DE60001318T2 - Verfahren zur regenerierung von reformierungskatalysatoren - Google Patents

Verfahren zur regenerierung von reformierungskatalysatoren

Info

Publication number
DE60001318T2
DE60001318T2 DE60001318T DE60001318T DE60001318T2 DE 60001318 T2 DE60001318 T2 DE 60001318T2 DE 60001318 T DE60001318 T DE 60001318T DE 60001318 T DE60001318 T DE 60001318T DE 60001318 T2 DE60001318 T2 DE 60001318T2
Authority
DE
Germany
Prior art keywords
regenerating
reforming catalysts
fuel
adjusted
methods
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE60001318T
Other languages
English (en)
Other versions
DE60001318D1 (de
Inventor
Robert Burch
Stanislaw Edmund Golunski
Barry William Luke Southward
David Wails
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Johnson Matthey PLC
Original Assignee
Johnson Matthey PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Johnson Matthey PLC filed Critical Johnson Matthey PLC
Application granted granted Critical
Publication of DE60001318D1 publication Critical patent/DE60001318D1/de
Publication of DE60001318T2 publication Critical patent/DE60001318T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
    • C01B3/326—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents characterised by the catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/02—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/06—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using steam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12—Treating with free oxygen-containing gas
    • B01J38/14—Treating with free oxygen-containing gas with control of oxygen content in oxidation gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1064—Platinum group metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1076—Copper or zinc-based catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
DE60001318T 1999-06-24 2000-06-20 Verfahren zur regenerierung von reformierungskatalysatoren Expired - Fee Related DE60001318T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB9914662.3A GB9914662D0 (en) 1999-06-24 1999-06-24 Catalysts
PCT/GB2000/002387 WO2001000524A1 (en) 1999-06-24 2000-06-20 Process for the regeneration of reforming catalysts

Publications (2)

Publication Number Publication Date
DE60001318D1 DE60001318D1 (de) 2003-03-06
DE60001318T2 true DE60001318T2 (de) 2003-08-21

Family

ID=10855898

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60001318T Expired - Fee Related DE60001318T2 (de) 1999-06-24 2000-06-20 Verfahren zur regenerierung von reformierungskatalysatoren

Country Status (9)

Country Link
US (1) US6878471B1 (de)
EP (1) EP1189833B1 (de)
JP (1) JP2003503186A (de)
AT (1) ATE231822T1 (de)
AU (1) AU5691200A (de)
CA (1) CA2377129A1 (de)
DE (1) DE60001318T2 (de)
GB (1) GB9914662D0 (de)
WO (1) WO2001000524A1 (de)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001199709A (ja) * 1999-11-12 2001-07-24 Idemitsu Kosan Co Ltd 水素製造用炭化水素組成物及びそれを用いる水素製造方法
WO2002009221A1 (en) * 2000-07-25 2002-01-31 Apollo Energy Systems, Incorporated Additives to the gas supply of fuel cells with circulating electrolytes and means to regenerate used stacks
US7025903B2 (en) * 2001-02-15 2006-04-11 Delphi Technologies, Inc. Reformer system process
JP4001723B2 (ja) * 2001-03-28 2007-10-31 本田技研工業株式会社 改質触媒装置の触媒性能回復方法
EP1306351B1 (de) * 2001-06-15 2007-09-12 Umicore AG & Co. KG Verfahren zur Herstellung eines schwefelarmen Reformatgases zur Verwendung in einem Brennstoffzellensystem
JP4039304B2 (ja) * 2003-04-18 2008-01-30 トヨタ自動車株式会社 改質触媒劣化判定装置、燃料改質装置および改質触媒劣化判定方法
US20050274104A1 (en) * 2004-06-15 2005-12-15 Leslie Bromberg Optimum regeneration of diesel particulate filters and NOx traps using fuel reformers
DE102004059647B4 (de) * 2004-12-10 2008-01-31 Webasto Ag Verfahren zum Regenerieren eines Reformers
US8115373B2 (en) 2005-07-06 2012-02-14 Rochester Institute Of Technology Self-regenerating particulate trap systems for emissions and methods thereof
JP4961769B2 (ja) * 2006-02-17 2012-06-27 株式会社豊田中央研究所 燃料電池システム
DE102006017614A1 (de) * 2006-04-12 2007-10-18 J. Eberspächer GmbH & Co. KG Brennstoffzellensystem und zugehöriges Betriebsverfahren
JP2008094681A (ja) * 2006-10-13 2008-04-24 Idemitsu Kosan Co Ltd 水素含有ガスの製造方法
US9061911B2 (en) 2008-06-09 2015-06-23 The University Of Toledo Gradiator reformer
US9358521B1 (en) 2008-12-09 2016-06-07 The University Of Toledo Robust high temperature sulfur sorbents and methods of making the same
AU2009344873A1 (en) * 2009-04-20 2011-11-10 Bp Corporation North America Inc. Process for regenerating coked particles
KR101291569B1 (ko) 2010-12-28 2013-08-08 지에스칼텍스 주식회사 연료전지 시스템 연료변환기의 개질촉매 재생방법
WO2012154042A1 (en) * 2011-05-10 2012-11-15 Biomethanol Chemie Nederland B.V. A process for catalytic steam reforming of a feedstock comprising an oxygenated hydrocarbon and a hydrocarbon
AU2019294262B2 (en) 2018-06-29 2021-11-18 Shell Internationale Research Maatschappij B.V. Electrically heated reactor and a process for gas conversions using said reactor
CN114249299B (zh) * 2021-11-09 2023-06-23 浙江思欣通氢能科技有限公司 一种富甲烷气等离子多重整反应催化剂预处理方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4083799A (en) * 1973-01-08 1978-04-11 Texaco Inc. Method of steam reforming
DE2403701A1 (de) * 1974-01-26 1975-08-07 Basf Ag Verfahren zur erzeugung von methanhaltigen gasen unter gleichzeitiger regeneration des katalysators
FR2328656A1 (fr) 1975-10-22 1977-05-20 Azote & Prod Chim Nouveau catalyseur de reformage a la vapeur
US5043518A (en) * 1989-07-31 1991-08-27 Exxon Chemical Patents Inc. Process for regenerating a catalyst and resultant regenerated catalyst and production of olefins by catalytic ether decomposition using regenerated catalyst
JPH04200640A (ja) * 1990-05-25 1992-07-21 Agency Of Ind Science & Technol メタノール改質用触媒の再生法
WO1991019888A1 (en) 1990-06-13 1991-12-26 Converter Services Corporation Automobile catalytic-converter rejuvenation by oxidation
DE4130718A1 (de) * 1991-09-14 1993-03-18 Metallgesellschaft Ag Verfahren zur erzeugung eins synthesegases fuer die methanolsynthese
US5461179A (en) 1993-07-07 1995-10-24 Raytheon Engineers & Constructors, Inc. Regeneration and stabilization of dehydrogenation catalysts
US5624964A (en) * 1995-06-06 1997-04-29 Mobil Oil Corporation Integration of steam reforming unit and cogeneration power plant
DE19725007C1 (de) * 1997-06-13 1999-03-18 Dbb Fuel Cell Engines Gmbh Verfahren zum Betrieb einer Methanolreformierungsanlage
JP3546658B2 (ja) 1997-09-03 2004-07-28 株式会社豊田中央研究所 メタノールの改質方法
JP2000351606A (ja) 1999-06-08 2000-12-19 Matsushita Electric Ind Co Ltd 燃料改質装置

Also Published As

Publication number Publication date
DE60001318D1 (de) 2003-03-06
EP1189833A1 (de) 2002-03-27
ATE231822T1 (de) 2003-02-15
AU5691200A (en) 2001-01-31
US6878471B1 (en) 2005-04-12
JP2003503186A (ja) 2003-01-28
WO2001000524A1 (en) 2001-01-04
EP1189833B1 (de) 2003-01-29
CA2377129A1 (en) 2001-01-04
GB9914662D0 (en) 1999-08-25

Similar Documents

Publication Publication Date Title
DE60001318T2 (de) Verfahren zur regenerierung von reformierungskatalysatoren
DE60224925D1 (de) Katalytisches verfahren zum reformieren von kohlenwasserstoff unter verwendung des katalysators
DE60044334D1 (de) Verwendung eines katalysators für die wasser-gas-umwandlungsreaktion, verfahren zur entfernung von krgieerzeugung aus einer brennstoffzelle
DE69912605D1 (de) Verfahren zur herstellung von kohlenwasserstoffen
NO20020587D0 (no) Kjemisk reaktor og fremgangsmåte for katalytiske reaksjoner med reaktanter i gassfase
DE69913164D1 (de) Verfahren zur herstellung von aromatischen kohlenwasserstoffen in parallelreformern
RU2011107275A (ru) Получение этанола из уксусной кислоты с использованием кобальтового катализатора
ATE266601T1 (de) Verfahren zur autothermen katalytischen dampf- reformierung
US20040091753A1 (en) Process and apparatus for removing sulfur compounds from hydrocarbon streams
CA2285224A1 (en) Slurry hydrocarbon synthesis with cyclic co purge and catalyst rejuvenation
ATE270702T1 (de) Verfahren zur katalytischen wasserstoffbehandlung von silizium enthaltendem naphtha
RU2005111977A (ru) Способ подавления гидрогенолиза суспензии катализатора и способ активации катализатора в синтезе фишера-тропша и способ получения углеводородов из синтез-газа
ATE321736T1 (de) Verfahren zur herstellung von ammoniak sowie katalysator hierzu
RS49892B (sr) Postupak za dobijanje l-fenilefrin hidrohlorida
JP4330846B2 (ja) 燃料電池システムにおいて用いられるための低硫黄改質油ガスを調製するプロセス
ATE310841T1 (de) Trägerkatalysatoren, methoden zu deren herstellung und methoden zu deren verwendung
BR9809715A (pt) Catalisador para produção de acetato vinìlico por reação de etileno, oxigênio e ácido acético e processo para produção do mesmo
RU2011129680A (ru) Регенерация катализатора фишера-тропша путем его окисления и обработки смесью карбоната аммония, гидроксида аммония и воды
DE3775672D1 (de) Verfahren zur durchfuehrung katalytischer reaktionen.
ATE438602T1 (de) Verfahren zur katalytischen alkylierung von kohlenwasserstoffen
ATE246163T1 (de) Verfahren zur herstellung von 1,1,1,3,3- pentafluorpropen und 1,1,1,3,3-pentafluorpropan
EP1400282A3 (de) Katalysatorregenerierung.
ATE199892T1 (de) Verfahren zur katalytischen, enantioselektiven reduktion von ketonen
ATE22681T1 (de) Herstellungsverfahren fuer methylformat und methanol in fluessiger phase.
DE60307844D1 (de) Verfahren zur dehydrierung eines ungesättigten kohlenwasserstoffs

Legal Events

Date Code Title Description
8339 Ceased/non-payment of the annual fee