DE3838295C2 - Method for producing a catalyst honeycomb body used for exhaust gas purification - Google Patents

Method for producing a catalyst honeycomb body used for exhaust gas purification

Info

Publication number
DE3838295C2
DE3838295C2 DE3838295A DE3838295A DE3838295C2 DE 3838295 C2 DE3838295 C2 DE 3838295C2 DE 3838295 A DE3838295 A DE 3838295A DE 3838295 A DE3838295 A DE 3838295A DE 3838295 C2 DE3838295 C2 DE 3838295C2
Authority
DE
Germany
Prior art keywords
honeycomb body
support
exhaust gas
producing
gas purification
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE3838295A
Other languages
German (de)
Other versions
DE3838295A1 (en
Inventor
Veikko Loukeinen
Reijo Lylykangas
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kemira Oyj
Original Assignee
Kemira Oyj
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kemira Oyj filed Critical Kemira Oyj
Publication of DE3838295A1 publication Critical patent/DE3838295A1/en
Application granted granted Critical
Publication of DE3838295C2 publication Critical patent/DE3838295C2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/28Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer comprising a deformed thin sheet, i.e. the layer having its entire thickness deformed out of the plane, e.g. corrugated, crumpled
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/50Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/56Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B1/00Layered products having a non-planar shape
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/10Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material
    • B32B3/12Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material characterised by a layer of regularly- arranged cells, e.g. a honeycomb structure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/266Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by an apertured layer, the apertures going through the whole thickness of the layer, e.g. expanded metal, perforated layer, slit layer regular cells B32B3/12
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/04Punching, slitting or perforating
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • F01N3/2803Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support
    • F01N3/2807Metal other than sintered metal
    • F01N3/281Metallic honeycomb monoliths made of stacked or rolled sheets, foils or plates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00Condition, form or state of the layers or laminate
    • B32B2305/02Cellular or porous
    • B32B2305/024Honeycomb
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2260/00Exhaust treating devices having provisions not otherwise provided for
    • F01N2260/18Exhaust treating devices having provisions not otherwise provided for for improving rigidity, e.g. by wings, ribs
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2330/00Structure of catalyst support or particle filter
    • F01N2330/02Metallic plates or honeycombs, e.g. superposed or rolled-up corrugated or otherwise deformed sheet metal
    • F01N2330/04Methods of manufacturing

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Toxicology (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Catalysts (AREA)
  • Exhaust Gas After Treatment (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)

Description

Die Erfindung betrifft ein Verfahren zur Herstellung eines zur Abgasreinigung dienenden Katalysatorwabenkörpers durch Bildung eines spiraligen Wabenkörpers aus abwechselnd übereinander angeordnetem gewellten und planen Folienband.The invention relates to a method for producing a catalyst honeycomb body used for exhaust gas purification Formation of a spiral honeycomb alternating stacked corrugated and flat film tape.

Bei einem bekannten Verfahren dieser Art (GB-A-20 69 364) wird der Wabenkörper zunächst aus unbeschichteten Folien­ bändern gewickelt, worauf an einer Stirnseite Schweißnähte gelegt werden, welche die Wicklung fixieren. Erst danach werden die bereits zum Wabenkörper vereinigten Folienbän­ der mit Stützmaterial und katalytisch aktivem Material beschichtet. Dabei können sich jedoch diese Materialien häufig nicht gleichmäßig auf den Folienbändern und damit im Wabenkörper verteilen.In a known method of this type (GB-A-20 69 364) the honeycomb body is initially made of uncoated films tapes, with welds on one end which fix the winding. Only after become the foil strips already combined to form the honeycomb body which is coated with support material and catalytically active material. However, these materials often cannot evenly on the foil strips and thus in the honeycomb body to distribute.

Es ist Aufgabe der Erfindung, ein gattungsgemäßes Verfah­ ren so zu verbessern, daß einerseits die Folienbänder gleichmäßig beschichtet und der Wabenkörper dennoch in sich zu einer stabilen Einheit fixiert ist.It is an object of the invention, a generic method Ren to improve so that the one hand the film tapes evenly coated and the honeycomb body still in is fixed in a stable unit.

Die Aufgabe wird bei einem gattungsgemäßen Verfahren da­ durch gelöst, daß das im voraus sowohl mit Stützmaterial als auch mit katalytisch aktivem Material beschichtete gewellte und plane Folienband einen Wabenkörper ohne Zen­ tralachse oder -blech bildet, und daß das Auflösen des Wabenkörpers und ein Aneinanderreiben der Folienbänder durch wenigstens eine durch den Wabenkörper hindurchge­ führte Stütze verhindert werden, wobei die Länge dieser Stütze 1 bis 10 mm größer als der Durchmesser des Waben­ körpers ist. The task is there in a generic method solved by that in advance with both support material as well as corrugated coated with catalytically active material and plan foil tape a honeycomb body without Zen tralachse or sheet forms, and that the dissolution of the Honeycomb body and rubbing the film strips together  through at least one through the honeycomb body led prop can be prevented, the length of this Support 1 to 10 mm larger than the diameter of the honeycomb body is.  

Man kann dies so ausführen, daß man im voraus mit einer Stützmaterial- und einer Schicht aus katalytisch aktivem Material beschichtetes planes und gewelltes Folienband so um eine Achse bestimmter Größe wickelt, daß nach dem Herausnehmen der Achse in Wabenkörpermitte ein länglicher Hohlraum gewünschter Größe verbleibt. Danach wird der Wabenkörper in ovale Form gestaucht, d. h. er hat dann im Querschnitt sog. oder "Fahr­ bahn"-Form, und der in seinem Zentrum vorhanden gewesene Hohlraum ist beseitigt. Danach wird durch den Wabenkörper eine Stütze gepreßt oder geschossen, die verhindert, daß sich der Wabenkör­ per auflöst und die Folienbänder aneinander reiben. So entsteht ein formbeständiger, starrer Körper.You can do this in such a way that ahead with a support material and a layer of flat and corrugated foil tape coated with catalytically active material around an axis certain size wraps that after removing the axle in the middle of the honeycomb body an elongated cavity of the desired size remains. Then the honeycomb body is compressed into an oval shape, d. H. he then has so-called "Fahr." orbital "shape, and the cavity present at its center is eliminated. Then the honeycomb is used to support the body pressed or shot, which prevents the honeycomb body per dissolves and rub the foil strips together. This is how it is created a dimensionally stable, rigid body.

Es besteht die Möglich­ keit, zur Herstellung des Wabenkörpers im voraus beschichtetes planes und gewelltes Folienband unmittelbar so zu einem im Quer­ schnitt runden Körper zu wickeln, daß in seinem Zentrum kein länglicher Hohlraum entsteht. Danach wird durch den Körper eine Stütze gedrückt oder geschossen, die verhindert, daß sich der Wabenkörper auflöst und sich die Folienbänder aneinander rei­ ben. So entsteht ein formbeständiger, starrer Körper. There is a possibility speed, coated in advance for the production of the honeycomb body flat and corrugated foil tape directly to one in the cross cut round body to wrap that in its center no elongated cavity is created. After that, one becomes through the body Support pressed or shot, which prevents the The honeycomb body dissolves and the film strips tear together ben. This creates a dimensionally stable, rigid body.  

Weiterhin können zwei oder mehr Stützen so durch den Wabenkörper gedrückt werden, daß sie entweder nebeneinander oder hintereinander zu liegen kommen.Furthermore two or more supports are pressed through the honeycomb body so that they either come to lie side by side or one behind the other.

Das Durchstoßen der Stützen durch den Wabenkörper kann entweder durch Drücken oder durch Schießen erfolgen. Man kann auch am Wabenkörper im voraus eine der Größe der Stütze entsprechende Öffnung, zum Beispiel durch Bohren, anbringen und anschließend eine diese Öffnung füllende Stütze einführen.Piercing the supports through the honeycomb body can either by pressing or by shooting. One can also on the honeycomb body beforehand an opening corresponding to the size of the support, for example by drilling, attaching and then one insert the support to fill this opening.

Die durch den Wabenkörper zu steckende Stütze hat im Querschnitt vorzugsweise runde, ovale, quadratische oder rechteckige Form. Die Länge der durch den Wabenkörper zu steckenden Stütze ist gleich dem Durchmesser des Körpers (runder Körper) oder gleich der Höhe des Körpers und ist um 1 bis 10 mm größer als der Wabenkörperdurchmesser bzw. die Wabenkörperhöhe.The cross-section of the support to be inserted through the honeycomb body preferably round, oval, square or rectangular shape. The length of the through the honeycomb body The support to be inserted is equal to the diameter of the body (rounder Body) or equal to the height of the body and is 1 to 10 mm larger than the honeycomb body diameter or the honeycomb body height.

Die durch den Wabenkörper gesteckte(n) Stütze(n) besteht/bestehen bevorzugt aus feuerbeständigem Stahl.The support (s) inserted through the honeycomb body exists preferably made of fire-resistant steel.

Im folgenden wird die Erfindung noch unter Bezugnahme auf die beigefügten Figuren beschrieben; es zeigen:In the following the invention will be described with reference to the attached figures described; show it:

Fig. 1 eine vorteilhafte Ausführungsform der Erfindung stirnseitig betrachtet und Fig. 1 an advantageous embodiment of the invention viewed from the front and

Fig. 2 einen Wabenkörper seitlich betrachtet. Fig. 2 laterally viewed a honeycomb body.

In Fig. 1 ist ein aus übereinander gelegtem gewellten (2) und planen (3) Folienband gewickelter Wabenkörper (1) gezeigt, der nach dem Wickeln vorzugsweise gestaucht wurde, wonach dann die Stütze (4) durch den Körper gedrückt wurde.In Fig. 1 is a corrugated of superimposed-laid (2) and plan (3) foil tape wound honeycomb body (1) is shown, which preferably has been compressed after the winding, after which the support (4) is pressed by the body.

In Fig. 2 ist ein aus übereinander gelegtem planen (3) und gewellten (2) Folienband gewickelter runder Waben­ körper (1) gezeigt, der von der Stütze (4) durchstoßen ist, deren Länge etwas größer als der Wabenkörperdurchmesser ist.In Fig. 2 a superimposed plan ( 3 ) and corrugated ( 2 ) film tape wound round honeycomb body ( 1 ) is shown, which is pierced by the support ( 4 ), the length of which is slightly larger than the honeycomb body diameter.

Claims (2)

1. Verfahren zur Herstellung eines zur Abgasreinigung dienenden Katalysatorwabenkörpers durch Bildung eines spiraligen Wabenkörpers (1) aus abwechselnd übereinander angeordnetem gewellten (2) und planen (3) Folienband, dadurch gekennzeichnet, daß das im voraus sowohl mit Stützmaterial als auch mit katalytisch aktivem Material beschichtete gewellte (2) und plane (3) Folienband einen Wabenkörper (1) ohne Zentralachse oder -blech bildet, und daß das Auflösen des Wa­ benkörpers und ein Aneinanderreiben der Folienbän­ der durch wenigstens eine durch den Wabenkörper hindurchgeführte Stütze (4) verhindert werden, wo­ bei die Länge dieser Stütze 1 bis 10 mm größer als der Durchmesser des Wabenkörpers (1) ist.1. A process for producing a catalyst honeycomb body used for exhaust gas purification by forming a spiral honeycomb body ( 1 ) from alternately arranged corrugated ( 2 ) and plan ( 3 ) film strip, characterized in that the coated in advance both with support material and with catalytically active material corrugated ( 2 ) and flat ( 3 ) film tape forms a honeycomb body ( 1 ) without a central axis or sheet, and that the dissolving of the wa benkörpers and rubbing against each other of the Folienbän by at least one through the honeycomb support ( 4 ) can be prevented where the length of this support is 1 to 10 mm larger than the diameter of the honeycomb body ( 1 ). 2. Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß die Stütze (4) durch den Wabenkörper hindurch­ geschlagen wird, oder daß für die Stütze (4) ein Loch durch den Wabenkörper gebohrt wird, in das man die Stütze (4) dann einsetzt.2. The method according to claim 1, characterized in that the support ( 4 ) is struck through the honeycomb body, or that a hole is drilled through the honeycomb body for the support ( 4 ), in which one then uses the support ( 4 ).
DE3838295A 1987-11-16 1988-11-11 Method for producing a catalyst honeycomb body used for exhaust gas purification Expired - Fee Related DE3838295C2 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FI875045A FI78161C (en) 1987-11-16 1987-11-16 FOERFARANDE FOER FRAMSTAELLNING OCH FOERSTAERKNING AV EN KATALYTCELLSTRUKTUR ANVAENDBAR FOER RENING AV AVGASER.

Publications (2)

Publication Number Publication Date
DE3838295A1 DE3838295A1 (en) 1989-05-24
DE3838295C2 true DE3838295C2 (en) 1994-05-05

Family

ID=8525420

Family Applications (1)

Application Number Title Priority Date Filing Date
DE3838295A Expired - Fee Related DE3838295C2 (en) 1987-11-16 1988-11-11 Method for producing a catalyst honeycomb body used for exhaust gas purification

Country Status (21)

Country Link
JP (1) JPH01155948A (en)
KR (1) KR890008432A (en)
AT (1) AT392750B (en)
AU (1) AU606226B2 (en)
BE (1) BE1002482A3 (en)
BR (1) BR8805954A (en)
CA (1) CA1323752C (en)
CH (1) CH675750A5 (en)
CS (1) CS277579B6 (en)
DD (1) DD283667A5 (en)
DE (1) DE3838295C2 (en)
ES (1) ES2011406A6 (en)
FI (1) FI78161C (en)
FR (1) FR2623244B1 (en)
GB (1) GB2212414B (en)
IT (1) IT8822586A0 (en)
NL (1) NL8802793A (en)
PL (1) PL159280B1 (en)
RU (1) RU1837962C (en)
SE (1) SE468323B (en)
YU (1) YU207488A (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5846495A (en) * 1995-07-12 1998-12-08 Engelhard Corporation Structure for converter body
DE102004024685A1 (en) 2004-05-19 2005-12-15 Emitec Gesellschaft Für Emissionstechnologie Mbh Catalyst carrier body for a close-coupled catalytic converter

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB753658A (en) * 1953-06-19 1956-07-25 Havilland Engine Co Ltd Metal catalyst packs
GB1531134A (en) * 1975-08-20 1978-11-01 Atomic Energy Authority Uk Methods of fabricating bodies and to bodies so fabricated
DE2733640C3 (en) * 1977-07-26 1981-04-30 Süddeutsche Kühlerfabrik Julius Fr. Behr GmbH & Co KG, 7000 Stuttgart Matrix for a catalytic reactor for exhaust gas cleaning in internal combustion engines
DE2746182A1 (en) * 1977-10-14 1979-04-19 Volkswagenwerk Ag Cylindrical catalyst carrier retention - using transverse hole and welded bolt to join carrier to casing
US4201947A (en) * 1978-02-10 1980-05-06 Rca Corporation Long-tailed-pair connections of MOSFET's operated in sub-threshold region
DE2924592C2 (en) * 1979-06-19 1983-05-26 Süddeutsche Kühlerfabrik Julius Fr. Behr GmbH & Co KG, 7000 Stuttgart Method for producing a carrier matrix for a catalytic reactor for exhaust gas purification in internal combustion engines of motor vehicles
GB2069364B (en) * 1980-02-19 1984-05-23 Johnson Matthey Co Ltd Exhaust gas purification catalyst units
DE3515681A1 (en) * 1985-05-02 1986-11-06 Üründül, Celâl, 6800 Mannheim Metal support in a single-foil design
US4598063A (en) * 1985-08-09 1986-07-01 Retallick William B Spiral catalyst support and method of making it
JPS62228616A (en) * 1986-03-29 1987-10-07 Nippon Kinzoku Kk Catalytic cartridge for exhaust gas emission control
FI74523C (en) * 1986-04-29 1988-02-08 Kemira Oy Preparation and fortification process of a catalytic cell intended for purification of exhaust gas.
ATE45410T1 (en) * 1986-05-12 1989-08-15 Interatom METALLIC HONEYCOMB BODY, IN PARTICULAR CATALYST CARRIER BODY, WITH SUPPORTING WALL AND PROCESS FOR ITS MANUFACTURE.
JPS6336842A (en) * 1986-07-29 1988-02-17 Nippon Radiator Co Ltd Metallic honeycomb carrier and its preparation
JPS63185456A (en) * 1987-01-26 1988-08-01 Calsonic Corp Production of metal honeycomb carrier
JPS6463045A (en) * 1987-09-03 1989-03-09 Toyota Motor Corp Metallic carrier

Also Published As

Publication number Publication date
FI78161B (en) 1989-02-28
AU2460088A (en) 1989-05-25
CS752088A3 (en) 1992-08-12
FR2623244A1 (en) 1989-05-19
FI78161C (en) 1989-06-12
FI875045A0 (en) 1987-11-16
BE1002482A3 (en) 1991-02-26
SE8804108D0 (en) 1988-11-15
YU207488A (en) 1990-04-30
DD283667A5 (en) 1990-10-17
KR890008432A (en) 1989-07-10
BR8805954A (en) 1989-08-08
AT392750B (en) 1991-05-27
GB8826363D0 (en) 1988-12-14
GB2212414B (en) 1991-09-25
AU606226B2 (en) 1991-01-31
SE8804108L (en) 1989-05-17
NL8802793A (en) 1989-06-16
JPH01155948A (en) 1989-06-19
SE468323B (en) 1992-12-14
CH675750A5 (en) 1990-10-31
CS277579B6 (en) 1993-03-17
DE3838295A1 (en) 1989-05-24
GB2212414A (en) 1989-07-26
ES2011406A6 (en) 1990-01-01
PL159280B1 (en) 1992-12-31
FR2623244B1 (en) 1994-04-29
PL275834A1 (en) 1989-07-24
CA1323752C (en) 1993-11-02
RU1837962C (en) 1993-08-30
IT8822586A0 (en) 1988-11-11
ATA274788A (en) 1990-11-15

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