DE19934254A1 - Washing or detergent portion comprises a measured amount of a washing composition(s) and a polymer material enclosing it and also containing a washing composition(s) - Google Patents

Abstract

Washing or detergent portion comprises a measured amount of a washing composition(s) and a polymer material enclosing it and also containing a washing composition(s). Washing or detergent portion comprises a measured amount of a washing composition(s) and a polymer material enclosing it and also containing a washing composition(s). Independent claims are included for an enclosure for a measured amount of a washing composition comprising water-soluble polymers containing at least one component of the washing composition, the production of the portions by forming a polymer containing a washing component(s) and enclosing a washing component and machine washing and cleaning processes involving using the above product.

Description

The present invention relates to a detergent or cleaning agent portion with a new packaging, especially with a water-soluble Verpac kung, further especially with a water-soluble at a certain temperature Chen packaging, but with the ingredients of the washing or cleaning serving portion no adverse interaction. The invention relates next a new packaging for detergents or cleaning agents with opposite properties improved in the prior art.

Detergents and cleaning agents as well as processes for their production have been around since have long been known and are extensively described in the prior art. Usual Detergents or cleaning agents are usually in the form of the consumer spray-dried or granulated solid products or as liquid goods for Provided. The desire of the consumer for options one Following the convenient dosage, in addition to the two classi mentioned variants are established and are on the market in pre-portioned form also described in the prior art. There are descriptions of detergents or cleaning agents in the form of pressed molded articles, i.e. Ta blanks, blocks, briquettes, rings and the like and packaged in bags portions of solid and / or liquid washing or cleaning agents.

In the case of single-dose amounts of detergents or cleaning agents that are in Packed bags come on the market, bags made of water-soluble  Foil enforced. These cause the packaging to tear open Consumers unnecessary. This makes it easy to dose a single one portion for a washing or cleaning cycle by inserting the bag directly into the washing machine or dishwasher target in their induction chamber or by throwing the bag into a be right amount of water, for example in a bucket, a bowl or in Hand wash or sink, possible. The washing or cleaning agent The portion of the surrounding pouch releases when a certain temperature is reached residue-free. Also packed in bags made of water-soluble film Detergents and cleaning agents are in large numbers in the prior art wrote.

For example, the older patent application DE 198 31 703 discloses a portioned portion Detergent or cleaning agent preparation in a bag made of water-soluble Foil, especially a pouch made of (optionally acetalized) Po lyvinyl alcohol (PVAL), in which at least 70% by weight of the particles of the washing or detergent preparation have particle sizes <800 µm.

The water content as well as the content of others contained in the film material Components settles with the content of water in the surrounding air (Humidity) and possibly other compounds in equilibrium. The same thing happens between the film and the inside of the bag. With others Words, phase equilibrium occurs over time.

Moisture environment ≷ Water content film ≷ Moisture inside the bag.

For the packaged product, this situation is almost equivalent to an of Open storage of the product in the ambient air.

Especially in connection with the moisture or the water content of the Folie brings problems with this situation and is very special in the case  the use of percarbonates as bleaching agents in washing or cleaning formulation undesirable. Percarbonates are in the presence of moisture activity is not stable in the long run, and water intake reduces activity this component noticeably. Under conditions of a certain humidity that is, detergents or cleaning agents containing percarbonate as bleach Preparations not stable in storage. The alternative usable perborates are less sensitive to moisture than percarbonates, but are cannot be used due to esterification with the polyvinyl alcohol of the foils.

A known solution is the water-soluble film material with another, for example a vapor barrier layer layers that result in a limited water vapor permeability of the Verpac kung leads. For example, vapor barrier layers can be used to protect percarbonate from moisture. In another example can be covered by an additional layer on the inside of the packaging mechanical and chemical separation of the bottom forming the outer packaging lyvinyl alcohol (PVAL) from the ester with PVAL-forming perborate and so that the packaging is stabilized.

For example, the publication WO 98/40464 (Unilever NV) describes combinations of at least one tablet of a compressed particulate detergent or cleaning agent preparation with a closed packaging system comprising this, which has a water vapor transmission rate of less than 20 g / m ² per day exhibits, ideally of 5 g / m ² per day. With this packaging system, an improvement in the physical properties of the packaged tablet during storage and an improved solution kinetics of the tablet upon contact with water are to be achieved.

The document EP-A 0 899 208 (The Procter & Gamble Company) describes combinations of detergent or cleaning agent preparations in the form of a stack of tablets which contain a bleaching agent which is not stable in a moist environment, and a packaging which comprises this and is not water-soluble a water vapor transmission rate of less than 20 g / m ² per day, ideally 0.5 g / m ² per day. The packaging consists, for example, of monolayers or coextruded or laminated films made of polyethylene, polypropylene, polystyrene and / or polyethylene terephthalate.

A clear disadvantage of these solutions described in the prior art consists in making one out of several (e.g. two) Layers of existing film material is expensive and the price of the pro products not insignificantly increased. On the other hand, the complete is regular Water solubility of the packaging in favor of water vapor impermeable abandoned what was due to packaging residues or cleaning process is also undesirable.

As an alternative to the proposals of the prior art described above Technology is the key for moisture-sensitive and / or hygroscopic products Use of an outer vapor barrier outer packaging is obvious. This makes the product opti against access to water or moisture times protected; however, there is one in the container compared to the norma very low equilibrium humidity. This is from of the packaged detergent or cleaning agent preparation. The water-soluble film material almost completely removes the water. There it makes it brittle and mechanically sensitive. The washing or cleaning Pouches containing detergent portions can then be used even with more care Consumer handling tears, and the content then pours into the vapor barrier outer packaging. This will take advantage of one for the direct use in a washing machine or dishwasher or detergent portion in a water-soluble film.

Surprisingly, it has now been found that either when washing or detergent ingredients that can also be  or cleaning agents are included, into which water-soluble films are incorporated, or if you use plasticizers compatible with detergents or cleaning agents, which are also contained in the water-soluble film, in the washing or cleaning compounded, both ideal packaging materials for laundry or cleaning agents as well as practical and conveniently metered detergents or detergent portions can be obtained from the ge mentioned packaging materials are included.

The invention relates to a detergent or cleaning agent portion, in particular for loading a washing machine or dishwasher for one in one aqueous phase program run that at least one measured amount of at least one detergent preparation and at least one the measured amount (s) of at least one active washing preparation comprehensive water-soluble polymer material, one or more of which re component (s) at least one of the detergent formulations also in the water-soluble polymer material are included.

In the same way, the invention relates to a washing or cleaning agent Portion, in particular for loading a washing machine or dishwasher ne for a program run taking place in an aqueous phase, the little at least a measured amount of at least one active detergent preparation and at least one of the measured amount (s) of at least one waschak tive preparation comprising water-soluble polymer material, where one or more components of the water-soluble polymer material are also contained in at least one of the detergent formulations.

In addition, the invention relates to an enclosure at least one abge measured amount of a wash-active preparation, especially for loading send a washing machine or dishwasher suitable Serving detergent in the form of a water-soluble polymer material, where  in the case of one or more component (s) at least one of the wash-active additives Preparations are also included in the water-soluble polymer material.

In the same way, the invention relates to an enclosure of at least one measured amount of a wash-active preparation, in particular for Loading a washing machine or dishwasher suitable for or detergent portion in the form of a water-soluble polymer Material, wherein one or more components of the water-soluble poly mer materials in at least one of the detergent formulations are holding.

The invention further relates to a method for producing at least one measured quantity of at least one wash-active preparation and at least one of the measured quantity (s) of at least one suitable for loading a washing machine or dishwasher for a program run taking place in an aqueous phase detergent-active preparation comprising water-soluble polymer material-containing detergent or cleaning agent portion, which is characterized by the steps that one

• - at least a measured amount of at least one active detergent Provides preparation;
• - Provides at least one water-soluble polymer material, we at least one water-soluble polymer material contains one or more components of at least one of the detergent formulations;
  and or
• - Provides at least one water-soluble polymer material, where we at least a measured amount of at least one wash-active Zu preparation of one or more component (s) of the water-soluble poly contains mer materials; and  
• - at least a measured amount of at least one active detergent Preparation with the at least one water-soluble polymer material includes.

The invention further relates to a washing or cleaning process in which

• - A detergent or cleaning agent portion according to the above De finition placed in a washing machine or dishwasher;
• - by adding water and adjusting the temperature to a first Temperature value at which there is at least a measured amount a wash-active preparation of detergents or cleaning agents Portion of water-soluble polymer material dissolves, at least releases a wash-active preparation into the fleet; and if necessary
• - by adding more water and adjusting the temperature to one or more additional temperature value (s) above the first Temperature value and possibly over other previous tempera values lie / lie, one or more further wash-active preparations releases into the washing or cleaning liquor.

The term "portion of detergent or cleaning agent" is used in the context of present invention take place for one in an aqueous phase Washing or cleaning process sufficient amount of a detergent or Understood detergent. This can be a machine, for example Washing or cleaning process as it is with commercially available washing machines machines or dishwashers. According to the invention However, this term also includes a (for example in a hand wash basin or handwashed in a bowl or by hand performed dishwashing or any other process of washing or cleaning understood. Servings of detergent or cleaning agent according to The invention can also be used, for example, for cleaning floors, for cleaning glass supply, for cleaning fittings, devices, equipment and surfaces in the  Kitchen, for cleaning fittings, equipment, devices and surfaces in the Bath and used as a hand wash. According to the invention before The detergent or cleaning agent portions are added to machine Washing or cleaning processes used.

Under the term "portion of detergent or cleaning agent" is in the frame the present invention a subset of a washing or cleaning with tel portion understood in one of other detergents or cleaning agents Portions of separate phases in spatial connection with other washing or detergent portions of the same detergent or detergent Portion is present and is prepared by suitable measures so that it ge separates portions of other detergents or cleaning agents Portion of detergent or cleaning agent added to the liquor and given if it can be dissolved or suspended. It can be a washing or Portion of detergent the same ingredients as another detergent or detergent portion of the same detergent or detergent Portion included; alternatively, two detergents or cleaning agents Portions of the same detergent or cleaning agent portion different Contain ingredients, especially different washing-active preparations The invention also includes detergent or cleaning agent pores tion with only one uniformly composed washing or cleaning medium portion, for example from powders, particles or moldings.

According to the detergent or cleaning agent portions contain measured amounts of active detergent preparations. It is possible that the Portions of only active detergent preparations of a certain composition contain. According to the invention, however, it is preferred that several, usual Usually at least two, wash-active preparations of different Zu composition contained in the detergent or cleaning agent portions. The composition can be in terms of the concentration of each Components of the detergent preparation (quantitative) and / or in terms of  the type of individual components of the detergent preparation (qualitative) be different. It is particularly preferred that the components with respect Lich type and concentration are adapted to the tasks that the washing or To fulfill detergent portions in the washing or cleaning process to have. The partial portions are in connection with the present invention tion preferably includes those comprised of various water-soluble materials first, second and possibly third or even higher (fourth, fifth etc.) measured amounts of one or more wash-active preparations tion (s) that form part of a detergent or cleaning agent according to the inven are combined.

Under the term "washing active preparation" are available in the context of the invention preparations of all conceivable, in connection with a Relevant substances for washing or cleaning. these are primarily the actual detergents or cleaning agents with their im further course of the description of individual components explained in more detail. Dar Active substances such as surfactants (anionic, non-ionic, cationic and amphoteric surfactants), builder substances (inorganic and organic builders substances), bleaching agents (such as peroxo bleaching agents and chlorine Bleach), bleach activators, bleach stabilizers, bleach catalysts, En enzymes, special polymers, dyes and fragrances (perfumes) without the Term is limited to these substance groups.

However, the term "detergent preparations" also includes washing tools and cleaning aids understood. Also laundry treatment detergents such as fabric softener or dishwashing detergent additives such as rinse aid are considered according to the invention as wash-active preparations.

According to the invention, the detergent or cleaning agent portion contains at least a the measured amount (s) of at least one detergent preparation comprehensive water-soluble polymer material. Preferably, a sol  ches polymer material comprises at least one wash-active preparation send packaging. Underneath, a flat or three-dimensional structure is ver stood that at least a measured amount of at least one wash completely surrounds active preparation and thus a washing or cleaning forms a medium portion that is regular (but not mandatory) in a narrow spatial area closeness to another, possibly also from a water-soluble Packaging included, but in any case measured quantity of another active detergent preparation in the form of a detergent or cleaning agent portion is arranged. The exact form of such packaging is not critical and can be largely adapted to the conditions of use. It come in various forms, for example (such as snooze Chen, pillows, cylinders, bottles, disks, etc.) worked or processed Plastic foils or plates, capsules or other conceivable shapes Question. Films according to the invention which, for example, form Verpac Cables such as hoses, pillows, etc. can be glued and / or sealed NEN, after having been served with portions of the washing or rice according to the invention detergent portion were filled.

More preferred according to the invention due to the excellent ge desirable physical conditions adaptable properties plastic Foil packaging made from water-soluble foils. Such films are in principle ell known from the prior art. Their materials can be special preferably the groups (acetalized) polyvinyl alcohol, polyvinyl pyrrolidone, Polyethylene oxide, gelatin, starch, cellulose and their derivatives and mixtures belong to the materials mentioned.

