DE430680C - Process for creating multicolor effects or mixed tones on the vegetable fiber - Google Patents
Process for creating multicolor effects or mixed tones on the vegetable fiberInfo
- Publication number
- DE430680C DE430680C DEC34409A DEC0034409A DE430680C DE 430680 C DE430680 C DE 430680C DE C34409 A DEC34409 A DE C34409A DE C0034409 A DEC0034409 A DE C0034409A DE 430680 C DE430680 C DE 430680C
- Authority
- DE
- Germany
- Prior art keywords
- vegetable fiber
- tones
- multicolor effects
- mixed
- effects
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 7
- 230000000694 effects Effects 0.000 title claims description 5
- 239000000835 fiber Substances 0.000 title claims description 4
- 235000013311 vegetables Nutrition 0.000 title claims description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 21
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 7
- 239000000987 azo dye Substances 0.000 claims description 6
- 239000000984 vat dye Substances 0.000 claims description 3
- 238000009835 boiling Methods 0.000 claims description 2
- 229920002678 cellulose Polymers 0.000 claims description 2
- 239000001913 cellulose Substances 0.000 claims description 2
- 238000004040 coloring Methods 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 210000002784 stomach Anatomy 0.000 claims 1
- 238000004043 dyeing Methods 0.000 description 10
- 229920000742 Cotton Polymers 0.000 description 5
- GRWZHXKQBITJKP-UHFFFAOYSA-L dithionite(2-) Chemical compound [O-]S(=O)S([O-])=O GRWZHXKQBITJKP-UHFFFAOYSA-L 0.000 description 5
- 239000000843 powder Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- AKCRQHGQIJBRMN-UHFFFAOYSA-N 2-chloroaniline Chemical compound NC1=CC=CC=C1Cl AKCRQHGQIJBRMN-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- RGCKGOZRHPZPFP-UHFFFAOYSA-N alizarin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- PFRYFZZSECNQOL-UHFFFAOYSA-N 2-methyl-4-[(2-methylphenyl)diazenyl]aniline Chemical compound C1=C(N)C(C)=CC(N=NC=2C(=CC=CC=2)C)=C1 PFRYFZZSECNQOL-UHFFFAOYSA-N 0.000 description 1
- 235000000177 Indigofera tinctoria Nutrition 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 229920001615 Tragacanth Polymers 0.000 description 1
- ZMJPCIAEJKVKMQ-UHFFFAOYSA-M [4-[[4-[benzyl(methyl)amino]phenyl]-[4-(dimethylamino)phenyl]methylidene]cyclohexa-2,5-dien-1-ylidene]-dimethylazanium;chloride Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C(C=1C=CC(=CC=1)N(C)CC=1C=CC=CC=1)=C1C=CC(=[N+](C)C)C=C1 ZMJPCIAEJKVKMQ-UHFFFAOYSA-M 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- UHOKSCJSTAHBSO-UHFFFAOYSA-N indanthrone blue Chemical compound C1=CC=C2C(=O)C3=CC=C4NC5=C6C(=O)C7=CC=CC=C7C(=O)C6=CC=C5NC4=C3C(=O)C2=C1 UHOKSCJSTAHBSO-UHFFFAOYSA-N 0.000 description 1
- 229940097275 indigo Drugs 0.000 description 1
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 1
- 210000004072 lung Anatomy 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 1
- 238000007447 staining method Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000000196 tragacanth Substances 0.000 description 1
- 229940116362 tragacanth Drugs 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/68—Preparing azo dyes on the material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
- B63B—SHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING
- B63B23/00—Equipment for handling lifeboats or the like
- B63B23/02—Davits, i.e. devices having arms for lowering boats by cables or the like
- B63B23/18—Davits, i.e. devices having arms for lowering boats by cables or the like with arms pivoting on substantially vertical axes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/0096—Multicolour dyeing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/22—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using vat dyestuffs including indigo
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/82—Textiles which contain different kinds of fibres
- D06P3/854—Textiles which contain different kinds of fibres containing modified or unmodified fibres, i.e. containing the same type of fibres having different characteristics, e.g. twisted and not-twisted fibres
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/916—Natural fiber dyeing
- Y10S8/918—Cellulose textile
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- Ocean & Marine Engineering (AREA)
- Coloring (AREA)
Description
Verfahren zur Erzeugung von blehrfarbeneffekten bzw. von Mischtönen auf der pflanzlichen Faser. Bisher war es nicht möglich, Mehrfarbeneffekte oder Mischtöne durch Überfärben der Färbungen von Azofarbstoffen mit Küpenfarbstoffen in Buntwebeartikeln bzw. auf unigefärbtem Baumwollgut zu erzeugen.Process for creating lead color effects or mixed tones on the vegetable fiber. So far it was not possible to create multicolor effects or Mixed shades by over-dyeing the dyeings of azo dyes with vat dyes to be produced in colored weave articles or on plain-colored cotton goods.
