DE4244467A1 - Cigarettes, cartridges and cartridges containing flavor mixtures - Google Patents

Abstract

Flavour compsns. for reducing undesirable `secondary smoke' effects (see `

Description

The invention relates to cigarettes containing flavor mixtures, Tobacco cartridges (fine-cut rolls) and (filter) sleeves, these Flavor blends on the cigarette paper or tobacco cartridges coating material applied or in the pulp or cellulose mass incorporated, to reduce the amount of secondary electricity-related undesirable effects.

The expert differentiates between tobacco products to be consumed between mainstream smoke (HSR) and secondary flow smoke (NSR). HSR is by definition, the smoke generated during the train; NSR is the smoke that comes from the train break. Details or further definitions are the DIN / ISO 4387 or the work of Neurath and Ehmke: "Apparatus for the investigation of the Sidestream smoke ", published in" Contributions to tobacco schung 2 "(1964) 117-121, to which reference is made here is taken.

Cigarette smoke is naturally cigarette smoke rather than felt pleasant. There are usually exceptions to this only with smoke overlaid or aged by NSR,  so-called "cold" smoke. Its especially from not Smoking properties that are perceived as unpleasant exist in the essentially in a "stale, bad smell" and, especially in sensitive people, in the cause and desired irritation effects on the eyes and nose, the so-called "Interfering factors" are triggered.

There are therefore already ver different efforts have been made, this unpleasant Counteracting properties. Basically you have it tries to influence the smell through additives flow what was previously only possible with simultaneous taste change of the HSR was possible and an adverse narrowing of the Represents degrees of freedom in cigarette design. A typical one An example of this is given in US Pat. No. 4,638,816, according to which tobacco added additives both the tobacco taste of the HSR as well change the smell of the NSR towards vanilla; a another example is EP-A 0 294 972, according to the similar Effects using additives incorporated in the cigarette paper should be achieved.

From DE-AS 17 71 622 it is also known to the Ciga rescue paper to apply microcapsules that taste or Contain flavorings. The known microcapsules have one Diameters from 5 to 100 microns and are more convenient wise on the tobacco side of the paper. A disadvantage here is both the application form of the microcapsules, which leads to a Reduction in the porosity of the cigarette paper leads as well Size of the capsules that are up to the thickness of common cigarette papers can exceed three times. Size and arrangement of the Capsules make advantageous processing difficult from the outset Availability of such cigarette papers, since the on the Ciga rescue paper on capsules from fast-moving Ferti machines are destroyed prematurely. Furthermore, from Disadvantage that the cigarettes provided with microcapsules paper-made cigarettes when smoked as intended as is known, as well as after own attempts to undesired Stains or condensation streaks tend to form. On top of that  the flavorings used are always such that a certain smell or taste gives the actual, typical cigarette smell or taste about stores or changes.

The object of the invention is therefore a cigarette or ciga rescue sleeve as well as a tobacco cartridge or tobacco cartridges to create envelopes with increased bypass smoke acceptance, without the disadvantages of the known methods listed in Having to buy d. that is, the forming NSR of this Cigarette is said to be even after a long time pleasant tobacco, but as inconspicuous or weak as possible Develop a fragrance note, also be free of interference factors, d. H. not eye or irritate nose, and by no means the taste of the HSR from Change the desired tobacco aroma differently. It should be the same good processability of the tobacco strand used casings as well as the usual burning behavior of this cigarette to be guaranteed.

To solve this problem, an aroma mixture for ver reduction of sidestream smoke effects proposed, existing out:

• a) aldehydes selected from the group consisting of saturated, mono- and polyunsaturated aliphati alicyclic and aromatic aldehydes with 4 up to 12 carbon atoms;
• b) heterocyclic compounds containing oxygen or Nitrogen as a hetero atom and at least one hydroxy contain group or a methyl group selected from the group consisting of mono- and oligocyclic Heterocycloalkanes, heterocycloalkenes and heteroaroma ten; and
• c) vanillin (4-hydroxy-3-methoxybenzaldehyde),  and optionally
• d) alcohols selected from the group consisting of saturated, mono- and polyunsaturated aliphati , alicyclic and aromatic alcohols with 7 up to 12 carbon atoms,
• e) carboxylic acid esters of the general formula where R denotes the radical derived from carboxylic acids consisting of 2 to 8 C atoms and R ′ denotes the alkyl radical of the alkoxy group consisting of 1 to 5 C atoms,
• f) saturated carboxylic acids with 4 to 6 carbon atoms,
• g) aroma extracts,
• h) heliotropin (3,4- (methylenedioxy) benzaldehyde),
• i) maltol (3-hydroxy-2-methyl-4-pyrone),
• j) Nicotine (3- (1-methyl-2-pyrrolidinyl) pyridine).

