DE1078095B - Corrosion-resistant discharge electrode for electrostatic precipitators - Google Patents

Corrosion-resistant discharge electrode for electrostatic precipitators

Info

Publication number
DE1078095B
DE1078095B DEM19303A DEM0019303A DE1078095B DE 1078095 B DE1078095 B DE 1078095B DE M19303 A DEM19303 A DE M19303A DE M0019303 A DEM0019303 A DE M0019303A DE 1078095 B DE1078095 B DE 1078095B
Authority
DE
Germany
Prior art keywords
corrosion
electrostatic precipitators
discharge electrode
resistant discharge
resistant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DEM19303A
Other languages
German (de)
Inventor
Dr Arnold Muenster
Dr Wilhelm Ruppert
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GEA Group AG
Original Assignee
Metallgesellschaft AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Metallgesellschaft AG filed Critical Metallgesellschaft AG
Priority to DEM19303A priority Critical patent/DE1078095B/en
Publication of DE1078095B publication Critical patent/DE1078095B/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03CMAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C3/00Separating dispersed particles from gases or vapour, e.g. air, by electrostatic effect
    • B03C3/34Constructional details or accessories or operation thereof
    • B03C3/40Electrode constructions
    • B03C3/60Use of special materials other than liquids

Description

Nach dem Hauptpatent 1 001 239 werden als korrosionsbeständige Elektroden für Elektrofilter, insbesondere als Sprühelektroden, Drähte mit einem Titannitridüberzug von geringer Stärke durch Ausscheiden aus der Gasphase verwendet.According to the main patent 1 001 239, corrosion-resistant electrodes for electrostatic precipitators, in particular as spray electrodes, wires with a titanium nitride coating of low thickness by precipitation used from the gas phase.

Erfindungsgemäß besteht ein korrosionschützender Überzug von geringer Stärke, der durch Ausscheiden aus der Gasphase hergestellt ist, aus einem Silizid, Borid oder Carbid eines Metalls der Titangruppe (insbesondere Titan, Zirkon, Hafnium) oder Vanadingruppe (Vanadin, Niob, Tantal) oder der Chromgruppe (Chrom, Wolfram, Molybdän) oder Legierungen derselben. Insbesondere eignen sich Titan und Tantal für diesen Zweck.According to the invention there is an anti-corrosion coating of low thickness, which is caused by precipitation is made from the gas phase, from a silicide, boride or carbide of a metal of the titanium group (in particular Titanium, zirconium, hafnium) or vanadium group (vanadium, niobium, tantalum) or the chromium group (Chromium, tungsten, molybdenum) or alloys of the same. In particular, titanium and Tantalum for this purpose.

Die Herstellung von Drähten aus korrosionsbeständigen Metallen, beispielsweise Tantal, ist schwierig und sehr teuer. Bisher hat man sich meist mit verbleiten Drähten für Sprühelektroden beholfen. Bei dem hohen spezifischen Gewicht des Bleis ist das Eigengewicht des Bleimantels nicht mehr zu vernachlässigen und belastet erheblich den eigentlichen Draht. Dieser Umstand zwingt dazu, Drähte mit größerem Querschnitt zu verwenden. Dies hat den Nachteil, daß der Wirkungsgrad des Filters erheblich herabgesetzt wird.Making wires from corrosion-resistant metals, such as tantalum, is difficult and very expensive. Until now, leaded wires for spray electrodes have mostly been used. at Due to the high specific weight of the lead, the dead weight of the lead jacket can no longer be neglected and puts a considerable strain on the actual wire. This fact forces you to use wires with larger To use cross-section. This has the disadvantage that the efficiency of the filter is considerably reduced will.

Die Überzüge nach der Erfindung können nach verschiedenen, an sich bekannten Verfahren aufgebracht werden. Die Abscheidung mit Hilfe einer Reaktion in der Gasphase bei höheren Temperaturen gestattet die Herstellung dünner und besonders gleichmäßiger Überzüge.The coatings according to the invention can be applied by various methods known per se will. The deposition with the help of a reaction in the gas phase at higher temperatures allows Production of thin and particularly uniform coatings.

Titanüberzüge lassen sich beispielsweise durch Reduktion oder thermische Spaltung der Halogenide aufbringen, insbesondere des Bromids oder Jodids. Die Nitride, Suizide, Bromide oder Carbide können direkt als solche aufgebracht werden oder durch nachträgliche Behandlung der entsprechenden metallischen Überzüge.Titanium coatings can be obtained, for example, by reducing or thermally cleaving the halides apply, especially the bromide or iodide. The nitrides, suicides, bromides or carbides can can be applied directly as such or by subsequent treatment of the corresponding metallic Coatings.

Da die Überzüge nur auf Korrosion beansprucht werden, sind Überzüge von etwa 20 bis 30 κμ schon völlig ausreichend. Das Eigengewicht der Überzüge kann praktisch vernachlässigt werden. Dies hat den Korrosionsbeständige AusströmerelektrodeSince the coatings are only exposed to corrosion, coatings of around 20 to 30 κμ are fine completely adequate. The weight of the coatings themselves can practically be neglected. This has the Corrosion-resistant discharge electrode

für Elektrofilterfor electrostatic precipitators

Zusatz zum Patent 1 001 239Addendum to patent 1 001 239

Anmelder:Applicant:

Metallgesellschaft Aktiengesellschaft,
Frankfurt/M., Reuterweg 14
Metallgesellschaft Aktiengesellschaft,
Frankfurt / M., Reuterweg 14

Dr. Arnold Münster und Dr. Wilhelm Ruppert,Dr. Arnold Münster and Dr. Wilhelm Ruppert,

Frankfurt/M.,
sind als Erfinder genannt worden
Frankfurt / M.,
have been named as inventors

Vorteil, daß man nun wesentlich kleinere Drahtquerschnitte zulassen kann, wodurch der Wirkungsgrad der Elektrofilter wesentlich verbessert wird.The advantage is that you can now allow much smaller wire cross-sections, which increases the efficiency the electrostatic precipitator is significantly improved.

Als Drahtmaterial können die bisher verwendeten Chromnickeldrähte oder auch ein billigerer Werkstoff eingesetzt werden.As wire material, the previously used chrome-nickel wires or a cheaper material can be used can be used.

Claims (1)

PATENTANSPRUCH:PATENT CLAIM: Korrosionsbeständige Ausströmerelektrode für Elektrofilter, insbesondere in Drahtform, mit einem korrosionschützenden Überzug von geringer Stärke, der durch Ausscheiden aus der Gasphase hergestellt ist, nach Patent 1 001 239, dadurch gekennzeichnet, daß der Überzug aus einem Silizid, Borid oder Carbid eines Metalls der Titan-, Vanadin- oder Chromgruppe besteht.Corrosion resistant Ausströmerelektrode for electrostatic precipitators, in particular in the form of wire, with a corrosion-protective coating of low thickness, which is made by leaving the gas phase, according to patent 1,001,239, characterized in that the coating consists of a silicide, boride or carbide of a metal of the titanium , Vanadium or chromium group. In Betracht gezogene Druckschriften:
Deutsche Patentschrift Nr. 465 276;
schweizerische Patentschrift Nr. 277 400;
französische Patentschrift Nr. 500 775;
belgische Patentschrift Nr. 500 574.
Considered publications:
German Patent No. 465 276;
Swiss Patent No. 277 400;
French Patent No. 500 775;
Belgian patent specification No. 500 574.
DEM19303A 1953-07-13 1953-07-13 Corrosion-resistant discharge electrode for electrostatic precipitators Pending DE1078095B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEM19303A DE1078095B (en) 1953-07-13 1953-07-13 Corrosion-resistant discharge electrode for electrostatic precipitators

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEM19303A DE1078095B (en) 1953-07-13 1953-07-13 Corrosion-resistant discharge electrode for electrostatic precipitators

Publications (1)

Publication Number Publication Date
DE1078095B true DE1078095B (en) 1960-03-24

Family

ID=7297942

Family Applications (1)

Application Number Title Priority Date Filing Date
DEM19303A Pending DE1078095B (en) 1953-07-13 1953-07-13 Corrosion-resistant discharge electrode for electrostatic precipitators

Country Status (1)

Country Link
DE (1) DE1078095B (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE500574A (en) *
FR500775A (en) * 1918-01-25 1920-03-24 Sidney Frazer Barclay Improvements in devices for separating suspended particles from the gases that contain them
DE465276C (en) * 1923-05-18 1928-09-15 Philips Nv Glow cathode for discharge tubes
CH277400A (en) * 1948-01-08 1951-08-31 Boehler & Co Ag Geb Process for increasing the resistance of the surface of steel parts to wear, especially at high temperatures.

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE500574A (en) *
FR500775A (en) * 1918-01-25 1920-03-24 Sidney Frazer Barclay Improvements in devices for separating suspended particles from the gases that contain them
DE465276C (en) * 1923-05-18 1928-09-15 Philips Nv Glow cathode for discharge tubes
CH277400A (en) * 1948-01-08 1951-08-31 Boehler & Co Ag Geb Process for increasing the resistance of the surface of steel parts to wear, especially at high temperatures.

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