DE4105134C1 - - Google Patents
Info
- Publication number
- DE4105134C1 DE4105134C1 DE19914105134 DE4105134A DE4105134C1 DE 4105134 C1 DE4105134 C1 DE 4105134C1 DE 19914105134 DE19914105134 DE 19914105134 DE 4105134 A DE4105134 A DE 4105134A DE 4105134 C1 DE4105134 C1 DE 4105134C1
- Authority
- DE
- Germany
- Prior art keywords
- acid
- polymer
- solution polymer
- solution
- mass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920000642 polymer Polymers 0.000 claims abstract description 39
- 239000000178 monomer Substances 0.000 claims abstract description 16
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000006386 neutralization reaction Methods 0.000 claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 12
- 150000004670 unsaturated fatty acids Chemical class 0.000 claims abstract description 12
- 238000007720 emulsion polymerization reaction Methods 0.000 claims abstract description 10
- 235000021122 unsaturated fatty acids Nutrition 0.000 claims abstract description 10
- 239000004908 Emulsion polymer Substances 0.000 claims abstract description 8
- 150000001412 amines Chemical class 0.000 claims abstract description 5
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 5
- 238000001035 drying Methods 0.000 claims abstract description 5
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 7
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 6
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 5
- 239000000194 fatty acid Substances 0.000 claims description 5
- 229930195729 fatty acid Natural products 0.000 claims description 5
- 150000004665 fatty acids Chemical class 0.000 claims description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 4
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 4
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 4
- 238000010528 free radical solution polymerization reaction Methods 0.000 claims description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 3
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims description 2
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 claims description 2
- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 claims description 2
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 2
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 claims description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- 239000001530 fumaric acid Substances 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 2
- 239000003921 oil Substances 0.000 claims description 2
- 235000019198 oils Nutrition 0.000 claims description 2
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 235000012424 soybean oil Nutrition 0.000 claims description 2
- 239000003549 soybean oil Substances 0.000 claims description 2
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 claims description 2
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 claims 1
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 claims 1
- 235000020661 alpha-linolenic acid Nutrition 0.000 claims 1
- 235000020778 linoleic acid Nutrition 0.000 claims 1
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 claims 1
- 229960004488 linolenic acid Drugs 0.000 claims 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 claims 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract description 8
- 238000000576 coating method Methods 0.000 abstract description 7
- 239000011230 binding agent Substances 0.000 abstract description 6
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 abstract description 4
- 239000004922 lacquer Substances 0.000 abstract 2
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 239000003995 emulsifying agent Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 239000002245 particle Substances 0.000 description 7
- 239000006185 dispersion Substances 0.000 description 6
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 239000004815 dispersion polymer Substances 0.000 description 4
- -1 ester unsaturated fatty acids Chemical class 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000002966 varnish Substances 0.000 description 3
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 239000012935 ammoniumperoxodisulfate Substances 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- HWCKGOZZJDHMNC-UHFFFAOYSA-M tetraethylammonium bromide Chemical compound [Br-].CC[N+](CC)(CC)CC HWCKGOZZJDHMNC-UHFFFAOYSA-M 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- HCUOEKSZWPGJIM-YBRHCDHNSA-N (e,2e)-2-hydroxyimino-6-methoxy-4-methyl-5-nitrohex-3-enamide Chemical compound COCC([N+]([O-])=O)\C(C)=C\C(=N/O)\C(N)=O HCUOEKSZWPGJIM-YBRHCDHNSA-N 0.000 description 1
- COXCGWKSEPPDAA-UHFFFAOYSA-N 2,4-dimethylpentanenitrile Chemical compound CC(C)CC(C)C#N COXCGWKSEPPDAA-UHFFFAOYSA-N 0.000 description 1
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 239000003708 ampul Substances 0.000 description 1
- 239000012874 anionic emulsifier Substances 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 229940043264 dodecyl sulfate Drugs 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid group Chemical group C(\C=C/C(=O)O)(=O)O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/003—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/02—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of acids, salts or anhydrides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F267/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated polycarboxylic acids or derivatives thereof as defined in group C08F22/00
- C08F267/02—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated polycarboxylic acids or derivatives thereof as defined in group C08F22/00 on to polymers of acids or salts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19914105134 DE4105134C1 (enrdf_load_stackoverflow) | 1991-02-15 | 1991-02-15 | |
| PCT/DE1992/000107 WO1992014763A1 (de) | 1991-02-15 | 1992-02-13 | Verfahren zur herstellung eines wässrigen, autoxidativ trocknenden emulsionspolymerisates vorzugsweise als bindemittel für lacke |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19914105134 DE4105134C1 (enrdf_load_stackoverflow) | 1991-02-15 | 1991-02-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE4105134C1 true DE4105134C1 (enrdf_load_stackoverflow) | 1992-10-08 |
Family
ID=6425391
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19914105134 Expired - Fee Related DE4105134C1 (enrdf_load_stackoverflow) | 1991-02-15 | 1991-02-15 |
Country Status (2)
| Country | Link |
|---|---|
| DE (1) | DE4105134C1 (enrdf_load_stackoverflow) |
| WO (1) | WO1992014763A1 (enrdf_load_stackoverflow) |
Cited By (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL1009254C2 (nl) * | 1998-05-25 | 1999-11-26 | Univ Eindhoven Tech | Poederverf. |
| WO2000063315A1 (de) * | 1999-04-16 | 2000-10-26 | Henkel Kommanditgesellschaft Auf Aktien | Fettchemische addukte als tackifier und bindemittel |
| CN1118495C (zh) * | 1996-02-22 | 2003-08-20 | 德克斯特公司 | 水分散性聚合物和含有该聚合物的涂料组合物 |
| US7235603B2 (en) * | 2003-04-07 | 2007-06-26 | Rohm And Haas Company | Ambient curable polymer |
| DE102007048189A1 (de) | 2007-10-08 | 2009-04-09 | Evonik Röhm Gmbh | Wässrige Dispersionen aufweisend mindestens ein Alkyd-Harz und mindestens ein Polymerisat mit mindestens einem (Meth)acrylat-Segment |
| DE102007048192A1 (de) | 2007-10-08 | 2009-04-09 | Evonik Röhm Gmbh | Emulsionspolymere, wässrige Dispersionen und Verfahren zu deren Herstellung |
| DE102008002254A1 (de) | 2008-06-06 | 2010-01-21 | Evonik Röhm Gmbh | Monomermischungen, Polymere sowie Beschichtungszusammensetzungen |
| DE102008002257A1 (de) | 2008-06-06 | 2010-01-28 | Evonik Röhm Gmbh | Wässrige Dispersionen aufweisend mindestens ein Alkyd-Harz |
| DE102008046075A1 (de) | 2008-09-08 | 2010-03-11 | Evonik Röhm Gmbh | (Meth)acrylatmonomer, Polymer sowie Beschichtungsmittel |
| DE102009001217A1 (de) | 2009-02-27 | 2010-09-02 | Evonik Röhm Gmbh | Monomermischungen, Polymere sowie Beschichtungszusammensetzungen |
| WO2010112285A1 (de) | 2009-03-30 | 2010-10-07 | Evonik Röhm Gmbh | (meth)acrylat-polymer, beschichtungsmittel, verfahren zur herstellung einer beschichtung und beschichteter gegenstand |
| DE102009001966A1 (de) | 2009-03-30 | 2010-10-07 | Evonik Röhm Gmbh | Beschichtungszusammensetzung,(Meth)acryl-Polymer und Monomermischung zur Herstellung des(Meth)acryl-Polymers |
| DE102009001965A1 (de) | 2009-03-30 | 2010-10-07 | Evonik Röhm Gmbh | Beschichtungsmittel, Verfahren zur Herstellung einer Beschichtung und beschichteter Gegenstand |
| DE102009001964A1 (de) | 2009-03-30 | 2010-10-07 | Evonik Röhm Gmbh | Multifunktionales(Meth)acryl-Polymer, Beschichtungszusammensetzung, Verfahren zur Herstellung einer Beschichtung und beschichteter Gegenstand |
| DE102009002888A1 (de) | 2009-05-07 | 2010-11-11 | Evonik Röhm Gmbh | Beschichtungsmittel, Verfahren zur Herstellung einer Beschichtung und beschichteter Gegenstand |
| DE102010029930A1 (de) | 2010-06-10 | 2011-12-15 | Evonik Röhm Gmbh | Verfahren zur Herstellung von Acetoacetoxyalkyl(meth)acrylat |
| DE102010030970A1 (de) | 2010-07-06 | 2012-01-12 | Evonik Röhm Gmbh | Zusammensetzung zur Herstellung von Polymeren, (Meth)acryl-Polymer, Beschichtungsmittel und Beschichtung |
| WO2012028627A1 (de) | 2010-09-01 | 2012-03-08 | Basf Se | Wässrige emulsionspolymerisate, deren herstellung und verwendung |
| DE102010041272A1 (de) | 2010-09-23 | 2012-03-29 | Evonik Röhm Gmbh | Beschichtungsmittel mit (Meth)acryl-Polymeren und Koaleszenzhilfsmitteln |
| WO2013083362A2 (de) | 2011-12-09 | 2013-06-13 | Evonik Industries Ag | Beschichteter verbundkörper, umfassend ein verbundmaterial |
| US8722756B2 (en) | 2010-09-01 | 2014-05-13 | Basf Se | Aqueous emulsion polymers, their preparation and use |
| DE102013223876A1 (de) | 2013-11-22 | 2015-05-28 | Evonik Industries Ag | Emulsionspolymere, wässrige Dispersionen und Verfahren zu deren Herstellung |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4330767A1 (de) * | 1993-09-10 | 1995-03-16 | Hoechst Ag | Polymermischungen mit Wasser |
| EP3088432A1 (en) * | 2015-04-27 | 2016-11-02 | ALLNEX AUSTRIA GmbH | Aqueous dispersions |
| CA3233791A1 (en) | 2021-10-04 | 2023-04-13 | Roelof Balk | Use of aqueous polymer compositions as stains for porous materials |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52102390A (en) * | 1976-02-25 | 1977-08-27 | Kansai Paint Co Ltd | Preparation of colloidal emulsions |
| EP0305795A2 (de) * | 1987-09-03 | 1989-03-08 | Vianova Kunstharz Aktiengesellschaft | Verfahren zur Herstellung von wässrigen Pfropfcopolymerisat- emulsionen und Verwendung der Emulsionen als Bindemittel für lufttrocknende wasserverdünnbare Anstrichmittel |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5425530B2 (enrdf_load_stackoverflow) * | 1974-03-28 | 1979-08-29 | ||
| US4122052A (en) * | 1976-03-09 | 1978-10-24 | Kansai Paint Company, Limited | Emulsion composition |
-
1991
- 1991-02-15 DE DE19914105134 patent/DE4105134C1/de not_active Expired - Fee Related
-
1992
- 1992-02-13 WO PCT/DE1992/000107 patent/WO1992014763A1/de active Application Filing
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| JPS52102390A (en) * | 1976-02-25 | 1977-08-27 | Kansai Paint Co Ltd | Preparation of colloidal emulsions |
| EP0305795A2 (de) * | 1987-09-03 | 1989-03-08 | Vianova Kunstharz Aktiengesellschaft | Verfahren zur Herstellung von wässrigen Pfropfcopolymerisat- emulsionen und Verwendung der Emulsionen als Bindemittel für lufttrocknende wasserverdünnbare Anstrichmittel |
Cited By (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1118495C (zh) * | 1996-02-22 | 2003-08-20 | 德克斯特公司 | 水分散性聚合物和含有该聚合物的涂料组合物 |
| NL1009254C2 (nl) * | 1998-05-25 | 1999-11-26 | Univ Eindhoven Tech | Poederverf. |
| WO2000063315A1 (de) * | 1999-04-16 | 2000-10-26 | Henkel Kommanditgesellschaft Auf Aktien | Fettchemische addukte als tackifier und bindemittel |
| US7235603B2 (en) * | 2003-04-07 | 2007-06-26 | Rohm And Haas Company | Ambient curable polymer |
| DE102007048189A1 (de) | 2007-10-08 | 2009-04-09 | Evonik Röhm Gmbh | Wässrige Dispersionen aufweisend mindestens ein Alkyd-Harz und mindestens ein Polymerisat mit mindestens einem (Meth)acrylat-Segment |
