DE19847192A1

DE19847192A1 - Mittel und Verfahren zur Färbung von Fasern

Mittel und Verfahren zur Färbung von Fasern

Info

Publication number: DE19847192A1
Authority: DE; Germany
Prior art keywords: hair; amino; nitro; methyl; phenylamine
Prior art date: 1998-10-13
Legal status : Withdrawn

Application number

DE19847192A

Other languages

German (de)

English (en)

Inventor

Hans-Juergen Braun

Pascal Andre Semadeni

Current Assignee

Procter and Gamble Deutschland GmbH

Original Assignee

Wella GmbH

Priority date

1998-10-13

Filing date

1998-10-13

Publication date

2000-04-27

1998-10-13 Application filed by Wella GmbH filed Critical Wella GmbH

1998-10-13 Priority to DE19847192A priority Critical patent/DE19847192A1/de

1999-09-08 Priority to EP99944624A priority patent/EP1037593B1/de

1999-09-08 Priority to DE59908466T priority patent/DE59908466D1/de

1999-09-08 Priority to PCT/EP1999/006601 priority patent/WO2000021496A1/de

1999-09-08 Priority to AT99944624T priority patent/ATE258782T1/de

1999-09-08 Priority to ES99944624T priority patent/ES2214882T3/es

1999-09-08 Priority to JP2000575472A priority patent/JP2002527369A/ja

1999-09-08 Priority to US09/581,367 priority patent/US6379400B1/en

1999-09-08 Priority to BR9906871-0A priority patent/BR9906871A/pt

2000-04-27 Publication of DE19847192A1 publication Critical patent/DE19847192A1/de

Status Withdrawn legal-status Critical Current

Links

210000004209 hair Anatomy 0.000 title claims abstract description 80
239000000835 fiber Substances 0.000 title claims abstract description 16
239000003086 colorant Substances 0.000 title abstract description 32
239000003795 chemical substances by application Substances 0.000 claims abstract description 16
238000004043 dyeing Methods 0.000 claims abstract description 11
125000000217 alkyl group Chemical group 0.000 claims abstract description 8
125000000753 cycloalkyl group Chemical group 0.000 claims abstract description 4
238000000034 method Methods 0.000 claims abstract description 4
125000003277 amino group Chemical group 0.000 claims abstract description 3
125000000623 heterocyclic group Chemical group 0.000 claims abstract description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 61
239000000118 hair dye Substances 0.000 claims description 48
239000000975 dye Substances 0.000 claims description 34
230000003647 oxidation Effects 0.000 claims description 18
238000007254 oxidation reaction Methods 0.000 claims description 18
239000000126 substance Substances 0.000 claims description 14
150000001875 compounds Chemical class 0.000 claims description 13
238000004040 coloring Methods 0.000 claims description 12
239000000203 mixture Substances 0.000 claims description 11
125000004432 carbon atom Chemical group C* 0.000 claims description 9
239000001005 nitro dye Substances 0.000 claims description 8
MSWZIQWDSQOYCJ-UHFFFAOYSA-N n-(2-methoxyethyl)-4-nitroaniline Chemical compound COCCNC1=CC=C([N+]([O-])=O)C=C1 MSWZIQWDSQOYCJ-UHFFFAOYSA-N 0.000 claims description 7
230000001590 oxidative effect Effects 0.000 claims description 7
239000001257 hydrogen Substances 0.000 claims description 6
229910052739 hydrogen Inorganic materials 0.000 claims description 6
BFAJPHCGGOBRGE-UHFFFAOYSA-N n-(2-methoxyethyl)-2-methyl-4-nitroaniline Chemical compound COCCNC1=CC=C([N+]([O-])=O)C=C1C BFAJPHCGGOBRGE-UHFFFAOYSA-N 0.000 claims description 6
229920000642 polymer Polymers 0.000 claims description 6
PGHLPLFPEDIYDC-UHFFFAOYSA-N 2-methyl-4-nitro-n-(oxolan-2-ylmethyl)aniline Chemical compound CC1=CC([N+]([O-])=O)=CC=C1NCC1OCCC1 PGHLPLFPEDIYDC-UHFFFAOYSA-N 0.000 claims description 5
LQPUAYMERQENBC-UHFFFAOYSA-N 4-(2-methyl-4-nitrophenyl)morpholine Chemical compound CC1=CC([N+]([O-])=O)=CC=C1N1CCOCC1 LQPUAYMERQENBC-UHFFFAOYSA-N 0.000 claims description 5
IAJDSUYFELYZCS-UHFFFAOYSA-N 4-(4-nitrophenyl)morpholine Chemical compound C1=CC([N+](=O)[O-])=CC=C1N1CCOCC1 IAJDSUYFELYZCS-UHFFFAOYSA-N 0.000 claims description 5
NKGAYJQLIXHYQX-UHFFFAOYSA-N n-(3-methoxypropyl)-2-methyl-4-nitroaniline Chemical compound COCCCNC1=CC=C([N+]([O-])=O)C=C1C NKGAYJQLIXHYQX-UHFFFAOYSA-N 0.000 claims description 5
JBTPRUMXWADORW-UHFFFAOYSA-N n-(3-methoxypropyl)-4-nitroaniline Chemical compound COCCCNC1=CC=C([N+]([O-])=O)C=C1 JBTPRUMXWADORW-UHFFFAOYSA-N 0.000 claims description 5
KNVDUESDKVAIJO-UHFFFAOYSA-N n-cyclopropyl-2-methyl-4-nitroaniline Chemical compound CC1=CC([N+]([O-])=O)=CC=C1NC1CC1 KNVDUESDKVAIJO-UHFFFAOYSA-N 0.000 claims description 5
CXYNKJVZMJLYSO-UHFFFAOYSA-N 4-nitro-n-(oxolan-2-ylmethyl)aniline Chemical compound C1=CC([N+](=O)[O-])=CC=C1NCC1OCCC1 CXYNKJVZMJLYSO-UHFFFAOYSA-N 0.000 claims description 4
239000001000 anthraquinone dye Substances 0.000 claims description 4
239000000987 azo dye Substances 0.000 claims description 4
239000000982 direct dye Substances 0.000 claims description 4
VTJZKYAGHWZYQC-UHFFFAOYSA-N n-cyclopropyl-4-nitroaniline Chemical compound C1=CC([N+](=O)[O-])=CC=C1NC1CC1 VTJZKYAGHWZYQC-UHFFFAOYSA-N 0.000 claims description 4
239000002243 precursor Substances 0.000 claims description 4
AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 claims description 4
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
229920005615 natural polymer Polymers 0.000 claims description 3
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 2
229910052757 nitrogen Inorganic materials 0.000 claims description 2
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 2
239000001301 oxygen Chemical group 0.000 claims description 2
229910052760 oxygen Chemical group 0.000 claims description 2
238000010186 staining Methods 0.000 claims 2
229920001059 synthetic polymer Polymers 0.000 claims 1
125000003545 alkoxy group Chemical group 0.000 abstract 1
230000002378 acidificating effect Effects 0.000 description 36
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 35
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-1 phosphoric acid Chemical class 0.000 description 28
239000007864 aqueous solution Substances 0.000 description 27
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 24
239000002253 acid Substances 0.000 description 23
VOQAOTALYZIMDB-UHFFFAOYSA-N 2-[2-[2-(2-hydroxyethoxy)ethoxy]ethoxy]ethyl hydrogen sulfate Chemical compound OCCOCCOCCOCCOS(O)(=O)=O VOQAOTALYZIMDB-UHFFFAOYSA-N 0.000 description 16
LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 16
239000011734 sodium Substances 0.000 description 16
229910052708 sodium Inorganic materials 0.000 description 16
239000004310 lactic acid Substances 0.000 description 15
235000014655 lactic acid Nutrition 0.000 description 15
239000007800 oxidant agent Substances 0.000 description 15
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 14
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 12
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 12
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
235000011114 ammonium hydroxide Nutrition 0.000 description 12
230000015572 biosynthetic process Effects 0.000 description 11
238000005259 measurement Methods 0.000 description 11
238000003786 synthesis reaction Methods 0.000 description 11
239000007795 chemical reaction product Substances 0.000 description 10
235000019441 ethanol Nutrition 0.000 description 10
238000002844 melting Methods 0.000 description 10
230000008018 melting Effects 0.000 description 10
238000010992 reflux Methods 0.000 description 10
GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 10
238000005406 washing Methods 0.000 description 10
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 9
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 9
BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 8
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229910021529 ammonia Inorganic materials 0.000 description 7
239000006071 cream Substances 0.000 description 7
235000013305 food Nutrition 0.000 description 7
239000004615 ingredient Substances 0.000 description 7
150000003839 salts Chemical class 0.000 description 7
239000007787 solid Substances 0.000 description 7
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CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Natural products OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 6
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 6
235000010323 ascorbic acid Nutrition 0.000 description 6
239000011668 ascorbic acid Substances 0.000 description 6
229960005070 ascorbic acid Drugs 0.000 description 6
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
TYQCGQRIZGCHNB-JLAZNSOCSA-N l-ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(O)=C(O)C1=O TYQCGQRIZGCHNB-JLAZNSOCSA-N 0.000 description 6
238000001953 recrystallisation Methods 0.000 description 6
GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 6
210000004243 sweat Anatomy 0.000 description 6
XUCYJGMIICONES-UHFFFAOYSA-N 1-fluoro-2-methyl-4-nitrobenzene Chemical compound CC1=CC([N+]([O-])=O)=CC=C1F XUCYJGMIICONES-UHFFFAOYSA-N 0.000 description 5
WFQDTOYDVUWQMS-UHFFFAOYSA-N 1-fluoro-4-nitrobenzene Chemical compound [O-][N+](=O)C1=CC=C(F)C=C1 WFQDTOYDVUWQMS-UHFFFAOYSA-N 0.000 description 5
CWLKGDAVCFYWJK-UHFFFAOYSA-N 3-aminophenol Chemical compound NC1=CC=CC(O)=C1 CWLKGDAVCFYWJK-UHFFFAOYSA-N 0.000 description 5
229940018563 3-aminophenol Drugs 0.000 description 5
238000002156 mixing Methods 0.000 description 5
235000010265 sodium sulphite Nutrition 0.000 description 5
239000000243 solution Substances 0.000 description 5
KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 4
WCPGNFONICRLCL-UHFFFAOYSA-N 2-(2,4-diaminophenoxy)ethanol Chemical compound NC1=CC=C(OCCO)C(N)=C1 WCPGNFONICRLCL-UHFFFAOYSA-N 0.000 description 4
SBUMIGFDXJIPLE-UHFFFAOYSA-N 2-(3-amino-4-methoxyanilino)ethanol Chemical compound COC1=CC=C(NCCO)C=C1N SBUMIGFDXJIPLE-UHFFFAOYSA-N 0.000 description 4
OBCSAIDCZQSFQH-UHFFFAOYSA-N 2-methyl-1,4-phenylenediamine Chemical compound CC1=CC(N)=CC=C1N OBCSAIDCZQSFQH-UHFFFAOYSA-N 0.000 description 4
DBFYESDCPWWCHN-UHFFFAOYSA-N 5-amino-2-methylphenol Chemical compound CC1=CC=C(N)C=C1O DBFYESDCPWWCHN-UHFFFAOYSA-N 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 4
229920000742 Cotton Polymers 0.000 description 4
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
UXEAWNJALIUYRH-UHFFFAOYSA-N [8-[(4-aminophenyl)hydrazinylidene]-7-oxonaphthalen-2-yl]-trimethylazanium;chloride Chemical compound [Cl-].C12=CC([N+](C)(C)C)=CC=C2C=CC(=O)\C1=N/NC1=CC=C(N)C=C1 UXEAWNJALIUYRH-UHFFFAOYSA-N 0.000 description 4
229960000541 cetyl alcohol Drugs 0.000 description 4
FPVGTPBMTFTMRT-UHFFFAOYSA-L disodium;2-amino-5-[(4-sulfonatophenyl)diazenyl]benzenesulfonate Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C(N)=CC=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 FPVGTPBMTFTMRT-UHFFFAOYSA-L 0.000 description 4
235000019233 fast yellow AB Nutrition 0.000 description 4
KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 4
230000037308 hair color Effects 0.000 description 4
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239000002904 solvent Substances 0.000 description 4
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ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
ASAQRGCLIPUSEK-UHFFFAOYSA-N 2-[4-amino-n-(2-hydroxyethyl)-3-nitroanilino]ethanol;hydrochloride Chemical compound Cl.NC1=CC=C(N(CCO)CCO)C=C1[N+]([O-])=O ASAQRGCLIPUSEK-UHFFFAOYSA-N 0.000 description 3
ASUDFOJKTJLAIK-UHFFFAOYSA-N 2-methoxyethanamine Chemical compound COCCN ASUDFOJKTJLAIK-UHFFFAOYSA-N 0.000 description 3
YFKNIPGAJBJZQT-UHFFFAOYSA-N 3-(4-amino-2-chloro-5-nitroanilino)propane-1,2-diol Chemical compound NC1=CC(Cl)=C(NCC(O)CO)C=C1[N+]([O-])=O YFKNIPGAJBJZQT-UHFFFAOYSA-N 0.000 description 3
QGNGOGOOPUYKMC-UHFFFAOYSA-N 4-hydroxy-6-methylaniline Chemical compound CC1=CC(O)=CC=C1N QGNGOGOOPUYKMC-UHFFFAOYSA-N 0.000 description 3
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
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235000005979 Citrus limon Nutrition 0.000 description 3
244000131522 Citrus pyriformis Species 0.000 description 3
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
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239000000654 additive Substances 0.000 description 3
239000004202 carbamide Substances 0.000 description 3
ONTQJDKFANPPKK-UHFFFAOYSA-L chembl3185981 Chemical compound [Na+].[Na+].CC1=CC(C)=C(S([O-])(=O)=O)C=C1N=NC1=CC(S([O-])(=O)=O)=C(C=CC=C2)C2=C1O ONTQJDKFANPPKK-UHFFFAOYSA-L 0.000 description 3
239000002537 cosmetic Substances 0.000 description 3
UKJLNMAFNRKWGR-UHFFFAOYSA-N cyclohexatrienamine Chemical group NC1=CC=C=C[CH]1 UKJLNMAFNRKWGR-UHFFFAOYSA-N 0.000 description 3
235000014113 dietary fatty acids Nutrition 0.000 description 3
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
TUXJTJITXCHUEL-UHFFFAOYSA-N disperse red 11 Chemical compound C1=CC=C2C(=O)C3=C(N)C(OC)=CC(N)=C3C(=O)C2=C1 TUXJTJITXCHUEL-UHFFFAOYSA-N 0.000 description 3
150000002148 esters Chemical class 0.000 description 3
239000000194 fatty acid Substances 0.000 description 3
229930195729 fatty acid Natural products 0.000 description 3
150000002191 fatty alcohols Chemical class 0.000 description 3
239000000499 gel Substances 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 3
AXMCIYLNKNGNOT-UHFFFAOYSA-N sodium;3-[[4-[(4-dimethylazaniumylidenecyclohexa-2,5-dien-1-ylidene)-[4-[ethyl-[(3-sulfophenyl)methyl]amino]phenyl]methyl]-n-ethylanilino]methyl]benzenesulfonate Chemical compound [Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](C)C)C=2C=CC(=CC=2)N(CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S(O)(=O)=O)=C1 AXMCIYLNKNGNOT-UHFFFAOYSA-N 0.000 description 3
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JUUXYSDWEGIGHM-UHFFFAOYSA-N (4-nitrophenyl)diazene Chemical group [O-][N+](=O)C1=CC=C(N=N)C=C1 JUUXYSDWEGIGHM-UHFFFAOYSA-N 0.000 description 2
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KWSVXCAQFTWTEF-UHFFFAOYSA-N 2-(2,5-diaminophenyl)ethanol Chemical compound NC1=CC=C(N)C(CCO)=C1 KWSVXCAQFTWTEF-UHFFFAOYSA-N 0.000 description 2
VBSLNFWECRRALP-UHFFFAOYSA-N 2-(2,5-diaminophenyl)ethanol;sulfuric acid Chemical compound [O-]S([O-])(=O)=O.[NH3+]C1=CC=C([NH3+])C(CCO)=C1 VBSLNFWECRRALP-UHFFFAOYSA-N 0.000 description 2
OWMQBFHMJVSJSA-UHFFFAOYSA-N 2-(2-amino-4-nitroanilino)ethanol Chemical compound NC1=CC([N+]([O-])=O)=CC=C1NCCO OWMQBFHMJVSJSA-UHFFFAOYSA-N 0.000 description 2
YUNHBAIHRNIODP-UHFFFAOYSA-N 2-(2-hydroxyethylamino)-5-nitrophenol Chemical compound OCCNC1=CC=C([N+]([O-])=O)C=C1O YUNHBAIHRNIODP-UHFFFAOYSA-N 0.000 description 2
LFOUYKNCQNVIGI-UHFFFAOYSA-N 2-(2-nitroanilino)ethanol Chemical compound OCCNC1=CC=CC=C1[N+]([O-])=O LFOUYKNCQNVIGI-UHFFFAOYSA-N 0.000 description 2
KDBUTNSQYYLYOY-UHFFFAOYSA-N 2-(4,5-diaminopyrazol-1-yl)ethanol Chemical compound NC=1C=NN(CCO)C=1N KDBUTNSQYYLYOY-UHFFFAOYSA-N 0.000 description 2
LGZSBRSLVPLNTM-UHFFFAOYSA-N 2-(4-amino-2-methyl-5-nitroanilino)ethanol Chemical compound CC1=CC(N)=C([N+]([O-])=O)C=C1NCCO LGZSBRSLVPLNTM-UHFFFAOYSA-N 0.000 description 2
LGGKGPQFSCBUOR-UHFFFAOYSA-N 2-(4-chloro-2-nitroanilino)ethanol Chemical compound OCCNC1=CC=C(Cl)C=C1[N+]([O-])=O LGGKGPQFSCBUOR-UHFFFAOYSA-N 0.000 description 2
HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
PBBRFJWECSDSDZ-UHFFFAOYSA-N 2-[2,4-diamino-5-(2-hydroxyethoxy)phenoxy]ethanol Chemical compound NC1=CC(N)=C(OCCO)C=C1OCCO PBBRFJWECSDSDZ-UHFFFAOYSA-N 0.000 description 2
NJZCRXQWPNNJNB-UHFFFAOYSA-N 2-[2-nitro-4-(trifluoromethyl)anilino]ethanol Chemical compound OCCNC1=CC=C(C(F)(F)F)C=C1[N+]([O-])=O NJZCRXQWPNNJNB-UHFFFAOYSA-N 0.000 description 2
WXGKXLXGYOYZMX-UHFFFAOYSA-N 2-[4-(2-aminoethylamino)-3-nitrophenoxy]ethanol Chemical compound NCCNC1=CC=C(OCCO)C=C1[N+]([O-])=O WXGKXLXGYOYZMX-UHFFFAOYSA-N 0.000 description 2
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GTKIEPUIFBBXJQ-UHFFFAOYSA-M sodium;2-[(4-hydroxy-9,10-dioxoanthracen-1-yl)amino]-5-methylbenzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1NC1=CC=C(O)C2=C1C(=O)C1=CC=CC=C1C2=O GTKIEPUIFBBXJQ-UHFFFAOYSA-M 0.000 description 1
239000011877 solvent mixture Substances 0.000 description 1
239000012192 staining solution Substances 0.000 description 1
235000019698 starch Nutrition 0.000 description 1
239000008107 starch Substances 0.000 description 1
238000003860 storage Methods 0.000 description 1
238000005728 strengthening Methods 0.000 description 1
150000003871 sulfonates Chemical class 0.000 description 1
150000003457 sulfones Chemical class 0.000 description 1
239000012209 synthetic fiber Substances 0.000 description 1
229920002994 synthetic fiber Polymers 0.000 description 1
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
YODZTKMDCQEPHD-UHFFFAOYSA-N thiodiglycol Chemical compound OCCSCCO YODZTKMDCQEPHD-UHFFFAOYSA-N 0.000 description 1
229950006389 thiodiglycol Drugs 0.000 description 1
230000002110 toxicologic effect Effects 0.000 description 1
231100000027 toxicology Toxicity 0.000 description 1
ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
JLGLQAWTXXGVEM-UHFFFAOYSA-N triethylene glycol monomethyl ether Chemical compound COCCOCCOCCO JLGLQAWTXXGVEM-UHFFFAOYSA-N 0.000 description 1
BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
SWGJCIMEBVHMTA-UHFFFAOYSA-K trisodium;6-oxido-4-sulfo-5-[(4-sulfonatonaphthalen-1-yl)diazenyl]naphthalene-2-sulfonate Chemical compound [Na+].[Na+].[Na+].C1=CC=C2C(N=NC3=C4C(=CC(=CC4=CC=C3O)S([O-])(=O)=O)S([O-])(=O)=O)=CC=C(S([O-])(=O)=O)C2=C1 SWGJCIMEBVHMTA-UHFFFAOYSA-K 0.000 description 1
239000011782 vitamin Substances 0.000 description 1
229940088594 vitamin Drugs 0.000 description 1
229930003231 vitamin Natural products 0.000 description 1
235000013343 vitamin Nutrition 0.000 description 1
235000010493 xanthan gum Nutrition 0.000 description 1
239000000230 xanthan gum Substances 0.000 description 1
229920001285 xanthan gum Polymers 0.000 description 1
229940082509 xanthan gum Drugs 0.000 description 1
OIHZGFWAMWHYPA-UHFFFAOYSA-N xanthylium Chemical compound C1=CC=CC2=CC3=CC=CC=C3[O+]=C21 OIHZGFWAMWHYPA-UHFFFAOYSA-N 0.000 description 1
229910052724 xenon Inorganic materials 0.000 description 1
FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
239000002888 zwitterionic surfactant Substances 0.000 description 1
239000004711 α-olefin Substances 0.000 description 1