DE2129231C3 - Verfahren zur Abscheidung von Schwefeldioxid aus den Rauchgasen schwefelhaltiger Brennstoffe - Google Patents
Verfahren zur Abscheidung von Schwefeldioxid aus den Rauchgasen schwefelhaltiger BrennstoffeInfo
- Publication number
- DE2129231C3 DE2129231C3 DE2129231A DE2129231A DE2129231C3 DE 2129231 C3 DE2129231 C3 DE 2129231C3 DE 2129231 A DE2129231 A DE 2129231A DE 2129231 A DE2129231 A DE 2129231A DE 2129231 C3 DE2129231 C3 DE 2129231C3
- Authority
- DE
- Germany
- Prior art keywords
- pipe
- pellets
- sulfur
- suspension
- flue gases
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 title claims description 14
- 238000000034 method Methods 0.000 title claims description 12
- 239000003546 flue gas Substances 0.000 title claims description 9
- 239000000446 fuel Substances 0.000 title claims description 9
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims description 7
- 229910052717 sulfur Inorganic materials 0.000 title claims description 7
- 239000011593 sulfur Substances 0.000 title claims description 7
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 26
- 239000008188 pellet Substances 0.000 claims description 25
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 22
- 239000000395 magnesium oxide Substances 0.000 claims description 17
- 238000010521 absorption reaction Methods 0.000 claims description 16
- 239000000725 suspension Substances 0.000 claims description 14
- 239000011230 binding agent Substances 0.000 claims description 11
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 11
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 11
- 239000006096 absorbing agent Substances 0.000 claims description 8
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- JESHZQPNPCJVNG-UHFFFAOYSA-L magnesium;sulfite Chemical compound [Mg+2].[O-]S([O-])=O JESHZQPNPCJVNG-UHFFFAOYSA-L 0.000 claims description 6
- 238000005406 washing Methods 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 230000008929 regeneration Effects 0.000 claims description 3
- 238000011069 regeneration method Methods 0.000 claims description 3
- 239000007900 aqueous suspension Substances 0.000 claims description 2
- 239000008187 granular material Substances 0.000 claims description 2
- 238000000926 separation method Methods 0.000 claims description 2
- 238000011144 upstream manufacturing Methods 0.000 claims description 2
- 239000007788 liquid Substances 0.000 description 22
- 239000007789 gas Substances 0.000 description 18
- 239000007787 solid Substances 0.000 description 14
- 239000013078 crystal Substances 0.000 description 11
- 239000000706 filtrate Substances 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 239000003245 coal Substances 0.000 description 5
- 239000011777 magnesium Substances 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- 239000002817 coal dust Substances 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 239000000428 dust Substances 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000000567 combustion gas Substances 0.000 description 2
- 229910000514 dolomite Inorganic materials 0.000 description 2
- 239000010459 dolomite Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- JEOQACOXAOEPLX-WCCKRBBISA-N (2s)-2-amino-5-(diaminomethylideneamino)pentanoic acid;1,3-thiazolidine-4-carboxylic acid Chemical compound OC(=O)C1CSCN1.OC(=O)[C@@H](N)CCCN=C(N)N JEOQACOXAOEPLX-WCCKRBBISA-N 0.000 description 1
- 240000007124 Brassica oleracea Species 0.000 description 1
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 description 1
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 description 1
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical class C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000004449 solid propellant Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 229910052815 sulfur oxide Inorganic materials 0.000 description 1
- 230000000153 supplemental effect Effects 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/48—Sulfur dioxide; Sulfurous acid
- C01B17/50—Preparation of sulfur dioxide
- C01B17/60—Isolation of sulfur dioxide from gases
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Biomedical Technology (AREA)
- Treating Waste Gases (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US6293070A | 1970-08-11 | 1970-08-11 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| DE2129231A1 DE2129231A1 (de) | 1972-02-24 |
| DE2129231B2 DE2129231B2 (de) | 1974-11-14 |
| DE2129231C3 true DE2129231C3 (de) | 1975-07-03 |
Family
ID=22045788
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE2129231A Expired DE2129231C3 (de) | 1970-08-11 | 1971-06-12 | Verfahren zur Abscheidung von Schwefeldioxid aus den Rauchgasen schwefelhaltiger Brennstoffe |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3758668A (enExample) |
| JP (1) | JPS5144496B1 (enExample) |
| CA (1) | CA955378A (enExample) |
| DE (1) | DE2129231C3 (enExample) |
| ES (1) | ES391709A1 (enExample) |
| FR (1) | FR2104214A5 (enExample) |
| GB (1) | GB1344700A (enExample) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3919394A (en) * | 1973-05-14 | 1975-11-11 | Dravo Corp | Process for the removal of oxides of sulfur from a gaseous stream |
| US3971844A (en) * | 1974-02-19 | 1976-07-27 | Davy Powergas Inc. | Method for removing sodium sulfate from aqueous solutions |
| JPS5710769B2 (enExample) * | 1974-06-03 | 1982-02-27 | ||
| US4218428A (en) * | 1976-11-15 | 1980-08-19 | Idemitsu Kosan Company Limited | Process for removing chlorine ions from the wet flue-gas processing system |
| CS225767B1 (en) * | 1982-01-14 | 1984-02-13 | Najmr Stanislav | The purification of magnesium raw materials |
| JPS6472915A (en) * | 1987-09-15 | 1989-03-17 | Kuraray Co | Production of ammonia and sulfur dioxide |
| DE3830390C1 (en) * | 1988-09-07 | 1989-12-07 | Deutsche Babcock Anlagen Ag, 4200 Oberhausen, De | Regenerative SO2 flue gas purification |
| DE4216404A1 (de) * | 1992-05-18 | 1993-11-25 | Testoterm Mestechnik Gmbh & Co | Gasentnahmevorrichtung für ein Rauchgas-Analysegerät |
| US6726748B2 (en) * | 2002-07-16 | 2004-04-27 | The Babcock & Wilcox Company | Method of converting a downflow/upflow wet flue gas desulfurization (WFGD) system to an upflow single-loop WFGD system |
| CN101607173B (zh) * | 2008-06-17 | 2012-05-23 | 陆泳凯 | 外部再生循环亚硫酸镁法烟气或废气的脱硫工艺 |
| US9192890B2 (en) * | 2013-11-15 | 2015-11-24 | The Babcock & Wilcox Company | Integrated sorbent injection and flue gas desulfurization system |
-
1970
- 1970-08-11 US US00062930A patent/US3758668A/en not_active Expired - Lifetime
-
1971
- 1971-04-20 CA CA110,793A patent/CA955378A/en not_active Expired
- 1971-05-18 GB GB1556571*[A patent/GB1344700A/en not_active Expired
- 1971-05-19 ES ES391709A patent/ES391709A1/es not_active Expired
- 1971-06-12 DE DE2129231A patent/DE2129231C3/de not_active Expired
- 1971-08-11 JP JP46060364A patent/JPS5144496B1/ja active Pending
- 1971-08-11 FR FR7129323A patent/FR2104214A5/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| US3758668A (en) | 1973-09-11 |
| CA955378A (en) | 1974-10-01 |
| FR2104214A5 (enExample) | 1972-04-14 |
| GB1344700A (en) | 1974-01-23 |
| DE2129231A1 (de) | 1972-02-24 |
| ES391709A1 (es) | 1973-06-16 |
| JPS5144496B1 (enExample) | 1976-11-29 |
| DE2129231B2 (de) | 1974-11-14 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C3 | Grant after two publication steps (3rd publication) |