化学工业株式会社 | 有机化合物的制备方法 |
| US7141703B2 (en) * | 2003-02-14 | 2006-11-28 | Shell Oil Company | Process for producing phenol and ketone using neutralizing base |
| US7282613B2 (en) * | 2003-02-14 | 2007-10-16 | Shell Oil Company | Process for producing phenol and methyl ethyl ketone |
-
2005
- 2005-12-27 US US11/318,731 patent/US7326815B2/en not_active Expired - Fee Related
-
2006
- 2006-12-13 TW TW095146692A patent/TW200736206A/zh unknown
- 2006-12-15 DE DE602006018358T patent/DE602006018358D1/de active Active
- 2006-12-15 KR KR1020087018418A patent/KR20080085062A/ko not_active Ceased
- 2006-12-15 WO PCT/EP2006/012323 patent/WO2007073916A1/en not_active Ceased
- 2006-12-15 CN CN2006800533739A patent/CN101389586B/zh not_active Expired - Fee Related
- 2006-12-15 AT AT06846991T patent/ATE488487T1/de not_active IP Right Cessation
- 2006-12-15 EP EP06846991A patent/EP1966114B1/en not_active Not-in-force
- 2006-12-15 JP JP2008547881A patent/JP2009521514A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| JP2009521514A (ja) | 2009-06-04 |
| WO2007073916A1 (en) | 2007-07-05 |
| EP1966114B1 (en) | 2010-11-17 |
| TW200736206A (en) | 2007-10-01 |
| CN101389586A (zh) | 2009-03-18 |
| US7326815B2 (en) | 2008-02-05 |
| ATE488487T1 (de) | 2010-12-15 |
| CN101389586B (zh) | 2012-06-27 |
| EP1966114A1 (en) | 2008-09-10 |
| US20070265476A1 (en) | 2007-11-15 |
| KR20080085062A (ko) | 2008-09-22 |
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