DE198508C - - Google Patents
Info
- Publication number
- DE198508C DE198508C DE1907198508D DE198508DA DE198508C DE 198508 C DE198508 C DE 198508C DE 1907198508 D DE1907198508 D DE 1907198508D DE 198508D A DE198508D A DE 198508DA DE 198508 C DE198508 C DE 198508C
- Authority
- DE
- Germany
- Prior art keywords
- nitroso
- chlorodiethylaniline
- dye
- acid
- gallamic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002253 acid Substances 0.000 claims description 3
- ZOINWKLNGKRQML-UHFFFAOYSA-N 3-chloro-N,N-diethyl-4-nitrosoaniline Chemical compound CCN(CC)C1=CC=C(N=O)C(Cl)=C1 ZOINWKLNGKRQML-UHFFFAOYSA-N 0.000 claims description 2
- YBGOLOJQJWLUQP-UHFFFAOYSA-N Gallocyanin Chemical compound OC(=O)C1=CC(=O)C(O)=C2OC3=CC(N(C)C)=CC=C3N=C21 YBGOLOJQJWLUQP-UHFFFAOYSA-N 0.000 claims 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- OXOBKZZXZVFOBB-UHFFFAOYSA-N 2-Diphenylmethylpyrrolidine Chemical compound C1CCNC1C(C=1C=CC=CC=1)C1=CC=CC=C1 OXOBKZZXZVFOBB-UHFFFAOYSA-N 0.000 description 1
- 241000182341 Cubitermes group Species 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000012458 free base Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 150000002832 nitroso derivatives Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- 229940001607 sodium bisulfite Drugs 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B19/00—Oxazine dyes
- C09B19/005—Gallocyanine dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
PATENTSCHRIFTPATENT LETTERING
-JVr 198508 -KLASSE 22 c. GRUPPE 4. -JVr 198508 - CLASS 22 c. GROUP 4.
Verfahren zur Darstellung eines Gallocyaninfarbstoffs.Process for the preparation of a gallocyanine dye.
Patentiert im Deutschen Reiche vom 22. Mai 1907 ab.Patented in the German Empire on May 22, 1907.
Es wurde gefunden, daß man durch Einwirkung von ρ -Nitroso- m-chlordiäthylanilin auf Gallaminsäure zu einem wertvollen Gallocyaninfarbstoff gelangt, der sich vor dem analogen halogenfreien Produkt, dem Cölestinblau, durch seine wertvollen grüneren klaren Nuancen auszeichnet.It has been found that the action of ρ -nitroso- m-chlorodiethylaniline on gallamic acid to a valuable gallocyanine dye which comes before the analogous halogen-free product, the cölestin blue, characterized by its valuable greener clear nuances.
17 kg Gallaminsäure und 37 kg salzsaures ρ-Nitroso-m-chlordiäthylanilin werden mit 250 1 Alkohol angerührt und die so erhaltene Masse so lange im Wasserbade erhitzt, bis die Nitrosoverbindung verschwunden ist. Der ausgeschiedene Farbstoff wird darauf abfiltriert und mit Wasser gewaschen. Der neue Körper bildet ein dunkles Pulver, das sich in konzentrierter Schwefelsäure mit violetter Farbe auflöst. Er wird zur Verwendung im Druck in bekannter Weise mit Hilfe von Natriumbisulfit in seine lösliche Leukoverbindung übergeführt und liefert so mit essigsaurem Chrom gedruckt grünstichig blaue klare Nuancen.17 kg of gallamic acid and 37 kg of hydrochloric acid ρ-nitroso-m-chlorodiethylaniline are with 250 1 alcohol and the resulting mass is heated in a water bath until the nitroso compound has disappeared. The precipitated dye is then filtered off and washed with water. The new body forms a dark powder that turns into concentrated sulfuric acid with purple color. It is used in the Pressure in a known manner with the help of sodium bisulfite into its soluble leuco compound and thus delivers greenish blue clear nuances printed with acetic acid chrome.
Das p-Nitroso-m-chlordiäthylanilin stellt in Form der freien Base ein dunkelgrünes Pulver dar, das sich in Alkohol mit gelber Farbe auflöst. Es schmilzt bei 76 bis 770. The p-nitroso-m-chlorodiethylaniline is a dark green powder in the form of the free base, which dissolves in alcohol with a yellow color. It melts at 76 to 77 0 .
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT37889D AT37889B (en) | 1907-05-21 | 1908-06-15 | Process for preparing a gallocyanine dye. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE198508C true DE198508C (en) |
Family
ID=461297
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1907198508D Expired - Lifetime DE198508C (en) | 1907-05-21 | 1907-05-21 |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE198508C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1118830A2 (en) | 2000-01-22 | 2001-07-25 | Modine Manufacturing Company | Device for joining two heat exchangers |
-
1907
- 1907-05-21 DE DE1907198508D patent/DE198508C/de not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1118830A2 (en) | 2000-01-22 | 2001-07-25 | Modine Manufacturing Company | Device for joining two heat exchangers |
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