Es wurde nun .gefunden, daß sich solche Azofarbstoffe, welche gegen die Einwirkung kochender, verdünnter Natronlauge in Gegenwart von Cellulose beständig, also bauchecht sind, ohne Schädigung der ursprünglichen Färbung mit Küpenfarbstoffen übersetzen lassen, so claß auf diese Weise Mehrfarbeneffekte und Mischtöne von vorzüglicher Echtheit erhalten «-erden können.It has now been found that such azo dyes which are against resistant to the action of boiling, dilute caustic soda in the presence of cellulose, that is, they are stomach-proof, without damaging the original coloration with vat dyes Let translate, so in this way multicolored effects and mixed tones of exquisite Preserving authenticity «- being able to earth.
Bei der bekannten Unbeständigkeit der Azofarbstoffe gegen alkalische Hydrosulfitlösung ist es durchaus überraschend, daß eine solche Färbeweise möglich ist.With the known instability of azo dyes against alkaline Hydrosulfite solution, it is quite surprising that such a staining method is possible is.
Als Azofarbstoffe kommen in diesem Verfahren hauptsächlich .die durch Entwicklung auf der Faser erzeugten unlöslichen Azofarbstoffe, soweit ihre Ausfärbungen natronlaugekochecht bzw. bauchecht sind, in Betracht, z. B. Kombinationen rriit 2 - 3-Oxynaphthoesäurearyliden, wie sie in der Patentschrift 25(i999 und den auf diesem grundlegenden Patent basierenden späteren Veröffentlichungen beschrieben sind, sowie die Farbstoffe aus Acylessigsäurearyliden, welche durch die Patentschrift 386o54 und ihre Zusätze Patent 39o666, Patent 391984 und 393267 bekannt geworden sind, u. dgl. Beispiel i. Baumwollgarn, vorgefärbt nach dem Verfahren der Patentschrift 2685d.2 mit 4-Nitroi - 2-anisidin auf 2 - 3-Oxynaphthoyl-ß-naphthylamin bzw. 2 - 5-Dichloranilin auf 2 - 3-Oxynaphthoyl-o-chloranilin und neben Weiß zu Buntwebeartikeln verwebt, wird überfärbt mit 0,5 Prozent Algolbrillantviolett R (S c h u 1 t z, Farbstofftabellen, 5. Aufl. Nr. 82o), 4 ccm Natronlauge 30° Be, 2 g Hydrosulfit konz. Pulver zu i 1 Flotte, Flotte i : io, Färbetemperatur 25°, Färbedauer 31, Stunden.The azo dyes in this process are mainly the insoluble azo dyes produced by development on the fiber, insofar as their colorations are caustic soda boil-proof or stomach-proof, e.g. B. combinations rriit 2 - 3-Oxynaphthoesäurearyliden, as described in Patent Document 25 (i999 and based on this basic patent later publications, and the dyes from Acylessigsäurearyliden represented by the patent 386o54 and their accessories Patent 39o666, Patent 39 1 984 and 393267 have become known, and the like. Example i. Cotton yarn, pre-dyed according to the process of patent specification 2685d.2 with 4-nitroi-2-anisidine on 2-3-oxynaphthoyl-β-naphthylamine or 2-5-dichloroaniline on 2 - 3-oxynaphthoyl-o-chloroaniline and woven into colored weave items next to white, overdyed with 0.5 percent algol brilliant violet R (S chu 1 tz, color tables, 5th edition No. 82o), 4 ccm sodium hydroxide solution 30 ° Be, 2 g hydrosulfite concentrated powder to 1 liquor, liquor i: io, dyeing temperature 25 °, dyeing time 31 hours.
