DE113638C - - Google Patents
Info
- Publication number
- DE113638C DE113638C DENDAT113638D DE113638DA DE113638C DE 113638 C DE113638 C DE 113638C DE NDAT113638 D DENDAT113638 D DE NDAT113638D DE 113638D A DE113638D A DE 113638DA DE 113638 C DE113638 C DE 113638C
- Authority
- DE
- Germany
- Prior art keywords
- pct
- rubber
- parts
- surrogate
- mixed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 240000008528 Hevea brasiliensis Species 0.000 claims description 6
- 229920001194 natural rubber Polymers 0.000 claims description 6
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N Oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 4
- 229920001971 elastomer Polymers 0.000 claims description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 4
- VXMKYRQZQXVKGB-CWWHNZPOSA-N Tannin Chemical compound O([C@H]1[C@H]([C@@H]2OC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)O[C@H]([C@H]2O)O1)O)C(=O)C1=CC(O)=C(O)C(O)=C1 VXMKYRQZQXVKGB-CWWHNZPOSA-N 0.000 claims description 3
- 229920000159 gelatin Polymers 0.000 claims description 3
- 235000019322 gelatine Nutrition 0.000 claims description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 3
- 235000011187 glycerol Nutrition 0.000 claims description 3
- 229920003051 synthetic elastomer Polymers 0.000 claims description 3
- 229920001864 tannin Polymers 0.000 claims description 3
- 235000018553 tannin Nutrition 0.000 claims description 3
- 239000001648 tannin Substances 0.000 claims description 3
- 239000005642 Oleic acid Substances 0.000 claims description 2
- 239000010426 asphalt Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims 1
- 239000001828 Gelatine Substances 0.000 claims 1
- 235000015450 Tilia cordata Nutrition 0.000 claims 1
- 235000011941 Tilia x europaea Nutrition 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K [O-]P([O-])([O-])=O Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
- 239000004571 lime Substances 0.000 claims 1
- 239000010452 phosphate Substances 0.000 claims 1
- 239000000047 product Substances 0.000 description 5
- 238000004821 distillation Methods 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 3
- 108010010803 Gelatin Proteins 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 239000008273 gelatin Substances 0.000 description 2
- 235000011852 gelatine desserts Nutrition 0.000 description 2
- 229920001206 natural gum Polymers 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- QORWJWZARLRLPR-UHFFFAOYSA-H Tricalcium phosphate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000249 desinfective Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 229920000591 gum Polymers 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000004572 hydraulic lime Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001225 therapeutic Effects 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
Den Gegenstand der vorliegenden Erfindung bildet ein neues Verfahren zur Herstellung von künstlichem Gummi.The subject of the present invention forms a new process for the production of artificial rubber.
Man verfährt dabei in der Weise, dafs ein bestimmter Procentsatz von natürlichem Gummi mit zwei Bestandtheilen A und B in entsprechendem Verhältnifs gemengt wird. Der Bestandtheil A stellt ein Product dar, welches das Aussehen und die Eigenschaften des natürlichen Gummis hat; der Bestandtheil B ist eine seifige Flüssigkeit, die den Zweck hat, eine .Vereinigung des Bestandteiles A mit dem natürlichen Gummi zu erleichtern.One proceeds in such a way that a certain percentage of natural rubber is mixed with two constituents A and B in an appropriate proportion. Ingredient A is a product which has the appearance and properties of natural gum; Ingredient B is a soapy liquid, the purpose of which is to facilitate a combination of ingredient A with natural gum.
Um den Bestandtheil A herzustellen, löst man circa 40 bis 45 Theile Gelatine in 20 Theilen heifsem Wasser auf und fügt derselben 25 bis 30 Theile gewöhnlichen Glycerins hinzu. Sind diese Theile gleichmäfsig durchgerührt, so setzt man etwa 3 Theile Kalkphosphat, 1 Theil einer Tanninlösung und etwa 6 Theile von irgend einem Bitumen (Erdpech) der Mischung zu. Die Tanninlösung soll die Elasticität des künstlichen Gummis erhöhen. Das Mischen der einzelnen Bestandtheile geschieht unter Erhitzen. Ist eine gründliche Mischung vollzogen, dann giefst man das erhaltene Product in Formen und läfst es darin erkalten.In order to prepare ingredient A , about 40 to 45 parts of gelatin are dissolved in 20 parts of hot water, and 25 to 30 parts of ordinary glycerine are added to it. When these parts have been stirred evenly, about 3 parts of calcium phosphate, 1 part of a tannin solution, and about 6 parts of some bitumen (pitch) are added to the mixture. The tannin solution is supposed to increase the elasticity of the artificial gum. The individual components are mixed with heating. Once the mixture has been thoroughly mixed, the product obtained is poured into molds and allowed to cool in them.
Die seifige Flüssigkeit B wird in folgender Weise hergestellt:Soapy liquid B is made in the following way:
Man giefst etwa 6 Theile concentrirter Sodalauge in etwa 5 Theile Oelsäure und rührt beides so lange gründlich durch, bis sich die Seife zu bilden anfängt. Sodann fügt man in kleinen Portionen bis zu etwa 89 Theile St. Champöl oder ein anderes gleichwerthiges OeI hinzu. Man rührt das Gemisch so lange, bis es dickflüssig geworden ist, und läfst die so gewonnene,dicke Flüssigkeit einige Stunden ruhig stehen.About 6 parts of concentrated soda lye are poured into about 5 parts of oleic acid and stirred thoroughly until the soap starts to form. Then add in small ones Add servings of up to about 89 parts St. Champöl or other equivalent oil. The mixture is stirred until it has become thick, and the thick one obtained in this way is poured Let the liquid stand still for a few hours.
Das St. Champöl ist ein Destillationsproduct, welches aus bei Ain im Departement Ain in Frankreich vorkommenden bituminösen Mineralproducten gewonnen wird. Bei der Destillation dieser bituminösen Stoffe erhält man ungefähr 8 pCt. flüchtige Bestandtheile. Davon sind 0,5 pCt. Rhizolene, 25 pCt. leicht schwefelhaltiges OeI, welches fast farblos, aber sehr flüchtig ist, 5 bis 6 pCt. eines benzoeähnlichen Productes, 35 bis 40 pCt. schwer zu trennender Theer, vermischt mit Schwefel, während etwa 6 pCt. Schwefel beim Destillationsprocefs verloren gehen. Der Rückstand bei der Destillation besteht aus etwa 92 pCt. hydraulischem Kalk.The St. Champöl is a distillation product, which comes from near Ain in the department of Ain in Bituminous mineral products occurring in France are extracted. During the distillation about 8 pCt of these bituminous substances are obtained. volatile components. Thereof 0.5 pCt. Rhizolene, 25 pCt. slightly sulphurous oil, which is almost colorless, but very is volatile, 5 to 6 pCt. of a benzoin-like product, 35 to 40 pCt. difficult to separate Tar mixed with sulfur, while about 6 pCt. Sulfur in the distillation process get lost. The residue from the distillation consists of about 92 pCt. hydraulic Lime.
Dieses St. Champöl, welches bisher seiner zusammenziehenden und desinficirenden Eigenschaft wegen nur für therapeutische Zwecke verwendet wurde, verbindet sich leicht mit Lösungen von Glycerin und Gelatine.This St. Champöl, which hitherto has been its astringent and disinfectant property Because it was only used for therapeutic purposes, it combines easily with solutions of glycerin and gelatin.
Durch den Zusatz des Bestandtheiles B soll nicht allein eine innige Verbindung zwischen dem Bestandtheil A und dem natürlichen Gummi herbeigeführt, sondern auch die Austrocknung des künstlichen Gummis verhütet werden.The addition of component B is not only intended to bring about an intimate connection between component A and the natural rubber, but also to prevent the artificial rubber from drying out.
Es ist hierbei zu bemerken, dafs zwar die bekannten Tumenol- und Ichthyolverbindungen Leimlösung zu einer kautschukartigen Masse fällen, doch war ein derartiges Verhalten nicht ohne Weiteres von dem St. Ghampöl voraus-It should be noted here that the well-known tumenol and ichthyol compounds Precipitate glue solution into a rubber-like mass, but there was no such behavior without further ado from the St. Ghampöl-
zusetzen, das weder mit Ichthyol oder Tumenol, noch mit deren Verbindungen etwas zu thun hat, wenn auch andererseits zugegeben wird, dafs der Bestandtheil B auf A in ähnlicher Weise einzuwirken scheint.add, which has nothing to do with ichthyol or tumenol, or with their compounds, although on the other hand it is admitted that the constituent B seems to act on A in a similar way.
Um natürliches Gummi mit dem Surrogat zu vereinigen, nimmt man etwa 60 pCt. von natürlichem Gummi und walzt dasselbe aus. Man fügt demselben dann unter fortwährendem Walzen etwa je 20 pCt. A und B in kleinen Portionen hinzu. . . To combine natural rubber with the surrogate, about 60 pCt are used. of natural rubber and rolls out the same. About 20 pCt are then added to it while rolling continuously. Add A and B in small portions. . .
Die so gewonnene Gummiplatte nimmt ebenso wie natürliches Gummi alle jene Bestandtheile (Farben und sonstige Zusätze) auf, die dem Gummi hinzugefügt werden, um ihn für die verschiedenen industriellen Zwecke verwenden zu können.The rubber sheet obtained in this way, like natural rubber, takes all of those components (Colors and other additives) that are added to the rubber in order to use it for various industrial purposes to be able to.
Claims (3)
Publications (1)
Publication Number | Publication Date |
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DE113638C true DE113638C (en) |
Family
ID=383204
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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DENDAT113638D Active DE113638C (en) |
Country Status (1)
Country | Link |
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DE (1) | DE113638C (en) |
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