DE2431434B2 - Dielektrische Polyolefinformmassen - Google Patents
Dielektrische PolyolefinformmassenInfo
- Publication number
- DE2431434B2 DE2431434B2 DE2431434A DE2431434A DE2431434B2 DE 2431434 B2 DE2431434 B2 DE 2431434B2 DE 2431434 A DE2431434 A DE 2431434A DE 2431434 A DE2431434 A DE 2431434A DE 2431434 B2 DE2431434 B2 DE 2431434B2
- Authority
- DE
- Germany
- Prior art keywords
- pyrene
- weight
- polyethylene
- voltage
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 229920000098 polyolefin Polymers 0.000 title claims description 28
- 238000000465 moulding Methods 0.000 title claims description 5
- 150000001875 compounds Chemical class 0.000 title claims 2
- 239000000203 mixture Substances 0.000 claims description 58
- 229920001577 copolymer Polymers 0.000 claims description 5
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 claims 1
- BBEAQIROQSPTKN-UHFFFAOYSA-N antipyrene Natural products C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 description 46
- -1 alkyl pyrene Chemical compound 0.000 description 45
- GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthrene Natural products C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 description 33
- 239000004698 Polyethylene Substances 0.000 description 30
- 229920000573 polyethylene Polymers 0.000 description 30
- HIOZPFGGCXEPAP-UHFFFAOYSA-N 1-propylpyrene Chemical compound C1=C2C(CCC)=CC=C(C=C3)C2=C2C3=CC=CC2=C1 HIOZPFGGCXEPAP-UHFFFAOYSA-N 0.000 description 24
- 239000000654 additive Substances 0.000 description 20
- YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 16
- 238000001035 drying Methods 0.000 description 13
- 238000006253 efflorescence Methods 0.000 description 11
- 206010037844 rash Diseases 0.000 description 11
- 230000015556 catabolic process Effects 0.000 description 9
- USXMMDRPRNSDOA-UHFFFAOYSA-N 2,7-dipropylpyrene Chemical compound C(CC)C=1C=C2C=CC3=CC(=CC4=CC=C(C=1)C2=C43)CCC USXMMDRPRNSDOA-UHFFFAOYSA-N 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 125000000217 alkyl group Chemical group 0.000 description 7
- 238000004132 cross linking Methods 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 230000000740 bleeding effect Effects 0.000 description 6
- 239000003431 cross linking reagent Substances 0.000 description 6
- YYHQDLFIPVKCQL-UHFFFAOYSA-N 1,2,3-tripropylpyrene Chemical compound C1=CC=C2C=CC3=C(CCC)C(CCC)=C(CCC)C4=CC=C1C2=C43 YYHQDLFIPVKCQL-UHFFFAOYSA-N 0.000 description 5
- ZWAMZDRREBOHIO-UHFFFAOYSA-N 1-ethylpyrene Chemical compound C1=C2C(CC)=CC=C(C=C3)C2=C2C3=CC=CC2=C1 ZWAMZDRREBOHIO-UHFFFAOYSA-N 0.000 description 5
- 230000000996 additive effect Effects 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 229920003020 cross-linked polyethylene Polymers 0.000 description 5
- 239000004703 cross-linked polyethylene Substances 0.000 description 5
- 230000007774 longterm Effects 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 4
- 150000001336 alkenes Chemical class 0.000 description 4
- 239000003849 aromatic solvent Substances 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 description 4
- 239000011810 insulating material Substances 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 239000008096 xylene Substances 0.000 description 4
- KBSPJIWZDWBDGM-UHFFFAOYSA-N 1-Methylpyrene Chemical compound C1=C2C(C)=CC=C(C=C3)C2=C2C3=CC=CC2=C1 KBSPJIWZDWBDGM-UHFFFAOYSA-N 0.000 description 3
- UFOTZLIYHMGVAV-UHFFFAOYSA-N 1-butylpyrene Chemical compound C1=C2C(CCCC)=CC=C(C=C3)C2=C2C3=CC=CC2=C1 UFOTZLIYHMGVAV-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- 230000003078 antioxidant effect Effects 0.000 description 3
- 238000006731 degradation reaction Methods 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- 150000003220 pyrenes Chemical class 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 230000000087 stabilizing effect Effects 0.000 description 3
- 230000004580 weight loss Effects 0.000 description 3
- IYDMICQAKLQHLA-UHFFFAOYSA-N 1-phenylnaphthalene Chemical compound C1=CC=CC=C1C1=CC=CC2=CC=CC=C12 IYDMICQAKLQHLA-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 229920001083 polybutene Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 210000002105 tongue Anatomy 0.000 description 2
- 229920000298 Cellophane Polymers 0.000 description 1
- 239000004971 Cross linker Substances 0.000 description 1
- 238000005727 Friedel-Crafts reaction Methods 0.000 description 1
- 230000002152 alkylating effect Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000011280 coal tar Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 239000012772 electrical insulation material Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 125000005575 polycyclic aromatic hydrocarbon group Chemical group 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000011973 solid acid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000011269 tar Substances 0.000 description 1
