DE3008445C2 - Verfahren und Vorrichtung zum Reduzieren eines teilchenförmigen Erzes zu Metallpartikeln - Google Patents
Verfahren und Vorrichtung zum Reduzieren eines teilchenförmigen Erzes zu MetallpartikelnInfo
- Publication number
- DE3008445C2 DE3008445C2 DE3008445A DE3008445A DE3008445C2 DE 3008445 C2 DE3008445 C2 DE 3008445C2 DE 3008445 A DE3008445 A DE 3008445A DE 3008445 A DE3008445 A DE 3008445A DE 3008445 C2 DE3008445 C2 DE 3008445C2
- Authority
- DE
- Germany
- Prior art keywords
- gas
- reduction zone
- reaction vessel
- cooling
- zone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 16
- 239000002923 metal particle Substances 0.000 title claims description 3
- 239000007789 gas Substances 0.000 claims description 110
- 238000006243 chemical reaction Methods 0.000 claims description 63
- 238000001816 cooling Methods 0.000 claims description 35
- 239000011261 inert gas Substances 0.000 claims description 30
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 26
- 238000002485 combustion reaction Methods 0.000 claims description 22
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 13
- 239000001569 carbon dioxide Substances 0.000 claims description 13
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 10
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 10
- 239000000112 cooling gas Substances 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 238000005086 pumping Methods 0.000 claims 1
- 238000006722 reduction reaction Methods 0.000 description 71
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 39
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 26
- 229910052742 iron Inorganic materials 0.000 description 19
- 229910001567 cementite Inorganic materials 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 238000001465 metallisation Methods 0.000 description 6
- 238000003746 solid phase reaction Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000006096 absorbing agent Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000005255 carburizing Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- KSOKAHYVTMZFBJ-UHFFFAOYSA-N iron;methane Chemical compound C.[Fe].[Fe].[Fe] KSOKAHYVTMZFBJ-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000010671 solid-state reaction Methods 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/0073—Selection or treatment of the reducing gases
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/02—Making spongy iron or liquid steel, by direct processes in shaft furnaces
- C21B13/029—Introducing coolant gas in the shaft furnaces
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
- C21B2100/20—Increasing the gas reduction potential of recycled exhaust gases
- C21B2100/28—Increasing the gas reduction potential of recycled exhaust gases by separation
- C21B2100/282—Increasing the gas reduction potential of recycled exhaust gases by separation of carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
- C21B2100/60—Process control or energy utilisation in the manufacture of iron or steel
- C21B2100/64—Controlling the physical properties of the gas, e.g. pressure or temperature
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/10—Reduction of greenhouse gas [GHG] emissions
- Y02P10/122—Reduction of greenhouse gas [GHG] emissions by capturing or storing CO2
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/10—Reduction of greenhouse gas [GHG] emissions
- Y02P10/134—Reduction of greenhouse gas [GHG] emissions by avoiding CO2, e.g. using hydrogen
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Iron (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/032,665 US4216011A (en) | 1979-04-23 | 1979-04-23 | Method and apparatus for the secondary gaseous reduction of metal ores |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3008445A1 DE3008445A1 (de) | 1980-11-06 |
| DE3008445C2 true DE3008445C2 (de) | 1987-03-19 |
Family
ID=21866147
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE3008445A Expired DE3008445C2 (de) | 1979-04-23 | 1980-03-05 | Verfahren und Vorrichtung zum Reduzieren eines teilchenförmigen Erzes zu Metallpartikeln |
Country Status (7)
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19853836A1 (de) * | 1998-11-21 | 2000-05-31 | Int Briquettes Holding Caracas | Verfahren zur Direktreduktion von Oxiden |