Man erhält lebhafte, satte Rot- bzw. Scharlachtöne auf hellviolettem Grund. Beispiele.Vibrant, rich red or scarlet tones are obtained on light purple Reason. Examples.
Buntgewebe aus Baumwollgarn, vorgefärbt wie in Beispiel i mit 4-Chlor-i - 2-tolttidin auf 2 - 3-Oxynaphthoyl-ß-naphthy lamin bzw. 5-Chlor-i - 2-toluidin auf 2 - 3-Oxynaphthoyl-5-chlor-2-toluidin bzw. 5-Chlor-i : 2-toluiditi auf 2 - 3-Oxvnaphthoyl-5-chlor-2-anisidin und Weiß, werden übersetzt mit i Prozent Indanthrenblau GC (S c h u 1 t z, Farbstofftabellen, 5. Aufl. Nr. 8d.3), 20 ccm Natronlauge 30° Be, 2 g Hydrosulfit konz. Pulver zu i 1 Flotte, Flotte i : io, Färbetemperatur 45 bis 6o°, Färbedauer 314 Stunden.Colored fabric made of cotton yarn, pre-dyed as in example i with 4-chloro-i - 2-tolttidine to 2 - 3-oxynaphthoyl-ß-naphthy lamin or 5-chloro-i - 2-toluidine to 2-3-oxynaphthoyl-5-chloro-2-toluidine or 5-chloro-i: 2-toluidite to 2-3-oxynaphthoyl-5-chloro-2-anisidine and white, are translated with i percent indanthrene blue GC (S c h u 1 t z, dye tables, 5th edition No. 8d.3), 20 ccm sodium hydroxide solution 30 ° Be, 2 g hydrosulfite conc. Powder to i 1 liquor, liquor i: io, dyeing temperature 45 to 60 °, dyeing time 314 hours.
Es resultieren dunkle Rot- bis Bordeauxtöne auf hellblauem Grund, Beispiel 3. The result is dark red to bordeaux tones on a light blue background, example 3.
Baumwollgut, vorgefärbt nach dem Eisfarbenverfahren mit o-Chloranilin auf Diacetessigsäure-o-toliditiic1 (Patent 386o54), wird überfärbt mit io Prozent AlgolblatT 3 G (S c h u 1 t z, Farbstofftabellen, 5. Aufl. Nr. 8.a.4), 15 ccm Natronlauge 30° Be, 3 g ITydrosulfit konz. Pulver zu 1 1 Flotte, Flotte i : io, Färbetemperatur 85°, Färbedauer 3l4 Stunden.Cotton goods, pre-dyed according to the ice color process with o-chloroaniline on diacetoacetic acid-o-toliditiic1 (patent 386o54), is overstained with 10 percent AlgolblatT 3 G (S c h u 1 t z, color tables, 5th edition No. 8.a.4), 15 ccm sodium hydroxide solution 30 ° Be, 3 g hydrosulfite conc. Powder to 1 1 liquor, liquor i: io, dyeing temperature 85 °, dyeing time 3l4 hours.
