DE820676C - Process for impregnating fibrous materials, in particular paper fibers - Google Patents

Process for impregnating fibrous materials, in particular paper fibers

Info

Publication number
DE820676C
DE820676C DEP146D DEP0000146D DE820676C DE 820676 C DE820676 C DE 820676C DE P146 D DEP146 D DE P146D DE P0000146 D DEP0000146 D DE P0000146D DE 820676 C DE820676 C DE 820676C
Authority
DE
Germany
Prior art keywords
fibrous materials
paper fibers
emulsion
particular paper
impregnating fibrous
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEP146D
Other languages
German (de)
Inventor
Marcel Ernest Degeorges
Francois Stephan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Progil SARL
Original Assignee
Progil SARL
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Progil SARL filed Critical Progil SARL
Application granted granted Critical
Publication of DE820676C publication Critical patent/DE820676C/en
Expired legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/09—Sulfur-containing compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/14—Carboxylic acids; Derivatives thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/60—Waxes
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/62—Rosin; Derivatives thereof

Description

(WiGBL S. 175)(WiGBL p. 175)

AUSGEGEBEN AM 12. NOVEMBER 1951ISSUED NOVEMBER 12, 1951

P P. 146 IVb 146 IVb /55-f/ 55-f

Bekanntlich müssen die für die Herstellung der verschiedenen Papiere verwendeten Cellulosefasern nach den Vorgängen des Kochens, Bleichens, Reinigens usw. mit Chemikalien versetzt werden, die ihre Wasserfestigkeit erhöhen sollen.It is known that the cellulose fibers used for the production of the various papers must chemicals are added after cooking, bleaching, cleaning, etc. to increase their water resistance.

Das hierfür üblichste Mittel ist das Natriumresinat, das durch Aluminiumsulfat als Aluminiumresinat auf der Faser niedergeschlagen wird.The most common means for this is sodium resinate, which is replaced by aluminum sulfate as aluminum resinate is deposited on the fiber.

Es wurde nun gefunden, daß man besonders wertvolle und den bisherigen Verfahren überlegene Ergebnisse hinsichtlich der Wasserfestigkeit und der Oberflächenbeschaffenheit des Papiers erzielen kann. Erfindungsgemäß wird dabei an Stelle des Natriumresinats eine Harzemulsion verwendet, die außerdem noch Paraffin und Zusatzstoffe, wie Netzmittel für die Erleichterung des Eindringens und fungizide Mittel, zur Verhinderung der Schimmelbildung enthält.It has now been found that they are particularly valuable and superior to the previous processes Achieve results in terms of water resistance and surface quality of the paper can. According to the invention, instead of the sodium resinate, a resin emulsion is used which also paraffin and additives such as wetting agents to facilitate penetration and contains fungicides to prevent mold growth.

Nachstehend ist zur näheren Erläuterung ein Ausführungsbeispiel für das Verfahren gegeben.An exemplary embodiment of the method is given below for a more detailed explanation.

Man vermischt in einem Kollergang bei einer Temperatur von 6o bis 8o°:Mix in a pan at a temperature of 6o to 8o °:

Harzseife (zu 25% aus Natriumresinat) 5 bis 25 kg Alkylarylsulfosaures Natrium . . . 1 bis 10 kgResin soap (25% from sodium resinate) 5 to 25 kg of alkylarylsulfonate sodium. . . 1 to 10 kg

Gelatine 20 bis 5 kgGelatin 20 to 5 kg

Paraffin 40 bis 5 kgParaffin 40 to 5 kg

Pentachlornatriumphenolat . . . . 1 bis 2 % Wasser bis auf 100 kg auffüllen.Pentachloro sodium phenolate. . . . 1 to 2 % Fill up with water up to 100 kg.

Die Harzseife kann ganz oder teilweise durch andere Erzeugnisse ersetzt werden, die ebenfalls unlösliche Aluminiumsalze ergeben, z. B. durch Seifen von Fettsäuren, Alkalisalze der Carboxymethyl-The resin soap can be replaced in whole or in part by other products that also result in insoluble aluminum salts, e.g. B. by soaps of fatty acids, alkali salts of the carboxymethyl

cellulose, Alginate usw. Auch Harnstoff kann zugesetzt werden.cellulose, alginates, etc. Urea can also be added.

Die Emulsion ist völlig beständig und kann in jedem Verhältnis mit Wasser ohne Rücksicht auf dessen Härte oder pH-Wert verdünnt werden.The emulsion is completely permanent and can be used in any proportion with water regardless of whose hardness or pH value are diluted.

Die so hergestellte Emulsion wird wie folgt angewandt: Sie wird in einer solchen Menge in einen Holländers gebracht, daß 0,5 bis io°/o Paraffin auf trockenen Zellstoff verwendet werden.The emulsion thus prepared is applied as follows: it is in such an amount in a Holländers said that 0.5 to 10 per cent of paraffin was used on dry pulp.

Der Zusatz eines Netzmittels zur Emulsion begünstigt nicht nur die Emulgierung, sondern führt auch zu einer beträchtlichen Verbesserung der Verteilung der Emulsion auf der Cellulosefaser und sogar des Eindringens derselben in die Cellulosefaser, was im Hinblick auf die gewünschte Wirkung von großer Bedeutung ist.The addition of a wetting agent to the emulsion not only favors emulsification, it also leads to it also to a considerable improvement in the distribution of the emulsion on the cellulose fiber and even the penetration of the same into the cellulose fiber, which in view of the desired effect is of great importance.

Sowie das Cellulose-Emulsionsgemisch eine gute Homogenität aufweist, wird zur Fällung als AIuminiumresinat Aluminiumsulfat zugesetzt. Man muß am Schluß bei einem ρκ-Wert von 4,5 arbeiten. Ist das Gemisch richtig homogen geworden, so läuft es durch die Papiermaschine, ohne daß hierdurch das Verfahren der Papierherstellung eine Änderung erführe.As soon as the cellulose-emulsion mixture has a good homogeneity, aluminum resinate is used for precipitation Aluminum sulfate added. At the end you have to work with a ρκ value of 4.5. If the mixture has become really homogeneous, it runs through the paper machine without this the papermaking process is changing.

Es kann jedoch auch so verfahren werden, daß man die wie oben hergestellte Emulsion alsbald nach ihrer Herstellung mit einem Aluminiumsalz versetzt und das so gewonnene Produkt zur Verarbeitung bringt, wobei sich die spätere Ausfällung mit einem Aluminiumsalz erübrigt, wodurch das Verfahren noch weiter vereinfacht wird.However, it is also possible to proceed in such a way that the emulsion prepared as above is immediately used After their production, an aluminum salt is added and the product obtained in this way for processing brings, whereby the later precipitation with an aluminum salt is unnecessary, whereby the Procedure is further simplified.

Das nach dem vorliegenden Verfahren erhaltene Papier zeichnet sich durch eine hohe Undurchlässigkeit, die bei einem Paraffingehalt von wenigen Prozenten vollständig sein kann, und durch eine beträchtliche Verbesserung der Gleichmäßigkeit seiner Flächen aus.The paper obtained by the present process is characterized by high impermeability, which can be complete with a paraffin content of a few percent, and by a considerable amount Improve the evenness of its surfaces.

Claims (2)

PATENTANSPRÜCHE:PATENT CLAIMS: 1. Verfahren zum Imprägnieren von Faserstoffen, insbesondere von Papierfasern, dadurch gekennzeichnet, daß diese zunächst mit einer Emulsion auf der Grundlage von Harzseifen, Seifen von Fettsäuren, Alkalisalzen der Carboxymethylcellulsoe oder Alginaten, Paraffin und Zusatzstoffen, wie Netzmitteln und fungiziden Stoffen, und darauf mit einem Aluminiumsalz behandelt werden.1. A method for impregnating fibrous materials, in particular paper fibers, thereby characterized in that this is initially carried out with an emulsion based on resin soaps, Soaps of fatty acids, alkali salts of carboxymethyl cellulose or alginates, paraffin and additives such as wetting agents and fungicides, and then with an aluminum salt be treated. 2. Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß die Emulsion mit einem Aluminiumsalz versetzt wird, bevor sie auf die Papierfaser zur Einwirkung gelangt.2. The method according to claim 1, characterized in that that the emulsion is mixed with an aluminum salt before it comes to act on the paper fiber. 2169 11'.2169 11 '.
DEP146D 1948-02-12 1949-10-29 Process for impregnating fibrous materials, in particular paper fibers Expired DE820676C (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1007006T 1948-02-12

Publications (1)

Publication Number Publication Date
DE820676C true DE820676C (en) 1951-11-12

Family

ID=9566229

Family Applications (1)

Application Number Title Priority Date Filing Date
DEP146D Expired DE820676C (en) 1948-02-12 1949-10-29 Process for impregnating fibrous materials, in particular paper fibers

Country Status (5)

Country Link
BE (1) BE505924A (en)
CH (1) CH295408A (en)
DE (1) DE820676C (en)
FR (1) FR1007006A (en)
NL (1) NL83242C (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1444751A (en) * 1973-01-22 1976-08-04 Tenneco Chem Paper sizing

Also Published As

Publication number Publication date
FR1007006A (en) 1952-04-30
BE505924A (en)
CH295408A (en) 1953-12-31
NL83242C (en)

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