DE2753595A1 - Galvanische ueberzugsaufbringung - Google Patents
Galvanische ueberzugsaufbringungInfo
- Publication number
- DE2753595A1 DE2753595A1 DE19772753595 DE2753595A DE2753595A1 DE 2753595 A1 DE2753595 A1 DE 2753595A1 DE 19772753595 DE19772753595 DE 19772753595 DE 2753595 A DE2753595 A DE 2753595A DE 2753595 A1 DE2753595 A1 DE 2753595A1
- Authority
- DE
- Germany
- Prior art keywords
- coating
- copolymer
- bath
- polymer
- graft
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
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- 239000011248 coating agent Substances 0.000 title claims description 79
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 70
- 229920000642 polymer Polymers 0.000 claims description 45
- 239000000758 substrate Substances 0.000 claims description 38
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 34
- 238000000034 method Methods 0.000 claims description 30
- 239000006185 dispersion Substances 0.000 claims description 26
- 229920000578 graft copolymer Polymers 0.000 claims description 24
- 229920001577 copolymer Polymers 0.000 claims description 19
- 239000004593 Epoxy Substances 0.000 claims description 18
- -1 hydroxyalkyl acrylates Chemical class 0.000 claims description 18
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 15
- 230000002378 acidificating effect Effects 0.000 claims description 10
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 10
- 230000008569 process Effects 0.000 claims description 10
- 125000002091 cationic group Chemical group 0.000 claims description 9
- 239000003431 cross linking reagent Substances 0.000 claims description 9
- 150000001412 amines Chemical class 0.000 claims description 6
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
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- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 125000004103 aminoalkyl group Chemical group 0.000 claims description 3
- 229940106691 bisphenol a Drugs 0.000 claims description 3
- 238000009833 condensation Methods 0.000 claims description 3
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- 125000000467 secondary amino group Chemical class [H]N([*:1])[*:2] 0.000 claims description 3
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- 239000011347 resin Substances 0.000 description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 27
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- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 20
- 239000010452 phosphate Substances 0.000 description 19
- 238000006243 chemical reaction Methods 0.000 description 14
- 238000005260 corrosion Methods 0.000 description 13
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 12
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- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
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- 150000003335 secondary amines Chemical class 0.000 description 7
- 150000003512 tertiary amines Chemical group 0.000 description 7
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 125000003277 amino group Chemical group 0.000 description 6
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- 150000002739 metals Chemical class 0.000 description 6
- 239000003973 paint Substances 0.000 description 6
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 239000004408 titanium dioxide Substances 0.000 description 6
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- 230000008859 change Effects 0.000 description 5
- MSYLJRIXVZCQHW-UHFFFAOYSA-N formaldehyde;6-phenyl-1,3,5-triazine-2,4-diamine Chemical compound O=C.NC1=NC(N)=NC(C=2C=CC=CC=2)=N1 MSYLJRIXVZCQHW-UHFFFAOYSA-N 0.000 description 5
- 238000010992 reflux Methods 0.000 description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 238000009713 electroplating Methods 0.000 description 4
- 230000014759 maintenance of location Effects 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 125000001453 quaternary ammonium group Chemical group 0.000 description 4
- 230000002829 reductive effect Effects 0.000 description 4
- 239000004576 sand Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 4
- 229910052725 zinc Inorganic materials 0.000 description 4
- 239000011787 zinc oxide Substances 0.000 description 4
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 3
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 239000008199 coating composition Substances 0.000 description 3
- 239000010960 cold rolled steel Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 210000003298 dental enamel Anatomy 0.000 description 3
- 238000004070 electrodeposition Methods 0.000 description 3
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 239000003784 tall oil Substances 0.000 description 3
- MFXMOUUKFMDYLM-UHFFFAOYSA-L zinc;dihydrogen phosphate Chemical compound [Zn+2].OP(O)([O-])=O.OP(O)([O-])=O MFXMOUUKFMDYLM-UHFFFAOYSA-L 0.000 description 3
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 2
- KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 description 2
- BEWCNXNIQCLWHP-UHFFFAOYSA-N 2-(tert-butylamino)ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCNC(C)(C)C BEWCNXNIQCLWHP-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 239000004923 Acrylic lacquer Substances 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 239000004606 Fillers/Extenders Substances 0.000 description 2
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- 229920001807 Urea-formaldehyde Polymers 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 229940072282 cardura Drugs 0.000 description 2
