DE2414272C2 - Vielzellige Formteile aus einem orientierbaren thermoplastischen Material und mindestens einem Zusatzstoff und Verfahren zu ihrer Herstellung - Google Patents
Vielzellige Formteile aus einem orientierbaren thermoplastischen Material und mindestens einem Zusatzstoff und Verfahren zu ihrer HerstellungInfo
- Publication number
- DE2414272C2 DE2414272C2 DE19742414272 DE2414272A DE2414272C2 DE 2414272 C2 DE2414272 C2 DE 2414272C2 DE 19742414272 DE19742414272 DE 19742414272 DE 2414272 A DE2414272 A DE 2414272A DE 2414272 C2 DE2414272 C2 DE 2414272C2
- Authority
- DE
- Germany
- Prior art keywords
- thermoplastic material
- additive
- stretching
- mixture
- udf54
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000012815 thermoplastic material Substances 0.000 title claims description 46
- 239000000654 additive Substances 0.000 title claims description 37
- 238000000034 method Methods 0.000 title claims description 30
- 230000008569 process Effects 0.000 title claims description 26
- 230000000996 additive effect Effects 0.000 title claims description 23
- 238000004519 manufacturing process Methods 0.000 title description 11
- 239000000203 mixture Substances 0.000 claims description 78
- 229910052751 metal Inorganic materials 0.000 claims description 61
- 239000002184 metal Substances 0.000 claims description 61
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 45
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 45
- 150000002148 esters Chemical class 0.000 claims description 45
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 45
- 239000000945 filler Substances 0.000 claims description 25
- 229920000642 polymer Polymers 0.000 claims description 20
- 238000000465 moulding Methods 0.000 claims description 19
- 229920001169 thermoplastic Polymers 0.000 claims description 17
- 229920000573 polyethylene Polymers 0.000 claims description 15
- IHBCFWWEZXPPLG-UHFFFAOYSA-N [Ca].[Zn] Chemical compound [Ca].[Zn] IHBCFWWEZXPPLG-UHFFFAOYSA-N 0.000 claims description 13
- 229920001903 high density polyethylene Polymers 0.000 claims description 13
- 239000000049 pigment Substances 0.000 claims description 13
- 229920001155 polypropylene Polymers 0.000 claims description 13
- 230000009477 glass transition Effects 0.000 claims description 12
- 239000004700 high-density polyethylene Substances 0.000 claims description 12
- 239000002253 acid Substances 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 9
- MXODCLTZTIFYDV-UHFFFAOYSA-L zinc;1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylate Chemical compound [Zn+2].C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C([O-])=O.C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C([O-])=O MXODCLTZTIFYDV-UHFFFAOYSA-L 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 239000005977 Ethylene Substances 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- -1 polyethylene Polymers 0.000 description 29
- 230000009467 reduction Effects 0.000 description 29
- 239000000463 material Substances 0.000 description 27
- 210000004027 cell Anatomy 0.000 description 18
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 16
- 239000004416 thermosoftening plastic Substances 0.000 description 15
- 239000004698 Polyethylene Substances 0.000 description 13
- 238000002844 melting Methods 0.000 description 13
- 230000008018 melting Effects 0.000 description 13
- 238000012360 testing method Methods 0.000 description 12
- 239000004743 Polypropylene Substances 0.000 description 11
- 210000003850 cellular structure Anatomy 0.000 description 10
- 238000001125 extrusion Methods 0.000 description 9
- 239000011148 porous material Substances 0.000 description 9
- 229910000019 calcium carbonate Inorganic materials 0.000 description 8
- 239000013078 crystal Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 238000011282 treatment Methods 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- 239000008187 granular material Substances 0.000 description 6
- 239000000155 melt Substances 0.000 description 6
- 238000004381 surface treatment Methods 0.000 description 6
- 239000004793 Polystyrene Substances 0.000 description 5
- 230000001413 cellular effect Effects 0.000 description 5
- 238000007645 offset printing Methods 0.000 description 5
- 229920002223 polystyrene Polymers 0.000 description 5
- 238000009864 tensile test Methods 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- 229920000098 polyolefin Polymers 0.000 description 4
- 229920000915 polyvinyl chloride Polymers 0.000 description 4
- 238000007639 printing Methods 0.000 description 4
- 230000009471 action Effects 0.000 description 3
- 238000007664 blowing Methods 0.000 description 3
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000010096 film blowing Methods 0.000 description 3
- 238000005188 flotation Methods 0.000 description 3
- 239000004800 polyvinyl chloride Substances 0.000 description 3
- 239000004408 titanium dioxide Substances 0.000 description 3
- 239000004604 Blowing Agent Substances 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000000292 calcium oxide Substances 0.000 description 2
- 235000012255 calcium oxide Nutrition 0.000 description 2
- DWPDSISGRAWLLV-JHZYRPMRSA-L calcium;(1r,4ar,4br,10ar)-1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylate Chemical compound [Ca+2].C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C([O-])=O.C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C([O-])=O DWPDSISGRAWLLV-JHZYRPMRSA-L 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000011800 void material Substances 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229920006125 amorphous polymer Polymers 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000001739 density measurement Methods 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910052806 inorganic carbonate Inorganic materials 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 150000004668 long chain fatty acids Chemical class 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000386 microscopy Methods 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000012766 organic filler Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920005553 polystyrene-acrylate Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
- B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/24—Formation of filaments, threads, or the like with a hollow structure; Spinnerette packs therefor
- D01D5/247—Discontinuous hollow structure or microporous structure
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- General Chemical & Material Sciences (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1451373A GB1470372A (en) | 1973-03-26 | 1973-03-26 | Thermoplastics compositions |
| GB5065473 | 1973-10-31 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE2414272A1 DE2414272A1 (de) | 1974-10-17 |
| DE2414272C2 true DE2414272C2 (de) | 1987-04-09 |
Family
ID=26250613
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19742414272 Expired DE2414272C2 (de) | 1973-03-26 | 1974-03-25 | Vielzellige Formteile aus einem orientierbaren thermoplastischen Material und mindestens einem Zusatzstoff und Verfahren zu ihrer Herstellung |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS6230896B2 (enrdf_load_stackoverflow) |
| BE (1) | BE812853A (enrdf_load_stackoverflow) |
| DE (1) | DE2414272C2 (enrdf_load_stackoverflow) |
| FR (1) | FR2223401B1 (enrdf_load_stackoverflow) |
| GB (1) | GB1470372A (enrdf_load_stackoverflow) |
| IT (1) | IT1004416B (enrdf_load_stackoverflow) |
| NL (1) | NL188627C (enrdf_load_stackoverflow) |
| SE (1) | SE396082B (enrdf_load_stackoverflow) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DK465887A (da) * | 1986-09-17 | 1988-03-18 | Charbonnages Ste Chimique | Fremgangsmaade til polymerisering og en derved fremstillet polystyren |
| EP0470760B1 (en) | 1990-08-09 | 1997-05-14 | BXL Plastics Limited | Composite plastics film or sheet |
| GB9419386D0 (en) | 1994-09-26 | 1994-11-09 | Arjobex Ltd | Composite plastics film or sheet |
| GB9704470D0 (en) * | 1997-03-04 | 1997-04-23 | Arjobex Ltd | Composite plastics film or sheet |
| EP1055711B1 (en) * | 1999-05-26 | 2004-11-24 | Arjobex Limited | Polymer coating composition for a plastics substrate |
| GB0006891D0 (en) | 2000-03-23 | 2000-05-10 | Arjobex Ltd | Coating composition |
| GB0216052D0 (en) | 2002-07-10 | 2002-08-21 | Arjobex Ltd | Synthetic paper label |
| FR2925864B1 (fr) * | 2007-12-28 | 2012-08-31 | Arjowiggins Licensing Sas | Feuille de securite comportant un support coextrude |
| GB2483653B (en) | 2010-09-14 | 2017-03-22 | Arjobex Ltd | Polymeric label material |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2447367A (en) * | 1944-10-07 | 1948-08-17 | Montclair Res Corp | Reaction product of rosin-polyhydric alcohol esters and process of making same |
| GB856834A (en) * | 1958-02-03 | 1960-12-21 | Westinghouse Brake & Signal | Improvements in and relating to thermo-plastic sealing compounds |
| US2950210A (en) * | 1958-12-08 | 1960-08-23 | Harold D Schrier | Coating composition |
| US3463752A (en) * | 1965-04-02 | 1969-08-26 | Grace W R & Co | Thermoplastic polymer of a monoolefin |
-
1973
- 1973-03-26 GB GB1451373A patent/GB1470372A/en not_active Expired
-
1974
- 1974-03-25 SE SE7404002A patent/SE396082B/xx not_active IP Right Cessation
- 1974-03-25 DE DE19742414272 patent/DE2414272C2/de not_active Expired
- 1974-03-26 FR FR7410269A patent/FR2223401B1/fr not_active Expired
- 1974-03-26 NL NL7404092A patent/NL188627C/xx not_active IP Right Cessation
- 1974-03-26 JP JP3382974A patent/JPS6230896B2/ja not_active Expired
- 1974-03-26 BE BE142470A patent/BE812853A/xx not_active IP Right Cessation
- 1974-03-26 IT IT4970674A patent/IT1004416B/it active
Also Published As
| Publication number | Publication date |
|---|---|
| BE812853A (fr) | 1974-09-26 |
| AU6714074A (en) | 1975-10-02 |
| NL188627B (nl) | 1992-03-16 |
| JPS6230896B2 (enrdf_load_stackoverflow) | 1987-07-06 |
| SE396082B (sv) | 1977-09-05 |
| FR2223401B1 (enrdf_load_stackoverflow) | 1977-09-30 |
| JPS5026846A (enrdf_load_stackoverflow) | 1975-03-19 |
| GB1470372A (en) | 1977-04-14 |
| NL188627C (nl) | 1992-08-17 |
| FR2223401A1 (enrdf_load_stackoverflow) | 1974-10-25 |
| NL7404092A (enrdf_load_stackoverflow) | 1974-09-30 |
| IT1004416B (it) | 1976-07-10 |
| DE2414272A1 (de) | 1974-10-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8141 | Disposal/no request for examination | ||
| 8128 | New person/name/address of the agent |
Representative=s name: SCHOENWALD, K., DR.-ING. FUES, J., DIPL.-CHEM. DR. |
|
| 8110 | Request for examination paragraph 44 | ||
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition |