DE5011C - Production of decorated metal and stone surfaces - Google Patents
Production of decorated metal and stone surfacesInfo
- Publication number
- DE5011C DE5011C DENDAT5011D DE5011DA DE5011C DE 5011 C DE5011 C DE 5011C DE NDAT5011 D DENDAT5011 D DE NDAT5011D DE 5011D A DE5011D A DE 5011DA DE 5011 C DE5011 C DE 5011C
- Authority
- DE
- Germany
- Prior art keywords
- metal
- production
- copper
- stone surfaces
- decorated metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229910052751 metal Inorganic materials 0.000 title claims description 12
- 239000002184 metal Substances 0.000 title claims description 12
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 239000004575 stone Substances 0.000 title 1
- 150000003839 salts Chemical class 0.000 claims description 2
- 239000011780 sodium chloride Substances 0.000 claims description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 5
- 229910052802 copper Inorganic materials 0.000 description 5
- 239000010949 copper Substances 0.000 description 5
- 229910001369 Brass Inorganic materials 0.000 description 4
- 239000010951 brass Substances 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- 229910052725 zinc Inorganic materials 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- 239000004332 silver Substances 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- ORTQZVOHEJQUHG-UHFFFAOYSA-L Copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- -1 chlorine silver Chemical compound 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- FAPDDOBMIUGHIN-UHFFFAOYSA-K Antimony trichloride Chemical compound Cl[Sb](Cl)Cl FAPDDOBMIUGHIN-UHFFFAOYSA-K 0.000 description 1
- 239000001293 FEMA 3089 Substances 0.000 description 1
- NMCUIPGRVMDVDB-UHFFFAOYSA-L Iron(II) chloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K Iron(III) chloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 210000002374 Sebum Anatomy 0.000 description 1
- 210000003491 Skin Anatomy 0.000 description 1
- LITYQKYYGUGQLY-UHFFFAOYSA-N [Fe].O[N+]([O-])=O Chemical compound [Fe].O[N+]([O-])=O LITYQKYYGUGQLY-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive Effects 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 239000002519 antifouling agent Substances 0.000 description 1
- WXYNCCWBUXKSBG-UHFFFAOYSA-N copper;nitric acid Chemical compound [Cu].O[N+]([O-])=O WXYNCCWBUXKSBG-UHFFFAOYSA-N 0.000 description 1
- 231100000078 corrosive Toxicity 0.000 description 1
- 231100001010 corrosive Toxicity 0.000 description 1
- 229910001651 emery Inorganic materials 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000001681 protective Effects 0.000 description 1
- 238000010023 transfer printing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- ing And Chemical Polishing (AREA)
Description
1878.1878.
Klasse -48*Class -48 *
RICHARD FALK in BERLIN. Herstellung decorirter Metallfiächen.RICHARD FALK in BERLIN. Production of decorated metal surfaces.
Patentirt im Deutschen Reiche vom 15. Mai 1878 ab.Patented in the German Empire on May 15, 1878.
Die Zeichnung wird mit Fettfarbe, einem Gemisch. von Talg, Wachs und einem Farbstoff, auf den zu verzierenden Gegenstand aufgetragen. Dieses kann mit der Hand oder im Wege des Umdrucks erfolgen.The drawing is made with fat paint, a mixture. of sebum, wax and a dye, applied to the object to be decorated. This can be done by hand or im Ways of transfer printing.
Soll diese Zeichnung in blankem Metall auf dunklem Grunde erscheinen, so wende ich hiernach das weiter unten beschriebene Aetzverfahren sofort an. . *If this drawing is to appear in bare metal on a dark background, I turn to this immediately start the etching process described below. . *
Soll aber die Zeichnung farbig auf blankem Metall hervortreten, so verfahre ich folgendermafsen: Ich lege den Gegenstand in ein Bad, welches eine Lösung von Chlorsilber oder von Chlorplatin enthält nnd lasse die Flüssigkeit so lange darauf wirken, bis die freien Stellen sich mit einem Niederschlag aus obiger Lösung bedeckt zeigen. Dies vollzieht sich in der Regel in Zeit einer halben Stunde, und gilt for; Kupfer und Messing. Besteht der Gegenstand aber aus Zink oder Stahl, so mufs, derselbe vor dieser Operation in einer cyankalischen oder ammoniakalischen Kupferiösiing verkupfert worden sein. ■..)'. ■>;, If, however, the drawing is to come out in color on bare metal, I proceed as follows: I place the object in a bath which contains a solution of chlorine silver or chlorine platinum and let the liquid act on it until the free areas are covered with a precipitate above solution show covered. As a rule, this takes half an hour and applies to; Copper and brass. But if the object is made of zinc or steel, it must have been copper-plated in a cyankalic or ammoniacal copper solution before this operation. ■ ..) '. ■>;,
Sobald nun das ursprüngliche Metall mit einem Silber- oder Platinniederschlag bedeckt ist, wird der Gegenstand von der darauf haftenden Farbe gereinigt und in ein Bad gebracht, welches die Lösung eines ätzenden und färbenden Metallsalzes enthält. Zu dem Zweck verwende ich für Zink: Eisen- oder Antimonchlorid; für Kupfer und Messing: Eisenchlorid oder Kupferchlorid, letzteres mit einem Zusatz von Salzsäure; für Stahl| Kupferchlorid. Für blank herzustellende Zeichnungen in Kupfer und Messing aufserd'em noch salpetersaures Eisen und salpetersäures Kupfer.As soon as the original metal with is covered by a precipitate of silver or platinum, the object is removed from the adhering to it Paint cleaned and placed in a bath containing the solution of a corrosive and containing coloring metal salt. For this purpose I use for zinc: iron or antimony chloride; for copper and brass: ferric chloride or copper chloride, the latter with an additive of hydrochloric acid; for steel | Copper chloride. For Drawings to be produced blank in copper and brass, plus iron nitric acid and copper nitric acid.
Nach Verlauf einer Zeit von einer viertel bis einer Stunde (je nach dem ^ Metall) hat sich eine Aetzung und Färbung· aller derjenigen Theile des Metalls vollzogen, welche nicht die schützende Farbe bei der Herstellung einer blanken Zeichnung und nicht die schützende Silber- oder Platinschicht bei der Herstellung einer farbigen Zeichnung besafsen. Es tritt nun auf Zink eine schwarze, bei Kupfer eine rölhliche, bei Messing eine grünliche und auf Stahl eine graue Färbung, ein. Der so gebeizte Gegenstand wird abgespült, mittelst eines Tuches gut abgewischt und getrocknet und· nun mit Ausnahme des bereits schwarz geätzten Zinks dem Sonnenlichte ausgesetzt.After a period of a quarter to an hour (depending on the ^ metal) an etching and coloring of all those parts of the metal which are not the protective paint in making a bare drawing and not the protective silver or platinum layer during manufacture a colored drawing. Now a black appears on zinc, a redish one on copper, a greenish coloration on brass and a gray color on steel. The object stained in this way is rinsed off, wiped off well with a cloth and dried and now with With the exception of the zinc that has already been etched black, exposed to sunlight.
Das Licht ruft nun den anfänglich matten Ton erst gehörig und so intensiv hervor, dafs derselbe in eine vollkommen dunkle, schwärzliche Farbe Verwandelt und auch befestigt wird. Bei gutem Licht erfolgt diese Veränderung in Zeit von einer halben Stunde. Nun werden die Gegenstände, welche die blanke Zeichnung enthalten, mittelst eines in Terpentinöl getauchten Läppchens von der noch darauf befindlichen Farbe gereinigt, wodurch das Metall glänzend hervortritt, während dieselben in dem anderen Falle mittelst feinen Schmirgels von ihrer Silber- oder Platinhaut wieder befreit werden, wodurch ihre Oberfläche 'in der ursprünglichen Farbe ihres Metalls ebenfalls glänzend wieder erscheint. . ·The light now evokes the initially dull tone properly and so intensely that it does it is transformed into a completely dark, blackish color and also attached. In good light, this change takes half an hour. Well be the objects containing the blank drawing by means of one dipped in turpentine oil The lobule is cleaned of the paint still on it, thereby removing the metal shining, while in the other case they are made of fine emery Their silver or platinum skin can be freed again, making their surface 'in its original state The color of your metal also appears shiny again. . ·
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE5011C true DE5011C (en) |
Family
ID=283607
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT5011D Active DE5011C (en) | Production of decorated metal and stone surfaces |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE5011C (en) |
-
0
- DE DENDAT5011D patent/DE5011C/en active Active
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