- 229920006317 cationic polymer Polymers 0.000 description 2
- 239000007810 chemical reaction solvent Substances 0.000 description 2
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical class [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 2
- 239000013065 commercial product Substances 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- RUZYUOTYCVRMRZ-UHFFFAOYSA-N doxazosin Chemical compound C1OC2=CC=CC=C2OC1C(=O)N(CC1)CCN1C1=NC(N)=C(C=C(C(OC)=C2)OC)C2=N1 RUZYUOTYCVRMRZ-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Substances O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- 229940083124 ganglion-blocking antiadrenergic secondary and tertiary amines Drugs 0.000 description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
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- IXGROVRQNCGHLL-UHFFFAOYSA-N (tert-butylamino)methyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCNC(C)(C)C IXGROVRQNCGHLL-UHFFFAOYSA-N 0.000 description 1
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- 238000012360 testing method Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- SPDJAIKMJHJYAV-UHFFFAOYSA-H trizinc;diphosphate;tetrahydrate Chemical compound O.O.O.O.[Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O SPDJAIKMJHJYAV-UHFFFAOYSA-H 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
- C09D5/4407—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications with polymers obtained by polymerisation reactions involving only carbon-to-carbon unsaturated bonds
- C09D5/4411—Homopolymers or copolymers of acrylates or methacrylates
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US74629876A | 1976-12-01 | 1976-12-01 | |
| US05/845,891 US4115227A (en) | 1976-12-01 | 1977-10-31 | Cathodic electrodeposition of paints |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE2753595A1 true DE2753595A1 (de) | 1978-06-08 |
Family
ID=27114588
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19772753595 Withdrawn DE2753595A1 (de) | 1976-12-01 | 1977-12-01 | Galvanische ueberzugsaufbringung |
Country Status (7)
| Country | Link |
|---|---|
| JP (1) | JPS53108128A (enrdf_load_stackoverflow) |
| BR (1) | BR7707978A (enrdf_load_stackoverflow) |
| CA (1) | CA1111590A (enrdf_load_stackoverflow) |
| DE (1) | DE2753595A1 (enrdf_load_stackoverflow) |
| ES (1) | ES464662A1 (enrdf_load_stackoverflow) |
| FR (3) | FR2393084A1 (enrdf_load_stackoverflow) |
| GB (3) | GB1595325A (enrdf_load_stackoverflow) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3003286A1 (de) * | 1980-01-30 | 1981-08-06 | Basf Farben + Fasern Ag, 2000 Hamburg | Gegenstand bestehend aus einem elektrisch leitfaehigen substrat und einem darauf festhaftend angeordneten metallisch aussehenden ueberzug |
| EP0067312A3 (en) * | 1981-06-13 | 1983-01-26 | Basf Farben + Fasern Aktiengesellschaft | Binders for cathodically precipitable paints, process for preparing them and their use |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5819760B2 (ja) * | 1980-03-10 | 1983-04-19 | 神東塗料株式会社 | 電着浴の管理方法 |
| JPS5951958A (ja) * | 1982-09-18 | 1984-03-26 | Nippon Paint Co Ltd | カチオン型電着塗料組成物 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1258535B (de) * | 1963-08-22 | 1968-01-11 | Roehm & Haas Gmbh | Additionspolymerisate als Schmieroelzusaetze |
| US3676384A (en) * | 1970-05-06 | 1972-07-11 | North Dakota State Univ Memori | Copolymers of hydroxyalkyl methacrylates and an acrylate of methacrylate ester reacted with a partially epoxidized drying oil |
| US3835076A (en) * | 1972-11-30 | 1974-09-10 | Du Pont | Aqueous sealer composition of an epoxy ester resin of a maleinized drying oil fatty acid and an epoxy resin and an acrylic-epoxy ester graft copolymer |
-
1977
- 1977-11-29 CA CA292,037A patent/CA1111590A/en not_active Expired
- 1977-11-30 GB GB1130880A patent/GB1595325A/en not_active Expired
- 1977-11-30 GB GB1130780A patent/GB1595324A/en not_active Expired
- 1977-11-30 GB GB4986177A patent/GB1595323A/en not_active Expired
- 1977-11-30 FR FR7736142A patent/FR2393084A1/fr not_active Withdrawn
- 1977-11-30 BR BR7707978A patent/BR7707978A/pt unknown
- 1977-12-01 JP JP14333977A patent/JPS53108128A/ja active Pending
- 1977-12-01 DE DE19772753595 patent/DE2753595A1/de not_active Withdrawn
- 1977-12-01 ES ES464662A patent/ES464662A1/es not_active Expired
-
1978
- 1978-04-10 FR FR7810534A patent/FR2396039A1/fr not_active Withdrawn
- 1978-04-10 FR FR7810533A patent/FR2396038A1/fr not_active Withdrawn
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3003286A1 (de) * | 1980-01-30 | 1981-08-06 | Basf Farben + Fasern Ag, 2000 Hamburg | Gegenstand bestehend aus einem elektrisch leitfaehigen substrat und einem darauf festhaftend angeordneten metallisch aussehenden ueberzug |
| EP0067312A3 (en) * | 1981-06-13 | 1983-01-26 | Basf Farben + Fasern Aktiengesellschaft | Binders for cathodically precipitable paints, process for preparing them and their use |
Also Published As
| Publication number | Publication date |
|---|---|
| ES464662A1 (es) | 1979-01-01 |
| FR2393084A1 (enrdf_load_stackoverflow) | 1978-12-29 |
| GB1595325A (en) | 1981-08-12 |
| BR7707978A (pt) | 1978-09-05 |
| JPS53108128A (en) | 1978-09-20 |
| CA1111590A (en) | 1981-10-27 |
| FR2396038A1 (enrdf_load_stackoverflow) | 1979-01-26 |
| GB1595324A (en) | 1981-08-12 |
| GB1595323A (en) | 1981-08-12 |
| FR2396039A1 (fr) | 1979-01-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8139 | Disposal/non-payment of the annual fee |