DE121462C - - Google Patents
Info
- Publication number
- DE121462C DE121462C DENDAT121462D DE121462DA DE121462C DE 121462 C DE121462 C DE 121462C DE NDAT121462 D DENDAT121462 D DE NDAT121462D DE 121462D A DE121462D A DE 121462DA DE 121462 C DE121462 C DE 121462C
- Authority
- DE
- Germany
- Prior art keywords
- sulfur
- dye
- solution
- violet
- black
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 7
- 239000011593 sulfur Substances 0.000 claims description 7
- 229910052717 sulfur Inorganic materials 0.000 claims description 7
- -1 dinitrochloroxydiphenylamine Chemical compound 0.000 claims description 4
- 229920000742 Cotton Polymers 0.000 claims description 3
- 239000000975 dye Substances 0.000 claims 1
- 239000000243 solution Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Natural products CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 1
- DMBHHRLKUKUOEG-UHFFFAOYSA-N Diphenylamine Chemical class C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N Sodium sulfide Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
- 235000011054 acetic acid Nutrition 0.000 description 1
- 150000001243 acetic acids Chemical class 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 230000003247 decreasing Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B49/00—Sulfur dyes
- C09B49/10—Sulfur dyes from diphenylamines, indamines, or indophenols, e.g. p-aminophenols or leucoindophenols
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
PATENTSCHRIFTPATENT LETTERING
JVs 121462 -KLASSE 22 d. JVs 121462 - CLASS 22 d.
Patentirt im Deutschen Reiche vom i. November 1900 ab.Patented in the German Empire from i. November 1900 onwards.
In der Patentschrift 113515 ist gezeigt worden , dafs ein Baumwolle direct grünschwarz färbender Farbstoff entsteht, wenn das Dinitrochloroxydiphenylamin folgender Constitution:The patent specification 113515 has been shown that a dye which stains cotton directly green-black is formed when the dinitrochloroxydiphenylamine of the following constitution:
NO.NO.
OHOH
mit Schwefel und Schwefelalkalien verschmolzen wird.is fused with sulfur and alkaline sulfur.
Es hat sich nun die überraschende Thatsache ergeben, dafs ein von diesem Farbstoff vollkommen verschiedenes Product erhalten wird, wenn die Einwirkung von Schwefel und Schwefelalkalien auf obiges Diphenylaminderivat in einer siedenden wässerigen Lösung erfolgt. Es entsteht nämlich unter diesen Arbeitsbedingungen ein Farbstoff, welcher auf Baumwolle direct gedeckte violettschwarze Töne erzeugt.The surprising fact has now been found that one of this dye a completely different product is obtained when the action of sulfur and Sulfur alkalis takes place on the above diphenylamine derivative in a boiling aqueous solution. This is because under these working conditions a dye is produced which is applied to cotton directly muted purple-black tones.
In eine Lösung von go kg krystallisirtem Schwefelnatrium und 31 kg Schwefel in 90 kg Wasser trägt man unter Rühren bei 80 bis 850 30 kg Dinitrochloroxydiphenylamin ein und erhitzt die Mischung dann während etwa 22 Stunden am Rückflufskühler zum Kochen. Aus der Lösung wird durch Einblasen von Luft der Farbstoff in Form eines braunschwarzen Pulvers gefällt; dieses löst sich in schwefelnatriumhaltigem Wasser mit dunkel rothvioletter Farbe auf, welche durch Zusatz von Natronlauge etwas röthlicher wird. Mineralsäuren und Essigsäuren erzeugen in der Lösung des Farbstoffs eine dunkelbraune Fällung. In Alkohol ist der Farbstoff unlöslich, in concentrirter Schwefelsäure löst er sich mit violettschwarzer Farbe auf und beim Verdünnen mit Wasser scheidet sich aus dieser Lösung ein dunkel violettbrauner Niederschlag aus.In a solution of sodium sulphide crystallized go kg and 31 kg of sulfur in 90 kg of water with stirring to at 80 to 85 0 30 kg Dinitrochloroxydiphenylamin, and then the mixture is heated about 22 hours Rückflufskühler for cooking. The dye is precipitated in the form of a brown-black powder from the solution by blowing in air; this dissolves in water containing sulphurous sodium with a dark reddish-violet color, which becomes somewhat redder with the addition of caustic soda. Mineral acids and acetic acids produce a dark brown precipitate in the solution of the dye. The dye is insoluble in alcohol; in concentrated sulfuric acid it dissolves with a violet-black color, and on dilution with water a dark violet-brown precipitate separates out of this solution.
Die Menge des Schwefelnatriums und die Dauer des Erhitzens spielen für die Färbeeigenschaft des entstehenden Productes insofern eine Rolle, als bei erhöhtem Zusatz von Schwefeinatrium und Schwefel die Nuance der mit dem Product erzielten Färbung einen etwas mehr bräunlich rofhen Ton, bei längerem Erhitzen mit den in dem Beispiel angegebenen Mengen dagegen einen Stich nach violett erhält ; letzteres tritt ebenfalls ein, wenn in obigem Beispiele die Mengen des angewendeten Schwefels und Schwefelnatriums vermindert werden.The amount of sulphurous sodium and the duration of the heating play a role in the coloring property of the resulting product insofar as the nuance of the the color obtained with the product gives a somewhat more brownish, raw hue, for a longer period of time Heating with the amounts given in the example, on the other hand, has a purple tinge ; The latter also occurs if, in the above example, the amounts of sulfur used and sulfur sodium can be decreased.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE121462C true DE121462C (en) |
Family
ID=390453
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT121462D Active DE121462C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE121462C (en) |
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0
- DE DENDAT121462D patent/DE121462C/de active Active
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