The optional connections can be added to the said consist of aldehydes, heterocycles and vanillin the basic aroma mixture according to the invention, individually or in Combination are used, especially in ver encapsulated form, alternatively in unencapsulated form in relation points to a special, double-layer cigarette wrapper, alternatively in or on a single-layer cigarette strand wrapping can be applied.  

When selecting the flavoring substances, it was taken into account that the Distribution of volatile substances in the main and sidestream smoke other depends on physico-chemical parameters (T. Samejina et. Al. TCRC 1985). It was found that aroma substances with the common characteristic of boiling points between 80 ° C and 250 ° C, preferably between 130 ° C and 160 ° C, particularly good are suitable to achieve the effect according to the invention. In addition, this effect was also found in flavorings, the sublime or are volatile in water.

For the manufacture of tobacco products with reduced, by NSR triggered undesirable effects are such. B. tobacco cartridges (Fine cut rolls) or (filter) sleeves on which the invented Aroma mixtures according to the invention are applied, which the at the finished cigarettes made from it their advantageous Have an effect. In the case of cigarettes themselves, the aroma mixture, preferably during the manufacturing process of the finished Cigarette applied to the cigarette rod wrapper.

For cigarettes, the one with a single or double layer Contained tobacco rod wrapped cigarette rod will the flavor mixture according to the invention in encapsulated or unencapsulated encapsulated form directly onto the cigarette wrapper brings. This is done with single-layer cigarette wrappers Application of the flavorings, either in encapsulated or unencapsulated form, directly on the used cigarette paper.

In the case of cigarettes with two-ply cigarette rod wrapping the outer, visible layer of conventional cigarette paper with an air permeability of 3 to 150 CORESTA, preferably 5 to 100 CORESTA and particularly preferably 10 to 60 CORESTA. This outer layer of cigarette paper can, as with single-layer cigarette wrappers to absorb the aroma serve in unencapsulated or encapsulated form. The inner, invisible position, which consists of a highly porous Schigen cellulose fiber network (tobacco cartridge wrapping material, K paper)  or highly porous paper fleece with an air passage casualness in the untreated state, d. H. before a possible Applying flavorings or those containing flavorings Microcapsules, from 4000 to 80,000 CORESTA, preferably 10,000 up to 50,000 CORESTA, serves in a particularly preferred form as the flavoring layer. The porosity of the inner Layer is after application of the capsules by brushing or similar processes to the fine mesh cellulose fiber network or highly porous paper fleece or when incorporating the capsules into the mass of material used in papermaking, 2000 up to 30,000 CORESTA.

As a general rule for the porosity ratio to be set The values for the two layers of paper are between 1:10 and 1: 1000 µm the control of the burning behavior of the cigarette alone to guarantee the outer location.

The porous, fine-mesh cellulose fiber network (tea bag-like Paper, highly porous wrapping paper or highly porous Paper fleece) as a carrier of the encapsulated flavors can be in one Working step, d. H. by simultaneously wrapping the tobacco stocks with both papers to form the cigarette rod are processed, the porous (tea bag-like) paper or highly porous paper fleece as the inner layer of the tobacco stick wrapped and without gluing to the outer layer (cigarettes paper) in an otherwise usual manner on cigarette rod machines is proceeded. By adapting the two accordingly (hollow cylinder-like) lateral surfaces or circumferences of the two Cigarette wrappings on top of each other also result a wrinkle-free and wrinkle-free (double-layer) cigarette strip, which looks purely from a conventional cigarette strand differs. Alternatively, processing in two work steps take place. For this, for example highly porous paper fleece in one step the outer paper by lamination or gluing over the entire surface or just connected at certain points. In the second step  the strands are formed in the usual way today a cigarette rod machine.

If the cigarette rod is made using the first method Envelope made with the two separate papers can do that Applying the microcapsules to the (tea bag-like) paper or highly porous paper fleece also immediately before production on the Cigarette machine done by placing the capsule slurry on the Paper is sprayed. Suitable devices for this are on the Market available.

The advantages of an aroma mixture according to the invention can be seen of course also with a tobacco cartridge (fine cut Role) if the aroma mixture is produced on the tobacco cartridge wrapping material (tea bag-like paper or highly porous paper fleece) is applied. In an analogous way can also use an empty (filter) sleeve to make your own Cigarette by the consumer as a carrier of an aroma mixture be used.

In all cases, an aroma mixture according to the invention unencapsulated or in encapsulated form on the corresponding Paper layer applied or in the pulp or cellulose fa sermasse, which can consist of pure tobacco cellulose be working.

Results from the use of the aroma mixture according to the invention itself when inserting or applying it onto the cigarette rod wrapper - especially when using the microencapsulated form - for Production of a cigarette, tobacco cartridge according to the invention (Fine cut roll) or (filter) sleeve when glowing the finished product, d. H. the finished cigarette, a com pensation of the negative sidestream smoke properties, so that the The impression arises that there was little smoking.  

The invention is described below using examples.

example 1

Aroma blend 1

5.00% 4-hydroxy-2,5-dimethyl-3 (2H) -furanone (Furaneol®)
2.50% vanillin
4.00% heliotropin
0.15% vanitrope (= trans 2-ethoxy-5 (1-propenyl) phenol)
0.80% homofuranol
0.50% benzaldehyde
2.00% cinnamon extract
2.50% anisaldehyde
18.00% coumarin flavor, Givaudan
4.55% 1,2-propylene glycol
Residual alcohol (ethanol) content.

The above flavor mixture was made by brushing or spraying directly onto cigarette paper 1 (table 1, positions 1-3) upset. The application can be done in a separate Operation as well as directly on the cigarette machine respectively. Although part of the necessary drying process volatile flavors is lost, you get a product that when smoking, a minor assessed as significantly improved electricity smoke supplies.

Disadvantage of this application is that the flavoring substances in the course of Migrate the storage of the finished cigarette into the tobacco rod. This changes the overall effect, the main electricity smoke influenced more than desired and part of the effect of Aromas reduced on the sidestream smoke.

Example 2

The aroma mixture according to Example 1 is in a manner known per se converted to an oil-soluble form. To improve the soluble it may be useful to use small amounts of benzyl alcohol,  Use benzyl benzoate and / or triacetin. The aroma obtained is microencapsulated according to known methods. The microcapsules have a diameter of 8-30 microns, preferably 10 to 20 microns. For the hardening of the capsules z. B. tannin, but in no case form or glutaraldehyde. Of the The melting point of these capsules is higher than 150 ° C. The aroma capsules by brushing or spraying on the cigarette paper brought or incorporated into the mass of fabric. The one with this Deliver paper (Table 1, Item 4) manufactured cigarettes when smoking a significantly improved sidestream smoke. The disadvantage of this application is that the so-called when burning Condensate strips are created, which makes the product optically negative is affected (brown streaks in single-layer cigarette paper fen). A second disadvantage is depending on the capsule concentration on paper significantly increased number of moves by the melting of the capsules as the glowing zone approaches and the associated reduction in paper porosity becomes.

Example 3

The capsules described above are made in the same way as in Example 2 for a highly porous paper (Table 1, Position 5-7) used. This paper is used to make cigarettes double-layer paper wrapping. The double layer becomes

• a) by directly processing 2 papers on the cigarettes machine (table 1, position 1 and position 8),
• b) by laminating the porous paper onto a normal one Cigarette paper (table 1, position 1 and position 9) and
• c) by inserting cartridges with the porous paper are encased in commercially available cigarette tubes  reached.

As a tobacco rod, all types of commercially available today Cigarettes and the tobacco mixtures used in them be set. The use according to the invention is both based on Strand cigarettes as well as filter cigarettes with any Formats are equally effective.

The cigarettes made with these papers are considered in The sidestream was judged to be much more pleasant than normal cigarettes (Table 1). The mainstream smoke of these cigarettes is said to be very slightly different from a comparative cigarette without added flavor judged.

The cigarettes do not have different numbers of trains still strips of condensate.

