DE1140544B - Process for changing the appearance of fabrics consisting of or containing polyester fibers - Google Patents
Process for changing the appearance of fabrics consisting of or containing polyester fibersInfo
- Publication number
- DE1140544B DE1140544B DEF18025A DEF0018025A DE1140544B DE 1140544 B DE1140544 B DE 1140544B DE F18025 A DEF18025 A DE F18025A DE F0018025 A DEF0018025 A DE F0018025A DE 1140544 B DE1140544 B DE 1140544B
- Authority
- DE
- Germany
- Prior art keywords
- fabric
- polyester fibers
- weight
- parts
- appearance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004744 fabric Substances 0.000 title claims description 21
- 239000000835 fiber Substances 0.000 title claims description 16
- 229920000728 polyester Polymers 0.000 title claims description 13
- 238000000034 method Methods 0.000 title claims description 8
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 claims description 14
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 claims description 10
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 claims description 7
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 claims description 7
- 235000010292 orthophenyl phenol Nutrition 0.000 claims description 5
- 238000010025 steaming Methods 0.000 claims description 5
- YODZTKMDCQEPHD-UHFFFAOYSA-N thiodiglycol Chemical compound OCCSCCO YODZTKMDCQEPHD-UHFFFAOYSA-N 0.000 claims description 5
- 229950006389 thiodiglycol Drugs 0.000 claims description 5
- 239000002562 thickening agent Substances 0.000 claims description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 3
- 230000000694 effects Effects 0.000 description 6
- STIAPHVBRDNOAJ-UHFFFAOYSA-N carbamimidoylazanium;carbonate Chemical compound NC(N)=N.NC(N)=N.OC(O)=O STIAPHVBRDNOAJ-UHFFFAOYSA-N 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 229920000591 gum Polymers 0.000 description 4
- 229920003043 Cellulose fiber Polymers 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000008961 swelling Effects 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 235000010980 cellulose Nutrition 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- 241000416162 Astragalus gummifer Species 0.000 description 1
- 229920000161 Locust bean gum Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 229920001615 Tragacanth Polymers 0.000 description 1
- 229920006221 acetate fiber Polymers 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000010000 carbonizing Methods 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 239000000986 disperse dye Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000000711 locust bean gum Substances 0.000 description 1
- 235000010420 locust bean gum Nutrition 0.000 description 1
- 229940012982 picot Drugs 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000000196 tragacanth Substances 0.000 description 1
- 235000010487 tragacanth Nutrition 0.000 description 1
- 229940116362 tragacanth Drugs 0.000 description 1
- 239000000984 vat dye Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
- D06M11/70—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with oxides of phosphorus; with hypophosphorous, phosphorous or phosphoric acids or their salts
- D06M11/71—Salts of phosphoric acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/001—Special chemical aspects of printing textile materials
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06Q—DECORATING TEXTILES
- D06Q1/00—Decorating textiles
- D06Q1/02—Producing patterns by locally destroying or modifying the fibres of a web by chemical actions, e.g. making translucent
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/04—Polyester fibers
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Coloring (AREA)
Description
Verfahren zur Veränderung des Warenbildes von aus Polyesterfasern bestehenden oder solche enthaltenden Geweben Es ist bereits bekannt, durch Einwirkung von Chemikalien z. B. auf Gewebe von Acetatfaser oder Cellulosefaser in einem gleichmäßigen Grundgewebe Mustereffekte zu erzeugen. Man kann dabei insbesondere bei Geweben aus Fasermischungen die eine Faser stark angreifen oder sogar zerstören, während die andere Faser vollkommen erhalten bleibt. Der sogenannte Ausbrennartikel, bei dem die Cellulosefasern durch karbonisierende Agenzien zerstört werden, ist in dieser Richtung ein klassisches Beispiel.Process for changing the appearance of goods made from polyester fibers existing or containing tissues It is already known by action of chemicals e.g. B. on fabric of acetate fiber or cellulose fiber in a uniform Base fabric to create pattern effects. You can do this in particular with tissues Fiber mixtures that attack or even destroy a fiber, while the other fiber is completely preserved. The so-called burn-out article, in which the cellulose fibers are destroyed by carbonizing agents is in this Direction a classic example.
Es ist auch bereits bekannt, Polyesterfasern in Gegenwart von Quellmitteln, unter anderem auch Guanidin, zu färben, wobei diese Quellmittel in einer Menge von etwa 2°/o eingesetzt werden. Eine Veränderung der Warenbildes kann mit den üblicherweise beim Färben verwendeten Quellmitteln, auch bei Anwendung in höherer Konzentration, nicht erreicht werden.It is also already known to use polyester fibers in the presence of swelling agents, including guanidine, to color, these swelling agents in an amount of about 2 ° / o are used. A change in the product image can usually be done with swelling agents used in dyeing, even when used in higher concentrations, cannot be achieved.
Es wurde nun gefunden, daß man das Warenbild von Geweben, die aus Polyesterfasern bestehen oder solche enthalten, dadurch verändern kann, daß man aus einem Verdickungsmittel und Guanidin, zweckmäßig in Form des Carbonats, bestehende Pasten aufdruckt und das bedruckte Gewebe einem Dämpfprozeß oder der Einwirkung hoher Temperaturen unterwirft, wenn hierbei die Konzentration der Paste an Guanidin mindestens 15 °/o, im Falle der Mitverwendung von o-Phenylphenol und/oder Thiodiglykol mindestens 5 % beträgt.It has now been found that the appearance of fabrics consisting of or containing polyester fibers can be changed by printing pastes made of a thickener and guanidine, advantageously in the form of carbonate, and the printed fabric by a steaming process or exposure Subject to high temperatures if the concentration of guanidine in the paste is at least 15% , in the case of the use of o-phenylphenol and / or thiodiglycol at least 5%.
Als Verdickungsmittel kommen die üblichen Druckverdickungen in Frage; beispielsweise seien genannt: Britischgummi, Industriegummi, Traganth, Polyvinylalkohol, Stärke- und Cellulosederivate, Johannisbrotkernmehl u. a. m.The usual print thickenings are suitable as thickeners; Examples include: British gum, industrial gum, tragacanth, polyvinyl alcohol, Starch and cellulose derivatives, locust bean gum and others. m.
Durch die Dauer und die Stärke des Erhitzungs-bzw. Dämpfprozesses kann die Stärke der Einwirkung variiert werden. So ist es z. B. möglich, daß durch anschließendes Dämpfen die bedruckten Stellen des Gewebes transparent werden. Erhitzt man dagegen auf hohe Temperaturen, z. B. auf 180 bis 220°C, so wird das Polyestergewebe an den bedruckten Stellen zerstört.By the duration and the strength of the heating or. Steaming process the strength of the action can be varied. So it is z. B. possible that through subsequent steaming, the printed areas of the fabric become transparent. Heated on the other hand, at high temperatures, e.g. B. to 180 to 220 ° C, the polyester fabric destroyed at the printed areas.
Die Konzentration an Guanidin wählt man üblicherweise bis zu 45 °/o, bezogen auf die Gesamtmenge der aufzudruckenden Paste. Durch die Mitverwendung von die Wirkung verstärkenden Hilfsstoffen, wie z. B. Thiodiglykol oder o-Phenylphenol, ist es möglich, die Konzentration auf 5 bis 10 % zu senken. Die Mengen an Hilfsstoff wählt man zweckmäßigerweise in der gleichen Größenordnung.The concentration of guanidine is usually chosen up to 45%, based on the total amount of the paste to be printed. Through the use of the effect enhancing auxiliaries, such as. B. thiodiglycol or o-phenylphenol, it is possible to reduce the concentration to 5 to 10%. The amounts of adjuvant are expediently chosen to be of the same order of magnitude.
Die Dauer des Dämpfprozesses bzw. des anschließenden Erhitzens auf hohe Temperaturen hängt von verschiedenen Faktoren, wie z. B. dem gewünschten Effekt, der Temperatur, den Hilfsstoffen usw. ab. Normalerweise genügt es, etwa 30 Minuten zu dämpfen oder etwa 1/2 bis 1 Minute auf eine Temperatur zweckmäßig zwischen 170 und 220°C zu erhitzen.The duration of the steaming process or the subsequent heating to high temperatures depends on various factors, such as: B. the desired effect, the temperature, the auxiliaries, etc. from. Usually it is sufficient to steam for about 30 minutes or to heat for about 1/2 to 1 minute to a temperature expediently between 170 and 220 ° C.
Der Aufdruck solcher abbauender Druckverdickungen kann auf rohweißes und gefärbtes Material, auf Textilien, die nur aus Polyesterfasern, und solchen, die aus Polyesterfasern im Gemisch mit anderen Faserstoffen, z. B. nativer Cellulose, Celluloseregeneratfaser, Wolle, und synthetischen Fasern, z. B. aus Polyacrylnitril, Superpolyamiden u. a., bestehen, erfolgen.The imprint of such degrading print thickenings can be on off-white and dyed material, on textiles made only of polyester fibers, and those made of polyester fibers in a mixture with other fibrous materials, e.g. B. native cellulose, Regenerated cellulose fiber, wool, and synthetic fibers, e.g. B. made of polyacrylonitrile, Superpolyamides, among others, are made.
Den aus den Verdickungsmitteln und Guanidin, zweckmäßigerweise in Form des Carbonats, bestehenden Pasten können zusätzlich noch andere Stoffe zugefügt werden, beispielsweise Farbstoffe, z. B. Dispersionsfarbstoffe, Küpenfarbstoffe, Pigmentfarbstoffe u. a., wodurch besondere wirkungsvolle Effekte, insbesondere bei Mischgeweben, erzielt werden können. Auch Ätzmittel können mitverwendet werden, wodurch sich weitere Variationsmöglichkeiten ergeben, z. B. durch Weiß- oder Buntätzen.The from the thickeners and guanidine, expediently in In the form of the carbonate, other substances can also be added to existing pastes are, for example, dyes, e.g. B. disperse dyes, vat dyes, Pigment dyes, among other things, which create particularly effective effects, especially in Blended fabrics, can be achieved. Etching agents can also be used, whereby there are further possible variations, z. B. by white or colored etching.
Beispiel 1 60 Gewichtsteile einer Mischung aus Britischgummi (1 : 1) und Industriegummi (1 : 2) werden mit 20 Gewichtsteilen Wasser und 20 Gewichtsteilen Guanidincarbonat vermischt.Example 1 60 parts by weight of a mixture of British rubber (1: 1) and industrial rubber (1: 2) are mixed with 20 parts by weight of water and 20 parts by weight Guanidine carbonate mixed.
Mit der so hergestellten Paste wird ein Gewebe aus Polyäthylenglykolterephthalatfasern bedruckt, getrocknet; 30 Sekunden auf 200°C erhitzt, gespült, kochend geseift, gespült und getrocknet: Das Gewebe erscheint an den nicht bedruckten Stellen milchigtrübe, während das aufgedruckte Muster klar ist. Beispiel 2 50 Gewichtsteile Britischgummi (1 : 1) werden mit 25 Gewichtsteilen Guanidincarbonat und 25 Gewichtsteilen Wasser verrührt und mit der erhaltenen Paste ein Gewebe aus Polyesterfasern bedruckt, getrocknet, 1 Minute auf 200°C erhitzt, gespült, kochend geseift, gespült und getrocknet.The paste produced in this way is used to create a fabric made of polyethylene glycol terephthalate fibers printed, dried; Heated to 200 ° C for 30 seconds, rinsed, boiling Soaped, rinsed and dried: The fabric appears in the unprinted areas milky, while the printed pattern is clear. Example 2 50 parts by weight British gum (1: 1) are made with 25 parts by weight of guanidine carbonate and 25 parts by weight Stirring water and printing a fabric made of polyester fibers with the paste obtained, dried, heated to 200 ° C. for 1 minute, rinsed, soaped at the boil, rinsed and dried.
Das Gewebe ist an den bedruckten Stellen vollkommen zerstört. Beispiel 3 Ein nesselähnliches Gewebe aus gesponnenem Polyesterfasergarn wird mit einer feinen Picot-Walze mit einer Paste aus 50 Gewichtsteilen Britischgummi (1 : 1); 25 Gewichtsteilen Guanidincarbonat und 25 Gewichtsteilen Wasser überdruckt, getrocknet, 1 Minute auf 200°C erhitzt, gespült, wieder getrocknet und gerauht. Während das unbehandelte Gewebe mit Rücksicht auf die hohe Festigkeit der Polyesterfaser nur sehr schlecht rauhbar ist, läßt sich das Material nunmehr in ausgezeichneter Weise rauhen. Durch Auswahl geeigneter Muster lassen sich auch beliebige Rauheffekte derart erzielen, daß an den bedruckten Stellen ein stärkerer rauher Pelz, an den nicht bedruckten Stellen kaum ein Rauheffekt auftritt. Selbst endlose Fasern lassen sich auf diese Weise für Rauhartikel vorteilhaft verarbeiten. Beispiel 4 50 Gewichtsteile Britischgummi (1 : 1) werden mit 10 Gewichtsteilen Guanidincarbonat, 30 Gewichtsteilen Wasser und 10 Gewichtsteilen Thiodiglykol vermischt.The fabric is completely destroyed in the printed areas. example 3 A nettle-like fabric made of spun polyester fiber yarn is combined with a fine Picot roller with a paste of 50 parts by weight British gum (1: 1); 25 parts by weight Guanidine carbonate and 25 parts by weight of water overprinted, dried, 1 minute Heated to 200 ° C, rinsed, dried again and roughened. While the untreated With regard to the high strength of the polyester fiber, fabrics are very poor can be roughened, the material can now be roughened in an excellent manner. By Selection of suitable patterns, any rough effects can be achieved in such a way that that in the printed areas a thicker, rough fur, in the unprinted areas There is hardly any rough effect. Even endless fibers can be attached to this Process advantageous for rough articles. Example 4 50 parts by weight British rubber (1: 1) are mixed with 10 parts by weight of guanidine carbonate and 30 parts by weight of water and 10 parts by weight of thiodiglycol mixed.
Mit der so hergestellten Druckpaste wird ein Gewebe aus Polyesterfasern bedruckt, getrocknet, 1 Minute auf 180°C erhitzt, gespült, kochend geseift, gespült und getrocknet. Das Polyestergewebe ist an den bedruckten Stellen zerstört. Beispiel 5 60 Gewichtsteile Britischgummi (1 : 1) werden mit 10 Gewichtsteilen Guanidincarbonat, 10 Gewichtsteilen o-Phenylphenol und 20 Gewichtsteilen Wasser vermischt. Mit dieser Paste wird ein Gewebe aus Polyäthylenglykolterephthalat bedruckt, getrocknet, 40 Sekunden auf 200°C erhitzt, gespült, kochend geseift, gespült und getrocknet.The printing paste produced in this way is used to create a fabric made of polyester fibers printed, dried, heated to 180 ° C for 1 minute, rinsed, soaped at the boil, rinsed and dried. The polyester fabric is destroyed at the printed areas. example 5 60 parts by weight of British rubber (1: 1) are mixed with 10 parts by weight of guanidine carbonate, 10 parts by weight of o-phenylphenol and 20 parts by weight of water mixed. With this Paste is printed on a fabric made of polyethylene glycol terephthalate, dried, 40 Heated to 200 ° C for seconds, rinsed, soaped at the boil, rinsed and dried.
Das Gewebe ist an den bedruckten Stellen vollkommen entfernt.The fabric has been completely removed from the printed areas.
Claims (1)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEF18025A DE1140544B (en) | 1955-07-25 | 1955-07-25 | Process for changing the appearance of fabrics consisting of or containing polyester fibers |
| US598741A US2990231A (en) | 1955-07-25 | 1956-07-19 | Process of modifying polyethylene glycol terephthalate fabrics with guanidine or guanidine carbonate and optionally thiodiglycol or omicron-phenylphenol |
| AT197779D AT197779B (en) | 1955-07-25 | 1956-07-23 | Process for changing the appearance of fabrics made from or containing polyester fibers |
| AT197780D AT197780B (en) | 1955-07-25 | 1956-07-23 | Process for changing the appearance of fabrics made from or containing polyester fibers |
| NL209223A NL89330C (en) | 1955-07-25 | 1956-07-24 | Method for making locally transparent or destroying fabrics consisting of or containing polyester fibers |
| FR1155207D FR1155207A (en) | 1955-07-25 | 1956-07-25 | Process for modifying the appearance of fabrics composed exclusively or in part of polyester fibers |
| FR1160355D FR1160355A (en) | 1955-07-25 | 1956-07-25 | Process for modifying the appearance of fabrics composed exclusively or in part of poly-ester fibers |
| GB23057/56A GB834888A (en) | 1955-07-25 | 1956-07-25 | Process for improving the appearance of fabrics made wholly or partly of polyester fibres |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEF18025A DE1140544B (en) | 1955-07-25 | 1955-07-25 | Process for changing the appearance of fabrics consisting of or containing polyester fibers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1140544B true DE1140544B (en) | 1962-12-06 |
Family
ID=7088791
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEF18025A Pending DE1140544B (en) | 1955-07-25 | 1955-07-25 | Process for changing the appearance of fabrics consisting of or containing polyester fibers |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US2990231A (en) |
| AT (2) | AT197779B (en) |
| DE (1) | DE1140544B (en) |
| FR (2) | FR1155207A (en) |
| GB (1) | GB834888A (en) |
| NL (1) | NL89330C (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0116717A1 (en) * | 1982-12-23 | 1984-08-29 | Mechanische Gardinenweberei Gerhard Siemko | Process for the preparation of a decorative material, especially for curtains |
| FR2565608A1 (en) * | 1984-06-08 | 1985-12-13 | Treviolo Textile Spa | Process for obtaining a ribbed fabric from a raw fabric for the production of a velvet |
| EP1449956A1 (en) * | 2003-02-09 | 2004-08-25 | Formosa Taffeta Co. Ltd. | Process for producing synthetic fiber fabric having translucent printing (dyeing) patterns and fabric thus obtained |
| US7670387B2 (en) * | 2003-01-30 | 2010-03-02 | Formosa Taffeta Co., Ltd. | Process for producing synthetic fiber fabric having translucent printing (dyeing) patterns and fabric thus obtained |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4113430A (en) * | 1976-10-04 | 1978-09-12 | Milliken Research Corporation | Method for modifying fibers of a fabric and the products so produced |
| JP4047305B2 (en) * | 2004-07-01 | 2008-02-13 | セーレン株式会社 | 3D pattern forming blanket |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR943964A (en) * | 1946-03-26 | 1949-03-23 | Ici Ltd | Fabric printing |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1588951A (en) * | 1924-09-20 | 1926-06-15 | American Cellulose & Chemical | Printing of fabrics and articles |
| US2287696A (en) * | 1940-03-02 | 1942-06-23 | Du Pont | Carbonization of cellulose esters |
| GB638338A (en) * | 1948-03-17 | 1950-06-07 | Bertram Pusey Ridge | Improvements in the production of textile fabrics |
| US2607655A (en) * | 1948-08-03 | 1952-08-19 | Heberlein Patent Corp | Striped, creped cellulose fabrics without moire effect |
| GB664921A (en) * | 1949-02-08 | 1952-01-16 | Calico Printers Ass Ltd | Improved process for the delustring of synthetic fibres |
-
1955
- 1955-07-25 DE DEF18025A patent/DE1140544B/en active Pending
-
1956
- 1956-07-19 US US598741A patent/US2990231A/en not_active Expired - Lifetime
- 1956-07-23 AT AT197779D patent/AT197779B/en active
- 1956-07-23 AT AT197780D patent/AT197780B/en active
- 1956-07-24 NL NL209223A patent/NL89330C/en active
- 1956-07-25 FR FR1155207D patent/FR1155207A/en not_active Expired
- 1956-07-25 FR FR1160355D patent/FR1160355A/en not_active Expired
- 1956-07-25 GB GB23057/56A patent/GB834888A/en not_active Expired
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR943964A (en) * | 1946-03-26 | 1949-03-23 | Ici Ltd | Fabric printing |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0116717A1 (en) * | 1982-12-23 | 1984-08-29 | Mechanische Gardinenweberei Gerhard Siemko | Process for the preparation of a decorative material, especially for curtains |
| FR2565608A1 (en) * | 1984-06-08 | 1985-12-13 | Treviolo Textile Spa | Process for obtaining a ribbed fabric from a raw fabric for the production of a velvet |
| US7670387B2 (en) * | 2003-01-30 | 2010-03-02 | Formosa Taffeta Co., Ltd. | Process for producing synthetic fiber fabric having translucent printing (dyeing) patterns and fabric thus obtained |
| EP1449956A1 (en) * | 2003-02-09 | 2004-08-25 | Formosa Taffeta Co. Ltd. | Process for producing synthetic fiber fabric having translucent printing (dyeing) patterns and fabric thus obtained |
Also Published As
| Publication number | Publication date |
|---|---|
| AT197779B (en) | 1958-05-27 |
| FR1155207A (en) | 1958-04-24 |
| NL89330C (en) | 1958-09-17 |
| GB834888A (en) | 1960-05-11 |
| US2990231A (en) | 1961-06-27 |
| AT197780B (en) | 1958-05-27 |
| FR1160355A (en) | 1958-07-15 |
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