Polyvinyl alcohols (PVAL for short) are polymers of the general structure

[-CH ₂ -CH (OH) -] _n

those in small quantities also structural units of the type

[-CH ₂ -CH (OH) -CH (OH) -CH ₂ -]

contain. Since the corresponding monomer (vinyl alcohol) is not in free form is stable, polyvinyl alcohols through polymer-analogous reactions Hydrolysis, technically in particular by alkaline-catalyzed transesterification of Polyvinyl acetates with alcohols, preferably with methanol, are obtained. By these technical processes are also accessible to PVAL, agreed residual portion of acetate groups contain ("acetalized PVAL").

Commercial PVAL (e.g. Mowiol® types from Hoechst) come as white-yellowish powder or granules with degrees of polymerization in the range of approx. 500 to 2500 (corresponding to molecular weights of approx. 20,000 to 100,000 g / mol) on the market and have different degrees of hydrolysis from 98 to 99 or 87 to 89 mole%. They are therefore partially saponified polyvinyl acetates with a residue holds on acetyl groups of about 1 to 2 or 11 to 13 mol%.

The water solubility of PVAL can be checked by post-treatment with aldehyde den (acetalization), by complexing with Ni or Cu salts or by Reduce treatment with dichromates, boric acid, borax and so on Set the desired values. PVAL films are largely impenetrable Lich for gases such as oxygen, nitrogen, helium, hydrogen, carbon dioxide, read water vapor, however.

Examples of suitable water-soluble PVAL films are those under designation "SOLUBLON®" from Syntana Handelsgesellschaft E. Harke GmbH & Co. available PVAL films. Their solubility in water can be determined to the degree set, and there are films in this range available, all of them for the Application relevant temperature ranges are soluble in the aqueous phase.  

Polyvinylpyrrolidones, abbreviated as PVP, can be described by the following general formula:

PVP are produced by radical polymerization of 1-vinylpyrrolidone poses. Commercial PVPs have molar masses in the range from approx. 2500 to 750,000 g / mol and are available as white, hygroscopic powders or as aqueous Solutions offered.

Polyethylene oxides, PEOX for short, are polyalkylene glycols of the general formula

H- [O-CH ₂ -CH ₂ ] _n -OH

the technically by base-catalyzed polyaddition of ethylene oxide (oxirane) in systems containing mostly small amounts of water with ethylene glycol as Starting molecule can be produced. They have molecular weights in the range of approx. 200 up to 5,000,000 g / mol, corresponding to degrees of polymerization n of approx. 5 to <100,000. Polyethylene oxides have an extremely low concentration reactive hydroxy end groups and show only weak glycol Characteristics.

Gelatin is a polypeptide (molecular weight: approx. 15,000 to <250,000 g / mol) that before conveniently by hydrolysis of the contained in animal skin and bones Collagen is obtained under acidic or alkaline conditions. The Amino acid composition of the gelatin largely corresponds to that of Collagen from which it was obtained and varies depending on the provenance. The use of gelatin as a water-soluble covering material  is especially in pharmacy in the form of hard or soft gelatine cape are extremely widespread. Gelatine is found in the form of foils because of its im Only low compared to the high-cost polymers mentioned above Use.

Washing and rice are also preferred in the context of the present invention Detergent portions, the packaging of which is made of water-soluble film from min a polymer from the group starch and starch derivatives, cellulose and cellulose derivatives, especially methyl cellulose and mixtures thereof consists.

Starch is a homoglycan, the glucose units ver. Α-glycosidic are knotted. Starch is made up of two components with different molecular weights weight built up: from approx. 20 to 30% straight-chain amylose (MW. approx. 50,000 up to 150,000) and 70 to 80% branched chain amylopectin (MW. approx. 300,000 up to 2,000,000). There are also small amounts of lipids, phosphoric acid and Cations included. During the amylose due to the binding in the 1,4-position long, helical, intertwined chains with about 300 to 1200 gluco forms se molecules, the chain branches through in amylopectin on average 25 glucose building blocks through 1,6 binding to a knot-like one Formations with about 1,500 to 12,000 molecules of glucose. In addition to pure strength are for the production of water-soluble enclosures for washing and cleaning agent portions in the context of the present invention also starch Derivatives obtainable from starch by polymer-analogous reactions. Sol chemically modified starches include products, for example from esterifications or etherifications in which hydroxy hydrogen atoms were substituted. But also strengths in which the hydroxy groups are against functional groups that are not linked via an oxygen atom are replaced were used as starch derivatives. In the group of strength Derivatives fall, for example, alkali starches, carboxymethyl starch (CMS), starch keester and ether as well as amino starches.  

Pure cellulose has the formal gross composition (C ₆ H ₁₀ O ₅ ) _n and, formally speaking, is a β-1,4-polyacetal of cellobiose, which in turn is made up of two molecules of glucose. Suitable celluloses consist of approximately 500 to 5000 glucose units and therefore have average molecular weights of 50,000 to 500,000. Cellulose-based disintegrants which can be used in the context of the present invention are also cellulose derivatives which can be obtained from cellulose by polymer-analogous reactions. Such chemically modified celluloses include, for example, products from esterifications or etherifications in which hydroxyl hydrogen atoms have been substituted. However, celluloses in which the hydroxy groups have been replaced by functional groups which are not bound via an oxygen atom can also be used as cellulose derivatives. The group of cellulose derivatives includes, for example, alkali celluloses, car boxymethyl cellulose (CMC), cellulose esters and ethers and aminocelluloses.

Preferred enclosures made of water-soluble film consist of a poly mer with a molecular weight between 5000 and 500,000 daltons, preferably between between 7,500 and 250,000 Daltons and especially between 10,000 and 100,000 daltons. The water-soluble film that forms the enclosure shows off preferably a thickness of 1 to 150 microns, preferably from 2 to 100 microns, be particularly preferably from 5 to 75 μm and in particular from 10 to 50 μm.

These water-soluble films can be made using various manufacturing processes getting produced. In principle, blowing, calendering and casting processes are closed here call. In a preferred method, the foils are starting out blown from a melt with air over a blow mandrel to a hose. In the calendering process, which is also one of the preferred ones Manufacturing processes are heard, the plasticized by suitable additives Raw materials for forming the films are atomized. Here it can be especially be necessary to connect a drying to the atomization. In which  Casting process, which is also one of the preferred manufacturing processes an aqueous polymer preparation against a heatable drying drum ben, after the evaporation of the water is optionally cooled and the film as Film peeled off. If necessary, this film is before or during the peeling hens additionally powdered.

According to the invention, the polymer material comprising at least one wash-active preparation does not consist solely of one of the polymers mentioned or a mixture comprising several polymers, but essentially contains further substances. At least two alternatives are conceivable according to the invention:

• - One or more component (s) of at least one of the washing active Preparations are also in the water-soluble polymer material contain; and or
• One or more component (s) of the water-soluble polymer Material is / are also in at least one of the wash-active preparations gene included.

According to the invention it is possible that either one of the two states al is given alternatively, d. H. that either one or more component (s) we at least one of the wash-active preparations also in the water-soluble Polymer material is / are or that alternatively one or more com component (s) of the water-soluble polymer material also in at least one of the active detergent preparations is / are. However, it is also one of the be preferred embodiments that both states are present at the same time, d. that is, both one or more component (s) at least one of the wash-active preparations also in the water-soluble polymer material is / are also included that at the same time one or more component (s) of the water-soluble polymer material also in at least one of the waschak tive preparations is / are. It corresponds to one particularly be  preferred embodiment of the invention when both alternatives simultaneously given are.

According to the invention, the fact that one or more components te (n) at least one of the wash-active preparations also in the water soluble polymer material is / are and / or that one or more Component (s) of the water-soluble polymer material also in at least one egg ner of the detergent formulations is / are achieved, achieved by the Stage of manufacturing at a phase balance between the ingredients a wash-active preparation and at least this comprehensive what ser soluble polymer material is set. It takes place between the two Phases a continuous mass transfer takes place; however, this does not lead to a streak beyond the concentration of phase equilibrium Protection of the respective substance (s) in one phase and one associated with it depletion of the respective substance (s) in another phase, the regularly with an undesirable change in the respective properties connected is. The constantly observed changes in the own create one or more ingredients of one or more washes active preparation (s) in terms of properties, e.g. B. the washing or Cleaning activity, in the washing or cleaning process and / or changes The properties of one or more of the detergent preparations surrounding enclosure (s) or packaging (s) with regard to the own shafts, e.g. B. the water solubility or brittleness remained with the inventions portion of detergent or cleaning agent according to the invention or at their Umfas solution.

Basically, the fact that one or more component (s) we at least one of the wash-active preparations also in the water-soluble Polymer material is / are and / or that one or more compo nente (s) of the water-soluble polymer material in at least one of the detergent preparations is / are, none from the perspective of the respective in  mandatory components contained in both phases imposed. Basically, it comes for installation in the water soluble (n) polymer material (a) and the adjustment of a phase equilibrium weight between a detergent preparation and a polymer material each of the components of the detergent preparation in question, as well as for compounding into the wash-active preparation (s) and the Ein position of a phase equilibrium between a polymer material and a wash-active preparation of each of the components of the polymer material it is a possibility.

According to the invention, however, certain ingredients are advantageous phases for the establishment of the equilibrium. The essential The advantage is to be seen in the fact that no other foreign substances in the film need to be incorporated, creating a complicated manufacturing process and an increase in the weight of the film can be avoided as well Rise in the cost of film manufacturing. There are also certain In then hold on because because of these substances a quick and therefore before partial adjustment of the phase balance can be achieved and thus the advantages of the invention come to fruition quickly. However, this can also be the case are due to the fact that in a special case in both phases (washing-active Preparation and water-soluble polymer material) contained fabric conveniently in both phases can be incorporated.

It corresponds to a further preferred embodiment of the invention than in substances containing at least two phases to select those which - given if small amounts are added (<20% by weight, advantageously <10% by weight, based on the preparation) water - liquid at room temperature or pa present from dense to waxy. Substances made after this from application Visible requirements are selected, lead to washing or cleaning Serving agent portions with full activity of the detergent substances and storage cheap, in terms of properties improved enclosures.  

According to the invention, an embodiment of the washing machine is particularly preferred. or detergent portions in which the water-soluble Component (s) containing polymer material at least one of the waschak tive preparation (s) is / are selected from the group that does not consist of ionic and anionic surfactants, as defined in detail below become.

Anionic surfactants used are, for example, those of the sulfonate and sulfate type. Preferred surfactants of the sulfonate type are cumene sulfonate, C _9-13 alkylbenzenesulfonates, olefin sulfonates, ie mixtures of alkene and hydroxyalkane sulfonates and disulfonates, as obtained, for example, from C _12-18 monoolefins with end or internal double bond by sulfonation with gaseous sulfur trioxide and subsequent alkaline or acid hydrolysis of the sulfonation products. Also suitable are alkanesulfonates obtained from C _12-18 alkanes, for example by sulfochlorination or sulfoxidation with subsequent hydrolysis or neutralization. Likewise, the esters of 2-sulfo fatty acids (ester sulfonates), e.g. B. the 2-sulfonated methyl ester of hydrogenated coconut, palm kernel or tallow fatty acids.

Other suitable anionic surfactants are sulfonated fatty acid glycerol esters. Under Fatty acid glycerol esters are the mono-, di- and triesters and their mixtures understand how they are made by esterification from a mono glycerin with 1 to 3 moles of fatty acid or in the transesterification of triglycerides can be obtained with 0.3 to 2 mol of glycerol. Preferred sulfated fatty acid glycol Pure esters are the sulfonation products of saturated fatty acids with 6 to 22 Carbon atoms, for example caproic acid, caprylic acid, capric acid, Myristic acid, lauric acid, palmitic acid, stearic acid or behenic acid.

As alk (en) yl sulfates are the alkali and especially the sodium salts of the sulfuric acid half esters of C ₁₂ -C 18 fatty alcohols, for example from coconut fatty alcohol, tallow fatty alcohol, lauryl, myristyl, cetyl or stearyl alcohol or the C ₁₀ -C ₂₀ oxo alcohols and those half-esters of secondary alcohols of this chain length are preferred. Also preferred are alk (en) yl sulfates of the chain length mentioned which contain a synthetic, petrochemical-based straight-chain alkyl radical which have a degradation behavior analogous to that of the adequate compounds based on oleochemical raw materials. The C ₁₂ -C ₁₆ alkyl sulfates and C ₁₂ -C ₁₅ alkyl sulfates as well as C ₁₄ -C ₁₅ alkyl sulfates are preferred from the point of view of washing technology. 2,3-Alkyl sulfates, which are produced, for example, according to US Pat. Nos. 3,234,258 or 5,075,041 and can be obtained as commercial products from the Shell Oil Company under the name DAN®, are also suitable anionic surfactants.

The sulfuric acid monoesters of the straight-chain or branched C _7-21 alcohols ethoxylated with 1 to 6 mol of ethylene oxide, such as 2-methyl-branched C _9-11 alcohols with an average of 3.5 mol of ethylene oxide (EO) or C _12-18 Fatty alcohols with 1 to 4 EO are suitable. Because of their high foaming behavior, they are used in cleaning agents only in relatively small amounts, for example in amounts of 1 to 5% by weight.

Other suitable anionic surfactants are also the salts of alkyl sulfosuccinic acid, which are also known as sulfosuccinates or as sulfosuccinic acid esters, and the monoesters and / or diesters of sulfosuccinic acid with alcohols, preferably fatty alcohols and especially ethoxylated fatty alcohols. Preferred sulfosuccinates contain C _8-18 fatty alcohol residues or mixtures thereof. Particularly preferred sulfosuccinates contain a fatty alcohol residue which is derived from ethoxylated fatty alcohols, which are nonionic surfactants in themselves (for a description see below). Again, sulfosuccinates, the fatty alcohol residues of which are derived from ethoxylated fatty alcohols with a narrow homolog distribution, are particularly preferred. It is also possible to use alk (en) ylsuccinic acid with preferably 8 to 18 carbon atoms in the alk (en) yl chain or salts thereof.

Soaps are particularly suitable as further anionic surfactants. Ge saturated fatty acid soaps, such as the salts of lauric acid, myristine, are suitable acid, palmitic acid, stearic acid, hydrogenated erucic acid and behenic acid as in particular from natural fatty acids, e.g. B. coconut, palm kernel or Tallow fatty acids, derived soap mixtures.

The anionic surfactants including the soaps can be in the form of their natri um, potassium or ammonium salts and as soluble salts of organic bases, such as mono-, di- or triethanolamine. The anioni are preferably located tensides in the form of their sodium or potassium salts, in particular in the form the sodium salts. In another embodiment of the invention Surfactants used in the form of their magnesium salts.

In the context of the present invention, detergents and cleaning agents are Portions preferred, the 5 to 50 wt .-%, preferably 7.5 to 40 wt .-% and in particular 15 to 25% by weight of one or more anionic ten sid (e), each based on the detergent and cleaning agent portion.

When choosing the anionic surfactants used in the invention Detergent and cleaning agent portions are used, the For No restrictions in the way of compliance. Preferred Detergent and cleaning agent portions according to the invention, however, have a soap content of 0.2 wt .-%, based on the total weight the detergent and detergent portion. Preferred to use anionic surfactants are the alkylbenzenesulfonates and fatty alcohol sulfates, preferred detergent and cleaning agent portions 2 to 20 wt .-%, preferably 2.5 to 15 wt .-% and in particular 5 to 10 wt .-% fatty alcohol  holsulfate (s), each based on the weight of the detergent and cleaning agent Serving.

The nonionic surfactants used are preferably alkoxylated, advantageously ethoxylated or propoxylated, in particular primary alcohols with preferably 8 to 18 carbon atoms and an average of 1 to 80, preferably 3 to 12, moles of ethylene oxide (EO) per mole of alcohol in which the alcohol radical is linear or can preferably be methyl-branched in the 2-position or can contain linear and methyl-branched radicals in the mixture, as are usually present in oxo alcohol radicals. In particular, however, alcohol ethoxylates with linear residues from alcohols of native origin with 12 to 18 carbon atoms, for. B. from coconut, palm, tallow or oleyl alcohol, and an average of 1 to 80, preferably 2 to 8 EO per mole of alcohol preferred. The preferred ethoxylated alcohols include, for example, C _12-14 alcohols with 3 EO or 4 EO, C _9-11 alcohol with 7 EO, C _13-15 alcohols with 3 EO, 5 EO, 7 EO or 8 EO, C _12-18 alcohols with 3 EO, 5 EO or 7 EO and mixtures thereof, and mixtures of C _12-14 alcohol with 3 EO and C _12-18 alcohol with 5 EO. The given degrees of ethoxylation are statistical averages, which can be an integer or a fraction for a specific product. Preferred alcohol ethoxylates have a narrow homolog distribution (nar row range ethoxylates, NRE). In addition to these nonionic surfactants, fatty alcohols with more than 12 EO can also be used. Examples include tallow fatty alcohol with 14 EO, 25 EO, 30 EO, 40 EO or up to 80 EO.

Another class of preferred non-ionic surfactants, which either not as the sole nonionic surfactant or in combination with others Ionic surfactants are used are alkoxylated, preferably ethoxy lated or ethoxylated and propoxylated fatty acid alkyl esters, preferably with 1 to 8 carbon atoms in the alkyl chain and 3 to 80, preferably up to 20 alk oxy groups, preferably ethoxy groups in the molecule, in particular fatty acids thylester, as for example in the Japanese patent application  JP 58/217598 are described or preferred according to that in the international Patent application WO-A-90/13533 disclosed methods.

Another class of nonionic surfactants that can be used advantageously are the alkyl polyglycosides (APG). Usable alkyl polyglycosides satisfy the general formula RO (G) _Z , in which R represents a linear or branched, in particular methyl-branched, saturated or unsaturated, aliphatic radical having 8 to 22, preferably 12 to 18, carbon atoms and G is the symbol which stands for a glycose unit with 5 or 6 carbon atoms, preferably for glucose. The degree of glycosidation z is between 1.0 and 4.0, preferably between 1.0 and 2.0 and in particular between 1.1 and 1.4.

Linear alkyl polyglucosides, ie alkyl polyglycosi, are preferably used de in which the polyglycosyl radical is a glucose radical and the alkyl radical is an n- Is alkyl radical.

The detergent and cleaning agent portions according to the invention can before contains alkyl polyglycosides, with levels of washing and cleaning Agent portions of APG over 0.2 wt .-%, based on the total Shaped bodies are preferred. Particularly preferred washing and cleaning Serving agent portions contain APG in amounts of 0.2 to 10% by weight preferably in amounts of 0.2 to 5 wt .-% and in particular in amounts of 0.5 to 3% by weight.

Also nonionic surfactants of the amine oxide type, for example N-coconut alkyl-N, N-dimethylamine oxide and N-tallow alkyl-N, N-dihydroxyethylamine oxide, and the fatty acid alkanolamides may be suitable. The amount of this non- Ionic surfactants is preferably no more than that of the ethoxylated ones Fatty alcohols, especially not more than half of them.  

Other suitable surfactants are polyhydroxy fatty acid amides of the formula (I),

in the RCO stands for an aliphatic acyl radical with 6 to 22 carbon atoms, R ¹ for hydrogen, an alkyl or hydroxyalkyl radical with 1 to 4 carbon atoms and [Z] for a linear or branched polyhydroxyalkyl radical with 3 to 10 carbon atoms and 3 to 10 hydroxyl groups . The polyhydroxy fatty acid amides are known substances which can usually be obtained by reductive amination of a reducing sugar with ammonia, an alkylamine or an alkanolamine and subsequent acylation with a fatty acid, a fatty acid alkyl ester or a fatty acid chloride.

The group of polyhydroxy fatty acid amides also includes compounds of the formula (II)

in which R represents a linear or branched alkyl or alkenyl radical having 7 to 12 carbon atoms, R ^{1 represents} a linear, branched or cyclic alkyl radical or an aryl radical having 2 to 8 carbon atoms and R ^{2 represents} a linear, branched or cyclic alkyl radical or an aryl radical or an oxyalkyl radical having 1 to 8 carbon atoms, C ₁₄ -alkyl or phenyl radicals being preferred and [Z] being a linear polyhydroxyalkyl radical whose alkyl chain is substituted by at least two hydroxyl groups, or alkoxylated, preferably ethoxylated or propylated, derivatives of this rest.

[Z] is preferably obtained by reductive amination of a reduced sugar obtained, for example glucose, fructose, maltose, lactose, galactose, Man nose or xylose. The N-alkoxy or N-aryloxy substituted compounds can then, for example, according to the teaching of the international application WO A-95/07331 by reaction with fatty acid methyl esters in the presence of a Alkoxide as a catalyst in the desired polyhydroxy fatty acid amides leads.

Even more preferred according to the invention are nonionic surfactants from the group of alkoxylated fatty alcohols with 8 to 20 carbon atoms in the fatty alcohol alkyl radical, with fatty alcohols of natural origin, ie straight-chain and generally predominantly containing an even number of carbon atoms in the alkyl group, compared to synthetic fatty alcohols ( z. B. branched or containing an odd number of carbon atoms fatty alcohols) are preferred. From the viewpoint of the availability of the compounds, examples of the fatty alcohols are lauryl alcohol (C ₁₂ ), myristyl alcohol (C ₁₄ ), cetyl alcohol (C ₁₆ ) etc. or mixtures originating from native sources. The number of alkoxy groups, which are primarily ethoxy groups or propoxy groups, particularly preferably ethoxy groups, can vary within wide limits and is particularly preferably between 3 and 80. Further nonionic surfactants, which are also present in the water-soluble polymer material ent can be, according to the invention, alkoxylated C ₈ to C ₂₀ fatty acid real alkyl esters having 1 to 8 carbon atoms in the alkyl radical and 3 to 80, preferably up to 20 alkoxy groups in the molecule, the alkoxy groups preferably being ethoxy groups. From a practical point of view, it will be advantageous to take into account the fact that those compounds from the above-mentioned groups are used which are still liquid to pasty even with longer chain lengths at the application temperatures.

According to the invention, anionic surfactants can also preferably be used for the stated purpose. From the group of these compounds come primarily alkylbenzenesulfonic acids with 9 to 13 carbon atoms in the alkyl groups and their salts (predominantly present in an alkaline medium), cumene sulfonic acid and their salts, fatty alcohol sulfates with 12 to 18 carbon atoms in the fatty alcohol alkyl radical and C ₈ - to C ₂₀ - fatty acids and their salts.

According to the invention, an embodiment of the is also particularly preferred Detergent or cleaning agent portions, in which also in at least one wash-active preparation contained component (s) of the water-soluble Polymer material is selected from the group of hydrophilic soft materials cher. According to the invention, polyols having 1 to 20 carbons are particularly preferred atoms and 2 to 6 hydroxy groups, polyalkylene glycols with 2 to 4 (before adds linear) alkylene carbon atoms (i.e. ethylene groups, propylene Groups or butylene groups) in the molecule, particularly preferably polyethylene long glycols and / or polypropylene glycols, further particularly preferably polyes ethylene glycols and / or polypropylene glycols with molecular weights in the range from 200 to 12,000, more preferably with molecular weights <1,500. Likewise the aforementioned polyalkylene glycols may be used with advantage naloge amines, d. H. Compounds in which the glycol -O- group is replaced by a Amine -NH- group is replaced. The abovementioned also apply to the amines given ranges of molecular weights. From a practical point of view, there are Compounds that can be used with advantage in the (increased) application temperature temperatures are still liquid to pasty.

According to another preferred embodiment of the invention also low molecular weight polyacrylates or polymethacrylates or polymaleinates (Acids or - preferred under alkaline conditions of use Salts including their amine or (also organic) ammonium salts) or  Use copolymers of polyacrylates / polymethacrylates and polymaleinates be det.

The concentrations of the respective compounds in the respective phases, i.e. H. in the wash-active preparation (s) and in the one (s) comprising them Water-soluble polymer material (ien) depend entirely on the specific Ein occasionally. The concentration values are of course influenced by the character of the current material in the two phases in question, ge possibly interactions between two or more current materials s, their respective interaction (s) with the other compos nenten of the respective phase, the temperature, the pressure and optionally other parameters. In general, the phase equilibrium Concentration in one of the two phases 0.5 to 50 in question % By weight, based on the total weight of the respective phase, preferably 1 to 30% by weight and more preferably 3 to 25% by weight. Crucial for that Concentration of a substance in question is only that one Phase equilibrium of the concentration of the respective substance (s) between the phases in which the properties of the wash-active preparation tion (s) on the one hand and the water-soluble polymer material / polymer material materials, on the other hand, are in a desirable range.

According to the invention it is of course also possible to do the washing or cleaning medium portion and / or also encompassing them or encompassing a partial portion to design the encapsulation so that one of the two phases does not the sub that later provides the expected property (s) in equilibrium punch contains, but the other phase so much that in the course of a con trolled time (e.g. hours or a few days) a Pha Sense balance between the two phases (at least one washing active Preparation and / or at least one enclosure) without the ent speaking substance in the phase in which it is initially contained, so strong is depleted that their desired or already optimized Eigen  deteriorate unacceptably, or without the properties the phase in which the corresponding substance initially does not exist at all or in one amount contained below the equilibrium concentration is so strong worsen that a later adjustment of a phase balance the Properties no longer improved to an acceptable degree. In this case can also one or more component (s) alone in one of the two Phases are incorporated while one or more other sub punch (s) is / are worked into the other phase alone. To Bringing the two phases together in the course of producing the invention appropriate detergent or cleaning agent portion by filling one or more active detergent preparation (s) in one or more enclosures one or more water-soluble polymer material (s) then turns controls a phase equilibrium through diffusion or adsorption effects of the respective substance in the two phases (detergent substance or water-soluble polymer material), which has the desired properties of the Both phases are not adversely affected even with long storage.

In the detergent and cleaning agent portions according to the invention are the Enclosures of a water-soluble polymer material active washing preparation (s) selected from the group consisting of Fo lien, capsules and coatings.

According to the invention, polyvinyl alcohol films are particularly preferred as encompassing solution for the at least one wash-active preparation. The preferred use The PVAL foils are soluble at cold water temperature, i.e. around 12 to 18 ° C. According to a further preferred embodiment, they are used PVAL foils soluble at a temperature in a range that the Temperature range of the washing cycle or cleaning cycle corresponds in which the respective measured amount of a detergent preparation used becomes. This is the case, for example, in the event that the measured amount of a detergent active preparation a preparation for the  The main wash cycle of a dishwasher is the temperature of the main wash gangs, for example in the range of <about 20 to about 55 ° C, preferably <25 ° C. to below 45 ° C, more preferably a temperature above 30 ° C to for example 40 ° C. In the case where, for example, the respective abge measured amount of a detergent active preparation a preparation for the Rinse a dishwasher, the temperature at which the Foil is water soluble, at the temperature of the rinse cycle and is included for example <45 ° C, e.g. B. in the range of 50 to 55 ° C or even higher. In Ab in accordance with the requirements and usual settings of the devices for washing processes in washing machines other temperature ranges, at for example up to about 25 ° C for the prewash, up to about 90 ° C for the main wash and up to about 30 ° C for washing. Of course they can Temperatures at which the water-soluble film dissolves in a wide range disc materials are available or are commercially available (see MOWIOL®-type films specified above or those specified above Films of the SOLUBLON® type), which are applied to a specific area of the temperature rature of water solubility are set; those skilled in the art can use such foils then select according to requirements and also in such foils incorporate the components or by adjusting the phase balance let come in, which are used according to the invention in the films.

It corresponds to a further preferred embodiment of the invention that the water-soluble material, which the respective measured amount of a detergent preparation, is a water-soluble capsule. Such chap seln are also known from the prior art. You can, for example wise, without this being a limitation, capsules made of PVAL, Be gelatin or similar materials. Such capsules are commercially available and are in connection with pharmaceutical preparations or food additives widely used. Especially be Capsules made of hard gelatin or soft gelatin have proven themselves, and they are therefore particularly preferred according to the invention.  

In a further, likewise preferred embodiment of the invention, this is the respective measured amount of a detergent preparation de water-soluble material a water-soluble coating. Such coatings or Enveloping substances are already used to encase detergent substances in the State of the art uses and can - comparable to the foil mat rialien - with regard to their physical properties such as visibly the water solubility, the melting point or melting range adjust precisely to certain technical requirements. In the sense of the present the invention are for coating detergent active coatings, which in narrow sense are water-soluble, just as suitable as coatings, which are in an aqueous environment when setting certain physical or chemical conditions such as at a certain temperature or dissolve a certain pH because, for example, they melt and the Enveloping substances are then dispersed in water and previously with the Um wrapping or surrounding ingredients, d. H. the washactive (n) zu Release preparation (s).

In this sense, the term "water-soluble" in the context of the present Invention generally not only the property of the enclosures of waschakti ven preparations, dissolved from an aqueous medium (in the narrower sense) to become, but also the property (in a broader sense), when adjusting certain physical or chemical conditions in the aqueous environment change in such a way that the physical integrity is lost and the Enclosing the ingredients released into the aqueous phase. The melting and then dispersing the material of the enclosure in the aqueous phase a typical (but not restrictive) example.

Basically, the coatings or coating substances should have a melting range have in such a temperature range at which to be encased detergent substances are not exposed to excessive thermal stress  the. On the other hand, the melting range must be sufficiently high to be too at least slightly elevated temperature still sufficient protection for the to provide enclosed detergent substances. The sub punch out the coatings or the coating substances on melting areas between between about 45 ° C and about 75 ° C. The term "melting range" be in this case indicates that the melting range within the specified tem temperature interval occurs and does not indicate the width of the melting range. Coatings have proven to be particularly effective in this context Waxing has been shown to work directly on the detergent preparation or its Individual components are applied, and such coatings are therefore we due to the ease of application and the possibility of water solubility ex Act and adjust to the circumstances optimally and an adjustment of a phase balance between embracing and around to allow for more active detergent preparation, particularly preferred.

"Waxing" is a series of natural or artificially derived substances understood that usually melt above 40 ° C without decomposition and already a little above the melting point, relatively low viscosity and not are stringy. They have a strongly temperature-dependent consistency and Solubility.

The waxes are divided into three groups according to their origin, namely natural che waxes, chemically modified waxes and synthetic waxes.

Natural waxes include, for example, vegetable waxes such as Candelilla wax, carnauba wax, Japanese wax, esparto grass wax, cork wax, guaruma wax, rice germ oil wax, sugar cane wax, ouricury wax or montan wax, animal waxes such as beeswax, shellac wax, whale rat, lanolin (wool wax), or pretzel fat, mineral waxes such as ceresin or ozo kerit (earth wax) or petrochemical waxes like petrolatum, paraffin waxes or micro waxes.  

The chemically modified waxes include hard waxes such as Montanester waxes, Sassol waxes or hydrogenated jojoba waxes.

Synthetic waxes generally include polyalkylene waxes or Understand polyalkylene glycol waxes.

Compounds made of an can also be used as covering materials or coatings their classes of substances that meet the above requirements with regard to Meet softening point. Have suitable synthetic compounds For example, higher esters of phthalic acid, especially dicyclohe xylphthalate, which is commercially available under the name Unimoll® 66 (Bayer AG) is available. Synthetic waxes are also suitable from lower carboxylic acids and fatty alcohols, for example dimyristyl tartrate, which is available under the name Cosmacol® ETLP (Condea). Vice there are also synthetic or partially synthetic esters from lower alcohols can be used with fatty acids from native sources. It falls into this class of substances for example the product Tegin® 90 (Goldschmidt), a glycerol mono stearate palmitate. Shellac-KPS-Dreiring-SP (from Kalkhoff GmbH) is also can be used according to the invention as a covering material or coating.

Also on the waxes within the scope of the present invention for example, the so-called wax alcohols. Are wax alcohols High molecular weight, water-insoluble fatty alcohols, usually around 22 to 40 Carbon atoms. The wax alcohols come in the form of, for example Wax esters of higher molecular fatty acids ("wax acids") as the main name component of many natural waxes. Examples of wax alcohols are Lignoceryl alcohol (1-tetracosanol), cetyl alcohol, myristyl alcohol or Melis syl alcohol. The wrapping of the detergent preparations can be given if also contain wool wax alcohols, including triterpenoid and stero id alcohols, for example lanolin, means that for example under the Han  The name Argowax® (Pamentier & Co.) is available. Likewise can be used at least in part as a covering material in the context of the present Invention fatty acid glycerol esters or fatty acid alkanolamides, but given also water-insoluble or only slightly water-soluble polyalkylene glycol kol connections.

The coating sub preferably contains in the coatings used according to the invention mainly punched paraffin wax. At least 50% by weight are further preferred. % of the total contained substances, more preferably even more, Paraffin waxes. Paraffin wax contents (based on the total coating substance) of about 60% by weight, about 70% by weight or about 80 % By weight, with even higher proportions of, for example, more than 90% by weight are particularly preferred. In a very special embodiment of the Er the total amount of the coating substance used consists of paraffin wax. Paraffin waxes are superior to the other natural ones mentioned Grow in the context of the present invention, the advantage that in a alkaline detergent or cleaning agent environment no hydrolysis of the Waxing takes place, as is to be expected, for example, from wax esters, because Paraffin wax contains no hydrolyzable groups.

Paraffin waxes consist mainly of alkanes and low levels on iso- and cycloalkanes. The preferred paraffin waxes to use have essentially no components with a melting point of more than 70 ° C, particularly preferably more than 60 ° C. Proportions of high-melting Alkanes in paraffin wax can drop below the melting temperature in unwanted wax residues in the detergent or cleaning agent fleet the laundry to be washed or the items to be cleaned. Such Wax residues lead to an unsightly appearance of laundry or Items to be cleaned and should therefore be avoided. The coating substances that are in the Used in the present invention contain a paraffin wax with a melting range of 50 ° C to 60 ° C.  

The content of the paraffin wax used is preferably at Umge training temperature (about 10 to about 30 ° C) solid alkanes, isoalkanes and Cy cloalkanes as high as possible. The more solid wax components in a wax are available at room temperature, the more useful it is in the context of present invention. With increasing proportion of solid wax components len increases the resilience of the particles coated with the coating material about bumps and friction on other surfaces, resulting in a better Protection of the washing-active substances contained in the particles leads.

In addition to paraffin waxes, the coating substance can also be a main component or more of the waxes or wax-like substances mentioned above hold. Basically, the one that forms the coating substance or the coating The mixture should be such that the particles coated with it are at least wide are insoluble in water. The solubility in water should be at a tempe temperature of 30 ° C do not exceed about 10 mg / l and should preferably be at 5 mg / l. In any case, the wrapping should be as low as possible have solubility in water at elevated temperatures, too temperature-independent release of the washing-active substances possible as far as possible to avoid.

The above principle serves to delay the release of active detergent preparations at a certain time in the washing or Cleaning cycle and can be used particularly advantageously if at for example when washing dishes in the main course at a relatively lower temperature rature (for example 45 ° C) is rinsed so that the detergent substance the coated particles containing a rinse aid only in the rinse cycle is released at higher temperatures (e.g. <55 ° C).

Envelope substances or coatings preferably used in the context of the invention comprise one or more substances with a melting range from 40 ° C to  75 ° C in amounts of 6 to 30% by weight, preferably 7.5 to 25% by weight and in particular from 10 to 20% by weight, in each case based on the particle size important.

It corresponds to a further preferred embodiment of the invention that the detergent or detergent portion in which one or more compo at least one of the wash-active preparations also in what is / are and / or in which one or several component (s) of the water-soluble polymer material also in little at least one of the detergent-active preparations is / are, in addition one Has enclosure or external enclosure, which is particularly preferred in a th embodiment for water vapor and / or for each in Pha balance or the setting of a phase balance the underlying component (s) is less permeable than that wash-active preparation (s) immediately surrounding enclosure (s). This additional enclosure can be used for washing or cleaning alone comprehensive portion or can be a multiple wash or detergent servings. Is preferred the latter case: several servings of detergent can be added to the Ver so to speak, consumers are offered in the "portion pack". This will not only a transport-related problem of the simultaneous delivery of several (e.g. six, ten or more) detergent or detergent portions dissolved, son optimal protection of the individual detergents or cleaning agents Portions for exchange with water vapor or substances from the inside the enclosure or substances from the environment. A special one Long storage stability can be guaranteed. The permeability water additional enclosure for water and for the invention in Pha Sense equilibrium component (s) may well be below to be different; so it is possible that the permeability for one or more of the components (if applicable) is slightly larger or smaller than for Water. An embodiment of the invention is further preferred, in which one  such additional enclosure after opening and removing one or more Portions of detergent or cleaning agent is resealable. This can be due to in a manner known per se from the prior art, for example as described in EP-A 0 899 208. The subject Such devices are known in this field of packaging technology to reclose such an enclosure and can according to his Select expertise without limitation.

It is further preferred according to the invention to use an outer enclosure according to the present description which has only limited permeability to water vapor. Desired enclosures that can be used according to the invention with particular advantage have a water vapor permeability of 10 g / m ² per day at 23 ° C. and 85% rel. Moisture, more preferably a water vapor permeability of ≦ 5 g / m ² per day. Outside enclosures that have no measurable water vapor permeability when measured in accordance with DIN EN 53122 are particularly preferred. Suitable materials for these purposes are also known from the prior art. For example, these can be, without limitation, single-layer, multilayer, laminated or co-extruded films made of materials such as polyethylene, polypropylene, polystyrene, polyethylene terephthalate, copolymers thereof or mixtures thereof. Polyethylene or polypropylene films with one or more layers are particularly advantageous.

In the detergent or cleaning agent portions according to the invention are preferably several, for example first, second and possibly higher (third te, fourth, etc.) measured amounts of detergent preparations each un depending on each other shaped, powdered, gel or liquid Detergent or cleaning agent preparations. Here, shaped bodies Detergent or cleaning agent preparations are in the form of granules or tablets ten, blocks, briquettes, rings or other shaped bodies; especially tablets, Blocks or briquettes can be uniformly shaped bodies or bodies that  Have depressions, recesses, grooves or the like, which be for accommodation serve special components of the preparations or for application technical purposes were set up or attached. Liquid washing or cleaning Detergent preparations can be solutions, suspensions or others for Known liquid systems for washing and cleaning purposes.

The detergent and cleaning agent portions according to the invention contain egg NEN or more substances from the group of tensides, tenside compounds, Ge builders, bleaches, bleach activators, enzymes, foam inhibitors, color and fragrances and - in the event that the washing or cleaning agents - Portions are at least partially in the form of shaped articles - binding and disinte conditioning aid. These classes of substances are described below.

To develop the washing performance, the washing and Portion of detergent surfactants from the group of anionic, nonionic, zwitterionic or cationic surfactants keep taking anionic surfactants for economic reasons and due their range of services are clearly preferred.

