DE501303C - Soap substitutes, wetting and emulsifying agents - Google Patents

Soap substitutes, wetting and emulsifying agents

Info

Publication number
DE501303C
DE501303C DEB119967D DEB0119967D DE501303C DE 501303 C DE501303 C DE 501303C DE B119967 D DEB119967 D DE B119967D DE B0119967 D DEB0119967 D DE B0119967D DE 501303 C DE501303 C DE 501303C
Authority
DE
Germany
Prior art keywords
wetting
weight
parts
emulsifying agents
soap
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEB119967D
Other languages
German (de)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG
Priority to DEB119967D priority Critical patent/DE501303C/en
Priority claimed from US109606A external-priority patent/US1853414A/en
Priority claimed from US308134A external-priority patent/US1853415A/en
Application granted granted Critical
Publication of DE501303C publication Critical patent/DE501303C/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C11D10/042—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/01—Sulfonic acids
    • C07C309/28—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C309/40—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing nitro or nitroso groups bound to the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/01—Sulfonic acids
    • C07C309/28—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C309/41—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing singly-bound oxygen atoms bound to the carbon skeleton
    • C07C309/43—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing singly-bound oxygen atoms bound to the carbon skeleton having at least one of the sulfo groups bound to a carbon atom of a six-membered aromatic ring being part of a condensed ring system
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/01—Sulfonic acids
    • C07C309/28—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C309/45—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing nitrogen atoms, not being part of nitro or nitroso groups, bound to the carbon skeleton
    • C07C309/52—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing nitrogen atoms, not being part of nitro or nitroso groups, bound to the carbon skeleton the carbon skeleton being further substituted by doubly-bound oxygen atoms
    • C07C309/53—Sulfonic acids having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing nitrogen atoms, not being part of nitro or nitroso groups, bound to the carbon skeleton the carbon skeleton being further substituted by doubly-bound oxygen atoms the carbon skeleton containing carbon atoms of quinone rings
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
    • C09B67/0084—Dispersions of dyes
    • C09B67/0085—Non common dispersing agents
    • C09B67/0086—Non common dispersing agents anionic dispersing agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/30—Sulfonation products derived from lignin

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Dispersion Chemistry (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

Seifenersatz, Netz- und Emulgiermittel Es ist bekannt, daß Alkylderivate von Kohlenwasserstoffsulfosäuren starke Netzwirkung zeigen. Es wurde nun gefunden, daß ganz allgemein solche aromatische Sulfosäuren oder deren Salze, die im Kern Halogen-, Nitro-, Hydroxyl- oder Aminogruppen oder mehrere solcher Substituenten und daneben, sei es im Kern oder im Substituen= ten oder in beiden, eine oder mehrere Alkylgruppen mit mindestens drei Kohlenstoffatomen enthalten, starke Netzwirkung ausüben und wertvolle Verwendung als Benetzungsmittel, als Seifenersatz u. dgl. sowie zur Herstellung von Emulsionen organischer Flüssigkeiten, Verteilung von Farbstoffpulvern oder als Dispersionsmittel für andere Zwecke finden können. Die Verbindungen haben den Vorteil, auch in sauren Lösungen und in Gegenwart von Kalksalzen wirksam zu sein.Soap substitutes, wetting agents and emulsifiers It is known that alkyl derivatives of hydrocarbon sulfonic acids show a strong wetting effect. It has now been found that in general such aromatic sulfonic acids or their salts, which are in the core Halogen, nitro, hydroxyl or amino groups or several such substituents and in addition, be it in the nucleus or in the substituent or in both, one or more Contains alkyl groups with at least three carbon atoms, strong network effect exercise and valuable use as a wetting agent, as a soap substitute and the like. as well as for the production of emulsions of organic liquids, distribution of dye powders or as a dispersant for other purposes. Have the connections the advantage of being effective even in acidic solutions and in the presence of calcium salts be.

Als in Betracht kommende Verbindungen der genannten Art seien beispielsweise angeführt: Dibutylanilinsulfosäure, N-Diamyla-naphthylaminsulfosäure, Chlorisopropylnaphthalinsulfosäure, isopropylierte Naphtholsulfosäuren usw. und deren Salze.Compounds of the type mentioned that may be considered are, for example listed: dibutylaniline sulfonic acid, N-diamyla-naphthylamine sulfonic acid, chloroisopropylnaphthalene sulfonic acid, isopropylated naphthol sulfonic acids, etc. and their salts.

Beispiel i io Gewichtsteile des Natriumsalzes des aus a-Chlornaphthalin durch Sulfonierung und Kondensation mit Isopropylalkohol erhaltenen Produktes werden in iooo Gewichtsteilen Wasser gelöst. Eingelegte Wolle wird augenblicklich benetzt. Die genannte Lösung besitzt gutes Schaumö vermögen.Example 10 parts by weight of the sodium salt of α-chloronaphthalene product obtained by sulfonation and condensation with isopropyl alcohol dissolved in 1,000 parts by weight of water. Pickled wool is instantly wetted. The solution mentioned has good foaming capacity.

Ähnliche Eigenschaften zeigen auch die wässerigen Lösungen von Produkten, die durch Sulfonierung von ß-Naphthol und nachfolgende Kondensation mit aliphatischen Alkoholen mit mindestens drei Kohlenstoffatomen erhalten werden.The aqueous solutions of products show similar properties that by sulfonation of ß-naphthol and subsequent condensation with aliphatic Alcohols with at least three carbon atoms can be obtained.

Beispiel 2 ioo Gewichtsteile einer wässerigen ioprozentigen Paste von Indanthrenblau RS (Schultz, Farbstofftabellen, 1923, Nr.838) werden mit einer Lösung von i Gewichtsteil diamyl-a-naphthylaminsulfosaurem Natrium gut verrührt und getrocknet. Man erhält ein Pulver, das sehr leicht netzbar ist und sich beim Anteigen mit Wasser sehr fein verteilt. In ähnlicher Weise lassen sich andere Farbstoffe zu Pulver verarbeiten.Example 2 100 parts by weight of an aqueous 10 percent paste of indanthrene blue RS (Schultz, Farbstofftabellen, 1923, No. 838) are stirred well with a solution of 1 part by weight of sodium diamyl-a-naphthylaminesulfonate and dried. The result is a powder which is very easily wettable and which is very finely divided when pasting with water. In a similar way, other dyes can be processed into powder.

Beispiel 3 Gewichtsteile Diamyl-a-Naphthylaminsulfosäure werden in iooo Gewichtsteilen Wasser gelöst. Die erhaltene Lösung besitzt ein hohes Netzvermögen.Example 3 parts by weight of diamyl-a-naphthylamine sulfonic acid are used in iooo parts by weight of water dissolved. The solution obtained has a high wetting power.

Beispiel q.Example q.

5 Gewichtsteile eines durch Nitrierung von propylierter Naphthalinsulfosäure erhaltenen Produktes werden in 8oo Gewichtsteilen Wasser gelöst. Die erhaltene Lösung zeigt, besonders auch in Gegenwart von Säuren, ein ausgezeichnetes Netzvermögen. Beispiel 5 5 Gewichtsteile--des Näiriumsalzes einer durch Verschmelzen von Butylnaphthalinsulfosäure mit,-Alkali und nachfolgende Sulfonierung erhaltenen butylierteri Naphtholsulfosäure werden in goo Gewichtsteilen Wasser gelöst. Das obige Produkt zeigt, besonders auch in stark alkalischen Bädern, gute Netzwirkung.5 parts by weight of one obtained by nitration of propylated naphthalene sulfonic acid product obtained are dissolved in 800 parts by weight of water. The solution obtained shows excellent wetting properties, especially in the presence of acids. example 5 5 parts by weight - of the sodium salt of one obtained by fusing butylnaphthalene sulfonic acid butylated naphtholsulphonic acid obtained with alkali and subsequent sulphonation are dissolved in 100 parts by weight of water. The above product shows especially too in strongly alkaline baths, good wetting effect.

An Stelle des Natriumsalzes der genannten butylierten Naphtholsulfosäure kann man auch die entsprechende freie Säure verwenden oder auch entsprechende Mengen einer propylierten. Naphtholsulfosäure oder deren Alkalisalze.Instead of the sodium salt of the butylated naphtholsulfonic acid mentioned you can also use the corresponding free acid or corresponding amounts one propylated. Naphtholsulfonic acid or its alkali salts.

Beispiel 6 ioo Gewichtsteile eines durch Verätherung von 242 Gewichtsteilen Cetylalkohöl mit 126 Gewichtsteilen Benzylchlorid und nachfolgende Sulfonierung erhaltenen Produktes werden in 5oo Gewichtsteilen Wasser gelöst. Die erhaltene Lösung zeigt z. B. gegenüber Kresylglykolen ein gutes Emulgiervermögen.Example 6 100 parts by weight of an etherification of 242 parts by weight Cetyl alcohol with 126 parts by weight of benzyl chloride and subsequent sulfonation product obtained are dissolved in 500 parts by weight of water. The solution obtained shows e.g. B. against cresyl glycols a good emulsifying power.

Claims (1)

PATENTANSPRUCH: Seifenersatz, Netz- und Emulgiermittel, bestehend in den freien Sulfosäuren oder deren Salzen von 'aromatischen Kohlenwasserstoffen, die Halogen-, Nitro-, Hydroxyl- oder Aminogruppen oder mehrere solcher Sübstituenten und außerdem noch eine oder mehrere Alkylgruppen mit min-Bestens drei Kohlenstoffatomen, sei es im Kern, in dem Substituenten oder in beiden enthalten. Von der Patentsucherin sind als die Erfinder angegeben worden:PATENT CLAIM: Soap substitute, wetting and emulsifying agent, consisting in the free sulphonic acids or their salts of aromatic hydrocarbons, the halogen, nitro, hydroxyl or amino groups or several such substituents and one or more alkyl groups with at least three carbon atoms, be it in the core, in the substituent or in both. From the patent seeker have been given as the inventors:
DEB119967D 1925-05-22 1925-05-23 Soap substitutes, wetting and emulsifying agents Expired DE501303C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEB119967D DE501303C (en) 1925-05-22 1925-05-23 Soap substitutes, wetting and emulsifying agents

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE278752X 1925-05-22
DEB119967D DE501303C (en) 1925-05-22 1925-05-23 Soap substitutes, wetting and emulsifying agents
US109606A US1853414A (en) 1925-05-22 1926-05-17 Wetting and cleaning agents
US308134A US1853415A (en) 1925-05-22 1928-09-24 Wetting, cleaning and emulsifying agents

Publications (1)

Publication Number Publication Date
DE501303C true DE501303C (en) 1930-06-30

Family

ID=27432271

Family Applications (1)

Application Number Title Priority Date Filing Date
DEB119967D Expired DE501303C (en) 1925-05-22 1925-05-23 Soap substitutes, wetting and emulsifying agents

Country Status (1)

Country Link
DE (1) DE501303C (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE745909C (en) * 1939-07-24 1944-05-24 Ig Farbenindustrie Ag Process for dissolving metal soaps and water-insoluble fatty acids in wash baths and on textiles

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE745909C (en) * 1939-07-24 1944-05-24 Ig Farbenindustrie Ag Process for dissolving metal soaps and water-insoluble fatty acids in wash baths and on textiles

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