DE597874C - Process for the production of soaps, soap substitutes and detergents - Google Patents

Process for the production of soaps, soap substitutes and detergents

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Publication number
DE597874C
DE597874C DEB144058D DEB0144058D DE597874C DE 597874 C DE597874 C DE 597874C DE B144058 D DEB144058 D DE B144058D DE B0144058 D DEB0144058 D DE B0144058D DE 597874 C DE597874 C DE 597874C
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Germany
Prior art keywords
soap
olein
soaps
detergents
production
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEB144058D
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German (de)
Inventor
Dr Mendel Burak
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Michael Ind A G
Original Assignee
Michael Ind A G
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Michael Ind A G filed Critical Michael Ind A G
Priority to DEB144058D priority Critical patent/DE597874C/en
Application granted granted Critical
Publication of DE597874C publication Critical patent/DE597874C/en
Expired legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00Compositions of detergents, not provided for by one single preceding group
    • C11D10/04Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C11D10/042Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02Water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06Metal compounds
    • C10M2201/065Sulfides; Selenides; Tellurides
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/02Well-defined aliphatic compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/02Well-defined aliphatic compounds
    • C10M2203/022Well-defined aliphatic compounds saturated
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/02Well-defined aliphatic compounds
    • C10M2203/024Well-defined aliphatic compounds unsaturated
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/04Well-defined cycloaliphatic compounds
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/102Aliphatic fractions
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/104Aromatic fractions
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/106Naphthenic fractions
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/108Residual fractions, e.g. bright stocks
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/021Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40Fatty vegetable or animal oils
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40Fatty vegetable or animal oils
    • C10M2207/404Fatty vegetable or animal oils obtained from genetically modified species
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10M2211/00Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/02Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only
    • C10M2211/022Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only aliphatic
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10M2211/00Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/06Perfluorinated compounds
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22Heterocyclic nitrogen compounds
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/221Six-membered rings containing nitrogen and carbon only
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/225Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
    • CCHEMISTRY; METALLURGY
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/225Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
    • C10M2215/226Morpholines
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/30Heterocyclic compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/22Metal working with essential removal of material, e.g. cutting, grinding or drilling
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Description

Gegenstand der Erfindung ist ein Verfahren zur Herstellung von Seifen, Seifenersatz- und Waschmitteln aller Art, insbesondere von Lösungs- und Emulgiermittelseifen, in Mischung mit Olein oder seinen Homologen und höhermolekularen Alkoholen. Das Verfahren zeichnet sich dadurch aus, daß der Gehalt an höhermolekularen Alkoholen bis zu ι 0/0 und der Gehalt an Olein oder seinen Homologen bis zu 10 o/o, berechnet auf die gesamte Menge der Seife oder Seifenersatz- oder Waschmittel, beträgt.The invention relates to a process for the production of soaps, soap substitutes and detergents of all kinds, in particular solvent and emulsifying agent soaps, in a mixture with olein or its homologues and higher molecular weight alcohols. The process is characterized in that the content of higher molecular weight alcohols is up to ι 0/0 and the content of olein or its homologues is up to 10 o / o , calculated on the total amount of soap or soap substitute or detergent.

Es ist bereits bekannt, derartige Körper in Mischung· mit Olein oder seinen Homologen und höhermolekularen Alkoholen zu bringen, wobei jedoch als unterste Grenze für die höhermolekularen Alkohole 2J/2 °/0 angegeben wird, bei welcher Grenze noch eine lösende und emulgierende Wirkung statthaben soll. Hierbei kommen jedoch beträchtliche Mengen an Olein zur Verwendung, und zwar soll die Menge des Oleins ungefähr gleich oder halb so groß sein wie die der in der Seife gebundenen Fettsäuren. Hierbei vermag eine Seife mit 50 o/o Olein lediglich etwas über das Doppelte der Oleinmenge an Kohlenwasserstoffen bzw. in Wasser unlöslichen organischen Verbindungen zu emulgieren.It is already known to bring such bodies in mixture · with olein or its homologs and higher molecular weight alcohols, but / is given 2 ° / 0 as the lowest limit for the higher molecular weight alcohols 2 J in which limit rather than have a dissolving and emulsifying action target. In this case, however, considerable amounts of olein are used, namely the amount of olein should be approximately the same as or half as large as that of the fatty acids bound in the soap. Here, a soap with 50 o / o olein is able to emulsify only slightly insoluble about twice the Oleinmenge of hydrocarbons in water or organic compounds.

