DE10345903A1 - Reaktive thermisch- und/oder strahlungshärtbare Lacke und deren Härteverfahren - Google Patents

Reaktive thermisch- und/oder strahlungshärtbare Lacke und deren Härteverfahren Download PDF

Info

Publication number
DE10345903A1
DE10345903A1 DE10345903A DE10345903A DE10345903A1 DE 10345903 A1 DE10345903 A1 DE 10345903A1 DE 10345903 A DE10345903 A DE 10345903A DE 10345903 A DE10345903 A DE 10345903A DE 10345903 A1 DE10345903 A1 DE 10345903A1
Authority
DE
Germany
Prior art keywords
initiators
reactive
paint
thermal
system including
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
DE10345903A
Other languages
English (en)
Other versions
DE10345903B4 (de
Inventor
Markus Bischof
Elisabeth Gemmler
Fritz Mezger
Thomas Raith
Christoph Ruechardt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mercedes Benz Group AG
Original Assignee
DaimlerChrysler AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DaimlerChrysler AG filed Critical DaimlerChrysler AG
Priority to DE10345903A priority Critical patent/DE10345903B4/de
Priority to US10/873,717 priority patent/US7091256B2/en
Publication of DE10345903A1 publication Critical patent/DE10345903A1/de
Application granted granted Critical
Publication of DE10345903B4 publication Critical patent/DE10345903B4/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
    • C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/06—Polymers provided for in subclass C08G
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/2815—Monohydroxy compounds
    • C08G18/283—Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
    • C09D175/16—Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Paints Or Removers (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

Reaktiver Lack zur vollständigen Aushärtung an Luft mit Bindemitteln, die ethylenisch ungesättigte Gruppen tragen und der thermisch oder nach dem Dual-Cure-Verfahren thermisch und durch UV-Licht oder energiereiche Strahlung mittels radikalischer Polymerisation aushärtbar ist. Der Lack enthält ein kombiniertes Initiatorsystem aus thermischem Initiator und UV-Initiator oder ein thermisches Initiatorsystem und reaktive Oligomere, die aus Additionsverbindungen gebildet werden, aus einem Edukt der DOLLAR F1 Formel (4) und einem Edukt der Formel (5), DOLLAR F2 Dabei bedeutet X = -CO-CH=CH¶2¶ oder -C¶n¶H¶m¶, mit -C¶n¶H¶m¶ = aliphatischer Rest mit 1 bis 3 C-Atomen, wobei 0, 1, 2 oder 3 Substituenten X durch -C¶n¶H¶m¶ gebildet werden und bedeutet Y = eine Kohlenstoffkette von 3 bis 8 Atomen, die auch Heteroatome enthalten kann. DOLLAR A Verfahren zur Härtung durch radikalische Polymerisation, wobei die Polymerisation zunächst an Luft thermisch gestartet und dann an Luft oder unter Schutzgas, thermisch oder photoinitiiert fortgeführt wird, sowie Verwendung in Lacksystemen, insbesondere im Automobilbau, oder als Binder.
DE10345903A 2003-06-25 2003-10-02 Reaktive thermisch oder kombiniert thermisch und UV-initiiert härtbare Lacke, deren Verwendung sowie Verfahren zu deren Härtung Expired - Fee Related DE10345903B4 (de)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DE10345903A DE10345903B4 (de) 2003-06-25 2003-10-02 Reaktive thermisch oder kombiniert thermisch und UV-initiiert härtbare Lacke, deren Verwendung sowie Verfahren zu deren Härtung
US10/873,717 US7091256B2 (en) 2003-06-25 2004-06-22 Reactive thermally-curing and/or radiation-curing paints and their curing methods

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10328474 2003-06-25
DE10328474.5 2003-06-25
DE10345903A DE10345903B4 (de) 2003-06-25 2003-10-02 Reaktive thermisch oder kombiniert thermisch und UV-initiiert härtbare Lacke, deren Verwendung sowie Verfahren zu deren Härtung

Publications (2)

Publication Number Publication Date
DE10345903A1 true DE10345903A1 (de) 2005-05-12
DE10345903B4 DE10345903B4 (de) 2012-05-31

Family

ID=34081629

Family Applications (1)

Application Number Title Priority Date Filing Date
DE10345903A Expired - Fee Related DE10345903B4 (de) 2003-06-25 2003-10-02 Reaktive thermisch oder kombiniert thermisch und UV-initiiert härtbare Lacke, deren Verwendung sowie Verfahren zu deren Härtung

Country Status (2)

Country Link
US (1) US7091256B2 (de)
DE (1) DE10345903B4 (de)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102005057925A1 (de) * 2005-12-05 2007-06-06 Basf Coatings Ag Radikalisch polymerisierbare Gemische, Verfahren zu ihrer Herstellung und ihre Verwendung
US7563831B2 (en) 2004-12-27 2009-07-21 Daimler Ag Method for curing a composition
DE102010023782A1 (de) * 2010-06-15 2011-12-15 Amcor Flexibles Singen Gmbh Schutzlack, Schichtanordnung, Halbzeug sowie Herstellungsverfahren

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070022625A1 (en) * 2005-07-28 2007-02-01 Garmat Usa, Inc. UV curing structure and process
KR100724797B1 (ko) * 2005-10-10 2007-06-04 에스에스씨피 주식회사 저점도 다관능 우레탄아크릴레이트 올리고머를 포함하는하이솔리드 자외선 경화형 도료 조성물
JP2012504168A (ja) * 2008-09-29 2012-02-16 スコット ベイダー カンパニー リミテッド 架橋可能成形組成物
US20100183820A1 (en) * 2009-01-16 2010-07-22 Ford Global Technologies, Llc Methods for curing uv-curable coatings
CN101824301B (zh) * 2010-03-22 2011-12-14 袁敏华 全防紫外线抗疲劳及防黑色素细胞粘合剂及其制备方法
JP2018065916A (ja) * 2016-10-19 2018-04-26 デクセリアルズ株式会社 接続体の製造方法
CN109852112B (zh) * 2018-12-17 2021-04-27 邦弗特新材料股份有限公司 一种膜压涂层和膜压地板及膜压地板的制备方法
CN109632572B (zh) * 2018-12-25 2021-03-30 山西霍家长化合成橡胶有限公司 Pdva油漆聚合终点判定方法
WO2021051257A1 (en) * 2019-09-17 2021-03-25 Henkel Ag & Co. Kgaa Acrylate adhesive composition

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59204837A (ja) * 1983-05-09 1984-11-20 Asahi Chem Ind Co Ltd 光重合性積層体及びそれを用いたレジスト像形成方法
JPH0689293B2 (ja) 1986-05-27 1994-11-09 日本油脂株式会社 紫外線硬化型塗料
US5492731A (en) * 1991-05-17 1996-02-20 Ppg Industries, Inc. Thermally curable coating composition
DE4133290A1 (de) 1991-10-08 1993-04-15 Herberts Gmbh Verfahren zur herstellung von mehrschichtlackierungen unter verwendung von radikalisch und/oder kationisch polymerisierbaren klarlacken
US5635544A (en) * 1992-11-27 1997-06-03 Mitsubishi Rayon Co., Ltd. Process for preparing a UV-curable coating material and anti-abrasion coating composition
US5747552A (en) * 1996-04-10 1998-05-05 Hehr International Inc. Radiant energy curable acrylic urethane prepolymer resin compositions and method
DE19709560C1 (de) * 1997-03-07 1998-05-07 Herberts Gmbh Überzugsmittel zur Mehrschichtlackierung und Verwendung der Überzugsmittel in einem Verfahren zur Lackierung
DE19940313A1 (de) * 1999-08-25 2001-03-01 Basf Ag Verfahren zur Herstellung kratzfester, witterungsstabiler Beschichtungen

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7563831B2 (en) 2004-12-27 2009-07-21 Daimler Ag Method for curing a composition
DE102005057925A1 (de) * 2005-12-05 2007-06-06 Basf Coatings Ag Radikalisch polymerisierbare Gemische, Verfahren zu ihrer Herstellung und ihre Verwendung
DE102010023782A1 (de) * 2010-06-15 2011-12-15 Amcor Flexibles Singen Gmbh Schutzlack, Schichtanordnung, Halbzeug sowie Herstellungsverfahren
EP2397529A3 (de) * 2010-06-15 2016-07-20 Amcor Flexibles Singen GmbH Schichtanordnung, sowie Herstellungsverfahren

Also Published As

Publication number Publication date
US20050020711A1 (en) 2005-01-27
US7091256B2 (en) 2006-08-15
DE10345903B4 (de) 2012-05-31

Similar Documents

Publication Publication Date Title
DE10345903A1 (de) Reaktive thermisch- und/oder strahlungshärtbare Lacke und deren Härteverfahren
EP3095614B1 (de) Herstellung von dekorflächen durch tintenstrahldruck
AU2017336195B2 (en) Manufacturing of decorative surfaces
EP3201278B1 (de) Verfahren zur herstellung eines prägeelements
AU2001269905A1 (en) Novel photoinitiators and applications therefor
AU2017333870B2 (en) Inkjet printing methods for decorative surfaces
EP3233511B1 (de) Uv-härtbare tintenstrahltinten zum drucken auf glas
US11578226B2 (en) Inkjet printing of wood colours
EP3686251B1 (de) Strahlungshärtbare tintenstrahltinten zur innenraumdekoration
DE602006008901D1 (de) Härtbare harzzusammensetzung zum tintenstrahldrucken, daraus gewonnenes gehärtetes objekt und daraus gewonnene leiterplatte
BR112020025967A2 (pt) iniciadores de óxido de acil fosfina
MX9201897A (es) Tinta para impresion por entallado termico.
WO2000018750A3 (en) Chelates comprising chinoid groups as photoinitiators
JP2017101213A (ja) 活性エネルギー線硬化型組成物、活性エネルギー線硬化型インク組成物、活性エネルギー線硬化型インクジェット用インク組成物、組成物収容容器、２次元又は３次元の像形成装置、及び２次元又は３次元の像形成方法
EP4050072B1 (de) Verfahren zur herstellung von dekorativen oberflächen
EP4050073A1 (de) Tintensatz und tintenstrahldruckverfahren
JP2018090715A (ja) 硬化型組成物、組成物収容容器、２次元又は３次元の像形成装置、２次元又は３次元の像形成方法、硬化物、加飾体、及び化合物

Legal Events

Date Code Title Description
OP8 Request for examination as to paragraph 44 patent law
8127 New person/name/address of the applicant

Owner name: DAIMLERCHRYSLER AG, 70327 STUTTGART, DE

8127 New person/name/address of the applicant

Owner name: DAIMLER AG, 70327 STUTTGART, DE

R016 Response to examination communication
R016 Response to examination communication
R016 Response to examination communication
R018 Grant decision by examination section/examining division
R020 Patent grant now final

Effective date: 20120901

R119 Application deemed withdrawn, or ip right lapsed, due to non-payment of renewal fee