Example 4

The microcapsules from Example 2 are in a slurry. The capsules usually settle down. In order to ensure a uniform dosage when coating highly porous paper - analogously to Example 3 - a medium-viscosity, stable suspension is produced with the aid of a 1-5% Na alginate solution, viscosity 350-850 mPa / s, which is applied evenly guaranteed from 0.5 to 50 g / m ² here in Example 4 of 30 g / m ² . The cigarettes made from this paper have approximately the same properties as in Example 3.

Example 5

The microcapsules from the slurry are commonly used Drying process, usually spray drying, dried and in dry form preferably in the mass of highly porous A two-ply cigarette wrapper wrapped in paper  is working. The aroma blends incorporated in this way allow one smell-less processing and save the additional work step of applying the flavor mixture to the cigarettes strand wrapping. Show cigarettes made in this way same properties as those in Example 3.

Example 6

The aroma from Example 1 is produced without solvent and encapsulated. This achieves a concentration that is beyond neatly small amounts of microcapsules for flavoring required. This will have negative effects, as in Example 2 are described, reduced in this way otherwise put cigarettes achieve the same sensory Results.  

Table 1

Overview of the papers used in the examples as carriers of the aroma mixture

Claims (17)

1. Aroma mixture to reduce undesirable secondary smoke effects, consisting of:

• a) aldehydes selected from the group consisting of saturated, mono- and polyunsaturated aliphatic, alicyclic and aromatic aldehydes having 4 to 12 carbon atoms;
• b) heterocyclic compounds which contain oxygen or nitrogen as a hetero atom and at least one hydroxyl group or a methyl group selected from the group consisting of mono- and oligocyclic heterocycloalkanes, heterocycloalkenes and heteroaromatics; and
• c) Vanillin (4-hydroxy-3-methoxybenzaldehyde).

2. Aroma mixture according to claim 1, characterized in that they continue to be alcohols selected from the group from saturated, mono- and polyunsaturated aliphati , alicyclic and aromatic alcohols with 7 to Contains 12 carbon atoms. 3. Aroma mixture according to one or both of the preceding claims, characterized in that it also contains carboxylic acid esters of the general formula contains, where R denotes the radical derived from carboxylic acids consisting of 2 to 8 carbon atoms and R 'denotes the alkyl radical of the alkoxy grouping consisting of 1 to 5 carbon atoms. 4. Flavor mixture after one, several or all of the previously going claims, characterized in that they continue contains saturated carboxylic acids with 4 to 6 carbon atoms. 5. Flavor mixture after one, several or all of the previously going claims, characterized in that they continue contains aroma extracts. 6. Flavor mixture after one, several or all of the previously going claims, characterized in that they continue contains heliotropin (3,4- (methylenedioxy) benzaldehyde). 7. Flavor mixture after one, several or all of the previously going claims, characterized in that they continue hin contains maltol (3-hydroxy-2-methyl-4-pyrone). 8. aroma mixture according to one of the preceding claims, characterized in that they continue to use nicotine (3- (1- Methyl-2-pyrrolinyl) pyridine) contains. 9. Flavor mixture after one, several or all of the previously going claims, characterized in that they are based on a highly porous cellulose fleece is applied, the one Fine-cut roll wrapped. 10. Flavor mixture after one, several or all of the previously going claims, characterized in that it relates to the Cigarette paper is applied to a cigarette. 11. Cigarette, the one with a single-layer cigarette contains wrapped tobacco rod, thereby characterized in that on the cigarette rod wrapping a  Aroma mixture according to one of claims 1 to 8 applied is. 12. Cigarette according to claim 11, characterized in that the Aroma mixture is applied in an encapsulated form. 13. Cigarette according to claim 11, characterized in that the Aroma mixture is applied in an encapsulated form. 14. Cigarette, one with a double-layer cigarette contains wrapped tobacco rod, the inner layer of the cigarette rod wrapping mentioned highly porous wrapping paper with an air permeability from 4000 to 60 000 CORESTA and the outer layer usual cigarette paper with an air permeability of 5-100 CORESTA, characterized in that on the inner layer of the double-layer cigarette wrapping one any flavor mixture applied in encapsulated form is. 15. Cigarette according to claim 14, characterized in that as Aroma mixture a mixture according to any one of claims 1-8 is used. 16. Cigarette according to claim 14 and / or 15, characterized records that the aroma mixture on the outer layer of the double-layer cigarette wrapping is applied. 17. A cigarette according to one or more of claims 14 to 16, characterized in that the aroma mixture on both Layers of the double-layer cigarette wrapping open is brought.