DE12787C - Innovations in the CULLMANN-LORENZ process for converting ordinary agate into onyx, consisting in the production of decorations on bleached agate. ' (Improvement patent on P. R. 6740.) - Google Patents
Innovations in the CULLMANN-LORENZ process for converting ordinary agate into onyx, consisting in the production of decorations on bleached agate. ' (Improvement patent on P. R. 6740.)Info
- Publication number
- DE12787C DE12787C DENDAT12787D DE12787DA DE12787C DE 12787 C DE12787 C DE 12787C DE NDAT12787 D DENDAT12787 D DE NDAT12787D DE 12787D A DE12787D A DE 12787DA DE 12787 C DE12787 C DE 12787C
- Authority
- DE
- Germany
- Prior art keywords
- agate
- decorations
- bleached
- cullmann
- onyx
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 238000000034 method Methods 0.000 title claims description 4
- 241001644482 Onyx Species 0.000 title description 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 24
- 235000011118 potassium hydroxide Nutrition 0.000 claims description 7
- GRYLNZFGIOXLOG-UHFFFAOYSA-N nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229940072033 potash Drugs 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 235000015320 potassium carbonate Nutrition 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 229910001948 sodium oxide Inorganic materials 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5025—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with ceramic materials
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Adornments (AREA)
Description
1879.1879.
Klasse 80.Class 80.
AUGUST DREHER in OBERTIEFENBACHAUGUST DREHER in OBERTIEFENBACH
(FüRSTENTHUM BlRKENFELD, GrOSSHERZOGTHUM OLDENBURG).(FÜRSTENTHUM BlRKENFELD, GREAT DUCHY OF OLDENBURG).
Neuerungen an dem Cullmann-Lorenz'schen Verfahren zur Umwandlung von gewöhnlichem Achat in Onyx, bestehend in der Herstellung von Verzierungen auf gebleichtem Achat.Innovations in the Cullmann-Lorenz process for converting the ordinary Agate in onyx, consisting in the manufacture of decorations on bleached agate.
Verbesserungs-Patent zu No. 6740 vom 10. November 1878. Patentirt im Deutschen Reiche vom 13. Juli 1879 ab.Improvement Patent to No. 6740 of November 10, 1878. Patented in the German Empire on July 13, 1879.
Diese Erfindung bezieht sich auf ein Verfahren, um Achatsteine mit farbigen Verzierungen auf chemischem Wege zu versehen.This invention relates to a method of making agate stones with colored decorations to be provided by chemical means.
Die aus Südbrasilien eingeführten Achatsteine werden entweder in Platten geschnitten oder in rohem Zustande verarbeitet.The agate stones imported from southern Brazil are either cut into slabs or processed in the raw state.
Die Steine werden zuerst in eine Lösung von ca. 200 g Aetzkali in 1 1 Wasser gelegt, bis dieselben vollständig durchdrungen sind.The stones are first placed in a solution of approx. 200 g of caustic potash in 1 liter of water until they are completely penetrated.
Die Steine werden sodann in ein Salpetersäure-Bad gelegt und bleiben so lange liegen, bis das Kali vollständig verdrängt ist.The stones are then placed in a nitric acid bath and remain there as long as until the potash is completely displaced.
Die Steine werden aus dem Bade entfernt und bei gelinder Ofenwärme getrocknet.The stones are removed from the bath and dried on the gentle heat of the oven.
Nach dem Trocknen werden sie in einem Brenntiegel gebrannt, wonach sie eine schöne weifse Farbe besitzen. 'After drying, they are burned in a baking crucible, after which they are beautiful are white in color. '
Anstatt des Aetzkalis kann man Natriumoxyd bezw. Aetznatron anwenden. Auch kann man die Salpetersäure zuerst anwenden.Instead of caustic potash, sodium oxide can be used. Use caustic soda. You can too apply the nitric acid first.
Die Steine werden nun mittelst Schablone oder durch die Hand mit beliebigen Verzierungen in Graphit oder gewöhnlichem Bleistift versehen, und zwar so, dafs die mit Graphit oder Bleistift bezeichneten Stellen die Abgrenzungslinien der Verzierungen bilden. Auch können die Abgrenzungslinien statt mit Graphit oder Bleistift mit einem beliebigen Metallstäbchen hergestellt werden.The stones are now decorated using a template or by hand in graphite or an ordinary pencil, in such a way that the ones with graphite or The areas marked in pencil form the delimitation lines of the decorations. Also can the demarcation lines with any metal stick instead of graphite or pencil getting produced.
