DE2713590A1 - Steel pressure vessel for storing hydrogen gas - with internal metal coating which prevents hydrogen from embrittling the steel - Google Patents

Steel pressure vessel for storing hydrogen gas - with internal metal coating which prevents hydrogen from embrittling the steel

Info

Publication number
DE2713590A1
DE2713590A1 DE19772713590 DE2713590A DE2713590A1 DE 2713590 A1 DE2713590 A1 DE 2713590A1 DE 19772713590 DE19772713590 DE 19772713590 DE 2713590 A DE2713590 A DE 2713590A DE 2713590 A1 DE2713590 A1 DE 2713590A1
Authority
DE
Germany
Prior art keywords
steel
pressure vessel
hydrogen
embrittling
metal coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE19772713590
Other languages
German (de)
Inventor
Eberhard Dipl Phys Dr Riedel
Wolfgang Dr Schreckenberg
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Messer Griesheim GmbH
Original Assignee
Messer Griesheim GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Messer Griesheim GmbH filed Critical Messer Griesheim GmbH
Priority to DE19772713590 priority Critical patent/DE2713590A1/en
Publication of DE2713590A1 publication Critical patent/DE2713590A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C1/00—Pressure vessels, e.g. gas cylinder, gas tank, replaceable cartridge
    • F17C1/10—Pressure vessels, e.g. gas cylinder, gas tank, replaceable cartridge with provision for protection against corrosion, e.g. due to gaseous acid
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2201/00—Vessel construction, in particular geometry, arrangement or size
    • F17C2201/01—Shape
    • F17C2201/0104—Shape cylindrical
    • F17C2201/0109—Shape cylindrical with exteriorly curved end-piece
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2201/00—Vessel construction, in particular geometry, arrangement or size
    • F17C2201/01—Shape
    • F17C2201/0104—Shape cylindrical
    • F17C2201/0119—Shape cylindrical with flat end-piece
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2201/00—Vessel construction, in particular geometry, arrangement or size
    • F17C2201/03—Orientation
    • F17C2201/032—Orientation with substantially vertical main axis
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2201/00—Vessel construction, in particular geometry, arrangement or size
    • F17C2201/05—Size
    • F17C2201/056—Small (<1 m3)
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00—Vessel construction, in particular walls or details thereof
    • F17C2203/06—Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0602—Wall structures; Special features thereof
    • F17C2203/0607—Coatings
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00—Vessel construction, in particular walls or details thereof
    • F17C2203/06—Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0602—Wall structures; Special features thereof
    • F17C2203/0612—Wall structures
    • F17C2203/0614—Single wall
    • F17C2203/0619—Single wall with two layers
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00—Vessel construction, in particular walls or details thereof
    • F17C2203/06—Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0634—Materials for walls or layers thereof
    • F17C2203/0636—Metals
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00—Vessel construction, in particular walls or details thereof
    • F17C2203/06—Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0634—Materials for walls or layers thereof
    • F17C2203/0636—Metals
    • F17C2203/0639—Steels
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00—Vessel construction, in particular walls or details thereof
    • F17C2203/06—Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0634—Materials for walls or layers thereof
    • F17C2203/0636—Metals
    • F17C2203/0653—Lead
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2205/00—Vessel construction, in particular mounting arrangements, attachments or identifications means
    • F17C2205/01—Mounting arrangements
    • F17C2205/0153—Details of mounting arrangements
    • F17C2205/018—Supporting feet
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2205/00—Vessel construction, in particular mounting arrangements, attachments or identifications means
    • F17C2205/03—Fluid connections, filters, valves, closure means or other attachments
    • F17C2205/0302—Fittings, valves, filters, or components in connection with the gas storage device
    • F17C2205/0308—Protective caps
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2223/00—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
    • F17C2223/01—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the phase
    • F17C2223/0107—Single phase
    • F17C2223/0123—Single phase gaseous, e.g. CNG, GNC
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2225/00—Handled fluid after transfer, i.e. state of fluid after transfer from the vessel
    • F17C2225/03—Handled fluid after transfer, i.e. state of fluid after transfer from the vessel characterised by the pressure level
    • F17C2225/035—High pressure, i.e. between 10 and 80 bars
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2225/00—Handled fluid after transfer, i.e. state of fluid after transfer from the vessel
    • F17C2225/04—Handled fluid after transfer, i.e. state of fluid after transfer from the vessel characterised by other properties of handled fluid after transfer
    • F17C2225/042—Localisation of the filling point
    • F17C2225/043—Localisation of the filling point in the gas
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2260/00—Purposes of gas storage and gas handling
    • F17C2260/05—Improving chemical properties
    • F17C2260/053—Reducing corrosion
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2270/00—Applications
    • F17C2270/07—Applications for household use
    • F17C2270/0745—Gas bottles
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/32—Hydrogen storage

