DE102011088815A1

DE102011088815A1 - Pulverförmige Kosmetika

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Info

Publication number: DE102011088815A1
Authority: DE; Germany
Prior art keywords: bis; group; metal oxide; und; keratin
Prior art date: 2011-12-16
Legal status : Withdrawn

Application number

DE102011088815A

Other languages

German (de)

English (en)

Inventor

Thorsten Knappe

Anna Henschel

Current Assignee

Henkel AG and Co KGaA

Original Assignee

Henkel AG and Co KGaA

Priority date

2011-12-16

Filing date

2011-12-16

Publication date

2013-06-20

2011-12-16 Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA

2011-12-16 Priority to DE102011088815A priority Critical patent/DE102011088815A1/de

2012-11-09 Priority to PCT/EP2012/072254 priority patent/WO2013087315A2/de

2012-11-09 Priority to EP12781360.8A priority patent/EP2814452B1/de

2012-11-09 Priority to US14/364,595 priority patent/US20140345640A1/en

2012-11-09 Priority to JP2014546383A priority patent/JP6163493B2/ja

2013-06-20 Publication of DE102011088815A1 publication Critical patent/DE102011088815A1/de

Status Withdrawn legal-status Critical Current

Links

239000002537 cosmetic Substances 0.000 title claims abstract description 52
239000000203 mixture Substances 0.000 claims abstract description 213
229920000642 polymer Polymers 0.000 claims abstract description 147
229910044991 metal oxide Inorganic materials 0.000 claims abstract description 111
150000004706 metal oxides Chemical class 0.000 claims abstract description 111
150000001875 compounds Chemical class 0.000 claims abstract description 87
210000004209 hair Anatomy 0.000 claims abstract description 72
239000000835 fiber Substances 0.000 claims abstract description 64
239000005300 metallic glass Substances 0.000 claims abstract description 51
150000002148 esters Chemical class 0.000 claims abstract description 41
239000000843 powder Substances 0.000 claims abstract description 36
239000003945 anionic surfactant Substances 0.000 claims abstract description 20
230000003647 oxidation Effects 0.000 claims abstract description 19
238000007254 oxidation reaction Methods 0.000 claims abstract description 19
239000002243 precursor Substances 0.000 claims abstract description 17
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 117
-1 aluminum silicates Chemical class 0.000 claims description 90
239000002245 particle Substances 0.000 claims description 85
239000000377 silicon dioxide Substances 0.000 claims description 51
239000011258 core-shell material Substances 0.000 claims description 45
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 45
102000011782 Keratins Human genes 0.000 claims description 37
108010076876 Keratins Proteins 0.000 claims description 37
239000004480 active ingredient Substances 0.000 claims description 33
239000007788 liquid Substances 0.000 claims description 30
239000008346 aqueous phase Substances 0.000 claims description 17
238000000034 method Methods 0.000 claims description 12
238000011282 treatment Methods 0.000 claims description 12
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 11
239000003125 aqueous solvent Substances 0.000 claims description 8
239000012153 distilled water Substances 0.000 claims description 8
239000002002 slurry Substances 0.000 claims description 8
230000002209 hydrophobic effect Effects 0.000 claims description 5
230000008569 process Effects 0.000 claims description 5
239000004408 titanium dioxide Substances 0.000 claims description 5
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150000004760 silicates Chemical class 0.000 claims description 2
239000013543 active substance Substances 0.000 abstract description 5
230000009466 transformation Effects 0.000 abstract description 2
229920001577 copolymer Polymers 0.000 description 100
125000000217 alkyl group Chemical group 0.000 description 52
239000000178 monomer Substances 0.000 description 47
WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 41
OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 description 40
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 39
150000003839 salts Chemical class 0.000 description 38
125000004435 hydrogen atom Chemical group [H]* 0.000 description 36
239000003795 chemical substances by application Substances 0.000 description 35
125000004432 carbon atom Chemical group C* 0.000 description 34
125000002091 cationic group Chemical group 0.000 description 32
DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 32
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 32
150000003254 radicals Chemical class 0.000 description 29
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125000003545 alkoxy group Chemical group 0.000 description 22
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125000003118 aryl group Chemical group 0.000 description 20
125000005843 halogen group Chemical group 0.000 description 20
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IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 19
239000001993 wax Substances 0.000 description 18
239000000975 dye Substances 0.000 description 17
238000001179 sorption measurement Methods 0.000 description 17
229910052739 hydrogen Inorganic materials 0.000 description 16
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 15
239000001257 hydrogen Substances 0.000 description 15
QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 14
125000000129 anionic group Chemical group 0.000 description 14
239000004205 dimethyl polysiloxane Substances 0.000 description 14
