DE4209962C1 - - Google Patents
Info
- Publication number
- DE4209962C1 DE4209962C1 DE19924209962 DE4209962A DE4209962C1 DE 4209962 C1 DE4209962 C1 DE 4209962C1 DE 19924209962 DE19924209962 DE 19924209962 DE 4209962 A DE4209962 A DE 4209962A DE 4209962 C1 DE4209962 C1 DE 4209962C1
- Authority
- DE
- Germany
- Prior art keywords
- adsorbent
- gas
- regeneration
- adsorber
- regeneration reactor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000007789 gas Substances 0.000 claims abstract description 84
- 230000008929 regeneration Effects 0.000 claims abstract description 48
- 238000011069 regeneration method Methods 0.000 claims abstract description 48
- 238000000034 method Methods 0.000 claims abstract description 42
- 239000000463 material Substances 0.000 claims abstract description 15
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000003054 catalyst Substances 0.000 claims abstract description 11
- 239000003463 adsorbent Substances 0.000 claims description 37
- 238000001179 sorption measurement Methods 0.000 claims description 16
- 238000010438 heat treatment Methods 0.000 claims description 8
- 239000003344 environmental pollutant Substances 0.000 claims description 7
- 231100000719 pollutant Toxicity 0.000 claims description 7
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 5
- 239000003575 carbonaceous material Substances 0.000 claims description 5
- 239000000571 coke Substances 0.000 claims description 5
- 229910017604 nitric acid Inorganic materials 0.000 claims description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 3
- 230000001473 noxious effect Effects 0.000 claims description 3
- 239000012080 ambient air Substances 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 150000002367 halogens Chemical class 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 238000012546 transfer Methods 0.000 claims description 2
- 238000011144 upstream manufacturing Methods 0.000 claims description 2
- 230000001617 migratory effect Effects 0.000 claims 1
- 238000000926 separation method Methods 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 230000001172 regenerating effect Effects 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 40
- 238000001816 cooling Methods 0.000 description 12
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 11
- 238000003795 desorption Methods 0.000 description 10
- 229910021529 ammonia Inorganic materials 0.000 description 9
- 239000003245 coal Substances 0.000 description 6
- 239000003570 air Substances 0.000 description 4
- 238000007599 discharging Methods 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 3
- 238000011049 filling Methods 0.000 description 3
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000011010 flushing procedure Methods 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 230000002000 scavenging effect Effects 0.000 description 2
- 239000002253 acid Substances 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 230000005641 tunneling Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9481—Catalyst preceded by an adsorption device without catalytic function for temporary storage of contaminants, e.g. during cold start
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/0462—Temperature swing adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/06—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
- B01D53/08—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds according to the "moving bed" method
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9495—Controlling the catalytic process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/3416—Regenerating or reactivating of sorbents or filter aids comprising free carbon, e.g. activated carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/3483—Regenerating or reactivating by thermal treatment not covered by groups B01J20/3441 - B01J20/3475, e.g. by heating or cooling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/102—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/302—Sulfur oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/304—Hydrogen sulfide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/40—Nitrogen compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/40—Nitrogen compounds
- B01D2257/404—Nitrogen oxides other than dinitrogen oxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/60—Heavy metals or heavy metal compounds
- B01D2257/602—Mercury or mercury compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40083—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
- B01D2259/40088—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating
- B01D2259/4009—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating using hot gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/402—Further details for adsorption processes and devices using two beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/50—Aspects relating to the use of sorbent or filter aid materials
- B01J2220/56—Use in the form of a bed
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Combustion & Propulsion (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Treating Waste Gases (AREA)
- Separation Of Gases By Adsorption (AREA)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19924209962 DE4209962C1 (enrdf_load_stackoverflow) | 1992-03-27 | 1992-03-27 | |
PCT/EP1993/000709 WO1993019835A1 (de) | 1992-03-27 | 1993-03-24 | Verfahren zur regeneration von mit stickoxiden adsorptiv beladenem kohlenstoffhaltigem material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19924209962 DE4209962C1 (enrdf_load_stackoverflow) | 1992-03-27 | 1992-03-27 |
Publications (1)
Publication Number | Publication Date |
---|---|
DE4209962C1 true DE4209962C1 (enrdf_load_stackoverflow) | 1993-09-16 |
Family
ID=6455145
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19924209962 Expired - Fee Related DE4209962C1 (enrdf_load_stackoverflow) | 1992-03-27 | 1992-03-27 |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE4209962C1 (enrdf_load_stackoverflow) |
WO (1) | WO1993019835A1 (enrdf_load_stackoverflow) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0640375A3 (en) * | 1993-08-24 | 1995-08-23 | Hitachi Shipbuilding Eng Co | Device for adsorbing and removing NOx. |
ITMO20120234A1 (it) * | 2012-09-27 | 2014-03-28 | Bortolani Maria Elisabetta | Filtro ad adsorbimento |
JP2017537248A (ja) * | 2014-10-06 | 2017-12-14 | ビーエイチエイ アルテア,エルエルシー | ガスタービンエンジンアセンブリに使用するためのろ過システム、及びその組立方法 |
EP3900823B1 (en) * | 2020-04-21 | 2024-05-29 | Desotec NV | Method of regeneration of carbonaceous adsorbent |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114377512A (zh) * | 2021-12-24 | 2022-04-22 | 松山湖材料实验室 | 一种用于地下空间氮氧化物的净化方法及装置 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3307087A1 (de) * | 1983-03-01 | 1984-09-06 | Bergwerksverband Gmbh, 4300 Essen | Verfahren zur entfernung von stickoxiden aus diese enthaltenden gasgemischen mittels druckwechseladsorption |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3795730A (en) * | 1971-03-29 | 1974-03-05 | J Kalvinskas | Carbon adsorption-reduction process for nitric oxides |
DE2911712C2 (de) * | 1979-03-24 | 1991-10-31 | Bergwerksverband Gmbh, 4300 Essen | Verfahren zur Entfernung von Schwefeloxiden und Stickstoffoxiden aus Abgasen |
DE3039477C2 (de) * | 1979-03-24 | 1987-04-09 | Bergwerksverband Gmbh, 4300 Essen | Verfahren zur Entfernung von Schwefeloxiden und Stickstoffoxiden aus Abgasen |
DE3663452D1 (en) * | 1986-01-21 | 1989-06-29 | Adsorptionstech Lab | Process for removing nitrogen oxides and sulfur oxides from a waste gas |
DE3602710A1 (de) * | 1986-01-30 | 1987-08-06 | Petersen Hugo Verfahrenstech | Verfahren zum regenerieren von mit schwefelsaeure und mit ammoniumsulfaten beladenem koernigem kohlenstoffhaltigem adsorptionsmittel |
JPH01299642A (ja) * | 1988-05-30 | 1989-12-04 | Hitachi Zosen Corp | 低濃度窒素酸化物の吸着除去剤 |
-
1992
- 1992-03-27 DE DE19924209962 patent/DE4209962C1/de not_active Expired - Fee Related
-
1993
- 1993-03-24 WO PCT/EP1993/000709 patent/WO1993019835A1/de active Application Filing
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3307087A1 (de) * | 1983-03-01 | 1984-09-06 | Bergwerksverband Gmbh, 4300 Essen | Verfahren zur entfernung von stickoxiden aus diese enthaltenden gasgemischen mittels druckwechseladsorption |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0640375A3 (en) * | 1993-08-24 | 1995-08-23 | Hitachi Shipbuilding Eng Co | Device for adsorbing and removing NOx. |
US5635142A (en) * | 1993-08-24 | 1997-06-03 | Hitachi Zosen Corporation | NOx adsorption and removal apparatus |
ITMO20120234A1 (it) * | 2012-09-27 | 2014-03-28 | Bortolani Maria Elisabetta | Filtro ad adsorbimento |
JP2017537248A (ja) * | 2014-10-06 | 2017-12-14 | ビーエイチエイ アルテア,エルエルシー | ガスタービンエンジンアセンブリに使用するためのろ過システム、及びその組立方法 |
EP3204625A4 (en) * | 2014-10-06 | 2018-10-10 | BHA Altair, LLC | Filtration system for use in a gas turbine engine assembly and method of assembling thereof |
US10502136B2 (en) | 2014-10-06 | 2019-12-10 | Bha Altair, Llc | Filtration system for use in a gas turbine engine assembly and method of assembling thereof |
EP3900823B1 (en) * | 2020-04-21 | 2024-05-29 | Desotec NV | Method of regeneration of carbonaceous adsorbent |
Also Published As
Publication number | Publication date |
---|---|
WO1993019835A1 (de) | 1993-10-14 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8100 | Publication of the examined application without publication of unexamined application | ||
D1 | Grant (no unexamined application published) patent law 81 | ||
8364 | No opposition during term of opposition | ||
8339 | Ceased/non-payment of the annual fee |