DE60120692D1 - Katalysatoren mit hoher kobaltoberfläche - Google Patents

Katalysatoren mit hoher kobaltoberfläche

Info

Publication number
DE60120692D1
DE60120692D1 DE60120692T DE60120692T DE60120692D1 DE 60120692 D1 DE60120692 D1 DE 60120692D1 DE 60120692 T DE60120692 T DE 60120692T DE 60120692 T DE60120692 T DE 60120692T DE 60120692 D1 DE60120692 D1 DE 60120692D1
Authority
DE
Germany
Prior art keywords
cobalt
cobal
catalysts
solid residue
ammine complex
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60120692T
Other languages
English (en)
Other versions
DE60120692T2 (de
Inventor
Martinus Lok
Gavin Gray
James Kelly
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Johnson Matthey PLC
Original Assignee
Johnson Matthey PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB0012087A external-priority patent/GB0012087D0/en
Priority claimed from GB0019182A external-priority patent/GB0019182D0/en
Application filed by Johnson Matthey PLC filed Critical Johnson Matthey PLC
Publication of DE60120692D1 publication Critical patent/DE60120692D1/de
Application granted granted Critical
Publication of DE60120692T2 publication Critical patent/DE60120692T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/0445—Preparation; Activation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
    • C07C209/32—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
    • C07C209/32—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups
    • C07C209/36—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups by reduction of nitro groups bound to carbon atoms of six-membered aromatic rings in presence of hydrogen-containing gases and a catalyst
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/44—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers
    • C07C209/48—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers by reduction of nitriles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/392—Metal surface area
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/75—Cobalt

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
DE60120692T 2000-05-19 2001-04-23 Katalysatoren mit hoher kobaltoberfläche Expired - Lifetime DE60120692T2 (de)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
GB0012087 2000-05-19
GB0012087A GB0012087D0 (en) 2000-05-19 2000-05-19 catalysts
GB0019182 2000-08-07
GB0019182A GB0019182D0 (en) 2000-08-07 2000-08-07 Catalysts
PCT/GB2001/001811 WO2001087480A1 (en) 2000-05-19 2001-04-23 Catalysts with high cobalt surface area

Publications (2)

Publication Number Publication Date
DE60120692D1 true DE60120692D1 (de) 2006-07-27
DE60120692T2 DE60120692T2 (de) 2006-10-19

Family

ID=26244312

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60120692T Expired - Lifetime DE60120692T2 (de) 2000-05-19 2001-04-23 Katalysatoren mit hoher kobaltoberfläche

Country Status (12)

Country Link
US (4) US20030119668A1 (de)
EP (2) EP1733791A3 (de)
AT (1) ATE329690T1 (de)
AU (2) AU2001248633B2 (de)
CA (2) CA2677762C (de)
DE (1) DE60120692T2 (de)
DK (1) DK1286767T3 (de)
EA (1) EA005420B1 (de)
ES (1) ES2266186T3 (de)
NO (2) NO324625B1 (de)
TW (1) TW527215B (de)
WO (1) WO2001087480A1 (de)

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US7452844B2 (en) * 2001-05-08 2008-11-18 Süd-Chemie Inc High surface area, small crystallite size catalyst for Fischer-Tropsch synthesis
GB0222240D0 (en) * 2002-09-25 2002-10-30 Ici Plc Cobalt catalysts
US7341976B2 (en) 2002-10-16 2008-03-11 Conocophillips Company Stabilized boehmite-derived catalyst supports, catalysts, methods of making and using
WO2004035193A2 (en) 2002-10-16 2004-04-29 Conocophillips Company Fischer-tropsch processes and catalysts made from a material comprising boehmite
AU2003277409C1 (en) 2002-10-16 2009-06-25 Conocophillips Company Fischer-Tropsch processes and catalysts using stabilized supports
US7176160B2 (en) 2002-10-16 2007-02-13 Conocophillips Company Method for forming a Fischer-Tropsch catalyst using a boehmite support
US7402612B2 (en) 2002-10-16 2008-07-22 Conocophillips Company Stabilized transition alumina catalyst support from boehmite and catalysts made therefrom
WO2005046855A2 (en) 2003-10-16 2005-05-26 Conocophillips Company Silica-alumina catalyst support, catalysts made therefrom and methods of making and using same
WO2005037745A1 (en) 2003-10-16 2005-04-28 Conocophillips Company Silica-alumina catalyst support with bimodal pore distribution, catalysts, methods of making and using same
GB2410449B (en) * 2004-01-28 2008-05-21 Statoil Asa Fischer-Tropsch catalysts
GB0410408D0 (en) * 2004-05-11 2004-06-16 Johnson Matthey Plc Catalysts
US7560412B2 (en) 2004-08-14 2009-07-14 Sud-Chemie Inc. Fluid/slurry bed cobalt-alumina catalyst made by compounding and spray drying
GB0418934D0 (en) * 2004-08-25 2004-09-29 Johnson Matthey Plc Catalysts
RU2389548C2 (ru) * 2004-09-23 2010-05-20 Статоил Аса Промотированный катализатор синтеза фишера-тропша, способ его получения и способ синтеза углеводородов фишера-тропша
GB0426473D0 (en) * 2004-12-03 2005-01-05 Johnson Matthey Plc Catalysts
GB0503818D0 (en) * 2005-02-25 2005-04-06 Johnson Matthey Plc Catalysts
GB0506976D0 (en) 2005-04-06 2005-05-11 Johnson Matthey Plc Catalyst supports
GB0512791D0 (en) * 2005-06-23 2005-07-27 Johnson Matthey Plc Catalysts
US8115373B2 (en) 2005-07-06 2012-02-14 Rochester Institute Of Technology Self-regenerating particulate trap systems for emissions and methods thereof
ITMI20051410A1 (it) * 2005-07-22 2007-01-23 Eni Spa Procedimento per la preparazione di catalizzatori di fischer-tropsch ad alta stabilita' meccanica, termica e chimica
JP2008168228A (ja) * 2007-01-12 2008-07-24 Okayama Univ 未燃カーボンを用いてディーゼルエンジン排ガス中の窒素酸化物を浄化するための触媒と方法
GB2446127A (en) * 2007-01-30 2008-08-06 Gtl F1 Ag Preparation of Fischer-Tropsch Catalysts
US20100101955A1 (en) * 2008-06-18 2010-04-29 Massachusetts Institute Of Technology Catalytic materials, electrodes, and systems for water electrolysis and other electrochemical techniques
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GB2473071B (en) 2009-09-01 2013-09-11 Gtl F1 Ag Fischer-tropsch catalysts
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GB201000045D0 (en) 2010-01-04 2010-02-17 Johnson Matthey Plc Catalyst and method of catalyst manufacture
CN103249481B (zh) 2010-08-09 2015-11-25 Gtl.F1公司 费托催化剂
US9180436B1 (en) 2013-11-19 2015-11-10 Emerging Fuels Technology, Inc. Optimized fischer-tropsch catalyst
US9358526B2 (en) 2013-11-19 2016-06-07 Emerging Fuels Technology, Inc. Optimized fischer-tropsch catalyst
RU2610526C2 (ru) * 2015-06-18 2017-02-13 Открытое акционерное общество "Нефтяная компания "Роснефть" Катализатор для осуществления процесса Фишера-Тропша в компактном варианте и способ его получения (варианты)
CN111867725A (zh) * 2018-03-20 2020-10-30 国际壳牌研究有限公司 含钴催化剂的制备
US11376567B2 (en) * 2019-12-05 2022-07-05 GM Global Technology Operations LLC Methods for preparing catalytic systems
CN113717635A (zh) * 2021-08-27 2021-11-30 复旦大学 一种超疏水纳米多孔钴蓝涂层的制备方法

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Also Published As

Publication number Publication date
NO324625B1 (no) 2007-11-26
ES2266186T3 (es) 2007-03-01
EP1286767B1 (de) 2006-06-14
EP1286767A1 (de) 2003-03-05
DK1286767T3 (da) 2006-10-16
AU4863301A (en) 2001-11-26
ATE329690T1 (de) 2006-07-15
US20050266987A1 (en) 2005-12-01
CA2407110A1 (en) 2001-11-22
DE60120692T2 (de) 2006-10-19
EP1733791A2 (de) 2006-12-20
CA2407110C (en) 2009-11-24
NO20073118L (no) 2003-01-15
CA2677762A1 (en) 2001-11-22
US20030119668A1 (en) 2003-06-26
EP1733791A3 (de) 2008-04-02
TW527215B (en) 2003-04-11
US20050065025A1 (en) 2005-03-24
US7501378B2 (en) 2009-03-10
EA200201231A1 (ru) 2003-04-24
US6927190B2 (en) 2005-08-09
WO2001087480A1 (en) 2001-11-22
EA005420B1 (ru) 2005-02-24
US7368625B2 (en) 2008-05-06
US20080227633A1 (en) 2008-09-18
NO20025522D0 (no) 2002-11-18
CA2677762C (en) 2012-01-17
NO20025522L (no) 2003-01-15
AU2001248633B2 (en) 2005-07-07

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