Es entstehen reine, brillante Grüntöne. Man kann auch nach dem Pflatsch-
oder Klotzverfahren (vgl. Patent 1777952) arbeiten. Beispiel Die mit o-Chloranilin
auf Diacetessigsäureo-tolidinid vorgefärbte Ware wird mit nachstehender Druckfarbe
bedruckt und getrocknet.
Man erhält ein grünes Muster auf gelbem Grund.A green pattern is obtained on a yellow background.
Beispiels. Baumwollgarn, vorgefärbt mit o-Aminoazotoluol auf Diacetessigsäure-o-tolidinid, verwebt mit Weiß zu Buntwebeartikeln,wird überfärbt mit 3 Prozent AlgolbrillantviolettR, ccm Natronlauge 30° Be, 2 g Hydrosulfit konz. Pulver zu 1 1 Flotte, Flotte i : io, Färbetemperatur 5o°, Färbedauer 3l4 Stunden.Example. Cotton thread, pre-dyed with o-aminoazotoluene on diacetoacetic acid-o-tolidinide, interweaves with white to create colored woven articles, is dyed with 3 percent Algol brilliant violetR, ccm sodium hydroxide solution 30 ° Be, 2 g hydrosulfite conc. Powder to 1 1 liquor, liquor i: io, Dyeing temperature 50 °, dyeing time 3-14 hours.
Man erhält klare Brauntöne auf hellviolettem Grund.Clear brown tones are obtained on a light purple background.
Claims (1)
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEC34409A DE430680C (en) | 1924-02-07 | 1924-02-07 | Process for creating multicolor effects or mixed tones on the vegetable fiber |
NL29056A NL11136C (en) | 1924-02-07 | 1925-01-14 | Method for preparing multi-colour effects or mixed colours on vegetable fibre |
US2604A US1594853A (en) | 1924-02-07 | 1925-01-15 | Process of producing multicolor effects on vegetable fibers and product thereof |
FR591827D FR591827A (en) | 1924-02-07 | 1925-01-21 | Process for the production of polychrome effects or combined shades on plant fiber |
GB2440/25A GB228878A (en) | 1924-02-07 | 1925-01-27 | Process of producing multi-colour effects or mixed tints or shades on vegetable fibre |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEC34409A DE430680C (en) | 1924-02-07 | 1924-02-07 | Process for creating multicolor effects or mixed tones on the vegetable fiber |
Publications (1)
Publication Number | Publication Date |
---|---|
DE430680C true DE430680C (en) | 1926-06-23 |
Family
ID=92970539
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DEC34409A Expired DE430680C (en) | 1924-02-07 | 1924-02-07 | Process for creating multicolor effects or mixed tones on the vegetable fiber |
Country Status (5)
Country | Link |
---|---|
US (1) | US1594853A (en) |
DE (1) | DE430680C (en) |
FR (1) | FR591827A (en) |
GB (1) | GB228878A (en) |
NL (1) | NL11136C (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2407247A1 (en) | 2002-07-22 | 2012-01-18 | Dürr Systems GmbH | Turbine of a rotary dispenser |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111350089A (en) * | 2020-05-09 | 2020-06-30 | 中纺院(浙江)技术研究院有限公司 | Method for dyeing mulberry silk/lyocell interwoven textile green by vegetable dye |
-
1924
- 1924-02-07 DE DEC34409A patent/DE430680C/en not_active Expired
-
1925
- 1925-01-14 NL NL29056A patent/NL11136C/en active
- 1925-01-15 US US2604A patent/US1594853A/en not_active Expired - Lifetime
- 1925-01-21 FR FR591827D patent/FR591827A/en not_active Expired
- 1925-01-27 GB GB2440/25A patent/GB228878A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2407247A1 (en) | 2002-07-22 | 2012-01-18 | Dürr Systems GmbH | Turbine of a rotary dispenser |
Also Published As
Publication number | Publication date |
---|---|
GB228878A (en) | 1925-10-15 |
US1594853A (en) | 1926-08-03 |
NL11136C (en) | 1927-06-15 |
FR591827A (en) | 1925-07-18 |
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