- 230000003685 thermal hair damage Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/01—Hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP48074364A JPS5112058B2 (cg-RX-API-DMAC7.html) | 1973-07-03 | 1973-07-03 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2431434A1 DE2431434A1 (de) | 1975-04-30 |
| DE2431434B2 true DE2431434B2 (de) | 1978-10-05 |
Family
ID=13545009
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2431434A Ceased DE2431434B2 (de) | 1973-07-03 | 1974-06-29 | Dielektrische Polyolefinformmassen |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3933772A (cg-RX-API-DMAC7.html) |
| JP (1) | JPS5112058B2 (cg-RX-API-DMAC7.html) |
| CA (1) | CA1031890A (cg-RX-API-DMAC7.html) |
| DE (1) | DE2431434B2 (cg-RX-API-DMAC7.html) |
| FR (1) | FR2235969B1 (cg-RX-API-DMAC7.html) |
| GB (1) | GB1461331A (cg-RX-API-DMAC7.html) |
| SU (1) | SU584816A3 (cg-RX-API-DMAC7.html) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52108661U (cg-RX-API-DMAC7.html) * | 1976-02-14 | 1977-08-18 | ||
| US5401794A (en) * | 1994-06-03 | 1995-03-28 | Shell Oil Company | Stabilized polyketone polymer compositions |
| US6162838A (en) * | 1998-06-05 | 2000-12-19 | Georgia Tech Research Corporation | Porous insulating compounds and method for making same |
| TWI226103B (en) * | 2000-08-31 | 2005-01-01 | Georgia Tech Res Inst | Fabrication of semiconductor devices with air gaps for ultra low capacitance interconnections and methods of making same |
| US6879861B2 (en) * | 2000-12-21 | 2005-04-12 | Medtronic, Inc. | Polymeric materials with improved dielectric breakdown strength |
| US8455096B2 (en) * | 2007-03-28 | 2013-06-04 | The University Of Massachusetts | Reinforced polymeric materials, methods of manufacture thereof and articles comprising the same |
| EP2622610B1 (en) | 2010-09-30 | 2014-08-20 | Union Carbide Chemicals & Plastics Technology LLC | Coated conductor with voltage stabilized inner layer |
| KR101856268B1 (ko) | 2010-09-30 | 2018-05-09 | 유니온 카바이드 케미칼즈 앤드 플라스틱스 테크날러지 엘엘씨 | 전압 안정화제를 첨가시킨 중합체 조성물 |
| US10490318B2 (en) | 2013-04-18 | 2019-11-26 | Dow Global Technologies Llc | Coated conductor with voltage-stabilized inner layer |
| CN103450205A (zh) * | 2013-09-02 | 2013-12-18 | 南开大学 | 一种基于多齿吡啶类喹喔啉荧光探针的制备方法和应用 |
| CA3197082A1 (en) * | 2020-10-30 | 2022-05-05 | Dow Global Technologies Llc | Polyolefin formulation |
| MX2024001049A (es) | 2021-08-04 | 2024-02-27 | Dow Global Technologies Llc | Formulacion de poliolefina que contiene combinacion de compuestos estabilizadores de voltaje. |
| KR20240041977A (ko) | 2021-08-04 | 2024-04-01 | 다우 글로벌 테크놀로지스 엘엘씨 | 크로토페논 화합물을 함유하는 폴리올레핀 제형 |
| CN120535861B (zh) * | 2025-07-29 | 2025-11-04 | 北京怀柔实验室 | 聚乙烯基绝缘料及其制备方法、高压直流交联电缆 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3075040A (en) * | 1957-07-26 | 1963-01-22 | Siemens Ag | Method for improving the electric strength and flash-over or glowdischarge resistance of olefine polymers |
| FR1432360A (fr) * | 1965-05-06 | 1966-03-18 | Siemens Ag | Câble électrique, de préférence à haute tension, avec une isolation constituée par un polymérisat oléfinique, en particulier du polyéthylène |
| US3445394A (en) * | 1967-06-27 | 1969-05-20 | Simplex Wire & Cable Co | Voltage stabilized solid polyolefin dielectric |
| US3632680A (en) * | 1968-03-20 | 1972-01-04 | Simplex Wire & Cable Co | Cross-linked polyolefin compositions |
| US3522183A (en) * | 1968-05-07 | 1970-07-28 | Simplex Wire & Cable Co | Solid dielectric polyolefin compositions containing various voltage stabilizers |
| US3542682A (en) * | 1968-06-19 | 1970-11-24 | Gaf Corp | Liquid toners for electrostatic printing |
| US3629110A (en) * | 1968-10-02 | 1971-12-21 | Simplex Wire & Cable Co | Solid dielectric polyolefin compositions containing voltage stabilizers |
-
1973
- 1973-07-03 JP JP48074364A patent/JPS5112058B2/ja not_active Expired
-
1974
- 1974-06-20 US US05/481,256 patent/US3933772A/en not_active Expired - Lifetime
- 1974-06-21 CA CA203,017A patent/CA1031890A/en not_active Expired
- 1974-06-27 FR FR7422461A patent/FR2235969B1/fr not_active Expired
- 1974-06-27 GB GB2859874A patent/GB1461331A/en not_active Expired
- 1974-06-29 DE DE2431434A patent/DE2431434B2/de not_active Ceased
- 1974-07-02 SU SU7402046187A patent/SU584816A3/ru active
Also Published As
| Publication number | Publication date |
|---|---|
| FR2235969B1 (cg-RX-API-DMAC7.html) | 1977-03-11 |
| SU584816A3 (ru) | 1977-12-15 |
| JPS5023439A (cg-RX-API-DMAC7.html) | 1975-03-13 |
| GB1461331A (en) | 1977-01-13 |
| CA1031890A (en) | 1978-05-23 |
| DE2431434A1 (de) | 1975-04-30 |
| JPS5112058B2 (cg-RX-API-DMAC7.html) | 1976-04-15 |
| US3933772A (en) | 1976-01-20 |
| FR2235969A1 (cg-RX-API-DMAC7.html) | 1975-01-31 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8235 | Patent refused |