DE112016003318A5 - Verfahren zur abscheidung von quecksilber in verbrennungsabgasen - Google Patents

Verfahren zur abscheidung von quecksilber in verbrennungsabgasen Download PDF

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Publication number
DE112016003318A5
DE112016003318A5 DE112016003318.4T DE112016003318T DE112016003318A5 DE 112016003318 A5 DE112016003318 A5 DE 112016003318A5 DE 112016003318 T DE112016003318 T DE 112016003318T DE 112016003318 A5 DE112016003318 A5 DE 112016003318A5
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DE
Germany
Prior art keywords
mercury
separation
combustion gases
gases
combustion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE112016003318.4T
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English (en)
Inventor
Jan Schütze
Ralf Paeslack
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Vpc GmbH
Original Assignee
Vpc GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Vpc GmbH filed Critical Vpc GmbH
Publication of DE112016003318A5 publication Critical patent/DE112016003318A5/de
Withdrawn legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/81—Solid phase processes
    • B01D53/83—Solid phase processes with moving reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8665—Removing heavy metals or compounds thereof, e.g. mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • B01J35/40—
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00—Arrangements of devices for treating smoke or fumes
    • F23J15/003—Arrangements of devices for treating smoke or fumes for supplying chemicals to fumes, e.g. using injection devices
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20723—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/2073—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20738—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20746—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20753—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20761—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20776—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20784—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20792—Zinc
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/20—Halogens or halogen compounds
    • B01D2257/204—Inorganic halogen compounds
    • B01D2257/2045—Hydrochloric acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/302—Sulfur oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/60—Heavy metals or heavy metal compounds
    • B01D2257/602—Mercury or mercury compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/0283—Flue gases
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2215/00—Preventing emissions
    • F23J2215/60—Heavy metals; Compounds thereof
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2219/00—Treatment devices
    • F23J2219/10—Catalytic reduction devices

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Treating Waste Gases (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Catalysts (AREA)
DE112016003318.4T 2015-07-23 2016-07-25 Verfahren zur abscheidung von quecksilber in verbrennungsabgasen Withdrawn DE112016003318A5 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102015009343.6 2015-07-23
DE102015009343 2015-07-23
PCT/DE2016/100333 WO2017012613A2 (de) 2015-07-23 2016-07-25 Verfahren zur abscheidung von quecksilber in verbrennungsabgasen

Publications (1)

Publication Number Publication Date
DE112016003318A5 true DE112016003318A5 (de) 2018-04-19

Family

ID=56939826

Family Applications (2)

Application Number Title Priority Date Filing Date
DE102016113650.6A Withdrawn DE102016113650A1 (de) 2015-07-23 2016-07-25 Verfahren zur Abscheidung von Quecksilber in Verbrennungsabgasen
DE112016003318.4T Withdrawn DE112016003318A5 (de) 2015-07-23 2016-07-25 Verfahren zur abscheidung von quecksilber in verbrennungsabgasen

Family Applications Before (1)

Application Number Title Priority Date Filing Date
DE102016113650.6A Withdrawn DE102016113650A1 (de) 2015-07-23 2016-07-25 Verfahren zur Abscheidung von Quecksilber in Verbrennungsabgasen

Country Status (5)

Country Link
US (1) US20180200672A1 (de)
EP (1) EP3319711A2 (de)
DE (2) DE102016113650A1 (de)
WO (1) WO2017012613A2 (de)
ZA (1) ZA201800808B (de)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108479389B (zh) * 2018-04-27 2021-03-26 华中科技大学 一种烟气协同脱硝脱汞系统及方法

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4403244A1 (de) * 1994-02-03 1995-08-10 Metallgesellschaft Ag Verfahren zur Reinigung von Verbrennungsabgasen
DE4437781A1 (de) 1994-10-25 1996-05-02 Steinmueller Gmbh L & C Verfahren zum Entfernen von Quecksilber aus einem quecksilberhaltigen Abgas
US6719828B1 (en) * 2001-04-30 2004-04-13 John S. Lovell High capacity regenerable sorbent for removal of mercury from flue gas
DE10233173B4 (de) 2002-07-22 2006-03-23 Bayer Industry Services Gmbh & Co. Ohg Verfahren zur Abscheidung von Quecksilber aus Rauchgasen
JP2004075441A (ja) * 2002-08-14 2004-03-11 Huzhou Daikyo Hari Seihin Yugenkoshi Ｌｉ２Ｏ−Ａｌ２Ｏ３−ＳｉＯ２系結晶性ガラス及び結晶化ガラス、ならびに該結晶性ガラス及び結晶化ガラスの製造方法
EP1583601A4 (de) * 2003-01-13 2006-04-05 Engineering Performance Soluti Magnetische aktivkohle und entfernung von verunreinigungen aus einem fluidstrom
US20070092419A1 (en) * 2005-10-26 2007-04-26 Iowa State University Research Foundation, Inc. Method for removal of mercury in gas streams
JP4277226B2 (ja) 2006-02-09 2009-06-10 バブコック日立株式会社 金属水銀酸化用触媒及び金属水銀酸化用触媒を備えた排ガス浄化用触媒とその製造方法
US8057576B1 (en) * 2008-06-10 2011-11-15 Calgon Carbon Corporation Enhanced adsorbents and methods for mercury removal
CN101528343B (zh) 2006-09-22 2012-04-25 巴布考克日立株式会社 金属汞的氧化催化剂
JP5553966B2 (ja) 2008-03-19 2014-07-23 千代田化工建設株式会社 水銀吸着材およびその吸着材を用いた排煙処理方法
AU2008282807A1 (en) * 2007-08-02 2009-02-05 The Benthamite Company, Llc Composition, production and use of sorbent particles for flue gas desulfurization
US8691722B2 (en) * 2008-07-03 2014-04-08 Corning Incorporated Sorbent comprising activated carbon particles, sulfur and metal catalyst
JP5636577B2 (ja) 2008-07-29 2014-12-10 バブコック日立株式会社 金属水銀を含む排ガスの浄化方法および排ガス中の金属水銀の酸化触媒
US20150336081A1 (en) * 2012-03-07 2015-11-26 Clear Carbon Innovations LLC Magnetic adsorbents, methods for manufacturing a magnetic adsorbent, and methods of removal of contaminants from fluid streams
WO2013147171A1 (ja) * 2012-03-30 2013-10-03 株式会社日本触媒 （メタ）アクリル酸系共重合体およびその製造方法
US9073008B2 (en) * 2013-03-07 2015-07-07 Redox Technology Group, Llc Use of ferrous sulfide suspension for the removal of mercury from flue gases
WO2015051363A1 (en) * 2013-10-04 2015-04-09 University Of Cincinnati Method and system for removing gaseous mercury in flue gases
US9802180B2 (en) * 2013-12-11 2017-10-31 Zhejiang University Catalyst for synergistic control of oxynitride and mercury and method for preparing the same

Also Published As

Publication number Publication date
ZA201800808B (en) 2019-03-27
EP3319711A2 (de) 2018-05-16
WO2017012613A2 (de) 2017-01-26
DE102016113650A1 (de) 2017-01-26
US20180200672A1 (en) 2018-07-19
WO2017012613A3 (de) 2017-03-16

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R119 Application deemed withdrawn, or ip right lapsed, due to non-payment of renewal fee