DE2452585B2 - Verfahren zur Herstellung scherstabiler wäßriger Copolymerisat-Dispersionen - Google Patents

Verfahren zur Herstellung scherstabiler wäßriger Copolymerisat-Dispersionen

Info

Publication number
DE2452585B2
DE2452585B2 DE2452585A DE2452585A DE2452585B2 DE 2452585 B2 DE2452585 B2 DE 2452585B2 DE 2452585 A DE2452585 A DE 2452585A DE 2452585 A DE2452585 A DE 2452585A DE 2452585 B2 DE2452585 B2 DE 2452585B2
Authority
DE
Germany
Prior art keywords
monomers
weight
parts
acid
acrylonitrile
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
DE2452585A
Other languages
German (de)
English (en)
Other versions
DE2452585C3 (oth
DE2452585A1 (de
Inventor
Dipl.-Chem. Dr. Fritz 6901 Eppelheim Reichel
Dipl.-Chem. Dr. Christof 6700 Ludwigshafen Taubitz
Dipl.-Chem. Dr. Kurt 6700 Ludwigshafen Wendel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to DE2452585A priority Critical patent/DE2452585B2/de
Priority to US05/626,749 priority patent/US4051093A/en
Priority to SE7512291A priority patent/SE417720B/xx
Priority to CA238,879A priority patent/CA1035074A/en
Priority to FR7533834A priority patent/FR2290454A1/fr
Priority to IT52081/75A priority patent/IT1060074B/it
Publication of DE2452585A1 publication Critical patent/DE2452585A1/de
Publication of DE2452585B2 publication Critical patent/DE2452585B2/de
Application granted granted Critical
Publication of DE2452585C3 publication Critical patent/DE2452585C3/de
Granted legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/41—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups
    • D21H17/42—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups anionic
    • D21H17/43—Carboxyl groups or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/42—Nitriles
    • C08F220/44—Acrylonitrile
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/41—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups
    • D21H17/42—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups anionic
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/41—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups
    • D21H17/44—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups cationic
    • D21H17/45—Nitrogen-containing groups
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/41—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups
    • D21H17/44—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups cationic
    • D21H17/45—Nitrogen-containing groups
    • D21H17/455—Nitrogen-containing groups comprising tertiary amine or being at least partially quaternised

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Paper (AREA)
DE2452585A 1974-11-06 1974-11-06 Verfahren zur Herstellung scherstabiler wäßriger Copolymerisat-Dispersionen Granted DE2452585B2 (de)

Priority Applications (6)

Application Number Priority Date Filing Date Title
DE2452585A DE2452585B2 (de) 1974-11-06 1974-11-06 Verfahren zur Herstellung scherstabiler wäßriger Copolymerisat-Dispersionen
US05/626,749 US4051093A (en) 1974-11-06 1975-10-29 Manufacture of shear-resistant aqueous copolymer emulsions
SE7512291A SE417720B (sv) 1974-11-06 1975-11-03 Forfarande for framstellning av skjuvningsstabila sampolymerdispersioner och anvendning av dessa for limning av papper
CA238,879A CA1035074A (en) 1974-11-06 1975-11-03 Manufacture of shear-resistant aqueous copolymer emulsions
FR7533834A FR2290454A1 (fr) 1974-11-06 1975-11-05 Procede de preparation de dispersions de copolymerisats aqueuses, resistant au cisaillement
IT52081/75A IT1060074B (it) 1974-11-06 1975-11-05 Procedimento per la produzione di dispersioni acquose di copolimeri stabili al taglio

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2452585A DE2452585B2 (de) 1974-11-06 1974-11-06 Verfahren zur Herstellung scherstabiler wäßriger Copolymerisat-Dispersionen

Publications (3)

Publication Number Publication Date
DE2452585A1 DE2452585A1 (de) 1976-05-13
DE2452585B2 true DE2452585B2 (de) 1981-07-30
DE2452585C3 DE2452585C3 (oth) 1982-05-13

Family

ID=5930136

Family Applications (1)