125000003837 (C1-C20) alkyl group Chemical group 0.000 description 13
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 13
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239000000047 product Substances 0.000 description 13
239000000839 emulsion Substances 0.000 description 12
239000012530 fluid Substances 0.000 description 12
MXRGSJAOLKBZLU-UHFFFAOYSA-N 3-ethenylazepan-2-one Chemical compound C=CC1CCCCNC1=O MXRGSJAOLKBZLU-UHFFFAOYSA-N 0.000 description 11
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 11
235000014113 dietary fatty acids Nutrition 0.000 description 11
239000000194 fatty acid Substances 0.000 description 11
229930195729 fatty acid Natural products 0.000 description 11
229910052731 fluorine Inorganic materials 0.000 description 11
238000010348 incorporation Methods 0.000 description 11
239000010445 mica Substances 0.000 description 11
229910052618 mica group Inorganic materials 0.000 description 11
238000007493 shaping process Methods 0.000 description 11
239000002594 sorbent Substances 0.000 description 11
239000000126 substance Substances 0.000 description 11
239000000454 talc Substances 0.000 description 11
229910052623 talc Inorganic materials 0.000 description 11
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 10
CWLKGDAVCFYWJK-UHFFFAOYSA-N m-Aminophenol Natural products NC1=CC=CC(O)=C1 CWLKGDAVCFYWJK-UHFFFAOYSA-N 0.000 description 10
239000011734 sodium Substances 0.000 description 10
CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical compound NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 9
PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical class NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 9
YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical group [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 9
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 9
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 9
150000004665 fatty acids Chemical class 0.000 description 9
239000011777 magnesium Substances 0.000 description 9
229910052749 magnesium Inorganic materials 0.000 description 9
CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical group C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 description 9
238000002360 preparation method Methods 0.000 description 9
235000012239 silicon dioxide Nutrition 0.000 description 9
239000007787 solid Substances 0.000 description 9
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 8
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 8
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 8
229910019142 PO4 Inorganic materials 0.000 description 8
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 8
229910052784 alkaline earth metal Inorganic materials 0.000 description 8
239000011575 calcium Substances 0.000 description 8
229910052791 calcium Inorganic materials 0.000 description 8
239000011737 fluorine Substances 0.000 description 8
229910052744 lithium Inorganic materials 0.000 description 8
125000000962 organic group Chemical group 0.000 description 8
229920000036 polyvinylpyrrolidone Polymers 0.000 description 8
GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 8
229920006395 saturated elastomer Polymers 0.000 description 8
OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 description 7
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 7
125000002252 acyl group Chemical group 0.000 description 7
125000003342 alkenyl group Chemical group 0.000 description 7
150000001735 carboxylic acids Chemical class 0.000 description 7
125000004122 cyclic group Chemical group 0.000 description 7
238000002156 mixing Methods 0.000 description 7
229910052757 nitrogen Inorganic materials 0.000 description 7
125000004433 nitrogen atom Chemical group N* 0.000 description 7
125000004430 oxygen atom Chemical group O* 0.000 description 7
239000010452 phosphate Substances 0.000 description 7
235000021317 phosphate Nutrition 0.000 description 7
229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 description 7
PMNLUUOXGOOLSP-UHFFFAOYSA-N 2-mercaptopropanoic acid Chemical compound CC(S)C(O)=O PMNLUUOXGOOLSP-UHFFFAOYSA-N 0.000 description 6
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 6
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 6
KIWBPDUYBMNFTB-UHFFFAOYSA-N Ethyl hydrogen sulfate Chemical compound CCOS(O)(=O)=O KIWBPDUYBMNFTB-UHFFFAOYSA-N 0.000 description 6
NBIIXXVUZAFLBC-UHFFFAOYSA-L Phosphate ion(2-) Chemical compound OP([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-L 0.000 description 6
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 6
229910052783 alkali metal Inorganic materials 0.000 description 6
150000001340 alkali metals Chemical class 0.000 description 6
150000001342 alkaline earth metals Chemical class 0.000 description 6
150000001412 amines Chemical class 0.000 description 6
229940077464 ammonium ion Drugs 0.000 description 6
150000001450 anions Chemical class 0.000 description 6
239000003153 chemical reaction reagent Substances 0.000 description 6
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
NBIIXXVUZAFLBC-UHFFFAOYSA-M dihydrogenphosphate Chemical compound OP(O)([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-M 0.000 description 6
230000000694 effects Effects 0.000 description 6
125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 6
150000002431 hydrogen Chemical class 0.000 description 6
QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 description 6
230000008018 melting Effects 0.000 description 6