Auf die freigebliebenen Stellen oder zwischen die Abgrenzungslinien wird Aetzkali mit einem Holzstäbchen bezw. einem Pinsel oder anderem passenden Gegenstande aufgetragen.Aetzkali is applied to the areas that have remained free or between the demarcation lines with a Wooden sticks resp. applied with a brush or other suitable object.
Bei groben Verzierungen, sowie bei ganz feinen Strichen kann man das Aetzkali auch ohne Abgrenzungslinien auftragen, es erfordert jedoch viel mehr Zeit und Aufmerksamkeit.The caustic potash can also be used for coarse decorations and very fine lines Apply without demarcation lines, but it requires a lot more time and attention.
Je nach der Stärke der zu bildenden weifsen Schicht bleiben" die vorerwähnten weifsen Stellen mit Aetzkali mehr oder weniger lange benetzt.Depending on the thickness of the white layer to be formed, the above-mentioned white areas remain wetted with caustic potash for a longer or shorter period.
Anstatt des Aetzkalis kann man auch Natriumoxyd bezw. Aetznatron anwenden.Instead of caustic potash you can also use sodium oxide respectively. Use caustic soda.
Nachdem die Flüssigkeit genügend tief in die Steine eingedrungen ist, werden dieselben getrocknet. After the liquid has penetrated deep enough into the stones, they are dried.
Die so behandelten Steine werden sodann in ein salpetersaures Bad gelegt, wo sie je nach der Stärke der Steine liegen bleiben.The stones treated in this way are then placed in a nitric acid bath, where they are depending on the strength of the stones remain.
Die Steine werden sodann vollständig getrocknet und nochmals gebrannt.The stones are then completely dried and fired again.
Die um die Verzierungen herumliegenden Theile können beliebig mit Farbstoff versehen werden, die mit Kali behandelten Theile, d. h. die Verzierungen, nehmen jedoch gar keine Farbe an.The parts surrounding the decorations can be provided with any dye the parts treated with potash, d. H. the decorations, but don't take any Color on.
Die vorher beschriebene Methode bezieht sich auf die Herstellung der Verzierungen in weifser Farbe.The method described earlier relates to the production of the decorations in white Colour.
Will man aber eine ro the Farbe erzeugen, so wendet man statt des Aetzkalis in Salpetersäure aufgelöstes Eisen an; auch kann man sämmtliche Anilinfarben anwenden und die schönsten Farbennuancen erzeugen.But if you want to create a red color, so instead of caustic potash, iron dissolved in nitric acid is used; also one can Use all aniline colors and create the most beautiful color nuances.
Es ist jedoch unbedingt nothwendig, dafs die Steine nach dem Auftragen der Farbe bezw. der Aetzmittel getrocknet und gebrannt werden, weil die Farben sonst an Kraft verlieren würden.It is, however, absolutely necessary that the stones be removed after the paint has been applied. the caustic must be dried and fired, otherwise the colors would lose their strength.
Die unter Behandlung sich befindenden Steine bezw. Platten müssen selbstverständlich in horizontaler Lage gehalten werden, um zu sichern, dafs die angewendeten Flüssigkeiten stehen bleiben.The stones under treatment respectively. Plates must of course be in a horizontal position Be kept in position to ensure that the fluids used remain in place.
Durch dies Verfahren können die billigeren Sorten Steine mit Verzierungen versehen werden, anstatt dafs die Verzierungen eingravirt werden.This process allows the cheaper types of stones to be decorated with instead of engraving the decorations.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE12787C true DE12787C (en) |
Family
ID=289980
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT12787D Active DE12787C (en) | Innovations in the CULLMANN-LORENZ process for converting ordinary agate into onyx, consisting in the production of decorations on bleached agate. ' (Improvement patent on P. R. 6740.) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE12787C (en) |
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- DE DENDAT12787D patent/DE12787C/en active Active
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