| DE19960575A1 (de) * | 1999-12-15 | 2001-06-21 | Krupp Polysius Ag | Verfahren und Anlage zur Reduktion von Feinerzen |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4381939A (en) * | 1981-01-29 | 1983-05-03 | Midrex Corporation | Method for selective reduction of metallic oxides |
| DE3317701C2 (de) * | 1983-05-16 | 1986-08-07 | Hylsa S.A., Monterrey, N.L. | Verfahren zum Betreiben eines Bewegtbett-Reduktionsreaktors mit vertikalem Schacht zum Reduzieren von Eisenerz zu Schwammeisen |
| US4536213A (en) * | 1984-09-10 | 1985-08-20 | Mildrex International, B.V. | Reforming of higher hydrocarbons for metal oxide reduction |
| ATE222568T1 (de) * | 1996-12-27 | 2002-09-15 | Michael Johann Dipl In Ruthner | Verfahren und vorrichtung zur herstellung von eisenoxiden aus salzsauren eisenchloridhaltigen lösungen |
| US8771638B2 (en) | 2009-04-20 | 2014-07-08 | Midrex Technologies, Inc. | Method and apparatus for sequestering carbon dioxide from a spent gas |
| KR101344940B1 (ko) * | 2009-04-20 | 2013-12-27 | 미드렉스 테크놀리지스, 인코오포레이티드 | 탑 가스를 처리하는 방법 및 그 장치 |
| US10065857B2 (en) | 2013-03-12 | 2018-09-04 | Midrex Technologies, Inc. | Systems and methods for generating carbon dioxide for use as a reforming oxidant in making syngas or reformed gas |
| CN113789420B (zh) * | 2021-08-10 | 2022-05-31 | 赵晓 | 一种含铁粉料在还原性气氛中直接炼钢装置及使用方法 |
| DE102021122351A1 (de) * | 2021-08-30 | 2023-03-02 | Thyssenkrupp Steel Europe Ag | Verfahren zur Herstellung einer Eisenschmelze |
| CN117419566B (zh) * | 2023-12-18 | 2024-03-15 | 河北睿阳稀有金属制品有限公司 | 一种海绵铪生产用还原装置 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2740706A (en) * | 1951-10-10 | 1956-04-03 | Texaco Development Corp | Method of reducing metal oxides |
| US3147106A (en) * | 1961-04-06 | 1964-09-01 | Hydrocarbon Research Inc | Use of lined passivation chamber in an iron powder passivating process |
| US3385694A (en) * | 1964-12-09 | 1968-05-28 | Stora Kopparbergs Bergslags Ab | Method of producing iron powder from pig iron or such and iron oxides |
| US3637368A (en) * | 1968-10-16 | 1972-01-25 | Exxon Research Engineering Co | Increased metallizations of iron ore from fluidized bed processes |
| US3788835A (en) * | 1970-12-30 | 1974-01-29 | Exxon Research Engineering Co | Iron ore reduction process(nu-9) |
| US3732092A (en) * | 1972-03-31 | 1973-05-08 | Bethlehem Steel Corp | Heat treatment of iron powder |
| JPS5219823B2 (US20100056889A1-20100304-C00004.png) * | 1972-12-25 | 1977-05-31 | ||
| US4017305A (en) * | 1975-04-15 | 1977-04-12 | United States Steel Corporation | Process for heat hardening |
| AU496945B2 (en) * | 1975-05-19 | 1978-11-16 | Midrex International B.V. Rotterdam | Producing metallized product |
| US4150972A (en) * | 1977-11-17 | 1979-04-24 | Fierro Esponja, S.A. | Controlling carburization in the reduction of iron ore to sponge iron |
-
1979
- 1979-04-23 US US06/032,665 patent/US4216011A/en not_active Expired - Lifetime
-
1980
- 1980-03-05 DE DE3008445A patent/DE3008445C2/de not_active Expired
- 1980-03-06 CA CA000347113A patent/CA1143574A/en not_active Expired
- 1980-03-13 JP JP3211580A patent/JPS55141507A/ja active Granted
- 1980-03-19 MX MX181641A patent/MX154949A/es unknown
- 1980-03-20 AR AR280372A patent/AR218580A1/es active
- 1980-03-20 ES ES489753A patent/ES8105395A1/es not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19853836A1 (de) * | 1998-11-21 | 2000-05-31 | Int Briquettes Holding Caracas | Verfahren zur Direktreduktion von Oxiden |
| DE19853836C2 (de) * | 1998-11-21 | 2002-02-21 | Internat Briquettes Holding Ca | Verfahren zur Direktreduktion von Oxiden |
| DE19960575A1 (de) * | 1999-12-15 | 2001-06-21 | Krupp Polysius Ag | Verfahren und Anlage zur Reduktion von Feinerzen |
Also Published As
| Publication number | Publication date |
|---|---|
| DE3008445A1 (de) | 1980-11-06 |
| ES489753A0 (es) | 1981-05-16 |
| US4216011A (en) | 1980-08-05 |
| CA1143574A (en) | 1983-03-29 |
| MX154949A (es) | 1988-01-13 |
| AR218580A1 (es) | 1980-06-13 |
| ES8105395A1 (es) | 1981-05-16 |
| JPS5744732B2 (US20100056889A1-20100304-C00004.png) | 1982-09-22 |
| JPS55141507A (en) | 1980-11-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8110 | Request for examination paragraph 44 | ||
| 8125 | Change of the main classification |
Ipc: C21B 13/02 |
|
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |