DE168080C - - Google Patents
Info
- Publication number
- DE168080C DE168080C DENDAT168080D DE168080DA DE168080C DE 168080 C DE168080 C DE 168080C DE NDAT168080 D DENDAT168080 D DE NDAT168080D DE 168080D A DE168080D A DE 168080DA DE 168080 C DE168080 C DE 168080C
- Authority
- DE
- Germany
- Prior art keywords
- fiber
- amido
- oxydiphenylamine
- ecm
- derivatives
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000835 fiber Substances 0.000 claims description 7
- 239000000975 dye Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 4
- JTTMYKSFKOOQLP-UHFFFAOYSA-N 4-Hydroxydiphenylamine Chemical compound C1=CC(O)=CC=C1NC1=CC=CC=C1 JTTMYKSFKOOQLP-UHFFFAOYSA-N 0.000 claims description 3
- 125000003368 amide group Chemical group 0.000 claims description 2
- 239000001045 blue dye Substances 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N Diphenylamine Chemical class C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 238000004043 dyeing Methods 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 230000004048 modification Effects 0.000 claims 1
- 238000006011 modification reaction Methods 0.000 claims 1
- 239000007800 oxidant agent Substances 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000006467 substitution reaction Methods 0.000 claims 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000000344 soap Substances 0.000 description 3
- VSCWAEJMTAWNJL-UHFFFAOYSA-K Aluminium chloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- KMUONIBRACKNSN-UHFFFAOYSA-N Potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating Effects 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- VYLVYHXQOHJDJL-UHFFFAOYSA-K Cerium(III) chloride Chemical compound Cl[Ce](Cl)Cl VYLVYHXQOHJDJL-UHFFFAOYSA-K 0.000 description 1
- 229940069002 Potassium Dichromate Drugs 0.000 description 1
- YZHUMGUJCQRKBT-UHFFFAOYSA-M Sodium chlorate Chemical compound [Na+].[O-]Cl(=O)=O YZHUMGUJCQRKBT-UHFFFAOYSA-M 0.000 description 1
- VXMKYRQZQXVKGB-CWWHNZPOSA-N Tannin Chemical compound O([C@H]1[C@H]([C@@H]2OC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)O[C@H]([C@H]2O)O1)O)C(=O)C1=CC(O)=C(O)C(O)=C1 VXMKYRQZQXVKGB-CWWHNZPOSA-N 0.000 description 1
- 240000000358 Viola adunca Species 0.000 description 1
- 235000005811 Viola adunca Nutrition 0.000 description 1
- 235000013487 Viola odorata Nutrition 0.000 description 1
- 235000002254 Viola papilionacea Nutrition 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 description 1
- 229940080281 sodium chlorate Drugs 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 235000018553 tannin Nutrition 0.000 description 1
- 229920001864 tannin Polymers 0.000 description 1
- 239000001648 tannin Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/32—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using oxidation dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/008—Preparing dyes in situ
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Description
öt-VUj ctla'l
öt-VUj
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
Die Patente 166308 und 167348 betreffen ein Verfahren zur Darstellung von blauen Farbstoffen auf der Faser, dadurch gekennzeichnet, daß man p-Amidodiphenylamin bezw.Patents 166308 and 167348 relate to a method for the representation of blue dyes on the fiber, characterized in that, that you respectively p-amidodiphenylamine.
verschiedene seiner Amido- und Oxyderivate mit alkylierten Diamidobenzhydrolen entweder auf der Faser oder außerhalb derselben kondensiert und dann innerhalb der Faser oxydiert. various of its amido and oxy derivatives with either alkylated diamidobenzhydrols condensed on or outside the fiber and then oxidized inside the fiber.
Bei weiterer Ausarbeitung dieser Verfahren wurde gefunden, daß man anstatt p-Amidodiphenylamin auch p-Oxydiphenylamin verwenden kann, wodurch man zu sehr lebhaften blauvioletten Farbstoffen gelangt, die auch ohne Tanninbeize sehr gut wasch- und seifecht sind. Namentlich der Farbstoff aus Tetraäthyldiamidobenzhydrol mit ρ - Oxydiphenylamin zeichnet sich durch vorzügliche Seif- und Sodaechtheit aus.On further elaboration of this process it was found that instead of p-amidodiphenylamine p-Oxydiphenylamine can also be used, which makes one very lively blue-violet dyes, which are very washable and soapy-proof even without tannin stain are. Namely the dye from tetraethyldiamidobenzhydrol with ρ - oxydiphenylamine is characterized by excellent soap and soda fastness.
Die Nuancen der mit ρ - Oxydiphenylamin gewonnenen Farbstoffe sind wesentlich reiner und lebhafter als die mit p-Amidodiphenylamin hergestellten und können daher sehr gut zum Nuancieren der nach ersterem Verfahren erhältlichen Marineblaunuancen dienen. Die Farbstoffe lassen sich sowohl durch Kondensation innerhalb wie außerhalb der Faser und durch Nachoxydieren erhalten.The nuances of the dyes obtained with ρ - oxydiphenylamine are much purer and livelier than those made with p-amidodiphenylamine and can therefore be very serve well to nuance the shades of navy blue obtainable by the former process. The dyes can be removed both by condensation inside and outside the Fiber and obtained by post-oxidation.
Beispiel I. 20 g Tetraäthyldiamidobenzhydrol (90 pro-Example I. 20 g of tetraethyldiamidobenzhydrol (90 pro
zentig) werden mit
10 g ρ-Oxydiphenylamin, IOO ecm Essigsäure (50 prozentig),
30 ecm Milchsäure (50 prozentig) am Wasserbad gelöst, incent) will be with
10 g ρ-oxydiphenylamine, 100 ecm acetic acid (50 percent), 30 ecm lactic acid (50 percent) dissolved in a water bath, in
600 g saure Stärke\^erdickung eingerührtStir in 600 g of acidic starch thickening
und zugefügt:
10 g Natriumchlorat,
20 ecm Wasser,and added:
10 g sodium chlorate,
20 ecm of water,
10 ecm Aluminiumchlorid 300 Be.,10 ecm aluminum chloride 30 0 Be.,
5 ecm Cerchlorid (20 prozentig), 195 ecm Wasser.5 ecm cerium chloride (20 percent), 195 ecm water.
ι kg.ι kg.
Drucken, trocknen, 3 Minuten Mather-Platt dämpfen, waschen und seifen.Print, dry, 3 minutes Mather-Platt steam, wash and soap.
25 g Leukobase aus Tetramethyldiamidobenzhydrol mit p-Oxydiphenylamin werden in25 g leuco base made from tetramethyldiamidobenzhydrol with p-oxydiphenylamine in
100 ecm Essigsäure 8° Be. gelöst, in 600 g saure Stärkeverdickung eingerührt100 ecm acetic acid 8 ° Be. dissolved, stirred into 600 g of acidic starch thickener
und mit
275 ecm Wasser aufand with
275 ecm of water
ι kg eingestellt.ι kg set.
Früheres Zusatzpatent: 167348.Former additional patent: 167348.
Drucken, trocknen, durch ein Bad von g Kaliumbichromat und 3 g Schwefelsäure i. L. bei etwa 6o° C. passieren, waschen und seifen.Print, dry, through a bath of g of potassium dichromate and 3 g of sulfuric acid i. L. at about 60 ° C., wash and soap.
Claims (2)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE168080C true DE168080C (en) |
Family
ID=433337
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT168080D Active DE168080C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE168080C (en) |
-
0
- DE DENDAT168080D patent/DE168080C/de active Active
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