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

Pressure vessel or bottle made of steel and used for storing gaseous hydrogen, has inner surface with protective layer made of a metal (a) without any d-band gaps. The pref. metals (a) are in the first or second sub-gp., or the third main gp. of the periodic system. The esp. pref. metals (a) are Zn, Cd, Ag, Au or Pb. Steel bottles etc. contg. H2 gas are damaged by hydrogen embrittlement and/or other defects due to the H2 entering the steel. Layer (a) prevents the H2 from reaching the steel.

Description

KG Io53KG Io53

MESSER GRIESHEIM GMBH EM 7MESSER GRIESHEIM GMBH EM 7

Kennwort: Anti-H2-Beschichtung STPHPassword: Anti-H 2 coating STPH

Erfinder: Dr. Riedel; Ba/HiInventor: Dr. Riedel; Ba / Hi

Dr. Schreckenberg 15.12.76 Mappe: DDr. Schreckenberg 12/15/76 Folder: D

Druckbehälter aus Stahl zur Aufbewahrung von gasförmigem Wasserstoff Steel pressure vessel for storing gaseous hydrogen

Die Erfindung betrifft einen Druckbehälter aus Stahl zur Aufbewahrung von gasförmigem Viasserstoff.The invention relates to a pressure vessel made of steel for storing gaseous hydrogen.

Es ist eine bekannte Erscheinung, daß Wasserstoff in atomarer oder ionisierter Form leicht in viele Metalle diffundiert. Insbesondere bei Stahl macht er sich hierdurchals "Metallschädling" bemerkbar. Die Schädigungen erfolgen bei Raumtemperatur oder nur wenig über der Raumtemperatur liegenden Temperaturen. Stahlschädigungen sind unter den Begriffen Flocken, Fischaugen, wasserstoffinduzierte Spannungsrisskorrosion, verzögerte Brücke, Wasserstoffversprödung u. ä. bekannt.Derartige Schädigungen können bei mit Wasserstoff gefüllten Druckgasbehältern zum Bersten der Behälter mit erheblichen Folgeschäden führen.It is a well known phenomenon that hydrogen in atomic or ionized form is easily converted into many Metals diffused. In the case of steel in particular, this makes it noticeable as a "metal pest". The damage occurs at room temperature or at temperatures only slightly above room temperature. Steel damage is classified under the terms flakes, fish eyes, hydrogen-induced stress corrosion cracking, Delayed bridging, hydrogen embrittlement, etc. are known. Such damage can in the case of pressurized gas containers filled with hydrogen, the containers burst with considerable consequential damage to lead.

Der Erfindung liegt die Aufgabe zugrunde, einen Druckbehälter aus Stahl zur Aufbewahrung von gasförmigem Wasserstoff zu schaffen, bei dem die Gefahr einer Schädigung durch den aufbewahrten Wasserstoff nicht gegeben ist.The invention is based on the object of a pressure vessel made of steel for storing gaseous To create hydrogen with the risk of damage from the stored hydrogen is not given.

809840/0183809840/0183

Es wurde nun ein Druckbehälter aus Stahl zur Aufbewahrung von gasförmigem Wasserstoff gefunden, bei dem gemäß der Erfindung die Innenoberfläche mit einer Schutzschicht aus einem Metall ohne d-Bandlücken versehen ist.A pressure vessel made of steel for storing gaseous hydrogen has now been found in which according to the invention, the inner surface is provided with a protective layer made of a metal without d-band gaps is.

Die Formulierung "Metalle ohne d-Bandlücken" besagt, daß es sich um Metalle ohne Lücken in den d-Schalen der Elektronenhülle handelt. Besonders geeignet sind Metalle aus der ersten und zweiten Nebengruppe, sowie der dritten Hauptgruppe des periodischen Systems der Elemente. Gut geeignete Metalle sind beispielsweise Zink, Cadmium, Silber, Gold und Blei.The phrase "metals with no d-band gaps" indicates that they are metals with no gaps in the d-shells the electron shell acts. Metals from the first and second subgroups as well as are particularly suitable the third main group of the periodic table of elements. Suitable metals are, for example Zinc, cadmium, silver, gold and lead.

Durch die erfindungsgemäße Schutzschicht wird jegliche Wasserstoffversprödung des Stahls völlig vermieden.An einer ungeschützten Stahloberfläche wird der Wasserstoff chemi-sorbiert und geht anschließend in den okkludierten Zustand über. Der Anteil an interstitiell eingebautem Wasserstoff erhöht sich dadurch derartig, daß er durch Desorption in den Korngrenzen und inneren Poren die bekannten Effekte der Wasserstoffverprödung erzeugt.The protective layer according to the invention is any Hydrogen embrittlement of the steel completely avoided The hydrogen is chemisorbed on an unprotected steel surface and then goes into the occluded state. This increases the proportion of interstitially incorporated hydrogen to such an extent that that it has the well-known effects of hydrogen embrittlement through desorption in the grain boundaries and inner pores generated.

Die gemäß der Erfindung für die Schutzschicht verwendeten Metalle zeigen eine außerordentlich geringe Tendenz,Gase, insbesondere Wasserstoff, zu chemisorbieren und zu lösen. Insbesondere ihre Eigenschaft, den Wasserstoff nicht zu lösen, verhindert, daß der Wasserstoff durch die metallische Schutzschicht dringt und schließlich den Stahl angreift. Die metallische Schutzschicht kann galvanisch oder mechanisch auf die innere Oberfläche der Druckbehälter aufgebracht werden.The metals used according to the invention for the protective layer are extremely low Tendency to chemisorb and dissolve gases, especially hydrogen. In particular, their property Failure to dissolve the hydrogen prevents the hydrogen from penetrating through the metallic protective layer and finally attacks the steel. The metallic protective layer can be galvanically or mechanically applied to the inner surface of the pressure vessel are applied.

Die Zeichnung veranschaulicht als Ausführungsbeispiel der Erfindung eine Stahlflasche zur Aufbewahrung von gasförmigem Sauerstoff.The drawing illustrates, as an embodiment of the invention, a steel bottle for storing gaseous oxygen.

809840/0183809840/0183

Die Stahlflasche 1 ist teilweise aufgebrochen dargestellt, so daß die Flaschenwand 2 aus Stahl mit der erfindungsgemäß aufgebrachten Schutzschicht 3 ,beispielsweise aus Blei, zu sehen ist.The steel bottle 1 is shown partially broken, so that the bottle wall 2 made of steel with the protective layer 3 applied according to the invention, for example made of lead, can be seen.

809840/0183809840/0183

Claims (3)

MG I053MG I053 EM 7EM 7 AnsprücheExpectations ./ Druckbehälter aus Stahl zur Aufbewahrung von gasförmigen Wasserstoff, dadurch gekennzeichnet, daß die Innenoberfläche des Druckbehälters (1) mit einer Schutzschicht (3) aus einem Metall ohne d-Bandlücken versehen ist../ Steel pressure vessel for storing gaseous Hydrogen, characterized in that the inner surface of the pressure vessel (1) with a Protective layer (3) is provided from a metal without d-band gaps. 2. Druckbehälter nach Anspruch 1, dadurch gekennzeichnet, daß die Schutzschicht aus Metallen der ersten oder zweiten Nebengruppe oder der dritten Hauptgruppe des periodischen Systems versehen ist.2. Pressure vessel according to claim 1, characterized in that the protective layer made of metals of the first or second subgroup or the third main group of the periodic system is provided. 3. Druckbehälter nach Anspruch 1, dadurch gekennzeichnet, daß die Schutzschicht aus Zink, Cadmium, Silber, Gold oder Blei besteht.3. Pressure vessel according to claim 1, characterized in that the protective layer made of zinc, cadmium, silver, Gold or lead. /NSPECTR,/ NSPECTR, 809840/0183809840/0183
DE19772713590 1977-03-28 1977-03-28 Steel pressure vessel for storing hydrogen gas - with internal metal coating which prevents hydrogen from embrittling the steel Withdrawn DE2713590A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE19772713590 DE2713590A1 (en) 1977-03-28 1977-03-28 Steel pressure vessel for storing hydrogen gas - with internal metal coating which prevents hydrogen from embrittling the steel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19772713590 DE2713590A1 (en) 1977-03-28 1977-03-28 Steel pressure vessel for storing hydrogen gas - with internal metal coating which prevents hydrogen from embrittling the steel

Publications (1)

Publication Number Publication Date
DE2713590A1 true DE2713590A1 (en) 1978-10-05

Family

ID=6004863

Family Applications (1)

Application Number Title Priority Date Filing Date
DE19772713590 Withdrawn DE2713590A1 (en) 1977-03-28 1977-03-28 Steel pressure vessel for storing hydrogen gas - with internal metal coating which prevents hydrogen from embrittling the steel

Country Status (1)

Country Link
DE (1) DE2713590A1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3815347A1 (en) * 1988-05-02 1989-11-16 Mannesmann Ag MULTI-PIECE PRESSURE TANK
DE102012023065A1 (en) * 2012-11-26 2014-05-28 Volkswagen Aktiengesellschaft Pressure tank for use in motor car, has housing having outer layer for enclosing inner metal and plastic layers, and several supplementary heat guide elements
CN107504364A (en) * 2017-08-09 2017-12-22 中国矿业大学 A kind of vertical hydrogen-holder

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3815347A1 (en) * 1988-05-02 1989-11-16 Mannesmann Ag MULTI-PIECE PRESSURE TANK
DE102012023065A1 (en) * 2012-11-26 2014-05-28 Volkswagen Aktiengesellschaft Pressure tank for use in motor car, has housing having outer layer for enclosing inner metal and plastic layers, and several supplementary heat guide elements
CN107504364A (en) * 2017-08-09 2017-12-22 中国矿业大学 A kind of vertical hydrogen-holder
CN107504364B (en) * 2017-08-09 2019-04-23 中国矿业大学 A kind of vertical hydrogen-holder

Similar Documents

Publication Publication Date Title
US20180371601A1 (en) KINETICALLY APPLIED GRADATED Zr-Al-C OR Ti-Al-C CERAMIC OR AMORPHOUS OR SEMI-AMORPHOUS STAINLESS STEEL WITH NUCLEAR GRADE ZIRCONIUM ALLOY METAL STRUCTURE
DE3108160A1 (en) &#34;METHOD FOR PRODUCING PROTECTIVE OXIDE LAYERS&#34;
DE2719986A1 (en) PRESSURE RELEASE DEVICE FOR A LIGHTWEIGHT PRESSURE VESSEL MADE OF A FIBER-WRAPPED COMPOSITE MATERIAL AND A PROCESS FOR MANUFACTURING THE SAME
DE4215664C1 (en) Process for the application of metallic intermediate layers and its application
DE69628583T2 (en) DIFFUSION BARRIERS TO PREVENT THE ATTACK OF HYDROGEN AT HIGH TEMPERATURES
DE2713590A1 (en) Steel pressure vessel for storing hydrogen gas - with internal metal coating which prevents hydrogen from embrittling the steel
DE8717392U1 (en) Catalyst carrier body
DE3742594A1 (en) Method for increasing the corrosion stability of metallic workpieces, and metallic workpiece having an anti-corrosive coating on its surface
DE1621204B1 (en) PROCESS FOR IMPROVING THE DURABILITY OF CHROME PROTECTIVE LAYERS ON METALS AT HIGH TEMPERATURES IN NITROGEN-CONTAINING ATOMIC SPHERE
DE19721080C1 (en) Corrosion protective coating especially of nuclear plant component
DE202019004197U1 (en) VCI - corrosion protection paper with additional functionality
EP0255465A2 (en) Small caliber multi-layered metal pipe
DE3827141C1 (en) Process for alitising objects of austenitic steel or nickel-based alloys
DE3500935A1 (en) COMPONENT WITH CORROSION-RESISTANT OXIDIC COATING APPLIED ON OPPOSITE SIDES OF A METAL CONSTRUCTION
EP4081731A1 (en) Method for producing a component for storing or distributing compressed gas, and component for storing or distributing compressed gas
DE10352569A1 (en) Protection layer for fuel tank of vehicle, using cover of intumescent material forming protection shield in case of fire
DE1796230A1 (en) Process for the production of coatings from metal oxides and ceramic materials on metals, in particular on iron and steel, as protection against chemical changes to the surface caused by the action of non-metallic attack agents at high temperatures
EP0024507A1 (en) Use of a composite material based on aluminium
KR19990087105A (en) Components designed for light water reactors and methods of manufacturing such components
DE3214918A1 (en) Shut-off valve
EP0683243B1 (en) Corrosion resistant tube with internal oxide layer
DE874233C (en) Process for the production of protective coatings on metals
DE300477C (en)
CH498946A (en) Process for producing high corrosion resistance and use of the process
DE1951141C3 (en) Corrosion-resistant laminate

Legal Events

Date Code Title Description
8139 Disposal/non-payment of the annual fee