DE3000383C2 - Verfahren zur katalytischen Reduktion von Stickoxiden - Google Patents
Verfahren zur katalytischen Reduktion von StickoxidenInfo
- Publication number
- DE3000383C2 DE3000383C2 DE19803000383 DE3000383A DE3000383C2 DE 3000383 C2 DE3000383 C2 DE 3000383C2 DE 19803000383 DE19803000383 DE 19803000383 DE 3000383 A DE3000383 A DE 3000383A DE 3000383 C2 DE3000383 C2 DE 3000383C2
- Authority
- DE
- Germany
- Prior art keywords
- nitrogen oxides
- clinoptilolite
- catalyst
- reduction
- catalytic reduction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 title claims description 46
- 238000000034 method Methods 0.000 title claims description 5
- 238000010531 catalytic reduction reaction Methods 0.000 title description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 26
- JYIBXUUINYLWLR-UHFFFAOYSA-N aluminum;calcium;potassium;silicon;sodium;trihydrate Chemical compound O.O.O.[Na].[Al].[Si].[K].[Ca] JYIBXUUINYLWLR-UHFFFAOYSA-N 0.000 claims description 9
- 239000003054 catalyst Substances 0.000 claims description 9
- 229910001603 clinoptilolite Inorganic materials 0.000 claims description 9
- 229910000069 nitrogen hydride Inorganic materials 0.000 claims description 7
- 230000009467 reduction Effects 0.000 claims description 7
- 229910021529 ammonia Inorganic materials 0.000 claims description 6
- 239000007789 gas Substances 0.000 claims description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 5
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- 229910021536 Zeolite Inorganic materials 0.000 claims 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims 1
- 238000005342 ion exchange Methods 0.000 claims 1
- 238000005406 washing Methods 0.000 claims 1
- 239000010457 zeolite Substances 0.000 claims 1
- 238000006722 reduction reaction Methods 0.000 description 5
- 229910052680 mordenite Inorganic materials 0.000 description 4
- 239000012159 carrier gas Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229910052622 kaolinite Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
- B01D53/8625—Nitrogen oxides
- B01D53/8628—Processes characterised by a specific catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biomedical Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Catalysts (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US297779A | 1979-01-12 | 1979-01-12 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3000383A1 DE3000383A1 (de) | 1980-07-31 |
| DE3000383C2 true DE3000383C2 (de) | 1987-02-12 |
Family
ID=21703472
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19803000383 Expired DE3000383C2 (de) | 1979-01-12 | 1980-01-07 | Verfahren zur katalytischen Reduktion von Stickoxiden |
Country Status (7)
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0755285B2 (ja) | 1988-11-29 | 1995-06-14 | 財団法人産業創造研究所 | 廃煙中の窒素酸化物除去法 |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3328653A1 (de) * | 1983-08-09 | 1985-02-28 | Steuler Industriewerke GmbH, 5410 Höhr-Grenzhausen | Vorrichtung zur durchfuehrung eines verfahrens zur ausscheidung von stickoxyden aus abgasen |
| GB2162830B (en) * | 1984-08-10 | 1988-08-10 | Babcock Hitachi Kk | Ammonia reduction-denitration process and apparatus therefor |
| NO167130C (no) * | 1985-10-22 | 1991-10-09 | Norton Co | Katalysator for selektiv reduksjon av nitrogenoksyder. |
| US4735930A (en) * | 1986-02-18 | 1988-04-05 | Norton Company | Catalyst for the reduction of oxides of nitrogen |
| DE3635284A1 (de) * | 1986-10-16 | 1988-04-28 | Steuler Industriewerke Gmbh | Katalysator zur entfernung von stickoxiden aus abgasen |
| US4867954A (en) * | 1988-04-07 | 1989-09-19 | Uop | Catalytic reduction of nitrogen oxides |
| US4874590A (en) * | 1988-04-07 | 1989-10-17 | Uop | Catalytic reduction of nitrogen oxides |
| KR100385715B1 (ko) * | 2001-02-05 | 2003-05-27 | 코오롱건설주식회사 | 클리놉틸로라이트를 이용하는 질소산화물 제거용 촉매 |
| DE102005010221A1 (de) * | 2005-03-05 | 2006-09-07 | S&B Industrial Minerals Gmbh | Verfahren zum Herstellen eines katalytisch wirkenden Minerals auf Basis eines Gerüstsilikates |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1393053A (en) * | 1972-08-30 | 1975-05-07 | Atomic Energy Commission | Catalytic reduction of nitrogen oxides |
| US3895094A (en) * | 1974-01-28 | 1975-07-15 | Gulf Oil Corp | Process for selective reduction of oxides of nitrogen |
| US4059543A (en) * | 1975-06-23 | 1977-11-22 | Norton Company | Clinoptilolite sorbent |
-
1979
- 1979-12-31 GB GB7944641A patent/GB2039863B/en not_active Expired
-
1980
- 1980-01-07 DE DE19803000383 patent/DE3000383C2/de not_active Expired
- 1980-01-08 FR FR8000295A patent/FR2446253A1/fr active Granted
- 1980-01-10 BE BE1/9676A patent/BE881077A/fr not_active IP Right Cessation
- 1980-01-10 LU LU82074A patent/LU82074A1/fr unknown
- 1980-01-11 JP JP146080A patent/JPS55119425A/ja active Granted
- 1980-01-11 NL NL8000179A patent/NL190437C/xx not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0755285B2 (ja) | 1988-11-29 | 1995-06-14 | 財団法人産業創造研究所 | 廃煙中の窒素酸化物除去法 |
Also Published As
| Publication number | Publication date |
|---|---|
| BE881077A (fr) | 1980-07-10 |
| GB2039863B (en) | 1982-11-24 |
| NL190437B (nl) | 1993-10-01 |
| GB2039863A (en) | 1980-08-20 |
| LU82074A1 (fr) | 1980-08-08 |
| DE3000383A1 (de) | 1980-07-31 |
| NL190437C (nl) | 1994-03-01 |
| FR2446253B1 (US20020167097A1-20021114-C00005.png) | 1983-11-25 |
| FR2446253A1 (fr) | 1980-08-08 |
| NL8000179A (nl) | 1980-07-15 |
| JPS6114847B2 (US20020167097A1-20021114-C00005.png) | 1986-04-21 |
| JPS55119425A (en) | 1980-09-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8110 | Request for examination paragraph 44 | ||
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition |