DE3421833A1 - Membran zur abtrennung von gasen aus gasgemischen und verfahren zu ihrer herstellung - Google Patents
Membran zur abtrennung von gasen aus gasgemischen und verfahren zu ihrer herstellungInfo
- Publication number
- DE3421833A1 DE3421833A1 DE19843421833 DE3421833A DE3421833A1 DE 3421833 A1 DE3421833 A1 DE 3421833A1 DE 19843421833 DE19843421833 DE 19843421833 DE 3421833 A DE3421833 A DE 3421833A DE 3421833 A1 DE3421833 A1 DE 3421833A1
- Authority
- DE
- Germany
- Prior art keywords
- silicon dioxide
- membrane
- membrane according
- gases
- dioxide layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000012528 membrane Substances 0.000 title claims abstract description 26
- 239000007789 gas Substances 0.000 title claims abstract description 18
- 239000000203 mixture Substances 0.000 title claims abstract description 10
- 238000000034 method Methods 0.000 title claims description 8
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 43
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 21
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 21
- 229910052734 helium Inorganic materials 0.000 claims abstract description 11
- 239000001307 helium Substances 0.000 claims abstract description 11
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229920001721 polyimide Polymers 0.000 claims abstract description 9
- 239000002985 plastic film Substances 0.000 claims abstract description 8
- 229920006255 plastic film Polymers 0.000 claims abstract description 8
- 239000004642 Polyimide Substances 0.000 claims abstract description 7
- 239000002131 composite material Substances 0.000 claims abstract description 7
- 229910052751 metal Inorganic materials 0.000 claims abstract description 6
- 239000002184 metal Substances 0.000 claims abstract description 6
- 239000001257 hydrogen Substances 0.000 claims abstract description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 5
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims abstract 2
- 238000000926 separation method Methods 0.000 claims description 12
- 238000004544 sputter deposition Methods 0.000 claims description 4
- 229910000831 Steel Inorganic materials 0.000 claims description 3
- 239000010959 steel Substances 0.000 claims description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims 3
- 239000004952 Polyamide Substances 0.000 claims 1
- 238000005266 casting Methods 0.000 claims 1
- 238000009792 diffusion process Methods 0.000 claims 1
- 229920002492 poly(sulfone) Polymers 0.000 claims 1
- 229920002647 polyamide Polymers 0.000 claims 1
- 229920000515 polycarbonate Polymers 0.000 claims 1
- 239000004417 polycarbonate Substances 0.000 claims 1
- 229920000728 polyester Polymers 0.000 claims 1
- -1 polytetrafluoroethylene Polymers 0.000 claims 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims 1
- 239000004810 polytetrafluoroethylene Substances 0.000 claims 1
- 238000001556 precipitation Methods 0.000 claims 1
- 238000005496 tempering Methods 0.000 claims 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 230000035699 permeability Effects 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- OGSYQYXYGXIQFH-UHFFFAOYSA-N chromium molybdenum nickel Chemical compound [Cr].[Ni].[Mo] OGSYQYXYGXIQFH-UHFFFAOYSA-N 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000003345 natural gas Substances 0.000 description 2
- 239000012466 permeate Substances 0.000 description 2
- 229920006254 polymer film Polymers 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 150000003377 silicon compounds Chemical class 0.000 description 2
- 101100165177 Caenorhabditis elegans bath-15 gene Proteins 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B23/00—Noble gases; Compounds thereof
- C01B23/001—Purification or separation processes of noble gases
- C01B23/0036—Physical processing only
- C01B23/0042—Physical processing only by making use of membranes
- C01B23/0047—Physical processing only by making use of membranes characterised by the membrane
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
- B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0039—Inorganic membrane manufacture
- B01D67/0046—Inorganic membrane manufacture by slurry techniques, e.g. die or slip-casting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0039—Inorganic membrane manufacture
- B01D67/0072—Inorganic membrane manufacture by deposition from the gaseous phase, e.g. sputtering, CVD, PVD
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/12—Composite membranes; Ultra-thin membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/0213—Silicon
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/501—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion
- C01B3/503—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion characterised by the membrane
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/04—Characteristic thickness
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2210/00—Purification or separation of specific gases
- C01B2210/0029—Obtaining noble gases
- C01B2210/0031—Helium
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2210/00—Purification or separation of specific gases
- C01B2210/0043—Impurity removed
- C01B2210/0068—Organic compounds
- C01B2210/007—Hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Combustion & Propulsion (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19843421833 DE3421833A1 (de) | 1984-06-13 | 1984-06-13 | Membran zur abtrennung von gasen aus gasgemischen und verfahren zu ihrer herstellung |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19843421833 DE3421833A1 (de) | 1984-06-13 | 1984-06-13 | Membran zur abtrennung von gasen aus gasgemischen und verfahren zu ihrer herstellung |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3421833A1 true DE3421833A1 (de) | 1985-12-19 |
| DE3421833C2 DE3421833C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1991-07-11 |
Family
ID=6238201
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19843421833 Granted DE3421833A1 (de) | 1984-06-13 | 1984-06-13 | Membran zur abtrennung von gasen aus gasgemischen und verfahren zu ihrer herstellung |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE3421833A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4902307A (en) * | 1988-11-18 | 1990-02-20 | California Institute Of Technology | Synthesis of SiO2 membrane on porous support and method of use of same |
| US5275726A (en) * | 1992-07-29 | 1994-01-04 | Exxon Research & Engineering Co. | Spiral wound element for separation |
| WO1994008706A1 (es) * | 1992-10-22 | 1994-04-28 | Consejo Superior Investigaciones Cientificas | Membranas microporosas de silice, su utilizacion y fabricacion |
| EP1097903A1 (fr) * | 1999-11-08 | 2001-05-09 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Procédé et installation pour la production d'hydrogène pur à partir d'un gaz contenant de l'hélium |
| WO2002026366A3 (en) * | 2000-09-25 | 2002-05-30 | Graver Technologies Inc | Filter element with porous nickel-based alloy substrate and metal oxide membrane |
| EP1167284A3 (en) * | 2000-06-27 | 2004-06-16 | Nisshin Steel Co., Ltd. | Device for recovery of hydrogen |
| EP2764908A4 (en) * | 2011-09-30 | 2015-05-27 | Fujifilm Corp | GASTRENNMEMBRAN, METHOD OF MANUFACTURING THEREFOR AND GASTRENNMEMBRANMODUL THEREWITH |
| WO2016130244A1 (en) * | 2015-02-10 | 2016-08-18 | Praxair Technology, Inc. | An integrated process and apparatus for recovery of helium rich streams |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10010387A1 (de) * | 2000-02-28 | 2001-09-06 | Mannesmann Ag | Kompositmembran und Kompositmembransystem sowie Verfahren zur Herstellung der Kompositmembranen |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3220037A1 (de) * | 1982-05-27 | 1983-12-01 | Sumitomo Electric Industries, Ltd., Osaka | Selektiv gasdurchlaessige verbundmembranen und verfahren zu ihrer herstellung |
| DE3420373A1 (de) * | 1984-06-01 | 1985-12-05 | Gkss - Forschungszentrum Geesthacht Gmbh, 2054 Geesthacht | Verfahren zur herstellung einer integralasymmetrischen membran |
-
1984
- 1984-06-13 DE DE19843421833 patent/DE3421833A1/de active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3220037A1 (de) * | 1982-05-27 | 1983-12-01 | Sumitomo Electric Industries, Ltd., Osaka | Selektiv gasdurchlaessige verbundmembranen und verfahren zu ihrer herstellung |
| DE3420373A1 (de) * | 1984-06-01 | 1985-12-05 | Gkss - Forschungszentrum Geesthacht Gmbh, 2054 Geesthacht | Verfahren zur herstellung einer integralasymmetrischen membran |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4902307A (en) * | 1988-11-18 | 1990-02-20 | California Institute Of Technology | Synthesis of SiO2 membrane on porous support and method of use of same |
| US5275726A (en) * | 1992-07-29 | 1994-01-04 | Exxon Research & Engineering Co. | Spiral wound element for separation |
| WO1994008706A1 (es) * | 1992-10-22 | 1994-04-28 | Consejo Superior Investigaciones Cientificas | Membranas microporosas de silice, su utilizacion y fabricacion |
| EP1097903A1 (fr) * | 1999-11-08 | 2001-05-09 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Procédé et installation pour la production d'hydrogène pur à partir d'un gaz contenant de l'hélium |
| FR2800725A1 (fr) * | 1999-11-08 | 2001-05-11 | Air Liquide | Procede et installation pour la production d'hydrogene pur a partir d'un gaz contenant de l'helium |
| US6669922B1 (en) | 1999-11-08 | 2003-12-30 | L'air Liquide - Societe Anonyme A Directoire Et Conseil De Surveillance Pour L'etude Et L'exploitation Des Procedes Georges Claude | Installation for the production of pure hydrogen from a gas containing helium |
| EP1167284A3 (en) * | 2000-06-27 | 2004-06-16 | Nisshin Steel Co., Ltd. | Device for recovery of hydrogen |
| WO2002026366A3 (en) * | 2000-09-25 | 2002-05-30 | Graver Technologies Inc | Filter element with porous nickel-based alloy substrate and metal oxide membrane |
| EP2764908A4 (en) * | 2011-09-30 | 2015-05-27 | Fujifilm Corp | GASTRENNMEMBRAN, METHOD OF MANUFACTURING THEREFOR AND GASTRENNMEMBRANMODUL THEREWITH |
| WO2016130244A1 (en) * | 2015-02-10 | 2016-08-18 | Praxair Technology, Inc. | An integrated process and apparatus for recovery of helium rich streams |
| US9623370B2 (en) | 2015-02-10 | 2017-04-18 | Praxair Technology, Inc. | Integrated process and apparatus for recovery of helium rich streams |
Also Published As
| Publication number | Publication date |
|---|---|
| DE3421833C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1991-07-11 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8110 | Request for examination paragraph 44 | ||
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |