DE3737595C2 - - Google Patents
Info
- Publication number
- DE3737595C2 DE3737595C2 DE3737595A DE3737595A DE3737595C2 DE 3737595 C2 DE3737595 C2 DE 3737595C2 DE 3737595 A DE3737595 A DE 3737595A DE 3737595 A DE3737595 A DE 3737595A DE 3737595 C2 DE3737595 C2 DE 3737595C2
- Authority
- DE
- Germany
- Prior art keywords
- rubber
- weight
- parts
- tire
- durability
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920001971 elastomer Polymers 0.000 claims description 40
- 239000005060 rubber Substances 0.000 claims description 40
- 239000000203 mixture Substances 0.000 claims description 31
- 239000011324 bead Substances 0.000 claims description 18
- 244000043261 Hevea brasiliensis Species 0.000 claims description 12
- 229920003052 natural elastomer Polymers 0.000 claims description 12
- 229920001194 natural rubber Polymers 0.000 claims description 12
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 7
- 229920003244 diene elastomer Polymers 0.000 claims description 7
- 239000005062 Polybutadiene Substances 0.000 claims description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 6
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 6
- 229920002857 polybutadiene Polymers 0.000 claims description 6
- 239000011593 sulfur Substances 0.000 claims description 6
- 229910052717 sulfur Inorganic materials 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 239000006235 reinforcing carbon black Substances 0.000 claims description 5
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 239000011701 zinc Substances 0.000 claims description 4
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- 239000011630 iodine Substances 0.000 claims description 3
- 229910052740 iodine Inorganic materials 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
- 229910052788 barium Inorganic materials 0.000 claims description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 239000011133 lead Substances 0.000 claims description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 229920001195 polyisoprene Polymers 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
- 238000007720 emulsion polymerization reaction Methods 0.000 claims 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 claims 1
- 229910052749 magnesium Inorganic materials 0.000 claims 1
- 239000011777 magnesium Substances 0.000 claims 1
- 239000000945 filler Substances 0.000 description 16
- LIQDVINWFSWENU-UHFFFAOYSA-K aluminum;prop-2-enoate Chemical compound [Al+3].[O-]C(=O)C=C.[O-]C(=O)C=C.[O-]C(=O)C=C LIQDVINWFSWENU-UHFFFAOYSA-K 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- 239000006229 carbon black Substances 0.000 description 6
- 239000011347 resin Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 4
- -1 polyethylene terephthalate Polymers 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- 239000004848 polyfunctional curative Substances 0.000 description 4
- 239000004071 soot Substances 0.000 description 4
- PIMBTRGLTHJJRV-UHFFFAOYSA-L zinc;2-methylprop-2-enoate Chemical compound [Zn+2].CC(=C)C([O-])=O.CC(=C)C([O-])=O PIMBTRGLTHJJRV-UHFFFAOYSA-L 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 229920001187 thermosetting polymer Polymers 0.000 description 3
- 238000004073 vulcanization Methods 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 2
- 101150116749 chuk gene Proteins 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 235000010299 hexamethylene tetramine Nutrition 0.000 description 2
- 239000004312 hexamethylene tetramine Substances 0.000 description 2
- DWLAVVBOGOXHNH-UHFFFAOYSA-L magnesium;prop-2-enoate Chemical class [Mg+2].[O-]C(=O)C=C.[O-]C(=O)C=C DWLAVVBOGOXHNH-UHFFFAOYSA-L 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229920002589 poly(vinylethylene) polymer Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- ZUROCNHARMFRKA-UHFFFAOYSA-N 4,5-dibromo-1h-pyrrole-2-carboxylic acid Chemical compound OC(=O)C1=CC(Br)=C(Br)N1 ZUROCNHARMFRKA-UHFFFAOYSA-N 0.000 description 1
- 229920001875 Ebonite Polymers 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 101100431668 Homo sapiens YBX3 gene Proteins 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- 102100022221 Y-box-binding protein 3 Human genes 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 235000019241 carbon black Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000001055 chewing effect Effects 0.000 description 1
- 229920003193 cis-1,4-polybutadiene polymer Polymers 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 229940082150 encore Drugs 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 238000010057 rubber processing Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000004636 vulcanized rubber Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
- XKMZOFXGLBYJLS-UHFFFAOYSA-L zinc;prop-2-enoate Chemical compound [Zn+2].[O-]C(=O)C=C.[O-]C(=O)C=C XKMZOFXGLBYJLS-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C15/00—Tyre beads, e.g. ply turn-up or overlap
- B60C15/06—Flipper strips, fillers, or chafing strips and reinforcing layers for the construction of the bead
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T152/00—Resilient tires and wheels
- Y10T152/10—Tires, resilient
- Y10T152/10495—Pneumatic tire or inner tube
- Y10T152/10819—Characterized by the structure of the bead portion of the tire
- Y10T152/10846—Bead characterized by the chemical composition and or physical properties of elastomers or the like
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Tires In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP27301786 | 1986-11-18 | ||
| JP62174775A JP2525821B2 (ja) | 1986-11-18 | 1987-07-15 | タイヤビ−ドフィラ−用ゴム組成物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3737595A1 DE3737595A1 (de) | 1988-05-26 |
| DE3737595C2 true DE3737595C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1991-12-12 |
Family
ID=26496266
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19873737595 Granted DE3737595A1 (de) | 1986-11-18 | 1987-11-05 | Kautschukmischung fuer wulstfueller von reifen |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US4824899A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) |
| DE (1) | DE3737595A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5221385A (en) * | 1988-12-30 | 1993-06-22 | The Yokohama Rubber Co., Ltd. | Pneumatic radial tire with noise suppressing rubber sheet in the bead region |
| WO1990008170A1 (en) * | 1989-01-17 | 1990-07-26 | Uniroyal Chemical Company, Inc. | Metal acrylates as rubber-to-metal adhesion promoters |
| US5217807A (en) * | 1989-01-17 | 1993-06-08 | Uniroyal Chemical Company, Inc. | Metal acrylates as rubber-to-metal adhesion promoters |
| US4898223A (en) * | 1989-01-30 | 1990-02-06 | The Goodyear Tire & Rubber Company | Stiff rubber composition and articles having components thereof |
| JPH0415111A (ja) * | 1990-05-07 | 1992-01-20 | Sumitomo Rubber Ind Ltd | 安全タイヤ |
| US5298562A (en) * | 1991-08-19 | 1994-03-29 | Sartomer Company, Inc. | Calcium di(meth)acrylate cured halogenated polyethylene polymers |
| US5253691A (en) * | 1992-01-13 | 1993-10-19 | The Goodyear Tire & Rubber Company | Tire having specified belt rubber composition |
| US5309971A (en) * | 1992-06-12 | 1994-05-10 | Michelin Recherche Et Technique S.A. | Tire flipper structure |
| US5660656A (en) * | 1992-08-05 | 1997-08-26 | Sedepro | Tire with anchored carcass |
| CA2081533A1 (en) * | 1992-09-16 | 1994-03-17 | Thomas Joseph Segatta | Tire with apex rubber blend |
| US5464899A (en) * | 1992-12-30 | 1995-11-07 | Bridgestone Corporation | High modulus low hysteresis rubber compound for pneumatic tires |
| ES2104028T3 (es) * | 1992-12-30 | 1997-10-01 | Bridgestone Corp | Compuesto de caucho de elevado modulo y baja histeresis para neumaticos. |
| JP2662172B2 (ja) * | 1993-09-29 | 1997-10-08 | 住友ゴム工業株式会社 | タイヤのビード部補強用ゴム組成物 |
| DE69707861D1 (de) * | 1996-05-09 | 2001-12-06 | Yokohama Rubber Co Ltd | Kautschukzusammensetzung zur vibrationsisolierung eines laminatkörpers |
| US20030015272A1 (en) * | 2000-07-03 | 2003-01-23 | Hiroyuki Teratani | Pneumatic tire |
| JP2004525022A (ja) * | 2001-03-30 | 2004-08-19 | ピレリ・プネウマティチ・ソチエタ・ペル・アツィオーニ | 補強されたビードを有する車両ホイール用タイヤ |
| JP5017703B2 (ja) * | 2007-05-16 | 2012-09-05 | 住友ゴム工業株式会社 | ビードエイペックスおよびタイヤ |
| CN104105713B (zh) | 2011-12-31 | 2016-03-02 | 株式会社普利司通 | 经官能化的聚合物 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2880186A (en) * | 1954-04-16 | 1959-03-31 | Int Latex Corp | Compositions containing natural rubber and a carboxyl-containing diene polymer, a film thereof, and method of making same |
| BE617871A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1961-05-22 | |||
| GB1520254A (en) * | 1974-12-30 | 1978-08-02 | Uniroyal Ltd | Golf balls |
| JPS52121653A (en) * | 1976-04-07 | 1977-10-13 | Bridgestone Corp | Wear-resistant rubber articles |
| GB2042553B (en) * | 1979-02-17 | 1982-12-08 | Dunlop Ltd | Cross-linked cellular elastomers |
| US4495326A (en) * | 1984-01-09 | 1985-01-22 | The Firestone Tire & Rubber Company | Rubber compounds containing zinc dimethacrylate |
| US4585826A (en) * | 1985-01-28 | 1986-04-29 | The Firestone Tire & Rubber Company | Natural rubber containing compositions with increased tear strength |
-
1987
- 1987-11-05 DE DE19873737595 patent/DE3737595A1/de active Granted
- 1987-11-18 US US07/122,712 patent/US4824899A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| DE3737595A1 (de) | 1988-05-26 |
| US4824899A (en) | 1989-04-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OM8 | Search report available as to paragraph 43 lit. 1 sentence 1 patent law | ||
| 8110 | Request for examination paragraph 44 | ||
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |