DE1214350B - High performance lubricant - Google Patents
High performance lubricantInfo
- Publication number
- DE1214350B DE1214350B DER25078A DER0025078A DE1214350B DE 1214350 B DE1214350 B DE 1214350B DE R25078 A DER25078 A DE R25078A DE R0025078 A DER0025078 A DE R0025078A DE 1214350 B DE1214350 B DE 1214350B
- Authority
- DE
- Germany
- Prior art keywords
- acid
- pentachlorobutyric
- mineral oil
- high performance
- amounts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M131/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing halogen
- C10M131/08—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing halogen containing carbon, hydrogen, halogen and oxygen
- C10M131/12—Acids; Salts or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/286—Esters of polymerised unsaturated acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/34—Esters having a hydrocarbon substituent of thirty or more carbon atoms, e.g. substituted succinic acid derivatives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
- C10M2207/402—Castor oils
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
- C10M2207/404—Fatty vegetable or animal oils obtained from genetically modified species
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2211/04—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen, halogen, and oxygen
- C10M2211/044—Acids; Salts or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2211/06—Perfluorinated compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/08—Amides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/08—Amides
- C10M2215/082—Amides containing hydroxyl groups; Alkoxylated derivatives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/28—Amides; Imides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
- C10M2219/083—Dibenzyl sulfide
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
- C10M2219/085—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing carboxyl groups; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/02—Unspecified siloxanes; Silicones
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/05—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Description
DEUTSCHESGERMAN
PATENTAMTPATENT OFFICE
Int. α.:Int. α .:
Nummer:
Aktenzeichen:
Anmeldetag:
Auslegetag:Number:
File number:
Registration date:
Display day:
ClOmClOm
Deutsche Kl.: 23 c -1/01 German class: 23 c - 1/01
1214350
R25078IVc/23c
3. März 1959
14. April 19661214350
R25078IVc / 23c
March 3, 1959
April 14, 1966
Als Hochleistungsschmiermittel sind Mischungen aus Mineralölen mit Salzen, wie Bleinaphthenat, Metallauraten oder organischen Verbindungen mit einem oder mehreren Atomen Chlor, Schwefel, Selen oder Phosphor bekannt.Mixtures of mineral oils with salts such as lead naphthenate, Metal aurates or organic compounds with one or more atoms of chlorine, sulfur, selenium or known phosphorus.
Handelsübliche Schmiermittel dieser Art enthalten vielfach zugleich ein Chlorderivat und ein sulfuriertes Derivat, da erkannt wurde, daß die Eignung jeder dieser beiden Gruppen zum Schutz gegen das Festsetzen durch ihre gleichzeitige Anwesenheit verstärkt wird.Commercially available lubricants of this type often contain a chlorine derivative and a sulfurized one at the same time Derivative, since it was recognized that the suitability of each of these two groups was to protect against setting is reinforced by their simultaneous presence.
So werden bei Höchstdruck besonders die chlorierten Laurinsäuren und die tetrachlorierten Buttersäuren mit endständiger CCl3-Gruppe und als sulfuriertes Produkt Dibenzylsulfid verwendet.At maximum pressure, the chlorinated lauric acids and the tetrachlorinated butyric acids with a terminal CCl 3 group and, as a sulfurized product, dibenzyl sulfide are used.
Tetrachlorbuttersäure mit endständiger Cls-Gruppe wird in einer Reihe von aufeinanderfolgenden Verfahrensstufen hergestellt, so daß der Gestehungspreis verhältnismäßig hoch ist. Während in besonderen Anwendungsfällen der hohe Preis tragbar ist, schließt er aber eine allgemeine Verwendung bei Schmiermitteln aus.Tetrachlorobutyric acid with a terminal Cl s group is produced in a number of successive process stages, so that the cost price is relatively high. While the high price is affordable in special applications, it excludes general use in lubricants.
Es wurde nun gefunden, daß unter Verwendung von Pentachlorbuttersäure der FormelIt has now been found that using pentachlorobutyric acid of the formula
CCl3 — CHCl — CHCl — CO2HCCl 3 - CHCl - CHCl - CO 2 H
als Zusatz zu Mineralölen in Mengen von 0,2 bis 5 % ein Schmiermittel erhalten wird, das eine Reibung ohne Festfressen ebenfalls bei außerordentlich hohen Belastungen wie bei einem Zusatz auf der Basis der erwähnten Tetrachlorbuttersäure zusammen mit einer Schwefelverbindung ermöglicht, wobei weiterhin eine Abnutzung der reibenden Flächen im viel geringeren Maße eintritt. Weiterhin wurde gefunden, daß der Zusatz in einer viel geringeren Menge angewendet werden kann.as an additive to mineral oils in amounts of 0.2 to 5%, a lubricant is obtained that has no friction Seizing also with extremely high loads such as an additive based on the allows mentioned tetrachlorobutyric acid together with a sulfur compound, with a further Wear of the rubbing surfaces occurs to a much lesser extent. It was also found that the Additive can be applied in a much smaller amount.
Bei Verwendung von Pentachlorbuttersäure kann auch bei hohen Belastungen auf den Zusatz von Schwefelverbindungen verzichtet werden. Diese Eigenschaft ist von besonderer praktischer Bedeutung, da schwefelhaltige Schmiermittel trotz der hervorragenden Eigenschaften in vielen Fällen nicht verwendet werden können, da sich dabei geringe Mengen von Schwefelsäuren bilden, die Korrosionen verursachen.When using pentachlorobutyric acid, even with high loads, the addition of Sulfur compounds are dispensed with. This property is of particular practical importance since Sulphurous lubricants, despite their excellent properties, are in many cases not used as small amounts of sulfuric acids are formed, which cause corrosion.
Bei Verwendung von Schwefelverbindungen zusammen mit Pentachlorbuttersäure ergibt sich zwar weiterhin eine merkliche Verringerung der Abnutzung, aber selbst bei Abwesenheit der Schwefelverbindung ist die Abnutzung noch geringer als bei bekannten Schmiermitteln.When using sulfur compounds together with pentachlorobutyric acid, it is true still a noticeable reduction in wear, but even in the absence of the sulfur compound the wear is even lower than with known lubricants.
Ein Vorteil besteht auch darin, daß die Pentachlor-Hochleistungsschmiermittel Another advantage is that the pentachloro is high-performance lubricant
Anmelder:Applicant:
Regie Nationale des Usines Renault,Directed by Nationale des Usines Renault,
Billancourt, Seine (Frankreich)Billancourt, Seine (France)
Vertreter:Representative:
Dr. K. Griesing, Patentanwalt,Dr. K. Griesing, patent attorney,
Hönebach (Hess.), Bahnhofstr. 9Hönebach (Hess.), Bahnhofstr. 9
Beanspruchte Priorität:Claimed priority:
Frankreich vom 6. März 1958 (759 870),France of March 6, 1958 (759 870),
vom 20. Oktober 1958 (777 050)dated October 20, 1958 (777 050)
buttersäure aus billigeren Ausgangsstoffen hergestellt und in geringeren Mengen angewandt werden kann.butyric acid can be produced from cheaper raw materials and used in smaller quantities.
Die Pentachlorbuttersäure wird in bekannter Weise durch Einwirkung von Chloral auf Trichloräthylen in Anwesenheit eines Katalysators hergestellt.The pentachlorobutyric acid is in a known manner by the action of chloral on trichlorethylene in Presence of a catalyst produced.
Das chlorierte Produkt wird in Mengen zwischen 0,2 und 5% verwendet. Zusammen mit 1 bis 5% Dibenzylsulfid genügen jedoch 0,1 bis 3 %·The chlorinated product is used in amounts between 0.2 and 5%. Together with 1 to 5% However, 0.1 to 3% of dibenzyl sulfide is sufficient
Die Tabelle zeigt die Abrieb werte nach Boer-1 a g e (Engineering, 136, S. 46, 1933) von Pentachlorbutersäure und Tetrachlorlaurinsäure bzw. Tetrachlorbuttersäure mit und ohne Dibenzylsulfid. A sind die Abriebwerte in Millimeter bei der Belastung B. D sind die Abriebwerte unter Einführung des Faktors der Belastung B, indemThe table shows the abrasion values according to Boer-age (Engineering, 136, p. 46, 1933) of pentachlorobutyric acid and tetrachlorauric acid or tetrachlorobutyric acid with and without dibenzyl sulfide. A are the abrasion values in millimeters at load B. D are the abrasion values with the introduction of the factor of load B by adding
D-D-
100100
umgerechnet wird. Für die Abriebwerte D wird weiterhin für den gesamten Belastungsbereich als auch für die Belastungen von 600 bis 800 kg der Mittelwert angegeben.is converted. For the abrasion values D , the mean value is given for the entire load range as well as for loads from 600 to 800 kg.
Schließlich kann dem erfindungsgemäß zu verwendeten Zusatz noch 0,2 bis 5% Methyl-, Äthyl-, Propyl- oder Isopropylstearat, -palmitat oder -behenat, und zwar einzeln oder in Mischungen in Mengen von 0,5 bis 5 % zugesetzt werden, wobei ohne Gefahr einer Korrosion auch das Festfressen vermieden wird.Finally, the additive to be used according to the invention can add 0.2 to 5% methyl, ethyl, Propyl or isopropyl stearate, palmitate or behenate, individually or in mixtures in quantities 0.5 to 5% can be added, with the seizure being avoided without the risk of corrosion.
Zur Erläuterung der Vorteil dieser besonderen Ausführungsform kann man die Feststellung anführen, daß man bei Zusatz von 1% Pentachlorbuttersäure und 1,5% Methylstearat zu einem Mineralöl vonTo explain the advantage of this particular embodiment, one can make the statement, that with the addition of 1% pentachlorobutyric acid and 1.5% methyl stearate to a mineral oil of
609 558/373609 558/373
geeigneter Viskosität ein Festfressen bei Versuchen auf der Vierkugelmaschine, selbst bei Belastung von 800 kg nicht erreichen kann, wobei der Abriebdurchmesser der Kugeln nach einem Versuch von einer Minute nicht mehr als 1,90 mm für diese Belastung beträgt.suitable viscosity a seizure in tests on the four-ball machine, even with a load of 800 kg cannot be reached, the abrasion diameter of the balls after an attempt by one Minute is not more than 1.90 mm for this load.
Andererseits war der Gewichtsverlust durch Korrosion einer Probe aus weichem Stahl, welche 24 Stunden lang in ein auf eine Temperatur yon 100° C gehaltenes Mineralöl mit einem Gehalt von 1 % Pentachlorbuttersäure, 1,5% Methylstearat und auch 1,7% Wasser, zehnmal geringer als derjenige einer Probe aus dem gleichen Stahl unter gleichen Bedingungen, . welche in einem1. Mineralöl mit: eüiem Gehalt von allein 2% Pentachlorbuttersäure und 1,7% Wasser eingetauscht war.On the other hand, the weight loss due to corrosion of a sample made of soft steel, which was immersed for 24 hours in a mineral oil kept at a temperature of 100 ° C. and containing 1% pentachlorobutyric acid, 1.5% methyl stearate and also 1.7% water, was ten times less than that of a sample made from the same steel under the same conditions,. which in a 1 . Mineral oil with: a content of only 2% pentachlorobutyric acid and 1.7% water was exchanged.
Tetrachlorlaurinsäure 5 %
Dibenzyldisulfid3%Mineral oil 92%
Tetrachlorauric acid 5%
Dibenzyl disulfide 3%
! D ! D.
300load
300
400 B in k
400
600G
600
Mittelin the
middle
Tetrachlorbuttersäure 2%
Dibenzyldisulfid3%Mineral oil 95%
Tetrachlorobutyric acid 2%
Dibenzyl disulfide 3%
J D J D
200B <
200
0,371.12
0.37
0,351.40
0.35
■P,362.13
■ P, 36
0,453.17
0.45
0,453.63
0.45
Pentachlorbuttersäure 2% "
Dibenzyldisulfid 3 %Mineral oil 95% ''
Pentachlorobutyric acid 2% "
Dibenzyl disulfide 3%
J D J D
0,550.55
0.55
0,520.73
0.52
0,450.90
0.45
0,370.92
0.37
0,281.10
0.28
1,56
0,26in the M]
1.56
0.26
1,54
0,22ttel =
1.54
0.22
1,75
0,220.422
1.75
0.22
Tetrachlorbuttersäure 2%
Mineralöl 98%
Pentachlorbuttersäure 2%Mineral oil 98%.
Tetrachlorobutyric acid 2%
Mineral oil 98%
Pentachlorobutyric acid 2%
J DJ D
1 A 1 A
J DJ D
0,520.52
0.52
0,510.72
0.51
0,380.75
0.38
0,280.84
0.28
0,250.98
0.25
1,26
0,21in the M
1.26
0.21
1,31
0,19ttel =
1.31
0.19
1,59
0,200.233
1.59
0.20
0,560.56
0.56
0,440.62
0.44
0,340.68
0.34
0,37
1,13
0,381.11
0.37
1.13
0.38
0,31
1,26
0,321.24
0.31
1.26
0.32
Vers
MiJ
W
1,-49
0,25in the M
verse
MiJ
W.
1, -49
0.25
chweil
idestw
ie bei
1,59
0,23ittel =
because
idestw
ie at
1.59
0.23
3ung
erte
A
1,72'
0,210.198
3ung
erte
A.
1.72 '
0.21
0,58
0,62
0,620.58
0.58
0.62
0.62
0,49
0,75
0,540.68
0.49
0.75
0.54
0,42
0,90
0,450.84
0.42
0.90
0.45
4040
Claims (2)
Deutsche Patentschrift Nr. 952 925;
französische Patentschriften Nr. 1145 476,1137 637Considered publications:
German Patent No. 952 925;
French patent specification No. 1145 476,1137 637
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR759870 | 1958-03-06 | ||
FR797215A FR75881E (en) | 1958-03-06 | 1959-06-11 | Lubricant for greasing under very severe conditions |
Publications (1)
Publication Number | Publication Date |
---|---|
DE1214350B true DE1214350B (en) | 1966-04-14 |
Family
ID=26184102
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DER25078A Pending DE1214350B (en) | 1958-03-06 | 1959-03-03 | High performance lubricant |
DER28054A Pending DE1236703B (en) | 1958-03-06 | 1960-05-28 | High performance lubricant |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DER28054A Pending DE1236703B (en) | 1958-03-06 | 1960-05-28 | High performance lubricant |
Country Status (4)
Country | Link |
---|---|
DE (2) | DE1214350B (en) |
FR (4) | FR1193094A (en) |
GB (2) | GB859732A (en) |
NL (3) | NL121865C (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3284355A (en) * | 1963-09-12 | 1966-11-08 | Mobil Oil Corp | Lubricating compositions |
EP0004957A3 (en) * | 1978-04-26 | 1980-04-16 | Ciba-Geigy Ag | Compositions and use of chlorinated derivatives of butyric acid as additives for lubricants |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE952925C (en) * | 1952-02-13 | 1956-11-22 | Renault | Additives to lubricants |
FR1137637A (en) * | 1955-10-13 | 1957-05-31 | Renault | Lubricants for extreme pressure |
FR1145476A (en) * | 1956-02-20 | 1957-10-25 | Renault | Lubricant for greasing under heavy loads |
-
0
- NL NL236778D patent/NL236778A/xx unknown
- NL NL252224D patent/NL252224A/xx unknown
-
1958
- 1958-03-06 FR FR1193094D patent/FR1193094A/en not_active Expired
- 1958-10-20 FR FR777050A patent/FR74300E/en not_active Expired
-
1959
- 1959-03-02 GB GB7206/59A patent/GB859732A/en not_active Expired
- 1959-03-03 DE DER25078A patent/DE1214350B/en active Pending
- 1959-06-11 FR FR797215A patent/FR75881E/en not_active Expired
-
1960
- 1960-05-25 GB GB18549/60A patent/GB940218A/en not_active Expired
- 1960-05-28 DE DER28054A patent/DE1236703B/en active Pending
- 1960-06-02 NL NL252224A patent/NL121865C/xx active
-
1962
- 1962-08-28 FR FR907988A patent/FR82195E/en not_active Expired
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE952925C (en) * | 1952-02-13 | 1956-11-22 | Renault | Additives to lubricants |
FR1137637A (en) * | 1955-10-13 | 1957-05-31 | Renault | Lubricants for extreme pressure |
FR1145476A (en) * | 1956-02-20 | 1957-10-25 | Renault | Lubricant for greasing under heavy loads |
Also Published As
Publication number | Publication date |
---|---|
NL121865C (en) | 1967-03-15 |
GB859732A (en) | 1961-01-25 |
FR82195E (en) | 1964-01-04 |
NL252224A (en) | |
DE1236703B (en) | 1967-03-16 |
NL236778A (en) | |
GB940218A (en) | 1963-10-30 |
FR1193094A (en) | 1959-10-30 |
FR75881E (en) | 1961-08-18 |
FR74300E (en) | 1960-11-07 |
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