| DE102007048192A1 (de) | 2007-10-08 | 2009-04-09 | Evonik Röhm Gmbh | Emulsionspolymere, wässrige Dispersionen und Verfahren zu deren Herstellung |
| DE102008002254A1 (de) | 2008-06-06 | 2010-01-21 | Evonik Röhm Gmbh | Monomermischungen, Polymere sowie Beschichtungszusammensetzungen |
| DE102008002257A1 (de) | 2008-06-06 | 2010-01-28 | Evonik Röhm Gmbh | Wässrige Dispersionen aufweisend mindestens ein Alkyd-Harz |
| DE102008046075A1 (de) | 2008-09-08 | 2010-03-11 | Evonik Röhm Gmbh | (Meth)acrylatmonomer, Polymer sowie Beschichtungsmittel |
| DE102009001217A1 (de) | 2009-02-27 | 2010-09-02 | Evonik Röhm Gmbh | Monomermischungen, Polymere sowie Beschichtungszusammensetzungen |
| WO2010112474A1 (de) | 2009-03-30 | 2010-10-07 | Evonik Röhm Gmbh | Beschichtungszusammensetzung, (meth)acryl-polymer und monomermischung zur herstellung des (meth)acryl-polymers |
| DE102009001966A1 (de) | 2009-03-30 | 2010-10-07 | Evonik Röhm Gmbh | Beschichtungszusammensetzung,(Meth)acryl-Polymer und Monomermischung zur Herstellung des(Meth)acryl-Polymers |
| DE102009001965A1 (de) | 2009-03-30 | 2010-10-07 | Evonik Röhm Gmbh | Beschichtungsmittel, Verfahren zur Herstellung einer Beschichtung und beschichteter Gegenstand |
| WO2010112288A1 (de) | 2009-03-30 | 2010-10-07 | Evonik Röhm Gmbh | Beschichtungsmittel, verfahren zur herstellung einer beschichtung und beschichteter gegenstand |
| WO2010112285A1 (de) | 2009-03-30 | 2010-10-07 | Evonik Röhm Gmbh | (meth)acrylat-polymer, beschichtungsmittel, verfahren zur herstellung einer beschichtung und beschichteter gegenstand |
| DE102009001964A1 (de) | 2009-03-30 | 2010-10-07 | Evonik Röhm Gmbh | Multifunktionales(Meth)acryl-Polymer, Beschichtungszusammensetzung, Verfahren zur Herstellung einer Beschichtung und beschichteter Gegenstand |
| DE102009001970A1 (de) | 2009-03-30 | 2010-10-14 | Evonik Röhm Gmbh | (Meth)acrylat-Polymer, Beschichtungsmittel, Verfahren zur Herstellung einer Beschichtung und beschichteter Gegenstand |
| DE102009002888A1 (de) | 2009-05-07 | 2010-11-11 | Evonik Röhm Gmbh | Beschichtungsmittel, Verfahren zur Herstellung einer Beschichtung und beschichteter Gegenstand |
| WO2010127910A1 (de) | 2009-05-07 | 2010-11-11 | Evonik Röhm Gmbh | Beschichtungsmittel, verfahren zur herstellung einer beschichtung und beschichteter gegenstand |
| DE102010029930A1 (de) | 2010-06-10 | 2011-12-15 | Evonik Röhm Gmbh | Verfahren zur Herstellung von Acetoacetoxyalkyl(meth)acrylat |
| DE102010030970A1 (de) | 2010-07-06 | 2012-01-12 | Evonik Röhm Gmbh | Zusammensetzung zur Herstellung von Polymeren, (Meth)acryl-Polymer, Beschichtungsmittel und Beschichtung |
| WO2012004160A1 (de) | 2010-07-06 | 2012-01-12 | Evonik Röhm Gmbh | Zusammensetzung zur herstellung von polymeren, (meth)acryl-polymer, beschichtungsmittel und beschichtung |
| WO2012028627A1 (de) | 2010-09-01 | 2012-03-08 | Basf Se | Wässrige emulsionspolymerisate, deren herstellung und verwendung |
| US8722756B2 (en) | 2010-09-01 | 2014-05-13 | Basf Se | Aqueous emulsion polymers, their preparation and use |
| US9150732B2 (en) | 2010-09-01 | 2015-10-06 | Basf Se | Aqueous emulsion polymers, their preparation and use |
| DE102010041272A1 (de) | 2010-09-23 | 2012-03-29 | Evonik Röhm Gmbh | Beschichtungsmittel mit (Meth)acryl-Polymeren und Koaleszenzhilfsmitteln |
| WO2012038197A1 (de) | 2010-09-23 | 2012-03-29 | Evonik Röhm Gmbh | Beschichtungsmittel mit (meth)acryl-polymeren und koaleszenzhilfsmitteln |
| WO2013083362A2 (de) | 2011-12-09 | 2013-06-13 | Evonik Industries Ag | Beschichteter verbundkörper, umfassend ein verbundmaterial |
| DE102011088149A1 (de) | 2011-12-09 | 2013-06-13 | Evonik Industries Ag | Beschichteter Verbundkörper, umfassend ein Verbundmaterial |
| DE102013223876A1 (de) | 2013-11-22 | 2015-05-28 | Evonik Industries Ag | Emulsionspolymere, wässrige Dispersionen und Verfahren zu deren Herstellung |
Also Published As
| Publication number | Publication date |
|---|---|
| WO1992014763A1 (de) | 1992-09-03 |
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