DE102014209635A1 - Herstellung von Synthesegas mit zwei autothermen Reformern - Google Patents

Herstellung von Synthesegas mit zwei autothermen Reformern Download PDF

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Publication number
DE102014209635A1
DE102014209635A1 DE102014209635.9A DE102014209635A DE102014209635A1 DE 102014209635 A1 DE102014209635 A1 DE 102014209635A1 DE 102014209635 A DE102014209635 A DE 102014209635A DE 102014209635 A1 DE102014209635 A1 DE 102014209635A1
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Prior art keywords
synthesis gas
vol
volume
pressure
gas
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Ceased
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DE102014209635.9A
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German (de)
English (en)
Inventor
Evgeni Gorval
Joachim Johanning
Bernd Keil
Katja Poschlad
Dr. Potthoff Christiane
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ThyssenKrupp AG
ThyssenKrupp Industrial Solutions AG
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ThyssenKrupp AG
ThyssenKrupp Industrial Solutions AG
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Priority to DE102014209635.9A priority Critical patent/DE102014209635A1/de
Priority to PCT/EP2015/060749 priority patent/WO2015177051A1/fr
Publication of DE102014209635A1 publication Critical patent/DE102014209635A1/de
Ceased legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382Multi-step processes
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/025Preparation or purification of gas mixtures for ammonia synthesis
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0283Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0283Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C01B2203/0288Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step containing two CO-shift steps
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0405Purification by membrane separation
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    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0415Purification by absorption in liquids
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042Purification by adsorption on solids
    • C01B2203/043Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0435Catalytic purification
    • C01B2203/0445Selective methanation
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/047Composition of the impurity the impurity being carbon monoxide
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/0475Composition of the impurity the impurity being carbon dioxide
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/048Composition of the impurity the impurity being an organic compound
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205Composition of the feed
    • C01B2203/1211Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235Hydrocarbons
    • C01B2203/1241Natural gas or methane
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    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1258Pre-treatment of the feed
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14Details of the flowsheet
    • C01B2203/141At least two reforming, decomposition or partial oxidation steps in parallel
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14Details of the flowsheet
    • C01B2203/142At least two reforming, decomposition or partial oxidation steps in series
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/16Controlling the process
    • C01B2203/169Controlling the feed

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Hydrogen, Water And Hydrids (AREA)
DE102014209635.9A 2014-05-21 2014-05-21 Herstellung von Synthesegas mit zwei autothermen Reformern Ceased DE102014209635A1 (de)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DE102014209635.9A DE102014209635A1 (de) 2014-05-21 2014-05-21 Herstellung von Synthesegas mit zwei autothermen Reformern
PCT/EP2015/060749 WO2015177051A1 (fr) 2014-05-21 2015-05-15 Production de gaz de synthèse avec deux reformeurs autothermes

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE102014209635.9A DE102014209635A1 (de) 2014-05-21 2014-05-21 Herstellung von Synthesegas mit zwei autothermen Reformern

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DE102014209635A1 true DE102014209635A1 (de) 2015-11-26

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DE102014209635.9A Ceased DE102014209635A1 (de) 2014-05-21 2014-05-21 Herstellung von Synthesegas mit zwei autothermen Reformern

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DE (1) DE102014209635A1 (fr)
WO (1) WO2015177051A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020007627A1 (fr) 2018-07-03 2020-01-09 Thyssenkrupp Industrial Solutions Ag Procédé pour éviter les émissions de cov et de pad d'installations de traitement de gaz de synthèse
EP3583067B1 (fr) 2017-02-15 2021-09-08 Casale SA Procédé de synthèse d'ammoniac avec de faibles émissions de co2 dans l'atmosphère