The ver in the detergent or cleaning agent portions according to the invention Reversible anionic and nonionic surfactants have already become broad above described. As indicated, the use of anionic surfactants is planned moves.

Furthermore, it can be preferred in addition to anionic and nonionic ten also use cationic surfactants. Their use is preferred as a washing performance bouster, using only small amounts of cationic surfactants required are. If cationic surfactants are used, they are in the Agents preferably in amounts of 0.01 to 10 wt .-%, in particular 0.1 to Contain 3.0% by weight.  

In the cases in which the washing and cleaning agents according to the invention Detergent portions are usually detergent one or more surfactant (s) in total amounts of 5 to 50 wt .-%, preferred in amounts of 10 to 35% by weight, partial portions of the invention Large detergent portions contain surfactants in larger or smaller amounts could be. In other words: the amount of surfactant is not in all partial portfolios equal to; rather partial portions with a relatively larger and partial portion NEN with a relatively small (or no) surfactant content.

In the cases in which the washing and cleaning agents according to the invention Detergent portions are detergents, especially dishes detergents, these usually contain one or more surfactant (s) in Ge total amounts from 0.1 to 10% by weight, preferably in amounts from 0.5 to 5% by weight %, being in partial portions of the detergent portions according to the invention Surfactants can be contained in larger or smaller amounts. With others Words: The amount of surfactant is also in cleaning or dishwashing detergents not the same in all portions; rather partial portions with a relatively large size more and partial portions with a relatively smaller (or no) surfactant content be seen.

In addition to the detergent substances, builders are the most important content fabrics of washing and cleaning agents. In the washing machines according to the invention and detergent portions can usually be found in washing and cleaning builders used, especially Zeo lithe, silicates, carbonates, organic cobuilders and - where no ecological There are prejudices against their use - including phosphates.

Suitable crystalline, layered sodium silicates have the general formula NaMSi _x O _{2x + 1} .H ₂ O, where M is sodium or hydrogen, x is a number from 1.9 to 4 and y is a number from 0 to 20 and preferred values for × 2, 3 or 4. Such crystalline layered silicates are described, for example, in European patent application EP-A-0 164 514. Preferred crystalline layered silicates of the formula given are those in which M is sodium and x is 2 or 3. In particular, both β- and δ-sodium disilicate Na ₂ Si ₂ O ₅ .yH ₂ O are preferred, wherein β-sodium disilicate can be obtained, for example, by the method described in the international patent application WO-A-91/08171.

Amorphous sodium silicates with a Na ₂ O: SiO ₂ modulus of 1: 2 to 1: 3, 3, preferably 1: 2 to 1: 2.8 and in particular 1: 2 to 1: 2.6, can also be used are delayed in dissolving and have secondary washing properties. The delay in dissolution compared to conventional amorphous sodium silicates can be caused in various ways, for example by surface treatment, compounding, compacting / compression or by overdrying. In the context of this invention, the term “amorphous” is also understood to mean “X-ray amorphous”. This means that the silicates in X-ray diffraction experiments do not provide sharp X-ray reflections, as are typical for crystalline substances, but at most one or more maxima of the scattered X-rays, which have a width of several degrees units of the diffraction angle. However, it can very well lead to particularly good builder properties if the silicate particles provide washed-out or even sharp diffraction maxima in electron diffraction experiments. This is to be interpreted in such a way that the products have microcrystalline areas of size 10 to a few hundred nm, values up to max. 50 nm and in particular up to max. 20 nm are preferred. Such termed so-called X-ray amorphous silicates, which also have a release delay compared to conventional water glasses, are described for example in the German patent application DE-A-44 00 024. Compacted / compacted amorphous silicates, compounded amorphous silicates and over-dried X-ray amorphous silicates are particularly preferred.

An optionally used finely crystalline, synthetic and bound water-containing zeolite is preferably zeolite A and / or P. Zeolite P-type is particularly preferred as zeolite MAP (e.g. commercial product: Doucil A24 from Crosfield). However, zeolite X and mixtures of A, X and / or P are also suitable. Commercially available and can preferably be used in the context of the present invention, for example a co-crystallizate of zeolite X and zeolite A (approx. 80% by weight Zeolite X), which is sold by CONDEA Augusta SpA under the brand name VEGOBOND AX® and by the formula

n Na ₂ O. (1-n) K ₂ O. Al ₂ O _3. (2-2.5) SiO ₂ (3.5-5.5) H ₂ O

can be described. Suitable zeolites have a medium particle size less than 10 µm (volume distribution; measurement method: Coulter Counter) and preferably contain 18 to 22% by weight, in particular 20 up to 22% by weight of bound water.

It goes without saying that there is also an application that is generally known in detergents ten phosphates as builder substances possible, provided such use should not be avoided for ecological reasons. Are suitable especially the sodium salts of orthophosphates, pyrophosphates and ins especially the tripolyphosphates.

Usable organic builders are, for example, those in the form of their Sodium salts usable polycarboxylic acids, with polycarboxylic acids those carboxylic acids are understood that tra more than one acid function gen. For example, these are citric acid, adipic acid, succinic acid, Glutaric acid, malic acid, tartaric acid, maleic acid, fumaric acid, sugar acids, Aminocarboxylic acids, Nitrilotriessigsäure (NTA), provided that their use from eco logical reasons is not objectionable, as well as mixtures of these. Preferred salts are the salts of polycarboxylic acids such as citric acid, Adi  pinic acid, succinic acid, glutaric acid, tartaric acid, sugar acids and mixtures from these. The acids themselves can also be used. The sow In addition to their builder effect, ren typically also have the property an acidifying component and thus also serve to adjust a low rigorous and milder pH of detergent and cleaning agent portions according to the invention. In this context, in particular, lemons acid, succinic acid, glutaric acid, adipic acid, gluconic acid and any To call mixtures of these.

Polymeric polycarboxylates are also suitable as builders. These are examples the alkali metal salts of polyacrylic acid or polymethacrylic acid, for example those with a molecular weight of 500 to 70,000 g / mol.

In the context of the present invention, the molar masses given for polymeric polycarboxylates are weight-average molar masses M _{W of} the particular acid form, which were basically determined by means of gel permeation chromatography (GPC), a UV detector being used. The measurement was carried out against an external polyacrylic acid standard, which provides realistic molecular weight values due to its structural relationship with the polymers investigated. These figures deviate significantly from the molecular weight figures for which polystyrene sulfonic acids are used as the standard. The molar masses measured against polystyrene acids are generally significantly higher than the molar masses specified in the context of the present invention.

Suitable polymers are in particular polyacrylates, which are preferably one mole have mass of 2,000 to 20,000 g / mol. Because of their superior solving From this group, the short-chain polyacrylates can be used be preferred, the molecular weights of 2,000 to 10,000 g / mol, particularly preferred from 3,000 to 5,000 g / mol.  

Also suitable are copolymeric polycarboxylates, especially those of Acrylic acid with methacrylic acid or with acrylic acid or methacrylic acid Maleic acid. Copolymers of acrylic acid have proven particularly suitable proven with maleic acid, the 50 to 90 wt .-% acrylic acid and 50 to 10 % By weight of maleic acid. Their relative molar mass, based on free acid ren, is generally 2,000 to 70,000 glmol, preferably 20,000 to 50,000 g / mol and in particular 30,000 to 40,000 g / mol.

The (co) polymeric polycarboxylates can either be as a powder or as aq solution. The content of the washing or detergent portions of (co) polymeric polycarboxylates preferably 0.5 to 20% by weight, in particular 3 to 10% by weight.

To improve water solubility, the polymers can also use allyl sulfone acids, such as, for example, in EP-B 0 727 448, allyloxybenzenesulfonic acid and contain methallylsulfonic acid as a monomer.

In particular, biodegradable polymers made of more are preferred as two different monomer units, for example those which according to DE-A 43 00 772 as monomer salts of acrylic acid and maleic acid as well as vinyl alcohol or vinyl alcohol derivatives or according to DE-C 42 21 381 as monomer salts of acrylic acid and 2-alkylallylsulfonic acid and zuc contain ker derivatives.

Further preferred copolymers are those described in the German patent applications be described DE-A 43 03 320 and DE-A 44 17 734 and as Mo Nomers are preferably acrolein and acrylic acid / acrylic acid salts or acrolein and contain vinyl acetate.  

Polymeric aminodicars are also further preferred builder substances bonic acids, their salts or their precursors. Especially more preferred are polyaspartic acids or their salts and derivatives, of which is disclosed in German patent application DE-A 195 40 086 that in addition to co-builder properties, it also has a bleach-stabilizing effect exhibit.

Other suitable builder substances are polyacetals, which are produced by implementation of dialdehydes can be obtained with polyol carboxylic acids, the 5 to 7 Have carbon atoms and at least 3 hydroxyl groups, for example as described in European patent application EP-A 0 280 223. Before pulled polyacetals are made from dialdehydes such as glyoxal, glutaraldehyde, Terephthalaldehyde and mixtures thereof and from polyol carboxylic acids such as Obtain gluconic acid and / or glucoheptonic acid.

Other suitable organic builder substances are dextrins, for example Oligomers or polymers of carbohydrates by partial hydrolysis of strengths can be obtained. The hydrolysis can be carried out in the usual way for example, acid or enzyme-catalyzed processes can be carried out. They are preferably hydrolysis products with medium molecular weights in the range of 400 to 500,000 g / mol. There is a polysaccharide with one Dextrose equivalent (DE) in the range from 0.5 to 40, in particular from 2 to 30, preferred, DE being a common measure of the reducing effect nes polysaccharide compared to dextrose, which has a DE of 100 be sits. Both maltodextrins with a DE between 3 and 20 can be used and dry glucose syrups with a DE between 20 and 37 as well as so-called called yellow dextrins and white dextrins with higher molar masses in the range of 2,000 to 30,000 g / mol. A preferred dextrin is in the British patent message 94 19 091.  

The oxidized derivatives of such dextrins are their reaction products with oxidizing agents which are capable of oxidizing at least one alcohol function of the saccharide ring to the carboxylic acid function. The type of oxidized dextrins and processes for their preparation are known in particular from European patent applications EP-A 0 232 202, EP-A 0 427 349, EP-A 0 472 042 and EP-A 0 542 496 and from international patent applications WO 92118542 , WO 93/08251, WO 93/16110, WO 94/28030, WO 95/07303, WO 95 / l 2619 and WO 95/20608. An oxidized oligosaccharide according to German patent application DE-A 196 00 018 is also suitable. A product oxidized at C _{6 of} the saccharide ring can be particularly advantageous.

Oxydisuccinates and other derivatives of disuccinates are also preferred Ethylene diamine disuccinate are other suitable co-builders. Ethy lendiamine-N, N'-disuccinate (EDDS), the synthesis of which, for example, in Document US-A 3,158,615 is described, preferably in the form of its natri um- or magnesium salts use 43095 00070 552 001000280000000200012000285914298400040 0002019934254 00004 42976det. Are further preferred in this also relate to glycerol disuccinate and glycerol trisuccinate, such as in for example in US Pat. Nos. 4,524,009 and 4,639,325, in European patent application EP-A 0 150 930 and in Japanese Patent application JP-A 93 / 339,896 can be described. Suitable use quantities in formulations containing zeolite and / or silicate are 3 up to 15% by weight.

Other useful organic co-builders are, for example, acetylated Hy droxycarboxylic acids or their salts, which may also be in lactone Form can be present and which have at least 4 carbon atoms and little contain at least one hydroxy group and a maximum of two acid groups. Derar For example, co-builders are used in international patent applications WO 95/20029.  

Another class of substances with co-builder properties are the Phos phonate. These are, in particular, hydroxyalkane or ami noalkane phosphonates. Among the hydroalkane phosphonates, the 1- Hydroxyethane-1,1-diphosphonate (HEDP) of particular importance as a co- Builder. It is preferably used as the sodium salt, with the disodium salt neutral and the tetrasodium salt reacts alkaline (pH = 9). As an aminoal Kanphosphonates are preferably ethylenediaminetetramethylenephospho nat (EDTMP), diethylene triamine pentamethylene phosphonate (DTPMP) and de higher homologues in question. They are preferably in the form of neutral reacting sodium salts, e.g. B. as the hexasodium salt of EDTMP or as Hepta and octasodium salt of DTPMP, used. As a builder, the class of phosphonates preferably uses HEDP. The aminoalkane phosphonates also have a strong ability to bind heavy metals. Accordingly, it can, especially if the invention Detergent or cleaning agent portions also contain bleach, preferred be to use aminoalkanephosphonates, especially DTPMP, or Mi to use mixtures from the named phosphonates.

In addition, all compounds that are able to complex with To form alkaline earth metal ions can be used as co-builders.

In addition to the above-mentioned ingredients surfactant and builder, the inventors detergents or cleaning agents according to the invention further in washing or cleaning agents agents typical ingredients from the group of bleaching agents, bleaching agents vators, enzymes, fragrances, perfume carriers, fluorescent agents, dyes, Foam inhibitors, silicone oils, anti-redeposition agents, optical brighteners, Graying inhibitors, color transfer inhibitors and corrosion inhibitors contain.

