DE2258299A1 - Verfahren und vorrichtung zur fraktionierung eines gasgemisches durch adsorption - Google Patents

Verfahren und vorrichtung zur fraktionierung eines gasgemisches durch adsorption

Info

Publication number
DE2258299A1
DE2258299A1 DE19722258299 DE2258299A DE2258299A1 DE 2258299 A1 DE2258299 A1 DE 2258299A1 DE 19722258299 DE19722258299 DE 19722258299 DE 2258299 A DE2258299 A DE 2258299A DE 2258299 A1 DE2258299 A1 DE 2258299A1
Authority
DE
Germany
Prior art keywords
adsorption
phase
pressure
zone
auxiliary
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DE19722258299
Other languages
German (de)
English (en)
Inventor
Claude Pivard
Guy Simonet
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Air Liquide SA
Original Assignee
Air Liquide SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Air Liquide SA filed Critical Air Liquide SA
Publication of DE2258299A1 publication Critical patent/DE2258299A1/de
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047—Pressure swing adsorption
    • B01D53/0476—Vacuum pressure swing adsorption
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B21/00—Nitrogen; Compounds thereof
    • C01B21/02—Preparation of nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/104—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B01D2253/108—Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/10—Nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/12—Oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/10—Single element gases other than halogens
    • B01D2257/102—Nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/10—Single element gases other than halogens
    • B01D2257/104—Oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/80—Water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
    • B01D2259/40043—Purging
    • B01D2259/4005—Nature of purge gas
    • B01D2259/40052—Recycled product or process gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
    • B01D2259/40058—Number of sequence steps, including sub-steps, per cycle
    • B01D2259/4006—Less than four
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
    • B01D2259/40058—Number of sequence steps, including sub-steps, per cycle
    • B01D2259/40062—Four
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/401—Further details for adsorption processes and devices using a single bed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/403—Further details for adsorption processes and devices using three beds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/406—Further details for adsorption processes and devices using more than four beds
    • B01D2259/4062—Further details for adsorption processes and devices using more than four beds using six beds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/65—Employing advanced heat integration, e.g. Pinch technology
    • B01D2259/655—Employing advanced heat integration, e.g. Pinch technology using heat storage materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/26—Drying gases or vapours
    • B01D53/261—Drying gases or vapours by adsorption
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Storage Of Fruits Or Vegetables (AREA)
  • Gas Separation By Absorption (AREA)
DE19722258299 1971-11-30 1972-11-29 Verfahren und vorrichtung zur fraktionierung eines gasgemisches durch adsorption Pending DE2258299A1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7142793A FR2162732A5 (enExample) 1971-11-30 1971-11-30

Publications (1)

Publication Number Publication Date
DE2258299A1 true DE2258299A1 (de) 1973-06-07

Family

ID=9086618

Family Applications (1)

Application Number Title Priority Date Filing Date
DE19722258299 Pending DE2258299A1 (de) 1971-11-30 1972-11-29 Verfahren und vorrichtung zur fraktionierung eines gasgemisches durch adsorption

Country Status (8)

Country Link
US (1) US3796022A (enExample)
JP (1) JPS4863972A (enExample)
BE (1) BE792039A (enExample)
CA (1) CA974462A (enExample)
DE (1) DE2258299A1 (enExample)
FR (1) FR2162732A5 (enExample)
GB (1) GB1421786A (enExample)
IT (1) IT971121B (enExample)

Families Citing this family (46)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2460513C3 (de) * 1974-12-20 1979-01-25 Linde Ag, 6200 Wiesbaden Verfahren und Vorrichtung zur Zerlegung von Gasgemischen durch adiabatische Ad- und Desorption
US4013429A (en) * 1975-06-04 1977-03-22 Air Products And Chemicals, Inc. Fractionation of air by adsorption
US4190424A (en) * 1975-07-17 1980-02-26 Boc Limited Gas separation
DE2604305A1 (de) * 1976-02-04 1977-08-11 Linde Ag Verfahren zum zerlegen von gasgemischen
US4077779A (en) * 1976-10-15 1978-03-07 Air Products And Chemicals, Inc. Hydrogen purification by selective adsorption
US4194890A (en) * 1976-11-26 1980-03-25 Greene & Kellogg, Inc. Pressure swing adsorption process and system for gas separation
DE2724763C2 (de) * 1977-06-01 1984-02-16 Linde Ag, 6200 Wiesbaden Verfahren zum Reinigen und Zerlegen eines Gasgemisches
US4263018A (en) * 1978-02-01 1981-04-21 Greene & Kellogg Pressure swing adsorption process and system for gas separation
US4171207A (en) * 1978-08-21 1979-10-16 Air Products And Chemicals, Inc. Separation of multicomponent gas mixtures by pressure swing adsorption
US4171206A (en) * 1978-08-21 1979-10-16 Air Products And Chemicals, Inc. Separation of multicomponent gas mixtures
US4197096A (en) * 1978-08-22 1980-04-08 Boc Limited Fluid supply system including a pressure-swing adsorption plant
US4264340A (en) * 1979-02-28 1981-04-28 Air Products And Chemicals, Inc. Vacuum swing adsorption for air fractionation
US4249915A (en) * 1979-05-30 1981-02-10 Air Products And Chemicals, Inc. Removal of water and carbon dioxide from air
US4305734A (en) 1979-09-19 1981-12-15 Mcgill Incorporated Recovery of hydrocarbon components from a hydrocarbon-carrier gas mixture
JPS5681119A (en) * 1979-12-07 1981-07-02 Toray Ind Inc Separation of mixed gas
US4329158A (en) * 1980-06-13 1982-05-11 Air Products And Chemicals, Inc. Air fractionation by pressure swing adsorption
US4431432A (en) * 1980-12-26 1984-02-14 Mitsubishi Jukogyo Kabushiki Kaisha Process and apparatus for separating a mixed gas such as air
US4386945A (en) * 1982-02-01 1983-06-07 Litton Systems, Inc. Process and compound bed means for evolving a first component enriched gas
US4452612A (en) * 1982-09-22 1984-06-05 Cubemco, Inc. Separation and purification of gases and vapors by continuous pressure-swing adsorption
FR2535981A1 (fr) * 1982-11-12 1984-05-18 Air Liquide Procede et installation de separation par adsorption d'un gaz composite
US4529416A (en) * 1983-02-11 1985-07-16 Air Products And Chemicals, Inc. Gas separation kinetics in commercial pellets
US4477264A (en) * 1983-03-30 1984-10-16 Air Products And Chemicals, Inc. Pressure swing adsorption process for a medical oxygen generator for home use
DE3483664D1 (de) * 1983-06-20 1991-01-10 Kawasaki Steel Co Verfahren zur herstellung von hochreinem kohlenmonoxid.
US4539020A (en) * 1983-07-10 1985-09-03 Kawasaki Steel Corporation Methods for obtaining high-purity carbon monoxide
US4561865A (en) * 1983-11-01 1985-12-31 Greene & Kellogg, Inc. Single bed pressure swing adsorption gas separation system
US4726816A (en) * 1983-11-08 1988-02-23 Union Carbide Corporation Reformer-pressure swing adsorption process for the production of carbon monoxide
US4512780A (en) * 1983-11-08 1985-04-23 Union Carbide Corporation Pressure swing adsorption with intermediate product recovery
DE3433058A1 (de) * 1984-09-08 1986-03-20 Bergwerksverband Gmbh, 4300 Essen Verfahren und vorrichtung zur erzeugung von stickstoff
US4681602A (en) * 1984-12-24 1987-07-21 The Boeing Company Integrated system for generating inert gas and breathing gas on aircraft
US4685939A (en) * 1985-03-19 1987-08-11 Air Products And Chemicals, Inc. Production of oxygen enriched air
US4711645A (en) * 1986-02-10 1987-12-08 Air Products And Chemicals, Inc. Removal of water and carbon dioxide from atmospheric air
JPS63166702A (ja) * 1986-12-26 1988-07-09 Osaka Oxygen Ind Ltd 酸素ガス濃縮法
US4810265A (en) * 1987-12-29 1989-03-07 Union Carbide Corporation Pressure swing adsorption process for gas separation
US4948391A (en) * 1988-05-12 1990-08-14 Vacuum Optics Corporation Of Japan Pressure swing adsorption process for gas separation
FR2633847B1 (fr) * 1988-07-08 1991-04-19 Air Liquide Procede de traitement d'un melange gazeux par adsorption
DE3829584A1 (de) * 1988-09-01 1990-03-08 Bayer Ag Trennung von gasgemischen durch vakuum swing adsorption in einem zwei-adsorber-system
DE3842930A1 (de) * 1988-12-21 1990-06-28 Bayer Ag Verfahren zur adsorptiven sauerstoffanreicherung von luft mit mischungen aus ca-zeolith a molekularsieben mittels vakuum-swing-adsorption
US5042994A (en) * 1990-05-25 1991-08-27 Union Carbide Industrial Gases Technology Corporation Control of pressure swing adsorption operations
US5163978A (en) * 1991-10-08 1992-11-17 Praxair Technology, Inc. Dual product pressure swing adsorption process and system
US5232473A (en) * 1992-05-07 1993-08-03 The Boc Group, Inc. Pressure swing adsorption with countercurrent feed pressurization
US5620501A (en) * 1995-08-15 1997-04-15 The Boc Group, Inc. Recovery of trace gases from gas streams
US5674311A (en) * 1995-10-20 1997-10-07 Praxair Technology, Inc. Adsorption process and system using multilayer adsorbent beds
US5997611A (en) * 1998-07-24 1999-12-07 The Boc Group, Inc. Single vessel gas adsorption system and process
US6162283A (en) * 1999-02-01 2000-12-19 Fantom Technologies Inc. Method and apparatus for concentrating a gas using a single stage adsorption zone
US6156100A (en) * 1999-02-01 2000-12-05 Fantom Technologies, Inc. Method and apparatus for concentrating a gas using a single stage adsorption zone
US6217635B1 (en) * 1998-11-09 2001-04-17 Fantom Technologies Inc. Method and apparatus for concentrating a gas using a single stage adsorption chamber

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE625444A (enExample) * 1961-12-14
FR2070387A5 (enExample) * 1969-12-03 1971-09-10 Air Liquide
FR2097633A5 (enExample) * 1970-07-16 1972-03-03 Air Liquide
DE2055425B2 (de) * 1970-11-11 1979-09-06 Bayer Ag, 5090 Leverkusen Adsorptionsverfahren zum Zerlegen von Gasgemischen

Also Published As

Publication number Publication date
GB1421786A (en) 1976-01-21
BE792039A (fr) 1973-05-29
JPS4863972A (enExample) 1973-09-05
FR2162732A5 (enExample) 1973-07-20
CA974462A (en) 1975-09-16
IT971121B (it) 1974-04-30
US3796022A (en) 1974-03-12

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