Application Number Title Priority Date Filing Date
DE2452585A Granted DE2452585B2 (de) 1974-11-06 1974-11-06 Verfahren zur Herstellung scherstabiler wäßriger Copolymerisat-Dispersionen

Country Status (6)

Country Link
US (1) US4051093A (oth)
CA (1) CA1035074A (oth)
DE (1) DE2452585B2 (oth)
FR (1) FR2290454A1 (oth)
IT (1) IT1060074B (oth)
SE (1) SE417720B (oth)

Families Citing this family (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2399448A1 (fr) * 1977-08-03 1979-03-02 Rhone Poulenc Ind Latex de polymeres vinyliques stables aux electrolytes
DE2854491A1 (de) 1978-12-16 1980-06-26 Bayer Ag Verfahren zur herstellung von copolymerisatdispersionen
US4313861A (en) * 1980-02-28 1982-02-02 Union Carbide Corporation Latex autodeposition coatings
NL8001928A (nl) * 1980-04-02 1981-11-02 Synres Internationaal Nv Werkwijze voor het maken van polymeerdispersies.
DE3025562A1 (de) * 1980-07-05 1982-02-11 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von copolymerdispersionen enger teilchengroessenverteilung mit breitem konzentrationsbereich dilatanten fliessverhaltens
DE3039976A1 (de) * 1980-10-23 1982-06-03 Basf Ag, 6700 Ludwigshafen Feinteilige, stickstoffhaltige monomere einpolymerisiert enthaltende polymerdispersion
DE3047688A1 (de) * 1980-12-18 1982-07-22 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung amphoterer copolymerisate und deren verwendung als emulsator
DE3103463A1 (de) * 1981-02-02 1982-08-26 Basf Ag, 6700 Ludwigshafen Verwendung von emulsionscopolymerisaten auf basis von acrylaten als alleiniges bindemittel fuer papierstreichmassen
FR2540127B1 (oth) * 1983-01-28 1985-03-29 Rhone Poulenc Spec Chim
FR2540126A1 (fr) * 1983-01-28 1984-08-03 Rhone Poulenc Spec Chim Latex stables et amphoteres de copolymeres a base de dienes conjugues
FR2540123A1 (fr) * 1983-01-28 1984-08-03 Rhone Poulenc Spec Chim Dispersions aqueuses stables et amphoteres de polymeres synthetiques
US4812510A (en) * 1986-04-17 1989-03-14 The Glidden Company Small particle size latex based on vinyl acetate polymers
FR2637511B1 (fr) * 1988-10-10 1994-02-11 Coatex Sa Agent de compatibilite pour suspensions aqueuses polypigmentaires dont l'un des pigments est du sulfate de calcium hydrate
US5312863A (en) * 1989-07-05 1994-05-17 Rohm And Haas Company Cationic latex coatings
US5663224A (en) * 1991-12-03 1997-09-02 Rohm And Haas Company Process for preparing an aqueous dispersion
US6080802A (en) * 1991-12-03 2000-06-27 Rohm And Haas Company Process for preparing an aqueous dispersion of composite particles including polymeric latex adsorbed to titanium dioxide
US5514758A (en) * 1994-09-30 1996-05-07 The Goodyear Tire & Rubber Company Process for making latex for high performance masking tape
US6423804B1 (en) * 1998-12-31 2002-07-23 Kimberly-Clark Worldwide, Inc. Ion-sensitive hard water dispersible polymers and applications therefor
AU5749601A (en) * 2000-05-04 2001-11-12 Kimberly Clark Co Ion-sensitive, water-dispersible polymers composition, a method of making same and items using same
US7772138B2 (en) 2002-05-21 2010-08-10 Kimberly-Clark Worldwide, Inc. Ion sensitive, water-dispersible polymers, a method of making same and items using same
US6994865B2 (en) * 2002-09-20 2006-02-07 Kimberly-Clark Worldwide, Inc. Ion triggerable, cationic polymers, a method of making same and items using same
US7101456B2 (en) * 2002-09-20 2006-09-05 Kimberly-Clark Worldwide, Inc. Ion triggerable, cationic polymers, a method of making same and items using same
US7141519B2 (en) 2002-09-20 2006-11-28 Kimberly-Clark Worldwide, Inc. Ion triggerable, cationic polymers, a method of making same and items using same
US7157389B2 (en) * 2002-09-20 2007-01-02 Kimberly-Clark Worldwide, Inc. Ion triggerable, cationic polymers, a method of making same and items using same
US20040058600A1 (en) * 2002-09-20 2004-03-25 Bunyard W. Clayton Water-dispersible, cationic polymers, a method of making same and items using same
US6960371B2 (en) * 2002-09-20 2005-11-01 Kimberly-Clark Worldwide, Inc. Water-dispersible, cationic polymers, a method of making same and items using same
US8163133B2 (en) * 2003-04-01 2012-04-24 Akzo Nobel N.V. Dispersion
DE102004027735A1 (de) 2004-06-07 2005-12-22 Basf Ag Feinteilige, amphotere, wässrige Polymerdispersionen, Verfahren zu ihrer Herstellung und ihre Verwendung
CN101558086B (zh) * 2006-12-14 2011-12-28 巴斯夫欧洲公司 细粒状阳离子聚合物分散体
BRPI1011137A2 (pt) 2009-06-04 2018-02-06 Basf Se dispersões aquosas de polímero catiônico finamente dividido, processo para a preparação das mesmas, e, uso das dispersões aquosas de polímero catiônico finamente dividido.
JP2013544934A (ja) 2010-11-25 2013-12-19 ビーエーエスエフ ソシエタス・ヨーロピア 微分散されたカチオン性又は両性の水性ポリマー分散液、その製造方法、その使用、カチオン性又は両性の保護コロイド及びその調製
EP2794698B1 (en) * 2011-12-19 2015-04-08 Rohm and Haas Company Sulfur acid functionalized latex polymer
US10647793B2 (en) 2014-03-28 2020-05-12 Synthomer (Uk) Limited Use of a sulphur or phosphorous-containing polymer as a processing aid in a polyvinyl chloride polymer composition
MX2016012328A (es) 2014-03-28 2017-01-23 Synthomer (Uk) Ltd Agente de suspension secundario para reaccion de polimerizacion en suspension.
ES2840649T3 (es) * 2015-12-01 2021-07-07 Solenis Technologies Cayman Lp Dispersiones poliméricas acuosas catiónicas finamente divididas, método para la producción de las mismas, y el uso de las mismas
CN109415462A (zh) 2016-06-30 2019-03-01 巴斯夫欧洲公司 细碎的阳离子性聚合物水分散体、其制备方法及其用途

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3296167A (en) * 1962-02-02 1967-01-03 Morton Int Inc Process for polymerizing an ethylenically unsaturated amine-containing monomeric mixture
US3404114A (en) * 1965-06-18 1968-10-01 Dow Chemical Co Method for preparing latexes having improved adhesive properties
DE1546236B2 (de) * 1965-09-21 1973-10-11 Badische Anilin- & Soda-Fabrik Ag, 6700 Ludwigshafen Verfahren zur Herstellung von ge leimten Papieren
CH479636A (de) * 1967-03-01 1969-10-15 Ciba Geigy Verfahren zur Herstellung von Copolymerisaten
US3536650A (en) * 1968-03-18 1970-10-27 Gaf Corp Preparation of stable aqueous emulsions
US3853803A (en) * 1971-01-27 1974-12-10 Ppg Industries Inc Method of preparing a cationic acrylic electrodepositable interpolymer
US3957710A (en) * 1972-04-26 1976-05-18 Basf Aktiengesellschaft Paper coating compositions from polymers of olefinically unsaturated monomers
US3925288A (en) * 1972-11-28 1975-12-09 Nat Starch Chem Corp Process for preparing salt stable latices

Also Published As

Publication number Publication date
SE7512291L (sv) 1976-05-07
IT1060074B (it) 1982-07-10
SE417720B (sv) 1981-04-06
US4051093A (en) 1977-09-27
FR2290454A1 (fr) 1976-06-04
FR2290454B1 (oth) 1979-07-20
CA1035074A (en) 1978-07-18
DE2452585C3 (oth) 1982-05-13
DE2452585A1 (de) 1976-05-13

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