Among the compounds which serve as bleaching agents and supply H ₂ O ₂ in water, sodium perborate tetrahydrate and sodium perborate monohydrate are of particular importance. Other useful bleaching agents are, for example, sodium percarbonate, peroxypyrophosphates, citrate perhydrates and H ₂ O ₂ -containing peracid salts or peracids, such as perbenzoates, peroxophthalates, di perazelaic acid, phthaloiminoperacid or diperdodecanedioic acid. If cleaning or bleaching preparations for machine dishwashing are produced, bleaching agents from the group of organic bleaching agents can also be used. Typical organic bleaches are the diacyl peroxides, such as. B. dibenzoyl peroxide. Other typical organic bleaching agents are peroxyacids, examples of which include alkylperoxyacids and arylperoxyacids. Preferred representatives are (a) peroxybenzoic acid and its ring-substituted derivatives, such as alkyl peroxybenzoic acids, but also peroxy-α-naphthoic acid and magnesium monoperphthalate; (b) the aliphatic or substituted aliphatic peroxyacids such as peroxylauric acid, peroxystearic acid, ε-phthalimidoperoxy caproic acid [phthaloiminoperoxyhexanoic acid (PAP)], o-carboxybenzamido peroxycaproic acid, N-nonenylamido operadipic acid and succinonate amide; and (c) aliphatic and araliphatic peroxydicarboxylic acids, such as 1,12-diperoxycarboxylic acid, 1,9-diperoxyazelaic acid, diperocysebacic acid, diperoxybrassylic acid, the diperoxyphthalic acids, 2-decyldiperoxybutane-1,4-diacid, N, N-terephthaloyl-diap (6 ) can be used who.

As a bleach in machine dishwashing compositions substances that release chlorine or bromine can also be used. Under the appropriate chlorine or bromine releasing materials for example heterocyclic N-bromo- and N-chloramides, for example Trichloroisocyanuric acid, tribromo isocyanuric acid, dibromo isocyanuric acid and / or Dichloroisocyanuric acid (DICA) and / or its salts with cations such as potassium and Sodium into consideration. Hydantoin compounds such as 1,3-dichloro-5,5-dimethylhy danthoin are also suitable.  

To be used when washing or cleaning at temperatures of 60 ° C and below To achieve an improved bleaching effect, bleach activators can be used in the Detergent and cleaning agent portions can be incorporated. As a bleaching stock vators can be compounds that are aliphatic under perhydrolysis conditions Peroxocarboxylic acids with preferably 1 to 10 carbon atoms, in particular 2 to 4 carbon atoms, and / or optionally substituted perbenzoic acid, be used. Substances containing O- and / or N-acyl groups are suitable the number of carbon atoms mentioned and / or optionally substituted benzoyl group wear pen. Multi-acylated alkylenediamines are preferred, in particular Tetraacetylethylenediamine (TAED), acylated triazine derivatives, in particular 1,5- Diacetyl-2,4-dioxohexahydro-1,3,5-triazine (DADHT), acylated glycolurils, esp special tetraacetylglycoluril (TAGU), N-acylimides, especially N-nonanoyl succinimide (NOSI), acylated phenol sulfonates, especially n-nonanoyl or Isononanoyloxybenzenesulfonat (n- or iso-NOBS), carboxylic anhydrides, ins special phthalic anhydride, acylated polyhydric alcohols, in particular Triacetin, ethylene glycol diacetate and 2,5-diacetoxy-2,5-dihydrofuran.

In addition to the conventional bleach activators or in their place so-called bleach catalysts in the detergents and cleaning agents Portions are incorporated. These fabrics are pale reinforcing transition metal salts or transition metal complexes as in for example, Mn, Fe, Co, Ru or Mo salt complexes or carbonyl complexes xe. Also Mn, Fe, Co, Ru, Mo, Ti, V and Cu complexes with N-containing tri pod ligands as well as Co, Fe, Cu and Ru amine complexes are known as Bleichka Talysators can be used.

Enzymes come from the class of proteases, lipases, amylases, Cellulases or their mixtures in question. Are particularly well suited Strains of bacteria or fungi such as Bacillus subtilis, Bacillus licheniformis and Streptomyces griseus enzymatic substances obtained. Preferably who the proteases of the subtilisin type and in particular proteases derived from Bacil  lus lentus are used. There are enzyme mixtures, at for example from protease and amylase or protease and lipase or pro tease and cellulase or from cellulase and lipase or from protease, amylase and lipase or protease, lipase and cellulase, but especially Cellu mixtures containing lase of particular interest. Peroxidases or Oxidases have been found to be suitable in some cases. The enzymes can NEN adsorbed on carriers and / or embedded in coating substances, to protect them against premature decomposition. The proportion of enzymes, En enzyme mixtures or enzyme granules in the combination according to the invention Settlement can, for example, about 0.1 to 5 wt .-%, preferably 0.1 to be about 2% by weight.

Contain the detergent or cleaning agent portions according to the invention according to a particularly preferred embodiment, further additives, as they are from the prior art as additives for washing or cleaning agent preparations are known. These can either be one or more If necessary, all portions (washing-active preparations) of the Detergent or cleaning agent portions according to the invention are added or - as in the co-pending patent application No. 199 29 098.9 with described in the title "Active ingredient portion pack" - in the water-soluble, the materials comprising detergent active preparations, for example in the water-soluble films, but also in the capsules according to the invention or Coatings are incorporated.

A preferred group of additives used according to the invention are optical Brightener. The opti usual in detergents can be used here brighteners. These are used as an aqueous solution or as a solution in one organic solvent added to the polymer solution, which in the film around is converted, or be a portion of a portion (active washing preparation) Nes detergent or cleaning agent added in solid or liquid form. Examples of optical brighteners are derivatives of diaminostilbenedisulfonic acid  or their alkali metal salts. Are suitable for. B. Salts of 4,4'-bis (2-anilino-4- morpholino 1,3,5-triazinyl-6-amino-) stilbene-2,2'-disulfonic acid or the like built-up compounds that a diethanol instead of the morpholino group amino group, a methylamino group, an anilino group or a 2- Wear methoxyethylamino group. Brighteners of the type of substituted Diphenylstyryle in the partial portions (washing active preparation gen) of the detergent or cleaning agent portions according to the invention be, e.g. B. the alkali salts of 4,4'-bis (2-sulfostyryl) diphenyl, 4,4'-bis (4- chloro-3-sulfostyryl) diphenyl or 4- (4-chlorostyryl) 4 '- (2-sulfostyryl) diphenyl. Mixtures of the aforementioned brighteners can also be used.

Another group of additives preferred according to the invention are UV Protective substances. These are substances that are used in the washing process or released in the washing liquor during the subsequent fabric softening process and accumulate on the fiber and then UV To achieve protection effect. Suitable are those under the name Tinosorb in Commercial products from the company Ciba Specialty Chemicals.

Other conceivable additives which are preferred in special embodiments are foam inhibitors, but also bitter substances that an accidental Ver swallow such packaging or parts of such packaging from children can prevent.

Another group of additives preferred according to the invention is color substances, in particular water-soluble or water-dispersible dyes. Be Dyes are preferred here as they improve the optical product appearance in detergents and cleaning agents are usually used. The selection of such dyes is not difficult for the person skilled in the art ten, especially since such conventional dyes have a long shelf life and Insensitivity to the other ingredients of the detergent active preparations and against light as well as no pronounced substantivity  Textile fibers so as not to stain them. The dyes are fiction according to in the detergent or cleaning agent portions in amounts below 0.01% by weight.

Another class of additives that the washing or Rei Detergent portions can be added are polymers. Under these Polymers can be used on the one hand, polymers that can be washed or Cleaning or rinsing show cobuilder properties, e.g. Po lyacrylic acids, also modified polyacrylic acids or corresponding copoly mere. Another group of polymers are polyvinyl pyrrolidone and others Graying inhibitors, such as copolymers of polyvinylpyrrolidone, cellulose Ether and the like. According to a further embodiment of the invention So-called soil repellents are also suitable as polymers. Are these Polymers that pull on fibers or hard surfaces and there a how counteract pollution. Relevant connections of this type are known to the detergent specialist. It is polyester of Terephthalic acid and ethylene glycol, some with sulfonic acid groups are modified.

Another group of additives are bleaching catalysts, in particular Bleaching catalysts for automatic dishwashing detergents or detergents. Ver Complexes of manganese and cobalt are used here, especially with nitrogenous ligands.

Another preferred group of additives for the purposes of the invention are Sil protective means. It is a variety of mostly cyclic or ganic compounds, which also addresses the specialist addressed here are common and help tarnishing silver containing counterparts to prevent during the cleaning process.  

Washing or cleaning can be used as further additives according to the invention Medium portions also contain components that contain the oil and fat positive influence on washability from textiles, so-called soil repellents. This effect becomes particularly clear when a textile is soiled previously several times with a detergent according to the invention, this contains oil and fat-dissolving component, was washed. To the preferred For example, non-ionic components include oil and fat-dissolving components Cellulose ethers such as methyl cellulose and methyl hydroxypropyl cellulose with egg Nem content of methoxy groups from 15 to 30 wt .-% and hydroxyprop oxyl groups of 1 to 15 wt .-%, each based on the nonionic Cellulose ether, as well as the polymers known from the prior art Phthalic acid and / or terephthalic acid or their derivatives, in particular special polymers of ethylene terephthalates and / or polyethylene glycol terephthalates or anionically and / or nonionically modified derivatives of this. Of these, the sulfonated derivatives of are particularly preferred Phthalic acid and terephthalic acid polymers.

All of these additives are used in the washing or cleaning of the invention medium portions in amounts up to at most 30 wt .-%, preferably 2 to 20 % By weight added. As already said, the addition can also be a matter al a water-soluble enclosure that the or one of the waschakti ve (n) preparation (s) includes. To maintain the balance of the recipe ten, it is therefore possible for the skilled person, the plastic material for the Umfas either increase its weight in order to increase the depot effect of the ge is achieved according to the invention, to exploit or the additives mentioned additionally at least partially in the rest of the active detergent preparation hold. However, this is less preferred.

Fragrances are the detergents and cleaning agents according to the invention Portions added to the overall aesthetic impression of the products improve and the consumer in addition to the technical performance (fabric softener  result) a sensorially typical and unmistakable product supply. As perfume oils or fragrances, individual fragrance Compounds are used, for example the synthetic products of the ester, ether, aldehyde, ketone, alcohol and hydrocarbon type. Fragrance compounds of the ester type are, for example, benzyl acetate, Phenoxyethyl isobutyrate, p-t-butylcyclohexyl acetate, linalyl acetate, dimethylbenz yl-carbinyl acetate, phenylethyl acetate, linalyl benzoate, benzyl formate, ethylme thylphenylglycinate, allylcyclohexylpropionate, styrallylpropionate and benzylsali cylate. The ethers include, for example, benzyl ethyl ether. To the aldehydes count z. B. linear alkanals with 8 to 18 carbon atoms, citral, citronellal, citronel lyloxyacetaldehyde, cyclamenaldehyde, hydroxycitronellal, Lileal and Bourgeonal.

The ketones include the ionones, α-isomethyl ionone, and methyl cedryl ketone. Alcohols include anethole, citronellol, eugenol, geraniol, linalool and Phe nylethyl alcohol and terpineol. The main hydrocarbons include Lich terpenes like limes and pinene. Mixtures are preferred whose odoriferous substances are used, which are coordinated so that they ge together create an appealing fragrance. Such perfume oils can also contain natural fragrance mixtures, such as those from vegetable sources len are accessible. Examples are pine, citrus, jasmine, patchouli, rose or ylang-ylang oil. Nutmeg oil, sage oil, chamomile oil, Clove oil, lemon balm oil, mint oil, cinnamon leaf oil, linden blossom oil, juniper berry oil, Vetiver oil, olibanum oil, galbanum oil and labdanum oil as well as orange blossom oil, Neroliol, orange peel oil and sandalwood oil.

The fragrance content is usually in the range up to 2% by weight entire detergent or cleaning agent portion.

The fragrances can be incorporated directly into the wash-active preparations become; but it can also be advantageous to apply the fragrances to carriers conditions that increase the adhesion of the perfume to the laundry and by a  slower fragrance release ensures long-lasting fragrance of the textiles. As such carrier materials have proven themselves, for example, cyclodextrins. There at can the cyclodextrin-perfume complexes additionally with other Auxiliaries are coated.

The perfumes and fragrances can basically in each of the portions (active washing preparations) of the washing or cleaning agents according to the invention Serving agent portions included. However, it is particularly preferred that them in a detergent in one for the post-wash or fabric softener cycle provided detergent portion or in a cleaning agent, esp in a dishwashing detergent, in one for the rinse or rinse aid portion of detergent provided, especially part detergent Serving, are included. Therefore, according to the invention, you only need one the conditions (especially at the temperature) of the post-wash cycle or rinse cycle water-soluble, under the conditions (especially at the temperature) of the previous wash or rinse cycle soluble material, especially from a corresponding film or capsule be included. According to the invention, this is for example with one of several Chamber existing bags from foils of different water solubility makeable.

The detergent and cleaning agent portions according to the invention can be in egg A whole series of different configurations are available. Such Refinements can depend on the components used in detail depend, in particular on the detergent preparations, but can be freely selectable even within certain limits.

There are numerous washing-active preparations in the form of powders, powders mixtures or in the form of particulate bodies, for example spheres or gra nulate before, so that it offers washing and cleaning agent portions ge according to the invention as single-portion packs or packs of combinations  to provide nations of powdery or particulate components, for example as combinations of powdery or particulate components in foil pouches with one or more chambers or layers or individually portions or combinations of powdered components in capsules. According to a further preferred embodiment of the invention, the fixed, for example powdery, components to granules or beads available and in the form of granules or pearls - comparable to the Powders - in foil pouches with several layers or chambers or in Capsules packed, in what form they are then immediately for washing or cleaning are used.

According to a further preferred embodiment of the invention the detergent or cleaning agent portions also in the form of bodies pressed solids are present, which can have any shape; derar shaped bodies (such as tablets, blocks, briquettes, rings or the like) are from the State of the art and can also within the scope of the present Er find use. In particular, such shaped bodies can also Have depressions, hollows, incisions or the like, the special purposes of Serve individual detergent preparations. Of course are also shaped bodies in combination with powders, in combination with liquid keiten (the latter, for example, then in an enclosure from a water-soluble Chen material according to the invention) or in combination with one in one meltable matrix embedded wash-active preparation under the present invention.

Preferred, but non-limiting, examples of detergent preparations which are combined into detergent or cleaning agent portions according to the invention can be:

• - One or more detergent preparations in powder, particle or Granular and / or liquid form for one or more courses of the  Washing or cleaning process in one or more enclosures gene from one or more water-soluble polymer material (s), preferably in a single polymer material bag or together hanging polymer material bags of different, further be prefers temperature-dependent water solubility; of such Preparations can also be different wash-active preparations cher composition for one and the same washing or cleaning be included, for example three washing-active preparations, of which z. B. one for the pre (washing or cleaning) course and two are provided for the main (washing or cleaning) aisle or z. B. two for the main (washing or cleaning) course and one are intended for the post-washing or cleaning cycle;
• - a washing-active preparation in powder form and a washing-active accessory riding in the form of a body melting at high temperature in an enclosure that dissolves in water at the temperature at which the Powdered detergent or cleaning agent portion in the fleet is needed;
• - A wash-active preparation in the form of a shaped body and one active washing preparation in the form of a melt at high temperature body in an enclosure that changes in temperature at Water dissolves in which the washing or cleaning agent is in solid form Partial portion of the detergent is needed in the fleet; this execution shape can comprise a shaped body that partially or completely loosens is delayed, for example by pressing or encasing with egg water for a certain time or at a certain temperature resistant coating; if in this case the enclosure contains cold water Lich, the molded body is in the washing or cleaning cycle early Fleet released and can quickly dissolve components for a preliminary (Washing or cleaning) course and (due to the release delay)  slowly soluble components for a main (washing or cleaning gear) or quickly soluble components for a first Part of the main (washing or cleaning) aisle and (due to the Lö delay) slowly soluble components for a second part the main (washing or cleaning) aisle included; the from the In any case, melting active detergent preparation is for determines the post (washing or cleaning) course;
• - a wash-active preparation in the form of a (if necessary by a water-soluble polymer material included, optionally dissolving shaped body in combination with one of a water-soluble Polymeric materials included active detergent preparation in, for example liquid form;
• - a wash-active preparation in the form of a formed body with a trough in which another wash-active Preparation in the form of a powder from a water temperature-soluble polymer material is maintained;
• - a wash-active preparation in the form of a formed body with a trough in which another wash-active Preparation in the form of a shaped body from one in water to one tuned temperature soluble polymer material is kept; through a The solubility of the second shaped body can be adjusted at be certain conditions (e.g. certain temperature) soluble compo dose the doses into the wash liquor;
• - several active washing preparations in the form gerter) moldings are un in water-soluble polymer materials different water solubility to a detergent or cleaning agent Portion summarized, if necessary together with other comm  components in other (under different conditions) water-soluble Chen polymer materials.

As indicated above, these cases are non-limiting examples of Detergent or cleaning agent portions according to the invention.

The process according to the invention for the production of a suitable, in particular for loading a washing machine or dishwasher for a program run taking place in an aqueous phase, at least one measured amount of at least one wash-active preparation and at least one the measured amount (s) of at least one wash-active preparation comprehensive detergent portion containing water-soluble polymer material is characterized by the steps of:

• - at least a measured amount of at least one active detergent Provides preparation;
• - Provides at least one water-soluble polymer material, we at least one water-soluble polymer material contains one or more components of at least one of the detergent formulations;
  and or
• - Provides at least one water-soluble polymer material, where we at least a measured amount of at least one wash-active Zu preparation of one or more component (s) of the water-soluble poly contains material; and
• - at least a measured amount of at least one active detergent Preparation with the at least one water-soluble polymer material includes.

The process steps depend in detail on whether one is measured a quantity or whether several measured quantities of active detergent preparations are contained in the detergent or cleaning agent portion to be produced. Basically, the method is suitable for the production of a wash-active addition  preparation of comprehensive detergent or cleaning agent portions or several wash-active preparations of comprehensive detergents or cleaning agents Servings. The second case is the preferred according to the invention: rule portions of detergent or cleaning agent are produced in which several washing-active preparations are combined in one serving.

In the simplest case of manufacture, each wash-active preparation is made by egg surrounded by a separate water-soluble polymer material. However, it is possible also, to wash multiple active preparations with a polymer material grasp. The respective water-soluble polymer material must be invented Manufacturing process according to the invention can be selected in which Temperature of the respective polymer material in the washing or cleaning detachment liquor and thus release the contents of the partial packaging into the fleet zen should. Another criterion for choosing the water-soluble polymer However, according to the invention, the material used is a detergent preparation of the respective polymer material is to be included. This is why of Meaning, because the decision depends on which component (s) the washing-active preparation, for the "packaging" of which the polymer material should also be included in the polymer material or alternatively or additionally, which component (s) of the water-soluble polymer material should also be included in the active detergent preparation.

According to the invention, at least for the wash-active preparation (s) a water soluble polymer material is provided which comprises one or more Contains component (s) contained in at least one of the detergent active Preparations is included. Alternatively, or at the same time, will be one or more detergent formulations compounded so that we at least or even several component (s) of the water comprising them soluble polymer material included. One or are particularly preferred several of the components mentioned, which in both phases (polymer Material (s) and detergent preparation (s)) are included, selected from the  Group of hydrophilic plasticizers and substances - if necessary when added small amounts (<20% by weight, advantageously <10% by weight, based on the addition preparation) water - liquid or pasty to waxy at room temperature available. The ones mentioned above are particularly preferred, very particularly preferably the surfactant components or polyols specifically described above, Polyalkylene glycols and structurally analogous amines. Of these, one or can be included in both phases.

The content of one or more of the components mentioned is invented in the method according to the invention chosen so that it in each of the phases of the respective corresponds to the concentration of the phase equilibrium. Both can do that Phases from the start in a mutual dynamic exchange of ideas respective component (s). However, it corresponds to another version form of the invention to choose the concentration of the component (s) so that a phase is the predominant amount or even the total amount of contains the respective component (s) and the other phase a smaller amount contains the same component or even the compo (s) in question not at all if the balance between the two involved phases wash-active preparation and water-soluble polymer mate rial after production of the washing or cleaning agent according to the invention Portion under controlled conditions. By diffusion and / or ad sorption then migrates the component in question, for example (each not restrictive) in hours or a few days in the phase in which the concentration is below the phase equilibrium concentration. So will after a short time, which is acceptable in practice, the phase equilibrium is established represents, and there are both stable wash-active preparations as well Storage-stable enclosures of the wash-active preparation (s) in combination won.

It is of course within the scope of the manufacturing process according to the invention It is also possible to drive several detergent preparations with one water  to comprise soluble polymer material. Examples of this have been mentioned above. In this case, the polymer material can contain one or more components ner or more detergent substances, such as alternative or at the same time also several washing-active substances one or more compos May contain elements of the polymer material.

The invention also relates to the new features for the invention Servings of detergent or cleaning agent.

These enclosures are particularly suitable for enclosing the fiction, ge regular detergent or cleaning agent portions or their partial portions. There in these enclosures are either designed so that one or more Component (s) at least one of the (later included) wash-active preparations tions also contained in the water-soluble polymer material of the enclosure is / are or that one or more component (s) of the water-soluble poly mer materials also in at least one of the (later included) wash-active Preparations is / are included. According to the invention preferably too tangled Chen is also an embodiment in which both one or more compo at least one of the wash-active preparations also in what is contained in the soluble polymer material as well as being one or more rere component (s) of the water-soluble polymer material in at least one of the detergent preparations is included.

According to preferred and advantageous embodiments of the order Versions is / are the component (s) that are also in the water-soluble poly merMaterial is / are selected from the group of substances that - if necessary with the addition of small amounts of water - liquid at room temperature or pasty to waxy.

Particularly preferred according to the invention is an embodiment of the inventions according to the invention, in which the component (s) also contained in the water-soluble polymer material at least one of the wash-active preparation (s) is / are selected from the group consisting of non-ionic and anionic surfactants as defined in detail above. Non-ionic surfactants from the group of alkoxylated fatty alcohols with 8 to 20 carbon atoms in the fatty alcohol alkyl radical are further preferred according to the invention, fatty alcohols of natural origin, ie straight-chain and generally predominantly containing an even number of carbon atoms in the alkyl group, compared to synthetic fatty alcohols (e.g. B. branched or containing an odd number of carbon atoms fatty alcohols) are preferred. Examples of the fatty alcohols are from the point of view of the availability of the compounds lauryl alcohol (C ₁₂ ), myristyl alcohol (C ₁₄ ), cetyl alcohol (C ₁₆ ) etc. or mixtures of such fatty alcohols originating from and processed accordingly. The number of alkoxy groups, which, according to the invention, are primarily ethoxy groups or propoxy groups, particularly preferably ethoxy groups, can vary within wide limits and is particularly preferably between 3 and 80. Further nonionic surfactants, which are also present in the water-soluble polymer material Can be contained, according to the invention, alkoxylated C ₈ to C ₂₀ fatty acid alkyl esters having 1 to 8 carbon atoms in the alkyl radical and 3 to 80, particularly preferably up to 20, alkoxy groups, preferably ethoxy groups, in the molecule. From a practical point of view, it will be advantageous to take into account the fact that those compounds from the above-mentioned groups are used which are still liquid to pasty even with longer chain lengths at the application temperatures.

According to the invention, anionic surfactants can also be used for the stated purpose. From the group of these compounds come primarily alkylbenzenesulfonic acids with 9 to 13 carbon atoms in the alkyl groups and their salts (predominantly present in an alkaline medium), cumene sulfonic acid and its salts, C ₁₂ to C ₁₈ fatty alcohol sulfates and C ₈ to C ₂₀ - fatty acids and their salts in question.

According to the invention, an embodiment of the is also particularly preferred Containers for detergent or cleaning agent portions, in which the also in at least one detergent active component (s) of the water-soluble polymer material is / are selected from the group of hydro phile plasticizer.

According to the invention, polyols having 1 to 20 carbons are particularly preferred atoms and 2 to 6 hydroxy groups, polyalkylene glycols with 2 to 4 (before adds linear) alkylene carbon atoms (i.e. ethylene groups, propylene Groups or butylene groups) in the molecule, particularly preferably polyethylene long glycols and / or polypropylene glycols, further particularly preferably poly ethylene glycols and / or polypropylene glycols with molecular weights in the loading ranging from 200 to 12,000, more preferably with molecular weights <1,500. The aforementioned polyalkylene glycols can also be used with advantage structurally analogous amines, d. H. Compounds in which the glycol -O- group is replaced by an amine -NH- group. The first also apply to the amines ranges of molecular weights indicated. From a practical point of view such compounds with advantage in the scope of the invention reversible, which at the (increased) application temperatures still liquid up to pa are nasty.

According to another preferred embodiment of the invention also low molecular weight polyacrylates or polymethacrylates or polymaleinates (Acids or - preferred under alkaline conditions of use Salts including their amine or (also organic) ammonium salts) or Use copolymers of polyacrylates / polymethacrylates and polymaleinates be det.

As already stated above, the concentrations of the respective compo nente (s) in the scope of the invention hardly any restrictions thrown depend on a number of parameters. General amounts  the phase equilibrium concentration in the enclosure 0.5 to 50% by weight, based on the total weight of the material of the enclosure, preferably 1 to 30% by weight and more preferably 3 to 25% by weight. In the above mentioned NEN case that in the preparation of the detergent or cleaning agent portion Including none of the desired components can of course the concentration at the beginning of the manufacturing step should be 0% by weight. It will however, later in the course of a controllable, comparatively short time a phase equilibrium concentration of the corresponding component (s) set in the enclosure, which a concentration in the above. Areas ent speaks.