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3047257A1 (de) * 1980-12-16 1982-07-08 Didier Engineering Gmbh, 4300 Essen Verfahren zur erzeugung von ammoniak-synthesegas
EP0999178A1 (fr) 1998-11-03 2000-05-10 Ammonia Casale S.A. Procédé pour la production de gaz de synthèse
US6444712B1 (en) 2000-09-28 2002-09-03 Exxonmobil Chemical Patents, Inc. Methanol, olefin, and hydrocarbon synthesis process
US6572837B1 (en) * 2000-07-19 2003-06-03 Ballard Power Systems Inc. Fuel processing system
WO2004083114A2 (fr) 2003-03-18 2004-09-30 Kellogg Brown & Root, Inc. Installation de reformeur autotherme-echangeur de reformage pour production d'hydrogene
DE102008039014A1 (de) * 2008-08-21 2010-02-25 Uhde Gmbh Mehrstufige Reaktorkaskade zur rußfreien Herstellung von Systhesegas
WO2012173483A1 (fr) * 2011-06-16 2012-12-20 Stamicarbon B.V. Acting Under The Name Of Mt Innovation Center Procédé de production d'hydrogène
WO2013013895A1 (fr) * 2011-07-25 2013-01-31 Haldor Topsøe A/S Procédé de production de gaz de synthèse
US20130312384A1 (en) 2012-05-23 2013-11-28 Herng Shinn Hwang Flex-Fuel Hydrogen Generator for IC Engines and Gas Turbines

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006117499A1 (fr) * 2005-05-03 2006-11-09 Quartey-Papafio Alexander H Procede de fabrication d'un gaz de synthese
WO2013033812A1 (fr) * 2011-09-08 2013-03-14 Steve Kresnyak Amélioration du procédé fischer-tropsch pour une formulation d'hydrocarbure combustible dans un environnement de transformation du gaz en liquide

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3047257A1 (de) * 1980-12-16 1982-07-08 Didier Engineering Gmbh, 4300 Essen Verfahren zur erzeugung von ammoniak-synthesegas
EP0999178A1 (fr) 1998-11-03 2000-05-10 Ammonia Casale S.A. Procédé pour la production de gaz de synthèse
US6572837B1 (en) * 2000-07-19 2003-06-03 Ballard Power Systems Inc. Fuel processing system
US6444712B1 (en) 2000-09-28 2002-09-03 Exxonmobil Chemical Patents, Inc. Methanol, olefin, and hydrocarbon synthesis process
WO2004083114A2 (fr) 2003-03-18 2004-09-30 Kellogg Brown & Root, Inc. Installation de reformeur autotherme-echangeur de reformage pour production d'hydrogene
DE102008039014A1 (de) * 2008-08-21 2010-02-25 Uhde Gmbh Mehrstufige Reaktorkaskade zur rußfreien Herstellung von Systhesegas
WO2012173483A1 (fr) * 2011-06-16 2012-12-20 Stamicarbon B.V. Acting Under The Name Of Mt Innovation Center Procédé de production d'hydrogène
WO2013013895A1 (fr) * 2011-07-25 2013-01-31 Haldor Topsøe A/S Procédé de production de gaz de synthèse
US20130312384A1 (en) 2012-05-23 2013-11-28 Herng Shinn Hwang Flex-Fuel Hydrogen Generator for IC Engines and Gas Turbines

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
A. Nielsen, I. Dybkjaer, Ammonia-Catalysis and Manufacture, Springer Berlin 1995, Kapitel 6, Seiten 202-326

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3583067B1 (fr) 2017-02-15 2021-09-08 Casale SA Procédé de synthèse d'ammoniac avec de faibles émissions de co2 dans l'atmosphère
WO2020007627A1 (fr) 2018-07-03 2020-01-09 Thyssenkrupp Industrial Solutions Ag Procédé pour éviter les émissions de cov et de pad d'installations de traitement de gaz de synthèse
DE102018210910A1 (de) 2018-07-03 2020-01-09 Thyssenkrupp Ag Verfahren zur Vermeidung von VOC und HAP Emissionen aus Synthesegas verarbeitenden Anlagen

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