238000002844 melting Methods 0.000 description 6
JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 6
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 6
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 6
229910052615 phyllosilicate Inorganic materials 0.000 description 6
235000013855 polyvinylpyrrolidone Nutrition 0.000 description 6
WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 6
229960001866 silicon dioxide Drugs 0.000 description 6
239000000758 substrate Substances 0.000 description 6
CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 6
JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 6
ITMCEJHCFYSIIV-UHFFFAOYSA-M triflate Chemical compound [O-]S(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-M 0.000 description 6
235000019386 wax ester Nutrition 0.000 description 6
WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 5
229940018563 3-aminophenol Drugs 0.000 description 5
LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 5
239000004164 Wax ester Substances 0.000 description 5
238000010521 absorption reaction Methods 0.000 description 5
125000002947 alkylene group Chemical group 0.000 description 5
125000001309 chloro group Chemical group Cl* 0.000 description 5
239000013065 commercial product Substances 0.000 description 5
239000000499 gel Substances 0.000 description 5
125000001072 heteroaryl group Chemical group 0.000 description 5
IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 5
FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 5
125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 5
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 5
239000007800 oxidant agent Substances 0.000 description 5
239000010695 polyglycol Substances 0.000 description 5
229920000151 polyglycol Polymers 0.000 description 5
125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 5
229940083082 pyrimidine derivative acting on arteriolar smooth muscle Drugs 0.000 description 5
229910052708 sodium Inorganic materials 0.000 description 5
AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Inorganic materials O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 5
125000003258 trimethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])[*:1] 0.000 description 5
KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 4
HQLVRJJDJGNYQW-UHFFFAOYSA-N 1-prop-1-enylimidazole Chemical compound CC=CN1C=CN=C1 HQLVRJJDJGNYQW-UHFFFAOYSA-N 0.000 description 4
JTHZUSWLNCPZLX-UHFFFAOYSA-N 6-fluoro-3-methyl-2h-indazole Chemical compound FC1=CC=C2C(C)=NNC2=C1 JTHZUSWLNCPZLX-UHFFFAOYSA-N 0.000 description 4
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 4
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235000013162 Cocos nucifera Nutrition 0.000 description 4
244000060011 Cocos nucifera Species 0.000 description 4
GDFCSMCGLZFNFY-UHFFFAOYSA-N Dimethylaminopropyl Methacrylamide Chemical compound CN(C)CCCNC(=O)C(C)=C GDFCSMCGLZFNFY-UHFFFAOYSA-N 0.000 description 4
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 4
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150000001252 acrylic acid derivatives Chemical class 0.000 description 4
239000003513 alkali Substances 0.000 description 4
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GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical compound BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 4
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229940079593 drug Drugs 0.000 description 4
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239000008266 hair spray Substances 0.000 description 4
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 4
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 4
OENHRRVNRZBNNS-UHFFFAOYSA-N naphthalene-1,8-diol Chemical compound C1=CC(O)=C2C(O)=CC=CC2=C1 OENHRRVNRZBNNS-UHFFFAOYSA-N 0.000 description 4
HMZGPNHSPWNGEP-UHFFFAOYSA-N octadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C HMZGPNHSPWNGEP-UHFFFAOYSA-N 0.000 description 4
150000004989 p-phenylenediamines Chemical class 0.000 description 4
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
229910052700 potassium Inorganic materials 0.000 description 4
239000011591 potassium Substances 0.000 description 4
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
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238000003756 stirring Methods 0.000 description 4
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125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 4
229910052725 zinc Inorganic materials 0.000 description 4
239000011701 zinc Substances 0.000 description 4
125000000008 (C1-C10) alkyl group Chemical group 0.000 description 3
125000004169 (C1-C6) alkyl group Chemical group 0.000 description 3
125000006663 (C1-C6) perfluoroalkyl group Chemical group 0.000 description 3
WSWCOQWTEOXDQX-MQQKCMAXSA-M (E,E)-sorbate Chemical compound C\C=C\C=C\C([O-])=O WSWCOQWTEOXDQX-MQQKCMAXSA-M 0.000 description 3
GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 3
QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 description 3
VIXBPSTZNCRCJE-UHFFFAOYSA-N 1,3-bis[4-amino-n-(2-hydroxyethyl)anilino]propan-2-ol Chemical compound C1=CC(N)=CC=C1N(CCO)CC(O)CN(CCO)C1=CC=C(N)C=C1 VIXBPSTZNCRCJE-UHFFFAOYSA-N 0.000 description 3
LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 3
CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 3
RAXXELZNTBOGNW-UHFFFAOYSA-N 1H-imidazole Chemical compound C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
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