Überraschenderweise hat es sich herausgestellt, daß man mit weit geringeren Mengen an höheren Alkoholen und Olein auskommt und trotzdem eine noch stärkere emulgierende Wirkung erzielt, wenn man bis zu etwa ι o/o an höheren Alkoholen 'und bis zu 10 o/0 an Olein oder seinen Homologen verwendet. Der technische Vorteil der Verwendung dieser geringen Mengen an Olein und höheren Alkoholen besteht u.a. darin, daß praktisch eine Geruchlosigkeit der Produkte möglich und das Ranzigwerden der Seife vermieden werden. Trotz des Zuzatzes von Olein bleibt die Seife fleckenlos und ansehnlich. Es ist zu bemerken, daß nicht nur die höheren Alkohole, sondern auch ihre Homologen und Derivate mit Erfolg verwendet werden kön-Surprisingly, it has been found that you can manage with much smaller amounts of higher alcohols and olein and still achieve an even stronger emulsifying effect if you use up to about ι o / o of higher alcohols and up to 10 o / 0 of olein or uses its homologue. The technical advantage of using these small amounts of olein and higher alcohols is, among other things, that the products are practically odorless and that the soap does not become rancid. Despite the addition of olein, the soap remains spotless and attractive. It should be noted that not only the higher alcohols but also their homologues and derivatives can be used with success.

B ei spiel 1Example 1

Eine Seife besteht aus 100 Teilen Kernseife mit 60 bis 64 0/0 Fettsäuregehalt, 1 Teil Olein, 0,5 Teilen Cyclohexanol. Die Seife vermag 20 Teile Terpentinöl, 10 Teile Dekahydronaphthalin, 10 Teile Vaselinöl, in haltbare Emulsion überzuführen und kann mit Erfolg zu Haushaltszwecken Verwendung finden.A soap consists of 100 parts curd soap with 60 to 64% fatty acid content, 1 part Olein, 0.5 part cyclohexanol. The soap is capable of 20 parts turpentine oil, 10 parts decahydronaphthalene, 10 parts of vaseline oil, to be converted into a long-lasting emulsion and can with Finding Success for Household Purposes.

B eisρ iel 2B eisρ iel 2

Eine Seife besteht aus 100 Teilen Kaliseife, 30 Teilen Terpentinöl, 10 Teilen Dekahydronaphthalin, 15 Teilen Vaselinöl, 8 Teilen Äthylalkohol, 9 Teilen Qlein und 1 Teil eines Derivates des Cyclohexanols, wie 2,2-Pentamethylen - 4 - oxymethyldihydrodioxol. DieseA soap consists of 100 parts potassium soap, 30 parts turpentine oil, 10 parts decahydronaphthalene, 15 parts of vaseline oil, 8 parts of ethyl alcohol, 9 parts of Qlein and 1 part of a Derivatives of cyclohexanol, such as 2,2-pentamethylene-4-oxymethyldihydrodioxole. These

*) Von dem Patentsucher ist als der Erfinder angegeben worden:*) The patent seeker stated as the inventor:

Dr. Mendel Burak in Berlin-Weißensee.Dr. Mendel Burak in Berlin-Weißensee.

Seife !kann mit gutem Erfolg für verschiedene Zwecke der Textilindustrie Verwendung finden. Soap! Can be used with good success for various Purposes of the textile industry use.

Die so hergestellten Seifen, Seifenersatzoder Waschmittel eignen sich infolge ihrer Geruchlosigkeit und der Tatsache, daß auch bei Zusatz von Olein keine Verfärbung eintritt, außer im Haushalt, der Wäscherei und Textilindustrie auch hervorragend als Lösungs- und Emulgiermittel für Fettstoffe aller Art, Mineralöle sowie als Grundlage für die Herstellung von Bohrölen, Schädlingsbekämpfungsmitteln, Saatgutbeizen, Metallputzmitteln und Holzschutzmitteln usw.The soaps, soap substitutes or detergents produced in this way are suitable because of them Odorlessness and the fact that no discoloration occurs even with the addition of olein, except in the household, laundry and textile industry also excellent as a solution and emulsifiers for fatty substances of all kinds, mineral oils and as a basis for Production of drilling oils, pesticides, seed dressings, metal cleaning agents and wood preservatives, etc.

Claims (1)

Patentanspruch.:Claim: Verfahren zur Herstellung von Seifen, Seifenersatz- und Waschmitteln aller Art, insbesondere von Lösungs- und Emulgiermittelseifen, unter Zusatz von Olein oder seinen Homologen und höhermolekularen Alkoholen, dadurch gekennzeichnet, daß der Gehalt an höhermolekularen Alkoholen bis etwa 1 0/0 und der Gehalt an Olein oder seinen Homologen bis 10 0/0, berechnet auf die Gesamtmenge, beträgt.Process for the production of soaps, soap substitutes and detergents of all kinds, in particular of solvent and emulsifying agent soaps, with the addition of olein or its homologues and higher molecular weight alcohols, characterized in that the content of higher molecular weight alcohols up to about 1 0/0 and the content of olein or its homologues up to 10 0/0, calculated on the total amount, amounts to. Berlin, gedruckt in derBerlin, printed in the
DEB144058D 1929-06-07 1929-06-08 Process for the production of soaps, soap substitutes and detergents Expired DE597874C (en)

Priority Applications (1)

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DEB144058D DE597874C (en) 1929-06-07 1929-06-08 Process for the production of soaps, soap substitutes and detergents

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE357128X 1929-06-07
DEB144058D DE597874C (en) 1929-06-07 1929-06-08 Process for the production of soaps, soap substitutes and detergents

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DE597874C true DE597874C (en) 1934-06-01

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