DE124973C - - Google Patents
Info
- Publication number
- DE124973C DE124973C DENDAT124973D DE124973DA DE124973C DE 124973 C DE124973 C DE 124973C DE NDAT124973 D DENDAT124973 D DE NDAT124973D DE 124973D A DE124973D A DE 124973DA DE 124973 C DE124973 C DE 124973C
- Authority
- DE
- Germany
- Prior art keywords
- paper
- zinc
- benzene
- fatty
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 12
- 239000004744 fabric Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 5
- 238000004078 waterproofing Methods 0.000 claims description 4
- 150000003751 zinc Chemical class 0.000 claims description 3
- 230000002378 acidificating Effects 0.000 claims 1
- 238000000034 method Methods 0.000 description 5
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- KREXGRSOTUKPLX-UHFFFAOYSA-N octadecanoic acid;zinc Chemical compound [Zn].CCCCCCCCCCCCCCCCCC(O)=O.CCCCCCCCCCCCCCCCCC(O)=O KREXGRSOTUKPLX-UHFFFAOYSA-N 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- LPEBYPDZMWMCLZ-CVBJKYQLSA-L zinc;(Z)-octadec-9-enoate Chemical compound [Zn+2].CCCCCCCC\C=C/CCCCCCCC([O-])=O.CCCCCCCC\C=C/CCCCCCCC([O-])=O LPEBYPDZMWMCLZ-CVBJKYQLSA-L 0.000 description 2
- MXODCLTZTIFYDV-UHFFFAOYSA-L zinc;1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylate Chemical compound [Zn+2].C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C([O-])=O.C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C([O-])=O MXODCLTZTIFYDV-UHFFFAOYSA-L 0.000 description 2
- 241000554155 Andes Species 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- -1 fatty acid salts Chemical class 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 210000001519 tissues Anatomy 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Paper (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
PATENTAMT.PATENT OFFICE.
Ja 124973 KLASSE 8«. Yes 124973 CLASS 8 «.
Es ist bekannt, eine Lösung von öl- oder fettsaurem Aluminium in Benzol, eventuell unter Zusatz von Fetten, Harzen oder Wachs zum Wasserdichtmachen von Geweben anzuwenden. Ferner ist schon die Anwendung von Fett- und Harzseifen des Zinks, bezw. von Mischungen, in welchen sich diese bilden, zum Wasserdichtmachen bekannt (s. Andes, Feuersicher-, Geruchlos- und Wasserdichtmachen, 1896, S. 200, 207 und 212).It is known to use a solution of oleic or fatty aluminum in benzene, possibly under Use the addition of fats, resins or wax to waterproof fabrics. Furthermore, the use of fat and resin soaps of zinc, respectively. of mixtures, in which these form, known for making waterproofing (see Andes, Feuersicher-, Odorless and Waterproofing, 1896, pp. 200, 207 and 212).
Alle diese Verfahren zeigen jedoch den Uebelstand, dafs die imprägnirten Stoffe einerseits klebrig werden, andererseits infolge der ausgeschiedenen Seife weifse Flecke erhalten, so dafs sie für gefärbte Stoffe oder Papiersorten nicht verwendbar sind.All these processes, however, show the disadvantage that the impregnated substances on the one hand become sticky, on the other hand white stains are obtained as a result of the excreted soap, so that they cannot be used for dyed fabrics or types of paper.
Durch das vorliegende Verfahren werden diese Uebelstände vermieden, da, wie Versuche gezeigt haben, Mischungen von fett- und harzsauren Zinksalzen, wenn sie entgegen den bekannten Verfahren in Lösung bezw. Mischung mit Benzol zur Benutzung gelangen, ein besseres technisches Resultat als alle bisher bekannten Verfahren ergeben; insbesondere erhält man dadurch einen Ueberzug, welcher durchsichtig bezw. durchscheinend, und vollkommen wasserdicht ist.These inconveniences are avoided by the present method, since, like experiments have shown mixtures of fatty and resinous zinc salts when opposed BEZW the known methods in solution. Mixture with benzene to be used, give a better technical result than any previously known method; in particular receives one thereby a coating, which respectively transparent. translucent, and perfect is waterproof.
Das Verfahren wird in folgender Weise ausgeführt. The procedure is carried out in the following manner.
Das Zinksalz irgend einer Fett- und Harzsäure wird in pulverisirter Form mit einem flüchtigen Lösungsmittel, wie Benzol oder Benzin, behandelt, bis die Masse plastisch geworden ist.The zinc salt of any fatty or resin acid is in powdered form with a volatile solvents, such as benzene or gasoline, are treated until the mass has become plastic is.
Es ist zweckmäfsig, zwei oder mehrere fettsaure Salze mit einem harzsauren Salze zu mischen. Für diesen Zweck empfiehlt sich Zinkoleat, Zinkstearat und Zinkresinat.It is advisable to combine two or more fatty acid salts with one resinous acid salt Mix. Zinc oleate, zinc stearate and zinc resinate are recommended for this purpose.
Folgende, hier lediglich als Beispiele angegebenen Verhältnisse haben sich als anwendbar erwiesen:The following ratios, given here only as examples, have proven to be applicable proven:
6 Theile Zinkoleat, 4 „ Zinkstearat, ! Theil Zinkresinat, 100 Theile Benzol.6 parts zinc oleate, 4 “zinc stearate,! Part of zinc resinate, 100 parts benzene.
Die Materialien werden in einer Knetmaschine oder dergleichen gut gemischt, bis eine gleich-, mäfsige zähe Flüssigkeit oder Masse erhalten ist. Dieses Mischen kann kalt oder bei gewöhnlicher Temperatur geschehen, es empfiehlt sich aber, zur Beschleunigung der Arbeit eine Temperatur von 30 bis 500 C. anzuwenden.The materials are mixed well in a kneading machine or the like until an even, moderate, viscous liquid or mass is obtained. This mixing can be done cold or at normal temperature, but it is advisable to use a temperature of 30 to 50 ° C. to accelerate the work.
Um nun das Gewebe, Papier oder dergleichen wasserdicht zu machen, kann die zähe Masse mit einer geeigneten Vorrichtung darauf ausgebreitet werden, man kann dieselbe aber auch durch Zusatz einer gröfseren Menge des Lösungsmittels in Lösung bringen und das betreffende Gewebe oder Papier, besonders Packpapier und Tapeten, mit der erhaltenen Lösung in irgend einer geeigneten Weise behandeln, worauf durch Hitze getrocknet wird.In order to make the fabric, paper or the like waterproof, the viscous mass can be spread on it with a suitable device, but you can also use the same by adding a larger amount of the solvent to bring into solution and the relevant Tissue or paper, especially wrapping paper and wallpaper, with the solution obtained in treat in any suitable manner, followed by heat drying.
Die Vortheile, welche durch das vorliegende Verfahren im Gegensatz zu den bekannten Verfahren erzielt werden, sind folgende:The advantages provided by the present process in contrast to the known processes are the following:
1. vollkommenes Wasserdichtmachen,1. perfect waterproofing,
2. das Imprägnirungsmittel ist auf weifsen oder gefärbten Stoffen oder Papier unsichtbar,2. the impregnation agent is invisible on white or colored fabrics or paper,
3. dasselbe macht das Papier nicht durchscheinender, als es vor der Behandlung war,3. the same does not make the paper more translucent, than it was before the treatment,
4. das Papier oder dergleichen wird während des Verfahrens nicht nafs und daher nicht weich,4. the paper or the like does not become wet and therefore not soft during the process,
5. das Gewebe kann nur wasserdicht, aber nicht luftdicht imprägnirt werden,5. the fabric can only be waterproofed, but not airtight,
6. das Gewebe, Papier oder dergleichen kann mit einer Schicht oder einem Ueberzug versehen werden.6. The fabric, paper or the like can be coated with a layer or coating be provided.
Claims (1)
Publications (1)
Publication Number | Publication Date |
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DE124973C true DE124973C (en) |
Family
ID=393724
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DENDAT124973D Active DE124973C (en) |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE124973C (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2709866A (en) * | 1952-06-23 | 1955-06-07 | Johnson | Decoy anchor |
DE976508C (en) * | 1952-03-15 | 1963-10-10 | Hoechst Ag | Process for making fibrous material water repellent |
-
0
- DE DENDAT124973D patent/DE124973C/de active Active
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE976508C (en) * | 1952-03-15 | 1963-10-10 | Hoechst Ag | Process for making fibrous material water repellent |
US2709866A (en) * | 1952-06-23 | 1955-06-07 | Johnson | Decoy anchor |
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