It is further preferred according to the invention that the material of the enclosure Polymer material is selected from the group consisting of (given if necessary acetalized) polyvinyl alcohol, polyvinyl pyrrolidone, polyethylene oxide, Gelatin, starch, cellulose and their derivatives and mixtures thereof. A Details of these materials have been given above.

According to the invention, water-soluble polymer Materials used, which are in the form of films, capsules or Coa tings. Details of these forms have also been related above explained with the detergent or cleaning agent portions.

The invention further includes a washing process using of the detergent portions indicated above and a cleaning process using the detergent portions given above. In at the process uses enclosures or wrappings in which one or more component (s) at least one of the (included later) wash-active preparations also in the water-soluble polymer material Containment is / are and / or in which one or more compo nente (s) of the water-soluble polymer material in at least one of the (later included) detergent preparations is / are.  

The washing process according to the invention is in particular a machine washing process in which

• - A detergent portion according to the detailed description above exercise placed in a washing machine;
• - by adding water and adjusting the temperature to a first Temperature value at which there is at least a measured amount a wash-active preparation of the detergent portion water-soluble polymer material dissolves at least one wash-active addition preparation releases into the wash liquor; and if necessary
• - by adding more water and adjusting the temperature to one or more additional temperature value (s) above the first Temperature value and possibly over other previous tempera values lie / lie, one or more further wash-active preparations released into the wash liquor.

The cleaning method according to the invention is in particular a method for machine washing dishes, in which

• - A detergent serving according to the previous detailed description writing placed in a dishwasher;
• - by adding water and adjusting the temperature to a first Temperature value at which there is at least a measured amount a detergent-active preparation of the detergent portion of the water-soluble polymer material dissolves at least one wash-active Releases the preparation into the cleaning liquor; and if necessary
• - by adding more water and adjusting the temperature to one or more additional temperature value (s) above the first Temperature value and possibly over other previous tempera values lie / lie, one or more further wash-active preparations released into the cleaning liquor.

The washing or cleaning process therefore aims to achieve an optimal con ditioning the washing or cleaning liquor to achieve that ent speaking detergent or cleaning agent portions under conditions, first Line and therefore preferred: released into the fleet under temperature conditions that allow the properties of the released washing-active Preparation to develop optimally, in particular with the staggered (er most, second and possibly higher) temperatures of the respective Washing or cleaning steps.

With the present invention, detergents or cleaning agents Portions and enclosures suitable for their wrapping provided also contain at least one component in the envelopes, which in a the active detergent preparations of the detergent or cleaning agent portions are contained and / or in at least one active washing preparation of the Detergent or cleaning agent portions contain at least one component ten, in an encompassing water-soluble polymer material is included. This not only results in ideal packaging or packaging solution materials for wash-active preparations, but also practical ones and detergent or cleaning agents that can be conveniently dosed by the consumer Portions with improved properties compared to the prior art.

Claims (28)

1. Detergent or cleaning agent portion, in particular for loading one Washing machine or dishwasher for one in an aqueous phase instead finding program run containing at least a measured amount at least one active washing preparation and at least one of the abge measured amount (s) of at least one detergent-active preparation Send water-soluble polymer material, one or more com component (s) of at least one of the wash-active preparations also in the water-soluble polymer material are included. 2. Detergent or cleaning agent portion, in particular for loading one Washing machine or dishwasher for one in an aqueous phase instead finding program run containing at least a measured amount at least one active washing preparation and at least one of the abge measured amount (s) of at least one detergent-active preparation Send water-soluble polymer material, one or more com component (s) of the water-soluble polymer material also in at least one of the active detergent preparations are included. 3. Detergent or cleaning agent portion, especially for loading one Washing machine or dishwasher for one in an aqueous phase instead finding program run containing at least a measured amount at least one active washing preparation and at least one of the abge measured amount (s) of at least one detergent-active preparation Send water-soluble polymer material, one or more com component (s) of at least one of the wash-active preparations also in the water-soluble polymer material are included and where one or more  rere component (s) of the water-soluble polymer material also in little least one of the detergent-active preparations are included. 4. detergent or cleaning agent portion according to one of claims 1 or 3, in which the (s) also contained in the water-soluble polymer material Component (s) selected at least one of the wash-active preparation (s) is / are from the group of substances which - if necessary, coagulate small amounts of water - liquid or pasty to wax at room temperature present well. 5. Detergent or detergent portion according to claim 4, wherein the component (s) is / are selected from the group consisting of alkoxylated fatty alcohols having 8 to 20 carbon atoms and 3 to 80 alkoxy groups, preferably ter ethoxy groups, im Molecule, alkoxylated C ₈ to C ₂₀ fatty acid alkyl esters with 1 to 8 carbon atoms in the alkyl radical and 3 to 80, preferably up to 20, alkoxy groups, more preferably ethoxy groups, in the molecule, C ₉ to C ₁₃ alkyl sulfonates, cumene sulfonate, C ₁₂ to C ₁₈ fatty alcohol sulfates and salts of C ₈ to C ₂₀ fatty acids. 6. detergent or cleaning agent portion according to one of claims 2 or 3, in which the (n) also contained in at least one active washing preparation Component (s) of the water-soluble polymer material is / are selected from the group of hydrophilic plasticizers. 7. washing or cleaning agent portion according to claim 6, wherein the compo nente (s) is / are selected from the group polyols with 1 to 20 carbon a toms and 2 to 6 hydroxyl groups, polyalkylene glycols with 2 to 4 carbons atoms in the alkylene radical, as well as structurally analogous amines with -NH- group pen instead of the -O- groups in the molecule, preferably polyethylene glycols and Polypropylene glycols or structurally analogous amines, more preferably poly ethylene glycols and polypropylene glycols with molecular weights in the range  from 200 to 12,000 or structurally analogous amines, even more preferably with Molecular weights <1,500 or structurally analogous amines. 8. detergent or cleaning agent portion according to one of claims 1 to 7, wherein the component (s) in the at least one water-soluble poly mer material and in the at least one wash-active preparation in one the concentration corresponding to the state of equilibrium is present gene, preferably in a concentration of 0.5 to 50 wt .-%, based on the total weight of the respective phase, more preferably in one Concentration of 1 to 30 wt .-%, very particularly preferably in one Concentration from 3 to 25% by weight. 9. washing or cleaning agent portion according to one of claims 1 to 7, wherein the component (s) in the at least one water-soluble poly mer material and in the at least one wash-active preparation in one above or below the concentration that corresponds to the state of equilibrium speaks, lying concentration is / are present and the same concentration corresponding to the weight within a controlled time sets, preferably a concentration of 0.5 to 50 wt .-%, based on the total weight of the respective phase, more preferably a con concentration of 1 to 30 wt .-%, very particularly preferably a concentra tion of 3 to 25 wt .-%. 10. detergent or cleaning agent portion according to one of claims 1 to 9, wherein the water-soluble polymer material is selected from the group consisting of consists of (optionally acetalized) polyvinyl alcohol, polyvinyl pyr rolidone, polyethylene oxide, gelatin, starch, cellulose and its derivatives and Mixtures of these.   11. detergent or cleaning agent portion according to one of claims 1 to 10, in which the water-soluble polymer material is in the form of films, chap seln or coatings. 12. detergent or cleaning agent portion according to one of claims 1 to 11, additionally containing an enclosure for water vapor and / or for the Component (s) is less permeable than the polymer material. 13. Detergent or detergent portion according to claim 12, wherein the Umfas solution has a water vapor permeability of ≦ 10 g / m ² per day at 23 ° C and 85% relative humidity, preferably a water vapor permeability of <5 g / m ² per day, more preferably no measurable water vapor permeability when measured according to DIN EN 53122. 14. Detergent or detergent portion according to one of claims 12 or 13, wherein the enclosure is resealable. 15. Enclose at least a measured amount of a washing active Preparation of a particular for loading a washing or Ge portion of suitable detergent or cleaning agent in Form of a water-soluble polymer material, one or more Component (s) at least one of the detergent formulations also in the water-soluble polymer material is / are contained. 16. Enclose at least a measured amount of a washing active Preparation of a particular for loading a washing or Ge portion of suitable detergent or cleaning agent in Form of a water-soluble polymer material, one or more Component (s) of the water-soluble polymer material also in at least one of the detergent preparations is included.   17. Enclosing at least a measured amount of a wash-active Preparation of a particular for loading a washing or Ge portion of suitable detergent or cleaning agent in Form of a water-soluble polymer material, one or more Component (s) at least one of the detergent formulations also in the water-soluble polymer material is / are and where a or more component (s) of the water-soluble polymer material also is / are contained in at least one of the wash-active preparations. 18. enclosure according to one of claims 15 or 17, wherein the also in the water-soluble polymer material containing component (s) at least one of the wash-active preparation (s) is selected from the group of substances that - if necessary with the addition of small amounts of water - Liquid or pasty to wax-like at room temperature. 19. The enclosure of claim 18, wherein the component (s) is / are selected from the group consisting of alkoxylated fatty alcohols having 8 to 20 carbon atoms and 3 to 80 alkoxy groups, more preferably ethoxy groups, in the molecule, alkoxylated C ₈ - bis C ₂₀ fatty acid alkyl esters with 1 to 8 carbon atoms in the alkyl radical and 3 to 80, preferably up to 20, alkoxy groups, more preferably ethoxy groups, in the molecule, C ₉ to C ₁₃ alkyl sulfonates, cumene sulfonate, C ₁₂ to C ₁₈ fatty alcohol sulfates and salts of C ₈ to C ₂₀ fatty acids. 20. enclosure according to one of claims 16 or 17, wherein the also in little component (s) of the wash active preparation water-soluble polymer material is / are selected from the group hydro phile plasticizer.   21. The enclosure of claim 20, wherein the component (s) is / are selected from the group of polyols with 1 to 20 carbon atoms and 2 to 6 Hy droxy groups, polyalkylene glycols with 2 to 4 carbon atoms in the alkylene rest, as well as structurally analogous amines with -NH- groups instead of the -O- group pen in the molecule, preferably polyethylene glycols and polypropylene glycols or structurally analogous amines, more preferably polyethylene glycols and polypropy lenglycols with molecular weights in the range from 200 to 12,000 or structurally analogous amines, even more preferably with molecular weights < 1,500 or structurally analogous amines. 22. enclosure according to one of claims 15 to 21, containing the compo nente (n) in a concentration corresponding to the state of equilibrium on, preferably in a concentration of 0.5 to 50% by weight, based on the total weight of the polymer phase, more preferably in a con concentration of 1 to 30 wt .-%, very particularly preferably in a con concentration of 3 to 25 wt .-%. 23. enclosure according to one of claims 15 to 21, containing the compo nente (n) in an above or below the concentration, the equivalent weight condition corresponds to lying concentration, whereby the Equilibrium state corresponding concentration within controlled Set time, preferably a concentration of 0.5 to 50 wt .-%, based on the total weight of the polymer phase, more preferably a con concentration of 1 to 30 wt .-%, very particularly preferably a concentra tion of 3 to 25 wt .-%. 24. The enclosure of any one of claims 15 to 23, wherein the water soluble Polymer material is selected from the group consisting of (given if acetalized) polyvinyl alcohol, polyvinyl pyrrolidone, polyethylene oxide, Gelatin, starch, cellulose and its derivatives and mixtures thereof.   25. The enclosure of any one of claims 15 to 24, wherein the water soluble Polymer material is in the form of foils, capsules or coatings. 26. A process for the production of at least a measured amount of at least one wash-active preparation and at least one the measured amount (s) of at least one wash-active preparation which is suitable in particular for loading a washing machine or dishwasher for a program run taking place in an aqueous phase comprehensive detergent or cleaning portion containing water-soluble polymer material, characterized by the steps that

• - Provides at least a measured amount of at least one wash-active preparation;
• - Provides at least one water-soluble polymer material, we at least one water-soluble polymer material contains one or more components of at least one of the detergent formulations; and or
• - Provides at least one water-soluble polymer material, we at least a measured amount of at least one detergent-active preparation contains one or more component (s) of the water-soluble polymer material; and
• - Contains at least a measured amount of at least one wash-active preparation with the at least one water-soluble polymer material.

27. Washing method, in particular method for machine washing, in which one

• - Placed a detergent portion according to any one of claims 1 to 14 in a washing machine;
• by adding water and adjusting the temperature to a first temperature value at which at least one water-soluble polymer material comprising a measured amount of a wash-active preparation of the detergent portion dissolves, at least one wash-active preparation is released into the wash liquor; and if necessary
• - By adding more water (s) and adjusting the temperature to one or more additional temperature value (s) which is / are above the first temperature value and possibly above other previous temperature values, one or more further washing-active preparations in releases the wash liquor.

28. Cleaning method, in particular method for machine washing dishes, in which one

• - Placed a detergent portion according to any one of claims 1 to 14 in a dishwasher;
• - by adding water and adjusting the temperature to a first temperature value at which at least one detached amount of a detergent preparation comprising the detergent portion of the water-soluble polymer material releases at least one detergent preparation into the cleaning liquor; and if necessary
• - By adding more water (s) and adjusting the temperature to one or more additional temperature value (s) which is / are above the first temperature value and possibly above other previous temperature values, one or more further washing-active preparations in releases the cleaning liquor.